公开(公告)号：US20050085582A1

公开(公告)日：2005-04-21

申请号：US10494460

申请日：2001-10-30

申请人： Maurizio Galimberti ,  Daniela Senatore ,  Luigi Fino ,  Giuseppina Ratti

发明人： Maurizio Galimberti ,  Daniela Senatore ,  Luigi Fino ,  Giuseppina Ratti

IPC分类号： B60C1/00 ,  C08K3/00 ,  C08K3/22 ,  C08K3/36 ,  C08K5/548 ,  C08L9/00 ,  C08L21/00 ,  B60C5/00 ,  C08K3/34

CPC分类号： B60C11/005 ,  B60C1/00 ,  B60C1/0016 ,  C08K3/013 ,  C08K3/22 ,  C08L21/00 ,  Y02T10/862 ,  Y10T152/10495 ,  C08L2666/08

摘要： An elastomeric composition includes at least one diene elastomeric polymer, at least one reinforcing filler including silica, at least one silica coupling agent including at least one hydrolyzable silane group, and titanium dioxide. A weight ratio of the at least one silica coupling agent to the titanium dioxide is greater than or equal to 0.5:1. Also disclosed is a tyre, tread band, and cross-linked elastomeric manufactured article including the elastomeric composition. The tyre includes at least one element of cross-linked elastomeric material including the elastomeric composition. The tread band may be that at least one element.

摘要翻译： 弹性体组合物包括至少一种二烯弹性体聚合物，至少一种包括二氧化硅的增强填料，至少一种包含至少一个可水解硅烷基的二氧化硅偶联剂和二氧化钛。 至少一种二氧化硅偶联剂与二氧化钛的重量比大于或等于0.5:1。 还公开了包括弹性体组合物的轮胎，胎面带和交联的弹性制品。 轮胎包括至少一种包括弹性体组合物的交联弹性材料的元件。 胎面带可以是至少一个元件。

公开(公告)号：US20050049371A1

公开(公告)日：2005-03-03

申请号：US10497000

申请日：2002-11-22

申请人： Maurizio Galimberti ,  Angelo Ferraro ,  Giovanni Baruzzi ,  Ofelia Fusco

发明人： Maurizio Galimberti ,  Angelo Ferraro ,  Giovanni Baruzzi ,  Ofelia Fusco

IPC分类号： C08F2/34 ,  C08F4/02 ,  C08F4/642 ,  C08F4/659 ,  C08F4/6592 ,  C08F10/00 ,  C08F10/06 ,  C08F110/06 ,  C08F210/18 ,  C08L23/10 ,  C08L23/12 ,  C08L23/16 ,  C08F4/44

CPC分类号： C08F210/18 ,  C08F4/65912 ,  C08F4/65927 ,  C08F110/06 ,  C08L23/10 ,  C08L23/16 ,  C08L2203/14 ,  C08F4/65916 ,  C08F4/027 ,  C08L2666/06 ,  C08F2500/17 ,  C08F2500/18 ,  C08F2500/24 ,  C08F2500/20 ,  C08F210/06 ,  C08F232/00 ,  C08F2500/25 ,  C08F2500/21

摘要： A process for the preparation of heterophasic elastomeric polymer comprising the step of polymerizing ethylene, an alpha-olefin CH2=CHL, where L is an alkyl, cycloalkyl or aryl radical with 1-10 carbon atoms and a non-conjugated diene in the presence of a catalyst system comprising a transition metal catalyst component supported on a porous alpha-olefin polymer, characterized in that at least part of the diene is impregnated on the porous alpha-olefin polymer.

