公开(公告)号：US3925447A

公开(公告)日：1975-12-09

申请号：US46375874

申请日：1974-04-24

申请人： LUMMUS CO

发明人： GELBEIN ABRAHAM P

IPC分类号： B01J23/22 ,  B01J23/28 ,  B01J37/02 ,  C07C120/14

CPC分类号： C07C255/00 ,  B01J23/22 ,  B01J23/28 ,  B01J37/023

摘要： Nitriles are produced by reaction of hydrocarbon and ammonia in the presence of a supported metal oxide, wherein the support has a surface area greater than 50m2/gm, and a porosity greater than 0.4 cc/gm. The metal oxide is present in the pores of the support in an amount from 25% to 75%, by weight.

摘要翻译： 在负载的金属氧化物的存在下，通过烃和氨的反应制备腈，其中载体的表面积大于50m 2 / gm，孔隙率大于0.4cc / gm。 金属氧化物以25重量％至75重量％的量存在于载体的孔中。

公开(公告)号：US2369524A

公开(公告)日：1945-02-13

申请号：US38266341

申请日：1941-03-10

申请人： HERBERT BERG ,  HANS HEIM

发明人： HERBERT BERG ,  HANS HEIM

IPC分类号： B01J21/18 ,  B01J31/02 ,  B01J31/04 ,  B01J37/02 ,  C07C67/04

CPC分类号： B01J31/0254 ,  B01J21/18 ,  B01J31/0239 ,  B01J31/04 ,  B01J37/0203 ,  B01J37/023 ,  B01J2231/323 ,  C07C67/04 ,  C07C69/01 ,  C07C69/15

公开(公告)号：US20180229220A1

公开(公告)日：2018-08-16

申请号：US15861965

申请日：2018-01-04

申请人： Clariant Corporation

发明人： Zhongyuan DANG ,  Greg CULLEN

IPC分类号： B01J23/63 ,  B01J23/62 ,  B01J23/10 ,  B01J21/06 ,  B01J21/08 ,  B01J21/04 ,  B01J35/04 ,  B01J37/02 ,  B01D53/86

CPC分类号： B01J23/63 ,  B01D53/864 ,  B01D53/8662 ,  B01D2255/1021 ,  B01D2255/1026 ,  B01D2255/2061 ,  B01D2255/2063 ,  B01D2255/2065 ,  B01D2255/2066 ,  B01D2255/2068 ,  B01D2255/20707 ,  B01D2255/2094 ,  B01D2255/40 ,  B01D2255/407 ,  B01D2257/2062 ,  B01D2257/502 ,  B01D2257/7027 ,  B01D2257/708 ,  B01J21/04 ,  B01J21/063 ,  B01J21/066 ,  B01J21/08 ,  B01J23/10 ,  B01J23/462 ,  B01J23/626 ,  B01J35/04 ,  B01J37/023 ,  B01J2523/821 ,  B01J2523/828 ,  Y02A50/2341

摘要： The current embodiments relate to ruthenium-containing supported catalysts, including processes for their manufacture and use, which destroy, through catalytic oxidation, hazardous compounds contained in chemical industrial emissions and otherwise produced from industrial processes.

公开(公告)号：US20170283258A1

公开(公告)日：2017-10-05

申请号：US15621734

申请日：2017-06-13

申请人： Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V.

发明人： Andreas Hornung ,  Samir Binder

IPC分类号： C01B3/28 ,  B01J35/08 ,  B01J37/00 ,  B01J8/12 ,  C01B3/22 ,  B01J35/00 ,  B01J35/02 ,  B01J23/42 ,  B01J37/02

CPC分类号： C01B3/28 ,  B01J8/12 ,  B01J8/20 ,  B01J8/382 ,  B01J8/386 ,  B01J23/42 ,  B01J23/44 ,  B01J35/002 ,  B01J35/0033 ,  B01J35/008 ,  B01J35/023 ,  B01J35/026 ,  B01J35/08 ,  B01J35/12 ,  B01J37/0081 ,  B01J37/0225 ,  B01J37/023 ,  B01J37/0242 ,  B01J37/34 ,  B01J2208/00132 ,  B01J2208/0015 ,  B01J2208/00389 ,  B01J2208/00415 ,  C01B3/22 ,  C01B3/26 ,  C01B2203/0277 ,  C01B2203/085 ,  C01B2203/107 ,  C01B2203/1082 ,  C01B2203/1211 ,  C01B2203/1252 ,  C09K5/063 ,  F28D20/023 ,  Y02E60/145 ,  Y02E70/30 ,  Y02P20/584

摘要： A catalyst support may be provided that comprises: an inner core, which includes at least one phase change material; a coating layer around the inner core, which includes at least one metal oxide; a catalytically active layer, which is positioned in interstices of the coating layer and/or lying on the coating layer, wherein at least one catalytically active substance is included in the catalytically active layer; and a supporting layer which is positioned under the coating layer. A recycle reactor may be provided comprising a reservoir for accommodating a chemical hydrogen storage substance; the catalyst support; a screw conveyor for input and transport of the catalyst support; and a heating device with which the catalyst support can be heated. A method for releasing hydrogen from a chemical hydrogen storage substance may be provided.

