Interconnected hollow nanostructures containing high capacity active materials for use in rechargeable batteries
    45.
    发明授权
    Interconnected hollow nanostructures containing high capacity active materials for use in rechargeable batteries 有权
    包含用于可充电电池的高容量活性材料的互连中空纳米结构

    公开(公告)号:US08450012B2

    公开(公告)日:2013-05-28

    申请号:US12787138

    申请日:2010-05-25

    IPC分类号: H01M5/58 H01M4/90 H01M4/583

    摘要: Provided are electrode layers for use in rechargeable batteries, such as lithium ion batteries, and related fabrication techniques. These electrode layers have interconnected hollow nanostructures that contain high capacity electrochemically active materials, such as silicon, tin, and germanium. In certain embodiments, a fabrication technique involves forming a nanoscale coating around multiple template structures and at least partially removing and/or shrinking these structures to form hollow cavities. These cavities provide space for the active materials of the nanostructures to swell into during battery cycling. This design helps to reduce the risk of pulverization and to maintain electrical contacts among the nanostructures. It also provides a very high surface area available ionic communication with the electrolyte. The nanostructures have nanoscale shells but may be substantially larger in other dimensions. Nanostructures can be interconnected during forming the nanoscale coating, when the coating formed around two nearby template structures overlap.

    摘要翻译: 提供了用于可再充电电池的电极层,例如锂离子电池以及相关制造技术。 这些电极层具有互连的中空纳米结构,其包含高容量的电化学活性材料,例如硅,锡和锗。 在某些实施例中,制造技术包括围绕多个模板结构形成纳米级涂层,并且至少部分地去除和/或收缩这些结构以形成中空腔。 这些空穴为纳米结构的活性材料在电池循环过程中提供空间。 该设计有助于降低粉碎的风险并保持纳米结构之间的电接触。 它还提供了与电解质的非常高的表面积可用的离子连通。 纳米结构具有纳米尺寸的壳,但在其它尺寸上可能显着更大。 当形成纳米尺度涂层时,当围绕两个附近的模板结构形成的涂层重叠时,纳米结构可以相互连接。

    ELECTRODES WITH ELECTROSPUN FIBERS
    48.
    发明申请
    ELECTRODES WITH ELECTROSPUN FIBERS 有权
    电极纤维电极

    公开(公告)号:US20120061124A1

    公开(公告)日:2012-03-15

    申请号:US13214570

    申请日:2011-08-22

    摘要: In accordance with various example embodiments, an apparatus includes two or more circuit nodes and a conductive material that is located between and configured to electrically couple the circuit nodes. The conductive material includes a network of elongated portions of at least one electrospun Cu-based nanostructure. Each elongated portion has an aspect ratio of at least 50,000 and a length that is greater than 100 microns, and at least one fused crossing point that joins with a fused crossing point of another of the elongated portions. The network of elongated portions is distributed and aligned in the conductive material to set a conductance level and a transparency level along the network, along at least one direction.

    摘要翻译: 根据各种示例性实施例,一种装置包括两个或多个电路节点和位于电耦合电路节点之间并被配置为电耦合电路节点的导电材料。 导电材料包括至少一个电纺丝基于Cu的纳米结构的细长部分的网络。 每个细长部分具有至少50,000的长宽比和大于100微米的长度,以及与另一个细长部分的融合交叉点连接的至少一个融合的交叉点。 细长部分的网络在导电材料中分布和对准,以沿着网络沿着至少一个方向设置电导水平和透明度水平。