摘要翻译： 一种用于制备多相弹性体聚合物的方法，包括聚合乙烯，α-烯烃CH 2 = CHL的步骤，其中L是具有1-10个碳原子的烷基，环烷基或芳基和非共轭二烯，在存在 包含负载在多孔α-烯烃聚合物上的过渡金属催化剂组分的催化剂体系，其特征在于至少部分二烯浸渍在多孔α-烯烃聚合物上。

公开(公告)号：US06822106B2

公开(公告)日：2004-11-23

申请号：US10700095

申请日：2003-11-03

申请人： Tiziano Dall'Occo ,  Ofelia Fusco ,  Maurizio Galimberti ,  Ilya Nifant'ev ,  Ilya Laishevtsev

发明人： Tiziano Dall'Occo ,  Ofelia Fusco ,  Maurizio Galimberti ,  Ilya Nifant'ev ,  Ilya Laishevtsev

IPC分类号： C08F464

CPC分类号： C07F17/00 ,  C07F7/0805 ,  C07F7/0814 ,  C08F4/65912 ,  C08F10/02 ,  C08F210/16 ,  C08F210/18 ,  Y10S526/943 ,  C08F4/65927 ,  C08F210/06 ,  C08F2500/20 ,  C08F2500/17 ,  C08F210/14 ,  C08F2500/25

摘要： Ethylene based polymers having high molecular weights can be obtained in high yields at temperatures of industrial interest, by carrying out the polymerization reaction in the presence of catalysts comprising silicon bridged metallocenes having a particular ligand system containing a heteroatom.

摘要翻译： 通过在包含具有特定的含有杂原子的配体体系的硅桥连金属茂的催化剂的存在下进行聚合反应，可以在工业感兴趣的温度下以高产率获得具有高分子量的乙烯基聚合物。

公开(公告)号：US06211108B1

公开(公告)日：2001-04-03

申请号：US08417735

申请日：1995-04-05

申请人： Clyde E. Bishop ,  Robert L. Jones, Jr. ,  Krishna Raman ,  Vu Anh Dang ,  Lin-Chen Yu ,  Luigi Resconi ,  Tiziano Dall'Occo ,  Maurizio Galimberti

发明人： Clyde E. Bishop ,  Robert L. Jones, Jr. ,  Krishna Raman ,  Vu Anh Dang ,  Lin-Chen Yu ,  Luigi Resconi ,  Tiziano Dall'Occo ,  Maurizio Galimberti

IPC分类号： B01J3100

CPC分类号： C08F10/00 ,  C07C2/862 ,  C07C49/643 ,  C07C49/675 ,  C07F7/0805 ,  C07F17/00 ,  C08F4/65912 ,  C08F4/65922 ,  C08F4/65927 ,  C08F110/02 ,  C08F110/06 ,  C08F210/16 ,  Y10S526/943 ,  C08F2500/12 ,  C08F2500/17 ,  C08F2500/03 ,  C08F2500/20 ,  C08F210/08 ,  C08F210/06

摘要： A class of bridged or unbridged metallocene compounds is disclosed, wherein the cyclopentadienyl ligands have two or four adjacent substituents forming one or two alkylenic cycles of from 4 to 8 carbon atoms. These metallocenes are useful as catalyst components for the polymerization of olefins, particularly for the (co)polymerization of ethylene and for the polymerization of propylene.

公开(公告)号：US5886123A

公开(公告)日：1999-03-23

申请号：US720537

申请日：1996-09-30

申请人： Luigi Resconi ,  Fabrizio Piemontesi ,  Maurizio Galimberti

发明人： Luigi Resconi ,  Fabrizio Piemontesi ,  Maurizio Galimberti

IPC分类号： C08F10/02 ,  C07F7/08 ,  C07F17/00 ,  C08F4/60 ,  C08F4/602 ,  C08F4/622 ,  C08F4/642 ,  C08F4/659 ,  C08F4/6592 ,  C08F10/00 ,  C08F110/02 ,  C08F210/16

CPC分类号： C08F210/16 ,  C08F110/02 ,  C08F4/65912 ,  C08F4/65927 ,  Y10S526/943

摘要： Homo- and copolymers of ethylene endowed with very high molecular weights and narrow molecular weight distributions are obtainable by carrying out the polymerization reaction in the presence of a metallocene-based catalyst wherein the metallocene is stereorigid and it is in its meso isomeric form.

