公开(公告)号：US20120168351A1

公开(公告)日：2012-07-05

申请号：US13331305

申请日：2011-12-20

Applicant: Erin P. Maris ,  Oleg Mironov ,  Julie Chabot

Inventor： Erin P. Maris ,  Oleg Mironov ,  Julie Chabot

IPC: B01J37/20 ,  B01J27/049 ,  C10G29/10 ,  B01J27/188 ,  C10G29/16 ,  B01J27/047 ,  C10G45/04

CPC classification number: B01J23/883 ,  B01J23/24 ,  B01J23/85 ,  B01J23/8872 ,  B01J23/8873 ,  B01J27/051 ,  B01J27/0515 ,  B01J35/0073 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1095 ,  B01J37/20 ,  C10G49/04 ,  C10G49/06 ,  C10G49/12 ,  C10G2300/107 ,  C10G2300/1077 ,  C10G2300/205 ,  C10G2300/301 ,  C10G2300/701 ,  C10G2300/703 ,  C10G2300/802

Abstract: An improved process for preparing a slurry catalyst for the upgrade of heavy oil feedstock is provided. The process employs rework material obtained from a process to prepare a hydroprocessing catalyst as part of the metal precursor feed. In one embodiment, the process comprises mixing the rework material with a hydrocarbon diluent to form a slurried metal precursor for subsequent in-situ sulfiding in a heavy oil upgrade process. In another embodiment, the rework is slurried in a hydrocarbon carrier and a sulfiding agent, forming a slurry catalyst. In yet another embodiment, the rework material is mixed directly with a heavy oil feedstock under in-situ sulfiding conditions, forming a slurry catalyst.

Abstract translation: 提供了一种用于制备用于重油原料升级的浆料催化剂的改进方法。 该方法采用从工艺获得的返工材料来制备加氢处理催化剂作为金属前体原料的一部分。 在一个实施方案中，该方法包括将返工材料与烃稀释剂混合以形成用于随后在重油升级过程中原位硫化的浆状金属前体。 在另一个实施方案中，返工在烃载体和硫化剂中浆化，形成淤浆催化剂。 在另一个实施方案中，返工材料在原位硫化条件下直接与重油原料混合，形成浆料催化剂。

公开(公告)号：US20120041160A1

公开(公告)日：2012-02-16

申请号：US12854750

申请日：2010-08-11

Applicant: Elizabeth A. Benham ,  Max P. McDaniel ,  Kathy S. Collins

Inventor： Elizabeth A. Benham ,  Max P. McDaniel ,  Kathy S. Collins

IPC: C08F4/24 ,  C08F10/02 ,  B01J37/00 ,  B01J21/08 ,  B01J21/04 ,  B01J27/188 ,  B01J21/16 ,  B01J31/34 ,  B01J27/132 ,  B01J27/053 ,  B01J21/06 ,  B01J21/02 ,  B01J29/04 ,  B01J29/00 ,  B01J21/18 ,  B01J37/16 ,  B01D15/00 ,  C08F4/69

CPC classification number: C08F4/24 ,  B01J23/26 ,  C08F10/02 ,  C08F110/02 ,  C08F210/02 ,  C08F210/16 ,  C08F236/06 ,  C08F210/06 ,  C08F2/14

Abstract: Systems and methods for the maintenance of active chromium-based catalysts and their use in polymerization processes are described. In one embodiment, a system for the introduction of multiple polymerization components to activate a chromium based catalyst within a mix tank is described. Other described features may include materials and methods to purify the liquid medium of a catalyst slurry so that the catalyst slurry maintains a high level of activity. The active chromium-based catalyst may provide polyolefins with a number of desirable properties in a reliable, consistent, and predictable manner.

