公开(公告)号：US10646853B2

公开(公告)日：2020-05-12

申请号：US15865517

申请日：2018-01-09

申请人： Clariant Corporation

发明人： Vladimir Fridman

IPC分类号： B01J23/26 ,  B01J37/02 ,  B01J37/08 ,  C07C5/03 ,  B01J37/00 ,  B01J37/04 ,  B01J21/04

摘要： The present disclosure relates to methods for making chromium-containing dehydrogenation catalysts using chromium feedstocks that need not include chromium(VI). The disclosure also relates to the catalysts made thereby, as well as to dehydrogenation methods using such catalysts. In one aspect of the disclosure, a method includes providing a formable mixture comprising, on a dry basis, an aluminum hydroxide, present in an amount within the range of about 40 wt. % to about 90 wt. %; an acid (e.g., nitric acid), present in an amount within the range of about 2 wt. % to about 15 wt. %; and a chromium(III) source, present in an amount within the range of about 2 wt. % to about 35 wt. %; forming the formable mixture; and calcining the formed mixture. In certain embodiments, the method further includes impregnating the calcined mixture with an aqueous impregnation solution including a chromium(III) salt; and calcining the impregnated mixture.

公开(公告)号：US10562008B2

公开(公告)日：2020-02-18

申请号：US16166249

申请日：2018-10-22

申请人： Clariant Corporation

发明人： Jason E. Spencer ,  Gabrielle C. Ferrer ,  Tobias A. Henkel

IPC分类号： B01J20/34 ,  B01J20/18 ,  B01J20/30 ,  B01D53/02 ,  C10L3/10 ,  B01J20/16 ,  B01J20/02

摘要： As an improvement to processes for desulfurization of natural gas and synthetic natural gas streams that employ conventional zeolitic materials (absorbents), including copper-containing zeolites, pre-treatment methods and post-treatment methods are provided that lower the level of leachable benzene following desulfurization with the absorbents to

公开(公告)号：US10479760B2

公开(公告)日：2019-11-19

申请号：US15427351

申请日：2017-02-08

申请人： Clariant Corporation

发明人： Claus G. Lugmair ,  Hailian Li

IPC分类号： C07C253/26 ,  B01J23/00 ,  B01J23/889 ,  C07C45/35

摘要： The present disclosure relates generally to catalyst materials and processes for making and using them. More particularly, the present disclosure relates to molybdenum, bismuth and iron-containing metal oxide catalyst materials useful, for example, in the partial oxidation or ammoxidation of propylene or isobutylene, processes for making them, and processes for making acrolein, methacrolein, acrylonitrile, and methacrylonitrile using such catalysts.

公开(公告)号：US20180356379A1

公开(公告)日：2018-12-13

申请号：US15986909

申请日：2018-05-23

申请人： Clariant Corporation

发明人： Robert D. DiMaggio ,  Mark Reese

IPC分类号： G01N31/22

CPC分类号： G01N31/222 ,  B65D79/02

摘要： The present invention is directed to methods for preparing and using a substrate having a deliquescent-containing area for a non-reversible humidity indicator card. Embodiments provided herein also are directed to formulations that are utilized with such cards, as well as the approach of dispensing a composition with a deliquescent material in solution upon a card that can be used as a non-reversible humidity indicator.

公开(公告)号：US10112830B2

公开(公告)日：2018-10-30

申请号：US14563084

申请日：2014-12-08

申请人： CLARIANT CORPORATION

发明人： Justin X. Wang ,  William M. Faris ,  David Tolle ,  Marc K. Born ,  Yeping Cai

IPC分类号： C01B3/16 ,  B01J35/10 ,  B01J35/02 ,  B01J37/20 ,  B01J35/00 ,  B01J21/04 ,  B01J37/04 ,  B01J23/887 ,  B01J37/02

摘要： The disclosure provides catalyst materials in the form of annular solids with high mechanical integrity useful for water gas shift reactions and methods for using such catalyst materials, for example, for converting carbon monoxide and steam to carbon dioxide and hydrogen.