公开(公告)号：US09586198B2

公开(公告)日：2017-03-07

申请号：US14391847

申请日：2013-10-24

申请人： KOREA INSTITUTE OF ENERGY RESEARCH

发明人： Ji-Chan Park ,  Heon Jung ,  Ho-Tae Lee ,  Jung-Il Yang ,  Dong-Hyun Chun ,  Sung-Jun Hong

IPC分类号： B01J29/40 ,  B01J31/28 ,  B01J23/75 ,  B01J37/02 ,  B01J29/06 ,  B01J35/10 ,  B01J37/00 ,  B01J21/04 ,  B01J21/08 ,  B01J23/755 ,  B01J23/89 ,  B01J31/06 ,  B01J35/00 ,  B01J35/04 ,  B01J37/14 ,  C10G2/00

CPC分类号： B01J31/28 ,  B01J21/04 ,  B01J21/08 ,  B01J23/75 ,  B01J23/755 ,  B01J23/8913 ,  B01J29/005 ,  B01J29/0333 ,  B01J29/06 ,  B01J29/40 ,  B01J29/46 ,  B01J31/06 ,  B01J35/0006 ,  B01J35/0013 ,  B01J35/006 ,  B01J35/04 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1076 ,  B01J37/0018 ,  B01J37/0045 ,  B01J37/0201 ,  B01J37/0217 ,  B01J37/0219 ,  B01J37/0225 ,  B01J37/023 ,  B01J37/0232 ,  B01J37/0244 ,  B01J37/0246 ,  B01J37/088 ,  B01J37/14 ,  B01J2229/186 ,  B01J2229/20 ,  B01J2231/62 ,  B01J2531/005 ,  C10G2/331 ,  C10G2400/22

摘要： This invention relates to a cobalt-based catalyst on a metal structure for selective production of synthetic oil via Fischer-Tropsch reaction, a method of preparing the same and a method of selectively producing synthetic oil using the same, wherein zeolite, cobalt and a support are mixed and ground to give a catalyst sol, which is then uniformly thinly applied on the surface of a metal structure using a spray-coating process, thereby preventing generation of heat during Fischer-Tropsch reaction and selectively producing synthetic oil having a carbon chain shorter than that of wax. This catalyst is prepared by burning a powder mixture obtained by melt infiltration of a cobalt hydrate and a metal oxide support to give a catalyst powder including cobalt oxide/metal oxide support; hybridizing the catalyst powder including cobalt oxide/metal oxide support with a zeolite powder to give a hybrid catalyst powder; mixing the hybrid catalyst powder with an organic binder and an inorganic binder and grinding the mixed hybrid catalyst powder to give a hybrid catalyst sol; spray-coating a metal structure surface-treated with alumina by atomic layer deposition with the hybrid catalyst sol; and thermally treating the metal structure spray-coated with the hybrid catalyst sol.

摘要翻译： 本发明涉及一种用于通过费 - 托反应选择性生产合成油的金属结构上的钴基催化剂，其制备方法和使用该合成油选择性生产合成油的方法，其中沸石，钴和载体 混合并研磨以得到催化剂溶胶，然后使用喷涂法将其均匀地薄涂在金属结构的表面上，从而防止费 - 托反应期间产生热量，并选择性地生产碳链短的合成油 比蜡。 该催化剂是通过将通过熔融渗透钴酸水合物和金属氧化物载体获得的粉末混合物燃烧得到包含氧化钴/金属氧化物载体的催化剂粉末来制备的; 将包含氧化钴/金属氧化物载体的催化剂粉末与沸石粉末杂化，得到混合催化剂粉末; 将混合催化剂粉末与有机粘合剂和无机粘合剂混合，并研磨混合的混合催化剂粉末，得到混合催化剂溶胶; 用混合催化剂溶胶通过原子层沉积喷涂用氧化铝表面处理的金属结构; 并对喷涂了混合催化剂溶胶的金属结构进行热处理。

公开(公告)号：US20160311684A1

公开(公告)日：2016-10-27

申请号：US15105464

申请日：2014-12-15

申请人： BASF SE

发明人： Andrian MILANOV ,  Ekkehard SCHWAB ,  Heiko URTEL ,  Stephan SCHUNK ,  Guido WASSERSCHAFF

IPC分类号： C01B3/40 ,  C01B3/38

CPC分类号： C01B3/40 ,  B01J23/005 ,  B01J23/007 ,  B01J23/63 ,  B01J23/78 ,  B01J23/83 ,  B01J35/0006 ,  B01J35/1038 ,  B01J37/0018 ,  B01J37/0201 ,  B01J37/023 ,  B01J37/08 ,  B01J37/32 ,  C01B3/382 ,  C01B2203/0233 ,  C01B2203/0238 ,  C01B2203/061 ,  C01B2203/062 ,  C01B2203/1052 ,  C01B2203/1058 ,  C01B2203/1064 ,  C01B2203/1082 ,  C01B2203/1241 ,  C01B2203/1247 ,  C01B2203/141 ,  C01B2203/142 ,  C01B2203/148 ,  Y02P20/52