Abstract translation: 描述了用于维持活性铬基催化剂的系统和方法及其在聚合方法中的用途。 在一个实施方案中，描述了用于引入多种聚合组分以在混合罐内活化铬基催化剂的体系。 其它描述的特征可以包括纯化催化剂浆液的液体介质的材料和方法，使得催化剂浆料维持高水平的活性。 活性铬基催化剂可以以可靠，一致和可预测的方式提供具有多种所需性质的聚烯烃。

公开(公告)号：US20110263415A1

公开(公告)日：2011-10-27

申请号：US13177093

申请日：2011-07-06

Applicant: Achim Fischer ,  Weimin Lu ,  Christoph Weckbecker ,  Klaus Huthmacher

Inventor： Achim Fischer ,  Weimin Lu ,  Christoph Weckbecker ,  Klaus Huthmacher

IPC: B01J27/188 ,  B01J37/03 ,  B01J37/08 ,  B01J37/04

CPC classification number: B01J23/002 ,  B01J23/24 ,  B01J23/28 ,  B01J23/652 ,  B01J23/887 ,  B01J27/0576 ,  B01J27/19 ,  B01J37/0045 ,  B01J37/0236 ,  B01J2523/00 ,  C07C45/33 ,  C07C45/34 ,  C07C45/35 ,  C07C51/215 ,  C07C51/252 ,  C07C47/22 ,  C07C57/04 ,  B01J2523/51 ,  B01J2523/64 ,  B01J2523/67 ,  B01J2523/68 ,  B01J2523/845 ,  B01J2523/842 ,  B01J2523/54

Abstract: Disclosed herein are mixed oxide catalysts for the catalytic gas phase oxidation of alkanes, or mixtures of alkanes and olefins, for the production of aldehydes and carboxylic acids with air or oxygen in the presence of inert gases at elevated temperatures and pressure, and a method for the production of catalysts.

Abstract translation: 本文公开了用于在惰性气体在升高的温度和压力下存在下用于在空气或氧气下生产醛和羧酸的烷烃或烷烃和烯烃的混合物的催化气相氧化的混合氧化物催化剂，以及用于 生产催化剂。

公开(公告)号：US20110230691A1

公开(公告)日：2011-09-22

申请号：US13059254

申请日：2009-07-29

Applicant: Audrey Bonduelle ,  Fabrice Bertoncini ,  Karima Ben Tayeb ,  Carole Lamonier ,  Michel Fournier ,  Edmond Payen

Inventor： Audrey Bonduelle ,  Fabrice Bertoncini ,  Karima Ben Tayeb ,  Carole Lamonier ,  Michel Fournier ,  Edmond Payen

IPC: C07C5/10 ,  B01J27/188 ,  B01J21/06 ,  B01J21/02 ,  C01B33/20 ,  B01J37/30 ,  C10G11/04

CPC classification number: C01G41/006 ,  B01J23/002 ,  B01J23/888 ,  B01J27/188 ,  B01J37/0213 ,  B01J37/20 ,  B01J37/30 ,  B01J2523/00 ,  C01G53/006 ,  C01P2002/82 ,  C01P2002/86 ,  C10G45/08 ,  C10G47/12 ,  C10G49/04 ,  B01J2523/51 ,  B01J2523/69 ,  B01J2523/847 ,  B01J2523/41

Abstract: The invention describes a heteropolycompound constituted by a nickel salt of a lacunary Keggin type heteropolyanion comprising tungsten in its structure, with formula: Nix+y/2AW11-yO39-5/2y,zH2O wherein Ni is nickel, A is selected from phosphorus, silicon and boron, W is tungsten, O is oxygen, y=0 or 2, x=3.5 if A is phosphorus, x=4 if A is silicon, x=4.5 if A is boron, and x=m/2+2 for the rest, and z is a number in the range 0 to 36, in which said heteropolycompound has no nickel atom in substitution for a tungsten atom in its structure, said nickel atoms being placed in the counter-ion position in the structure of said compound.

Abstract translation: 本发明描述了由其结构中包含钨的缺口Keggin型杂多阴离子的镍盐构成的杂多化合物，其结构为：Nix + y / 2AW11-yO39-5 / 2y，zH2O，其中Ni是镍，A选自磷，硅 和硼，W是钨，O是氧，y = 0或2，如果A是磷，x = 3.5，如果A是硅，x = 4，如果A是硅则x = 4.5，如果A是硼则x = 4.5，并且x = m / 2 + 2 其余，z为0〜36的数，其中所述杂多化合物在其结构中不具有取代钨原子的镍原子，所述镍原子位于所述化合物的结构中的反离子位置 。