公开(公告)号：US10065910B2

公开(公告)日：2018-09-04

申请号：US15463911

申请日：2017-03-20

申请人： Clariant Corporation

发明人： Wenqin Shen ,  Franz Petzold ,  Karen Libby ,  Wayne Turbeville ,  Matthew Purcell ,  Marc K. Born

IPC分类号： C07C29/132 ,  B01J23/755 ,  B01J23/72 ,  B01J23/75 ,  B01J23/745 ,  B01J23/06 ,  B01J23/83 ,  B01J23/44 ,  B01J23/843 ,  B01J35/00 ,  B01J37/03 ,  B01J37/04 ,  B01J37/02 ,  B01J37/00 ,  B01J37/08 ,  B01J37/06

摘要： The present disclosure relates generally to ceramic materials suitable for use as catalyst support materials, catalysts using such materials and methods for using them, such as methods for converting sugars, sugar alcohols, glycerol, and bio-renewable organic acids to commercially-valuable chemicals and intermediates. One aspect of the invention is a ceramic material including zirconium oxide and one or more metal oxides selected from nickel oxide, copper oxide, cobalt oxide, iron oxide and zinc oxide, the ceramic material being at least about 50 wt. % zirconium oxide. In certain embodiments, the ceramic material is substantially free of any binder, extrusion aid or additional stabilizing agent.

公开(公告)号：US09545619B2

公开(公告)日：2017-01-17

申请号：US14560057

申请日：2014-12-04

申请人： CLARIANT CORPORATION

发明人： Justin X. Wang ,  Jason E. Spencer ,  Jennifer G. Renn ,  Yeping Cai

IPC分类号： C01B31/20 ,  C07C7/163 ,  B01J21/00 ,  B01J23/06 ,  B01J23/10 ,  B01J23/32 ,  B01J23/70 ,  B01J23/72 ,  B01J23/80 ,  B01J23/83 ,  B01J23/889 ,  C07C5/03 ,  B01J37/03 ,  B01J37/18 ,  B01J23/755 ,  B01J37/00 ,  C01B3/16

CPC分类号： B01J23/72 ,  B01J23/002 ,  B01J23/755 ,  B01J23/80 ,  B01J23/83 ,  B01J23/8892 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J37/0009 ,  B01J37/0018 ,  B01J37/03 ,  B01J37/036 ,  B01J37/08 ,  B01J37/18 ,  B01J2523/00 ,  C01B3/16 ,  C01B32/50 ,  C07C5/03 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2521/08 ,  C07C2521/16 ,  C07C2523/72 ,  C07C2523/80 ,  C07C2523/83 ,  C07C2523/889 ,  Y02P20/52 ,  C07C9/06 ,  C07C9/08 ,  B01J2523/17 ,  B01J2523/27 ,  B01J2523/72 ,  B01J2523/3712 ,  B01J2523/31

摘要： The disclosure provides catalyst materials useful for hydrogenating olefins and shifting carbon monoxide and methods for using such catalyst materials. In one aspect, the disclosure provides catalyst materials including (a) copper, present in the range of about 20 weight % to about 80 weight %; (b) one or more stabilizer oxides stable under reducing conditions, each stabilizer oxide being a transition metal oxide or a metalloid oxide, the one or more stabilizer oxides being present in a total amount in the range of about 20 weight % to about 70 weight %; and (c) one or more multiple-valence metals, each multiple-valence metal being present in a positive oxidation state, the one or more multiple-valence metals are present in the range of about 0.1 weight % to about 40 weight %, all on an oxide basis.