摘要翻译： 具有非常高分子量和窄分子量分布的乙烯的均聚物和共聚物可以通过在金属茂基催化剂存在下进行聚合反应，其中金属茂是立体刚性的并且是其内消旋异构形式。

公开(公告)号：US09328181B2

公开(公告)日：2016-05-03

申请号：US13977167

申请日：2011-12-29

申请人： Alexandra Romina Albunia ,  Riccardo Bianchi ,  Luciano Di Maio ,  Maurizio Galimberti ,  Gaetano Guerra ,  Roberto Pantani ,  Stanislao Senatore

发明人： Alexandra Romina Albunia ,  Riccardo Bianchi ,  Luciano Di Maio ,  Maurizio Galimberti ,  Gaetano Guerra ,  Roberto Pantani ,  Stanislao Senatore

IPC分类号： C08F112/08 ,  C09D125/06 ,  C08J5/18 ,  C08J7/02 ,  C08J7/04 ,  C08J9/28 ,  D01F6/22

CPC分类号： C08F112/08 ,  C08J5/18 ,  C08J7/02 ,  C08J7/047 ,  C08J9/28 ,  C08J2323/12 ,  C08J2325/06 ,  C08J2425/06 ,  C08J2433/06 ,  C09D125/06 ,  D01F6/22 ,  Y10T428/2982

摘要： There is described a new disordered nanoporous crystalline form of syndiotactic polystyrene, characterized by a specific X-ray diffractrogram, the process for its preparation and various articles comprising this form of s-PS. This disordered nanoporous crystalline form exhibits empty crystalline cavities of nanometric sizes, and in this case performs the function of absorbing molecules with low molecular mass and is useful in particular as functionally active packaging for plant products.

摘要翻译： 描述了间同立构聚苯乙烯的新的无序纳米孔结晶形式，其特征在于特定的X射线衍射图，其制备方法和包含这种形式的s-PS的各种制品。 这种无序的纳米多孔结晶形式呈现出纳米尺寸的空的晶体空腔，在这种情况下，其具有吸收低分子量分子的功能，尤其可用作植物产品的功能活性包装。

公开(公告)号：US08240350B2

公开(公告)日：2012-08-14

申请号：US11919423

申请日：2005-04-28

申请人： Emiliano Resmini ,  Francesca Baione ,  Diego Tirelli ,  Luigi Fino ,  Maurizio Galimberti ,  Attilio Citterio

发明人： Emiliano Resmini ,  Francesca Baione ,  Diego Tirelli ,  Luigi Fino ,  Maurizio Galimberti ,  Attilio Citterio

IPC分类号： B60C1/00 ,  B60C11/00 ,  B60C13/00 ,  C08F20/00

CPC分类号： C08F220/36 ,  B60C1/00 ,  B60C1/0016 ,  B60C1/0025 ,  C08K3/013 ,  C08L7/00 ,  C08L9/00 ,  C08L21/00 ,  C08L33/14 ,  Y10T152/10495 ,  C08L2666/08 ,  C08L2666/02

摘要： A tire includes at least one structural element including a crosslinked elastomeric material obtained by crosslinking a crosslinkable elastomeric composition including: (a) an amount higher than or equal to 30 phr, preferably 40 phr to 100 phr, of at least one polyisoprene rubber; (b) an amount lower than or equal to 70 phr, preferably 0 phr to 60 phr, of at least one diene elastomeric polymer other than the polyisoprene rubber (a); (c) an amount higher than or equal to 30 phr, preferably 40 phr to 120 phr, of at least one carbon black reinforcing filler; (d) 0.2 phr to 10 phr, preferably 1 phr to 5 phr, of at least one copolymer of at least one ethylenically unsaturated carboxylic acid or a derivative thereof with at least one ethylenically unsaturated monomer containing at least one polyoxyalkylene side chain. Preferably, the structural element is a tire's sidewall.