公开(公告)号：US07662742B2

公开(公告)日：2010-02-16

申请号：US10577136

申请日：2004-10-27

Applicant: Hiroyuki Naitou ,  Takashi Karasuda ,  Tomoki Fukui

Inventor： Hiroyuki Naitou ,  Takashi Karasuda ,  Tomoki Fukui

IPC: B01J27/00 ,  B01J27/198 ,  B01J27/188 ,  B01J27/19 ,  B01J27/192 ,  B01J27/185 ,  B01J23/00 ,  B01J23/32 ,  B01J23/02 ,  B01J23/04 ,  B01J23/70 ,  B01J23/72 ,  B01J23/08

CPC classification number: C07C51/235 ,  B01J23/002 ,  B01J23/8877 ,  B01J27/199 ,  B01J37/0236 ,  B01J37/04 ,  B01J2523/00 ,  C07C57/04 ,  B01J2523/15 ,  B01J2523/17 ,  B01J2523/51 ,  B01J2523/55 ,  B01J2523/68 ,  B01J2523/842 ,  B01J2523/48 ,  B01J2523/52

Abstract: A method for producing a catalyst containing given atoms in a given atomic proportion for use in producing methacrylic acid through gas-phase catalytic oxidation of methacrolein with molecular oxygen comprising the steps of: (i) preparing a solution or slurry containing at least molybdenum, phosphorus, and vanadium (liquid I); (ii) preparing a solution or slurry containing ammonium radical (liquid II); (iii) preparing a mixture of the liquid I and the liquid II by introducing one liquid (liquid PR) of the liquid I and the liquid II into a tank (tank A) and pouring the other liquid (liquid LA) on a continuous region in the surface of the liquid PR, the continuous region occupying 0.01 to 10% of the whole area of the surface of the liquid PR; and (iv) drying and calcining the resultant solution or slurry containing a catalyst precursor comprising all the catalyst constituents.

Abstract translation: 一种制备含有给定原子比例的催化剂的方法，用于通过用分子氧气体催化氧化甲基丙烯醛来生产甲基丙烯酸，包括以下步骤：（i）制备至少包含钼，磷 ，和钒（液体I）; （ii）制备含有铵基（液体II）的溶液或浆液; （iii）通过将液体I和液体II的一种液体（液体PR）引入罐（罐A）中并将另一种液体（液体LA）倒入连续区域来制备液体I和液体II的混合物 在液体PR的表面中，连续区域占液体PR表面的整个面积的0.01〜10％ 和（iv）干燥和煅烧含有包含所有催化剂组分的催化剂前体的所得溶液或浆料。

公开(公告)号：US07618916B2

公开(公告)日：2009-11-17

申请号：US10539400

申请日：2003-12-17

Applicant: Takashi Fujikawa ,  Masahiro Kato ,  Nobumasa Nakajima ,  Minoru Hashimoto

Inventor： Takashi Fujikawa ,  Masahiro Kato ,  Nobumasa Nakajima ,  Minoru Hashimoto

IPC: B01J27/00 ,  B01J27/188 ,  B01J27/19 ,  B01J27/185 ,  B01J23/00

CPC classification number: C10G45/08 ,  B01J23/85 ,  B01J23/882 ,  B01J23/883 ,  B01J23/8885 ,  B01J31/04 ,  B01J31/2234 ,  B01J31/34 ,  B01J35/002 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1061 ,  B01J37/04 ,  B01J37/20 ,  B01J37/28 ,  B01J2231/641 ,  B01J2531/84 ,  B01J2531/845 ,  B01J2531/847 ,  C10G2300/1059 ,  C10G2300/4018

Abstract: An object of the present invention is to provide a hydrotreating catalyst capable of being produced by a simple method and capable of realizing ultra-deep desulfurization of sulfur components in gas oil without requiring severer operating conditions as well as capable of reducing nitrogen components simultaneously, to provide a process for producing the catalyst, and to provide a process for desulfurizing gas oil using the catalyst.The invention relates to a catalyst containing on an inorganic oxide support 10 to 40% by weight of a metal in the Group 6 of the periodic table, 1 to 15% by weight of a metal in the Group 8 of the periodic table, 1.5 to 8% by weight of phosphorus, each in terms of an oxide amount based on the catalyst, and 2 to 14% by weight of carbon in terms of an element amount based on the catalyst, wherein the catalyst has a specific surface area of 150 to 300 m2/g, a pore volume of 0.3 to 0.6 ml/g, and an average pore diameter of 65 to 140 Å, and wherein the catalyst has a certain NO adsorption FT-IR spectrum after sulfidation treatment, a process for producing the catalyst, and a process for desulfurizing gas oil using the catalyst.