摘要翻译： 本公开提供了可用于氢化烯烃和转移一氧化碳的催化剂材料以及使用这种催化剂材料的方法。 一方面，本公开内容提供了催化剂材料，其包括（a）约20重量％至约80重量％范围内的铜; （b）在还原条件下稳定的一种或多种稳定剂氧化物，每种稳定剂氧化物是过渡金属氧化物或类金属氧化物，所述一种或多种稳定剂氧化物以约20重量％至约70重量％的量存在 ％; 和（c）一种或多种多价金属，每个多价金属以正氧化态存在，一种或多种多价金属以约0.1重量％至约40重量％的范围存在，全部 以氧化物为基础。

公开(公告)号：US20160158735A1

公开(公告)日：2016-06-09

申请号：US14563084

申请日：2014-12-08

申请人： CLARIANT CORPORATION

发明人： Justin X. WANG ,  William M. FARIS ,  David TOLLE ,  Marc K. BORN ,  Yeping CAI

IPC分类号： B01J23/882 ,  B01J35/04 ,  C01B3/16 ,  B01J35/00 ,  B01J23/02 ,  B01J23/10

CPC分类号： C01B3/16 ,  B01J21/04 ,  B01J23/8871 ,  B01J23/8872 ,  B01J35/002 ,  B01J35/0026 ,  B01J35/023 ,  B01J35/026 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J37/0201 ,  B01J37/04 ,  B01J37/20 ,  C01B2203/0283 ,  C01B2203/1041 ,  C01B2203/1052 ,  C01B2203/1082 ,  Y02P20/52

摘要： The disclosure provides catalyst materials in the form of annular solids with high mechanical integrity useful for water gas shift reactions and methods for using such catalyst materials, for example, for converting carbon monoxide and steam to carbon dioxide and hydrogen.

摘要翻译： 本公开提供具有用于水煤气变换反应的高机械完整性的环形固体形式的催化剂材料和使用这种催化剂材料的方法，例如将一氧化碳和蒸汽转化为二氧化碳和氢气。

公开(公告)号：US20150314274A1

公开(公告)日：2015-11-05

申请号：US14267948

申请日：2014-05-02

申请人： CLARIANT CORPORATION

发明人： Wenqin SHEN ,  Franz PETZOLD ,  Karen LIBBY ,  Wayne TURBEVILLE ,  Matthew PURCELL ,  Marc K. BORN

IPC分类号： B01J23/89 ,  B01J23/755 ,  B01J23/745 ,  B01J23/06 ,  C07C29/00 ,  B01J23/843 ,  B01J23/83 ,  C07C29/60 ,  C07C29/141 ,  B01J23/75 ,  B01J23/72

CPC分类号： C07C29/132 ,  B01J21/066 ,  B01J23/06 ,  B01J23/40 ,  B01J23/44 ,  B01J23/48 ,  B01J23/72 ,  B01J23/74 ,  B01J23/745 ,  B01J23/75 ,  B01J23/755 ,  B01J23/83 ,  B01J23/8435 ,  B01J23/892 ,  B01J35/0006 ,  B01J35/002 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J37/0009 ,  B01J37/0215 ,  B01J37/0236 ,  B01J37/031 ,  B01J37/04 ,  B01J37/06 ,  B01J37/08 ,  B01J37/088 ,  B01J37/18 ,  B01J2523/00 ,  C01G3/02 ,  C01G25/00 ,  C01G25/02 ,  C01G51/04 ,  C01G53/04 ,  C01P2002/54 ,  C01P2002/72 ,  C01P2006/12 ,  C01P2006/14 ,  C01P2006/21 ,  C04B35/486 ,  C04B35/488 ,  C04B2235/3206 ,  C04B2235/3208 ,  C04B2235/3225 ,  C04B2235/3227 ,  C04B2235/3229 ,  C04B2235/3232 ,  C04B2235/3251 ,  C04B2235/3258 ,  C04B2235/3262 ,  C04B2235/327 ,  C04B2235/3272 ,  C04B2235/3275 ,  C04B2235/3277 ,  C04B2235/3279 ,  C04B2235/3281 ,  C04B2235/3284 ,  C04B2235/3293 ,  C04B2235/3294 ,  C04B2235/3409 ,  C04B2235/6021 ,  C04B2235/72 ,  C04B2235/721 ,  C04B2235/765 ,  C07C29/00 ,  C07C29/141 ,  C07C29/60 ,  Y02P20/52 ,  C07C31/205 ,  C07C31/18 ,  C07C31/202 ,  C07C31/225 ,  B01J2523/3706 ,  B01J2523/48 ,  B01J2523/847

