Stabilized ceramic composition, apparatus and methods of using the same
    43.
    发明授权
    Stabilized ceramic composition, apparatus and methods of using the same 有权
    稳定的陶瓷组合物,使用它们的装置和方法

    公开(公告)号:US08734729B2

    公开(公告)日:2014-05-27

    申请号:US13769620

    申请日:2013-02-18

    IPC分类号: B01J19/00 C04B35/482

    摘要: In one aspect, the invention includes a refractory material, said material comprising: (i) at least 20 wt. % of a first grain mode stabilized zirconia based upon the total weight of said material, said first grain mode having a D50 grain size in the range of from 5 to 2000 μm, said stabilized zirconia including a matrix oxide stabilizer; (ii) at least 1 wt. % of a second grain mode having a D50 grain size in the range of from 0.01 μm up to not greater than one-fourth the D50 grain size of said first grain mode zirconia, based upon the total weight of said material; and (iii) at least 1 wt. % of a preservative component within at least one of said first grain mode stabilized zirconia, said second grain mode stabilized zirconia, and an optional another grain mode; wherein after sintering, said material has porosity at 20° C. in the range of from 5 to 45 vol %.

    摘要翻译: 一方面,本发明包括耐火材料,所述材料包括:(i)至少20wt。 基于所述材料的总重量的第一晶粒模式稳定化氧化锆的%,所述第一晶粒模式具有在5至2000μm范围内的D50晶粒尺寸,所述稳定化氧化锆包括基体氧化物稳定剂; (ii)至少1wt。 基于所述材料的总重量,具有D50晶粒尺寸在0.01μm至不超过所述第一晶粒模式氧化锆的D50晶粒尺寸的四分之一范围内的第二晶粒模式的%。 和(iii)至少1wt。 所述第一晶粒模式稳定化氧化锆,所述第二晶粒模式稳定化氧化锆和任选的另一晶粒模式中的至少一种中的防腐剂组分% 其中烧结后,所述材料在20℃下的孔隙率为5-45体积%。

    High performance coated material with improved metal dusting corrosion resistance
    48.
    发明授权
    High performance coated material with improved metal dusting corrosion resistance 有权
    高性能涂层材料具有改善的金属除尘耐腐蚀性

    公开(公告)号:US08029914B2

    公开(公告)日:2011-10-04

    申请号:US11827013

    申请日:2007-07-10

    摘要: High performance coated metal compositions resistant to metal dusting corrosion and methods of providing such compositions are provided by the present invention. The coated metal compositions are represented by the structure (PQR), wherein P is an oxide layer at the surface of (PQR), Q is a coating metal layer interposed between P and R, and R is a base metal. P includes alumina, chromia, silica, mullite or mixtures thereof. Q includes Ni and Al, and at least one element selected from the group consisting of Cr, Si, Mn, Fe, Co, B, C, N, P, Ga, Ge, As, In, Sn, Sb, Pb, Sc, La, Y, Ce, Ti, Zr, Hf, V, Nb, Ta, Mo, W, Ru, Rh, Ir, Pd, Pt, Cu, Ag, Au and mixtures thereof. R is selected from the group consisting of carbon steels, low chromium steels, ferritic stainless steels, austenetic stainless steels, duplex stainless steels, Inconel alloys, Incoloy alloys, Fe—Ni based alloys, Ni-based alloys and Co-based alloys. Advantages exhibited by the disclosed coated metal compositions include improved metal dusting corrosion resistance at high temperatures in carbon-supersaturated environments having relatively low oxygen partial pressures. The coated metal compositions are suitable for use in syngas generation process equipment.

    摘要翻译: 通过本发明提供了耐金属粉尘腐蚀的高性能涂覆金属组合物和提供这种组合物的方法。 涂覆的金属组合物由结构(PQR)表示,其中P是(PQR)表面处的氧化物层,Q是介于P和R之间的涂层金属层,R是贱金属。 P包括氧化铝,氧化铬,二氧化硅,莫来石或其混合物。 Q包括Ni和Al,以及选自Cr,Si,Mn,Fe,Co,B,C,N,P,Ga,Ge,As,In,Sn,Sb,Pb,Sc中的至少一种元素 ,La,Y,Ce,Ti,Zr,Hf,V,Nb,Ta,Mo,W,Ru,Rh,Ir,Pd,Pt,Cu,Ag,Au及其混合物。 R选自碳钢,低铬钢,铁素体不锈钢,奥氏体不锈钢,双相不锈钢,Inconel合金,Incoloy合金,Fe-Ni基合金,Ni基合金和Co基合金。 所公开的涂覆的金属组合物显示的优点包括在具有相对低的氧分压的碳过饱和环境中在高温下提高的金属粉尘耐腐蚀性。 涂覆的金属组合物适用于合成气生成工艺设备。