Abstract translation: 本发明的目的是提供一种加氢处理催化剂，其能够通过简单的方法制备，并且能够在不需要更严格的操作条件以及能够同时还原氮组分的情况下实现瓦斯油中硫成分的超深度脱硫， 提供催化剂的制造方法，提供使用该催化剂使瓦斯油脱硫的方法。 本发明涉及一种含有无机氧化物载体的催化剂，其含有10至40重量％的元素周期表第6族中的金属，1至15重量％的周期表第8族中的金属，1.5至 8重量％的磷，各自以基于催化剂的氧化物量计，以基于催化剂的元素量计为2〜14重量％的碳，其中，所述催化剂的比表面积为150〜 300m 2 / g，孔体积为0.3〜0.6ml / g，平均孔径为65〜140，其中催化剂在硫化处理后具有一定的NO吸附FT-IR光谱，制备催化剂的方法 ，以及使用该催化剂使瓦斯油脱硫的方法。

公开(公告)号：US20080200330A1

公开(公告)日：2008-08-21

申请号：US12148028

申请日：2008-04-16

Applicant: Darryl P. Klein

Inventor： Darryl P. Klein

IPC: B01J27/19 ,  B01J27/188

CPC classification number: C10G47/14 ,  B01J21/04 ,  B01J23/85 ,  B01J23/883 ,  B01J27/188 ,  B01J27/19 ,  B01J35/002 ,  B01J35/04 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1061 ,  B01J37/0009 ,  B01J37/0213 ,  C10G45/06 ,  C10G45/08

Abstract: Stable catalyst carrier impregnating solutions can be prepared using a component of a Group VIB metal, e.g., molybdenum, at high concentration, a component of a Group VIII metal, e.g., nickel, at low concentration, and a phosphorous component, e.g., phosphoric acid, at low concentration, provided that the Group VIII metal is in a substantially water-insoluble form and a particular sequence of addition of the components is followed, even when a substantially water-insoluble form of the Group VIB component is used. The resulting stabilized impregnating solution can be supplemented with additional Group VIII metal in water-soluble form to achieve increased levels of such metal in the final catalyst. Furthermore, uncalcined catalyst carriers impregnated with the stable solution and subsequently shaped, dried and calcined, have unexpectedly improved performance when used in the hydroprocessing of heavy hydrocarbon feedstocks. High conversion can be achieved at reduced levels of sediment, especially in comparison to standard commercial catalysts.

公开(公告)号：US07208441B2

公开(公告)日：2007-04-24

申请号：US10997727

申请日：2004-11-23

Applicant: Elizabeth A. Benham ,  Paul J. DesLauriers ,  Max P. McDaniel ,  Al R. Wolfe

Inventor： Elizabeth A. Benham ,  Paul J. DesLauriers ,  Max P. McDaniel ,  Al R. Wolfe

IPC: B01J27/188 ,  B01J31/14 ,  C08F4/52 ,  C08F4/69

CPC classification number: F16L9/127 ,  C08F10/00 ,  C08F210/16 ,  Y10T428/139 ,  C08F4/69 ,  C08F210/14 ,  C08F2500/12 ,  C08F2500/07 ,  C08F2500/13 ,  C08F2500/04 ,  C08F4/025

Abstract: A copolymer of ethylene and a higher alpha olefin, preferably 1-hexene, can be produced using an activated chromium containing catalyst system and a cocatalyst selected from the group consisting of trialkylboron, trialkylsiloxyalutninum, and a combination of trialkylboron and thalkylaluminum compounds. The polymerization process must be carefully controlled to produce a copolymer resin having an exceptionally broad molecular weight distribution, extremely high PENT ESCR values, and a natural branch profile that impacts branching preferably into the high molecular weight portion of the polymer. The resulting copolymer resin is especially useful in high stiffness pipe applications.