摘要： The present disclosure relates generally to ceramic materials suitable for use as catalyst support materials, catalysts using such materials and methods for using them, such as methods for converting sugars, sugar alcohols, glycerol, and bio-renewable organic acids to commercially-valuable chemicals and intermediates. One aspect of the invention is a ceramic material including zirconium oxide and one or more metal oxides selected from nickel oxide, copper oxide, cobalt oxide, iron oxide and zinc oxide, the ceramic material being at least about 50 wt. % zirconium oxide. In certain embodiments, the ceramic material is substantially free of any binder or additional stabilizing agent.

摘要翻译： 本公开一般涉及适合用作催化剂载体材料的陶瓷材料，使用这种材料的催化剂及其使用方法，例如将糖，糖醇，甘油和生物可再生有机酸转化为商业上有价值的化学品的方法，以及 中间体。 本发明的一个方面是包括氧化锆和一种或多种选自氧化镍，氧化铜，氧化钴，氧化铁和氧化锌的金属氧化物的陶瓷材料，所述陶瓷材料为至少约50wt。 ％的氧化锆。 在某些实施方案中，陶瓷材料基本上不含任何粘合剂或其它稳定剂。

公开(公告)号：US09132418B2

公开(公告)日：2015-09-15

申请号：US14306332

申请日：2014-06-17

申请人： CLARIANT CORPORATION

发明人： Wenqin Shen ,  Franz G. Petzold ,  Karen Libby ,  Wayne Turbeville

IPC分类号： C07C29/00 ,  B01J21/00 ,  B01J23/889 ,  B01J37/03 ,  B01J37/08 ,  B01J21/06 ,  B01J23/34 ,  B01J23/46 ,  B01J23/72 ,  B01J23/755 ,  B01J23/843 ,  B01J35/00 ,  B01J35/10 ,  C12P19/02 ,  B01J23/656 ,  C07C29/17 ,  C07C29/60 ,  C07C29/132 ,  C07C29/149

CPC分类号： B01J23/8892 ,  B01J21/066 ,  B01J23/34 ,  B01J23/462 ,  B01J23/6562 ,  B01J23/72 ,  B01J23/755 ,  B01J23/8435 ,  B01J35/002 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1038 ,  B01J37/031 ,  B01J37/08 ,  C07C29/00 ,  C07C29/132 ,  C07C29/149 ,  C07C29/172 ,  C07C29/60 ,  C12P19/02 ,  Y02P20/52 ,  C07C31/202 ,  C07C31/205 ,  C07C31/225 ,  C07C31/26

摘要： The present disclosure relates generally to catalyst support materials, catalysts and methods for using them, such as methods for converting sugars, sugar alcohols, glycerol, and bio-renewable organic acids to commercially-valuable chemicals and intermediates. One aspect of the invention is catalyst support material including ZrO2 and one or more oxides of manganese (MnOx), the catalyst support material being at least about 50 wt % ZrO2 and MnOx. In certain embodiments, the weight ratio of ZrO2 to MnOx is within the range of about 1:1 to about 30:1; and/or the catalyst support material is substantially free of any binder, extrusion aid or additional stabilizing agent.

摘要翻译： 本公开一般涉及催化剂载体材料，催化剂和使用它们的方法，例如将糖，糖醇，甘油和生物可再生有机酸转化成商业上有价值的化学品和中间体的方法。 本发明的一个方面是包括ZrO 2和一种或多种锰氧化物（MnO x）的催化剂载体材料，催化剂载体材料为至少约50重量％的ZrO 2和MnO x。 在某些实施方案中，ZrO 2与MnO x的重量比在约1:1至约30:1的范围内; 和/或催化剂载体材料基本上不含任何粘合剂，挤出助剂或其它稳定剂。