    Porous Pyrolysis Reactor Materials And Methods
    49.
    发明申请
    Porous Pyrolysis Reactor Materials And Methods 有权
    多孔热解反应堆材料与方法

    公开(公告)号:US20110120853A1

    公开(公告)日:2011-05-26

    申请号:US12623046

    申请日:2009-11-20

    IPC分类号: C10G9/00 C10B29/00 C10B57/16

    摘要: In one aspect, the invention includes a reactor apparatus for pyrolyzing a hydrocarbon feedstock, said apparatus including: a reactor component comprising a refractory material in oxide form, the refractory material having a melting point of no less than 2060° C. and which remains in oxide form when exposed to a gas having carbon partial pressure of 10−22 bar and oxygen partial pressure of 10−10 bar, at a temperature of 1200° C.; wherein said refractory material has no less than 4 vol % formed porosity, measured at 20° C., based upon the bulk volume of said refractory material. In another embodiment, the refractory material has total porosity in the range of from 4 to 60 vol %.

    摘要翻译: 在一个方面,本发明包括用于热解烃原料的反应器装置,所述装置包括:反应器组件,其包含氧化物形式的耐火材料,耐火材料的熔点不低于2060℃,并保持在 在1200℃的温度下暴露于碳分压为10-22巴,氧气分压为10-10巴的气体时,氧化物形式。 其中所述耐火材料具有基于所述耐火材料的体积体积在20℃下测量的不少于4体积%的孔隙率。 在另一个实施方案中,耐火材料具有4至60体积%的总孔隙率。

    High performance coated material with improved metal dusting corrosion resistance
    50.
    发明申请
    High performance coated material with improved metal dusting corrosion resistance 有权
    高性能涂层材料具有改善的金属除尘耐腐蚀性

    公开(公告)号:US20080020216A1

    公开(公告)日:2008-01-24

    申请号:US11827013

    申请日:2007-07-10

    IPC分类号: B32B15/04 C23C16/00 C23C4/06

    摘要: High performance coated metal compositions resistant to metal dusting corrosion and methods of providing such compositions are provided by the present invention. The coated metal compositions are represented by the structure (PQR), wherein P is an oxide layer at the surface of (PQR), Q is a coating metal layer interposed between P and R, and R is a base metal. P includes alumina, chromia, silica, mullite or mixtures thereof. Q includes Ni and Al, and at least one element selected from the group consisting of Cr, Si, Mn, Fe, Co, B, C, N, P, Ga, Ge, As, In, Sn, Sb, Pb, Sc, La, Y, Ce, Ti, Zr, Hf, V, Nb, Ta, Mo, W, Ru, Rh, Ir, Pd, Pt, Cu, Ag, Au and mixtures thereof. R is selected from the group consisting of carbon steels, low chromium steels, ferritic stainless steels, austenetic stainless steels, duplex stainless steels, Inconel alloys, Incoloy alloys, Fe—Ni based alloys, Ni-based alloys and Co-based alloys. Advantages exhibited by the disclosed coated metal compositions include improved metal dusting corrosion resistance at high temperatures in carbon-supersaturated environments having relatively low oxygen partial pressures. The coated metal compositions are suitable for use in syngas generation process equipment.

    摘要翻译: 通过本发明提供了耐金属粉尘腐蚀的高性能涂覆金属组合物和提供这种组合物的方法。 涂覆的金属组合物由结构(PQR)表示,其中P是(PQR)表面处的氧化物层,Q是介于P和R之间的涂层金属层,R是贱金属。 P包括氧化铝,氧化铬,二氧化硅,莫来石或其混合物。 Q包括Ni和Al,以及选自Cr,Si,Mn,Fe,Co,B,C,N,P,Ga,Ge,As,In,Sn,Sb,Pb,Sc中的至少一种元素 ,La,Y,Ce,Ti,Zr,Hf,V,Nb,Ta,Mo,W,Ru,Rh,Ir,Pd,Pt,Cu,Ag,Au及其混合物。 R选自碳钢,低铬钢,铁素体不锈钢,奥氏体不锈钢,双相不锈钢,Inconel合金,Incoloy合金,Fe-Ni基合金,Ni基合金和Co基合金。 所公开的涂覆的金属组合物显示的优点包括在具有相对低的氧分压的碳过饱和环境中在高温下提高的金属粉尘耐腐蚀性。 涂覆的金属组合物适用于合成气生成工艺设备。