摘要翻译： 轮胎包括至少一种结构元件，其包括通过交联可交联弹性体组合物获得的交联弹性体材料，所述交联弹性体组合物包含：（a）高于或等于30phr，优选40phr至100phr的至少一种聚异戊二烯橡胶; （b）低于或等于70phr，优选0phr至60phr的至少一种除聚异戊二烯橡胶（a）以外的二烯弹性体聚合物的量; （c）高于或等于30phr，优选40phr至120phr的至少一种炭黑增强填料的量; （d）0.2phr至10phr，优选1phr至5phr的至少一种烯键式不饱和羧酸或其衍生物与至少一种含有至少一个聚氧化烯侧链的烯属不饱和单体的共聚物。 优选地，结构元件是轮胎的侧壁。

公开(公告)号：US20100069529A1

公开(公告)日：2010-03-18

申请号：US11919423

申请日：2005-04-28

申请人： Emiliano Resmini ,  Francesca Baione ,  Diego Tirelli ,  Luigi Fino ,  Maurizio Galimberti ,  Attilio Citterio

发明人： Emiliano Resmini ,  Francesca Baione ,  Diego Tirelli ,  Luigi Fino ,  Maurizio Galimberti ,  Attilio Citterio

IPC分类号： C08K3/04 ,  C08K3/36

CPC分类号： C08F220/36 ,  B60C1/00 ,  B60C1/0016 ,  B60C1/0025 ,  C08K3/013 ,  C08L7/00 ,  C08L9/00 ,  C08L21/00 ,  C08L33/14 ,  Y10T152/10495 ,  C08L2666/08 ,  C08L2666/02

摘要： A tire includes at least one structural element including a crosslinked elastomeric material obtained by crosslinking a crosslinkable elastomeric composition including: (a) an amount higher than or equal to 30 phr, preferably 40 phr to 100 phr, of at least one polyisoprene rubber; (b) an amount lower than or equal to 70 phr, preferably 0 phr to 60 phr, of at least one diene elastomeric polymer other than the polyisoprene rubber (a); (c) an amount higher than or equal to 30 phr, preferably 40 phr to 120 phr, of at least one carbon black reinforcing filler; (d) 0.2 phr to 10 phr, preferably 1 phr to 5 phr, of at least one copolymer of at least one ethylenically unsaturated carboxylic acid or a derivative thereof with at least one ethylenically unsaturated monomer containing at least one polyoxyalkylene side chain. Preferably, the structural element is a tire's sidewall.

摘要翻译： 轮胎包括至少一种结构元件，其包括通过交联可交联弹性体组合物获得的交联弹性体材料，所述交联弹性体组合物包含：（a）高于或等于30phr，优选40phr至100phr的至少一种聚异戊二烯橡胶; （b）低于或等于70phr，优选0phr至60phr的至少一种除聚异戊二烯橡胶（a）以外的二烯弹性体聚合物的量; （c）高于或等于30phr，优选40phr至120phr的至少一种炭黑增强填料的量; （d）0.2phr至10phr，优选1phr至5phr的至少一种烯键式不饱和羧酸或其衍生物与至少一种含有至少一个聚氧化烯侧链的烯属不饱和单体的共聚物。 优选地，结构元件是轮胎的侧壁。

公开(公告)号：US20090247682A1

公开(公告)日：2009-10-01

申请号：US12083098

申请日：2005-10-26

申请人： Maurizio Galimberti ,  Lisa Grassi ,  Stefano Testi ,  Michela Caprio ,  Luca Giannini

发明人： Maurizio Galimberti ,  Lisa Grassi ,  Stefano Testi ,  Michela Caprio ,  Luca Giannini

IPC分类号： C08K3/34 ,  C08L23/18 ,  C08K3/10 ,  C08K3/26 ,  C08K3/12

CPC分类号： B60C1/00 ,  C08J3/226 ,  C08J2307/00 ,  C08J2421/00 ,  C08K3/346 ,  C08L21/00

摘要： Method for producing a crosslinkable elastomeric composition including: (a) at least one first elastomeric polymer; (b) at least one layered material having an individual layer thickness of 0.01 nm to 30 nm, preferably of 0.05 nm to 15 nm; and (c) at least one vulcanizing agent; includes the following steps: (i) feeding the at least one layered material (b) and at least one second elastomeric polymer (d), into at least one extruder including a housing, at least one screw rotatably mounted in the housing including at least one feed opening and a discharge opening, the at least one layered material being fed into the at least one extruder in an amount higher than or equal to 70 phr; (ii) mixing and softening the mixture so as to obtain a masterbatch; (iii) discharging the obtained masterbatch through a discharge opening; and (iv) mixing the obtained masterbatch with the at least one first elastomeric polymer (a) and the at least one vulcanizing agent (c), to obtain the crosslinkable elastomeric composition, the mixing being carried out in a batchwise manner.