Abstract translation: 乙烯和较高级α-烯烃，优选1-己烯的共聚物可以使用活化的含铬催化剂体系和选自三烷基硼，三烷基硅氧烷和三烷基硼与三烷基铝化合物的组合的助催化剂来制备。 聚合过程必须仔细控制，以产生具有非常宽的分子量分布，极高的PENT ESCR值和天然分支分布的共聚物树脂，其优选地影响聚合物的高分子量部分的分支。 所得共聚物树脂在高刚度管道应用中特别有用。

公开(公告)号：US20050152829A1

公开(公告)日：2005-07-14

申请号：US11033102

申请日：2005-01-11

Applicant: Boris Shpeizer ,  Abraham Clearfield

Inventor： Boris Shpeizer ,  Abraham Clearfield

IPC: B01J23/26 ,  B01J23/83 ,  B01J27/185 ,  B01J27/188 ,  B01J35/10 ,  B01J37/03 ,  B01J37/10 ,  C01B13/32 ,  C01G1/00 ,  C01G1/02 ,  C01G3/00 ,  C01G37/00 ,  C01G37/02 ,  C01G53/00 ,  C01F7/00

CPC classification number: B01J35/10 ,  B01J23/26 ,  B01J23/83 ,  B01J27/1853 ,  B01J27/188 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1057 ,  B01J37/033 ,  B01J37/10 ,  C01B13/32 ,  C01G1/00 ,  C01G1/02 ,  C01G3/00 ,  C01G3/02 ,  C01G37/00 ,  C01G37/02 ,  C01G53/006 ,  C01P2002/50 ,  C01P2006/12 ,  C01P2006/14 ,  C01P2006/16 ,  C01P2006/37

Abstract: A new class of supermicroporous mixed oxides, with pore sizes in the 10-20 Å range has been prepared utilizing basic metal acetates. The reactions are carried out in non-aqueous solvent media to which an excess of amine is added. Hydrolysis of the reagents is effected by addition of a water-propanol mixture and refluxing. The amine and solvent are removed by thorough washing and/or calcining at temperatures as low as 200° C. Mixtures of transition metal oxides with either ZrO2, TiO2, La2O3, SiO2, Al2O3 or mixtures thereof were prepared. The surface area curves of the pure oxides are Type I with surface areas of 400-600 m2/g and up to 1100 m2/g for the mixed oxides.

Abstract translation: 使用碱性金属乙酸酯制备了一类新型超微孔混合氧化物，孔径在10-20埃范围内。 反应在非水溶剂介质中进行，向其中加入过量的胺。 试剂的水解通过加入水 - 丙醇混合物并回流来进行。 通过在低至200℃的温度下彻底洗涤和/或煅烧来除去胺和溶剂。过渡金属氧化物与ZrO 2，TiO 2，La 或者它们的混合物是：其中，O 2，O 2，O 2， 准备 纯氧化物的表面积曲线为混合氧化物的表面积为400-600m 2 / g且高达1100m 2 / g的I型。

公开(公告)号：US20050143256A1

公开(公告)日：2005-06-30

申请号：US11069034

申请日：2005-02-28

Applicant: Dengling Wei ,  Shaozhong Peng

Inventor： Dengling Wei ,  Shaozhong Peng

IPC: B01J21/12 ,  B01J23/85 ,  B01J23/883 ,  B01J27/182 ,  B01J27/188 ,  B01J35/00 ,  B01J35/10 ,  B01J37/00 ,  C10G45/08 ,  B01J27/14 ,  B01J21/02

CPC classification number: C10G45/08 ,  B01J21/12 ,  B01J23/85 ,  B01J23/883 ,  B01J27/182 ,  B01J27/188 ,  B01J35/0006 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/108 ,  B01J37/0009

Abstract: A silicon-containing alumina support, a process for preparing the support, and a catalyst containing the support are provided. The alumina support includes an additive silicon enriched on its surface, with the difference between the atomic ratio of silicon to aluminum on the surface of alumina support and that of the alumina support is at least 0.10. The process for preparing the silicon-containing alumina support comprises adding a nanometer silicon compound. The inventive alumina support can be used in manufacturing a catalyst for hydrotreating hydrocarbons with good physico-chemical properties and performance.