摘要翻译： 用于生产可交联弹性体组合物的方法，包括：（a）至少一种第一弹性体聚合物; （b）具有0.01nm至30nm，优选为0.05nm至15nm的单层厚度的至少一种层状材料; 和（c）至少一种硫化剂; 包括以下步骤：（i）将至少一种层状材料（b）和至少一种第二弹性体聚合物（d）进料至包括壳体的至少一个挤出机中，至少一个可旋转地安装在壳体中的螺杆至少包括 一个进料口和排出口，所述至少一个层压材料以高于或等于70phr的量进料到所述至少一个挤出机中; （ii）混合和软化混合物以获得母料; （iii）通过排出口排出所获得的母料; 和（iv）将获得的母料与至少一种第一弹性体聚合物（a）和至少一种硫化剂（c）混合，以获得可交联的弹性体组合物，所述混合以间歇方式进行。

公开(公告)号：US20090218026A1

公开(公告)日：2009-09-03

申请号：US12085690

申请日：2005-11-29

申请人： Luca Giannini ,  Luigi Fino ,  Maurizio Galimberti ,  Attilio Citterio

发明人： Luca Giannini ,  Luigi Fino ,  Maurizio Galimberti ,  Attilio Citterio

IPC分类号： B60C1/00 ,  C08L21/00 ,  C08K3/34 ,  C08K5/44 ,  C08K5/09

CPC分类号： C08K3/32 ,  B60C1/00 ,  B60C1/0016 ,  B60C1/0025 ,  B60C2015/0614 ,  C08K3/30 ,  C08K3/346 ,  C08K3/38 ,  C08K5/09 ,  C08K5/44 ,  C08K9/02 ,  Y10T152/10495 ,  Y10T152/10846 ,  Y10T428/269 ,  C08L21/00

摘要： Tire including at least one structural element including a crosslinked elastomeric material obtained by crosslinking a crosslinkable elastomeric composition includes: (a) 100 phr of at least one diene elastomeric polymer; (b) 5 phr to 120 phr, preferably 10 phr to 80 phr, more preferably 20 phr to 50 phr, of at least one layered material modified with at least one alkyl ammonium or alkyl phosphonium salt, the layered material having an individual layer thickness of 0.01 nm to 30 nm, preferably 0.05 nm to 15 nm, more preferably 0.1 nm to 2 nm; (c) 0.05 phr to 2 phr, preferably 0.1 phr to 1 phr, more preferably 0.2 phr to 0.5 phr, of at least one N-acyl-sulfenyl amide; and (d) 0.3 phr to 5 phr, preferably 0.5 phr to 4 phr, of least one organic or inorganic acid or a derivative thereof selected from: carboxylic acids, phosphoric acids, sulfonic acids, boric acids, or derivatives thereof. Preferably, the at least one structural element is selected from bead filler, sidewall insert, treat underlayer, tread base.

摘要翻译： 包括至少一种包括通过交联可交联弹性体组合物获得的交联弹性材料的结构元件包括：（a）100phr的至少一种二烯弹性体聚合物; （b）5phr至120phr，优选10phr至80phr，更优选20phr至50phr的至少一种用至少一种烷基铵或烷基鏻盐改性的层状材料，所述层状材料具有单独的层厚度 为0.01nm〜30nm，优选为0.05nm〜15nm，更优选为0.1nm〜2nm; （c）0.05phr至2phr，优选0.1phr至1phr，更优选0.2phr至0.5phr的至少一种N-酰基 - 硫酰基酰胺; 和（d）0.3phr至5phr，优选0.5phr至4phr的选自以下的至少一种有机或无机酸或其衍生物：羧酸，磷酸，磺酸，硼酸或其衍生物。 优选地，所述至少一个结构元件选自珠填料，侧壁插入物，处理底层，胎面基底。