摘要： A method of reforming mixtures of hydrocarbons, preferably methane, and carbon dioxide, wherein the method comprises at least two stages. In a first stage, a reactant gas is contacted with a precious metal catalyst and converted to a first product gas (also referred to hereinafter as product gas 1). In a second stage, the first product gas obtained in the first stage is contacted with a non-precious metal catalyst and converted to a second product gas (also referred to hereinafter as product gas 2). The process can also include adding gases to the product gas 1 obtained in the first stage. The practice of the process can minimize the formation of coke on the catalyst in an efficient manner. The combination of a first stage with a precious metal catalyst and at least one second stage with non-precious metal catalyst allows considerable amounts of costly precious metals to be saved.

摘要翻译： 一种重整碳氢化合物，优选甲烷和二氧化碳的混合物的方法，其中该方法包括至少两个阶段。 在第一阶段中，使反应气体与贵金属催化剂接触并转化为第一产物气体（以下也称为产物气体1）。 在第二阶段中，将第一阶段获得的第一产物气体与非贵金属催化剂接触并转化为第二产物气体（以下也称为产物气体2）。 该方法还可以包括向在第一阶段获得的产物气体1中加入气体。 该方法的实践可以以有效的方式最小化催化剂上焦炭的形成。 第一阶段与贵金属催化剂的组合和至少一个第二阶段与非贵金属催化剂的组合允许节省大量昂贵的贵金属。

公开(公告)号：US20160296919A1

公开(公告)日：2016-10-13

申请号：US15103216

申请日：2014-12-10

申请人： MITSUI CHEMICALS, INC.

发明人： Shinichiro ICHIKAWA ,  Naoya TAKAHASHI ,  Masami MURAKAMI

IPC分类号： B01J27/232 ,  B01J21/18 ,  B01J37/08 ,  B01J35/10 ,  B01J35/00 ,  B01J37/04 ,  C07C2/24 ,  B01J23/04

CPC分类号： B01J27/232 ,  B01J21/18 ,  B01J23/04 ,  B01J27/236 ,  B01J35/002 ,  B01J35/1038 ,  B01J35/1066 ,  B01J35/1071 ,  B01J35/1076 ,  B01J35/12 ,  B01J37/023 ,  B01J37/04 ,  B01J37/08 ,  C07C2/14 ,  C07C2/24 ,  C07C2521/18 ,  C07C2523/04 ,  C07C2527/232 ,  C07C11/113

摘要： Provided is a formed body containing at least one carbonate compound (A1) selected from Na2CO3 or K2CO3, the formed body having a volume of pores with a pore diameter of from 0.05 μm to 10 μm of from 0.10 mL/g to 0.30 mL/g and a crushing strength of from 1.8 kgf to 10.0 kgf.

摘要翻译： 提供了含有至少一种选自Na 2 CO 3或K 2 CO 3的碳酸酯化合物（A1）的成形体，成形体的孔径为0.05〜10μm的孔体积为0.10mL / g〜0.30mL / g 破碎强度从1.8kgf至10.0kgf。

公开(公告)号：US08962703B2

公开(公告)日：2015-02-24

申请号：US13925361

申请日：2013-06-24

申请人： Korea Institute of Energy Research

发明人： Jichan Park ,  Heon Jung ,  Hotae Lee ,  Jungil Yang ,  Donghyun Chun ,  Sungjun Hong

IPC分类号： C07C1/04 ,  C10G2/00 ,  B01J27/22 ,  B01J23/745

CPC分类号： C07C1/044 ,  B01J23/745 ,  B01J27/22 ,  B01J35/1061 ,  B01J37/023 ,  B01J37/08 ,  C07C1/0445 ,  C07C2527/22 ,  C10G2/332 ,  C10G2300/703 ,  C10G2300/705

摘要： Iron/carbon (Fe/C) nanocomposite catalysts are prepared for Fischer-Tropsch synthesis reaction. A preparation method includes steps of mixing iron hydrate salts and a mesoporous carbon support to form a mixture, infiltrating the iron hydrate salts into the carbon support through melt infiltration of the mixture near a melting point of the iron hydrate salts, forming iron-carbide particles infiltrated into the carbon support through calcination of the iron hydrate salts infiltrated into the carbon support under a first atmosphere, and vacuum-drying the iron-carbide particles after passivation using ethanol. Using such catalysts, liquid hydrocarbons are produced.

摘要翻译： 制备铁/碳（Fe / C）纳米复合催化剂用于费 - 托合成反应。 一种制备方法包括混合铁水合物盐和介孔碳载体以形成混合物的步骤，通过在铁水合物盐的熔点附近熔融渗透混合物将铁水合物盐浸入碳载体中，形成碳化铁颗粒 通过在第一个气氛下渗入碳载体中的铁水合物盐的煅烧而渗透到碳载体中，并且使用乙醇钝化后对该碳化铁颗粒进行真空干燥。 使用这种催化剂，生产液态烃。

公开(公告)号：US08795772B2

公开(公告)日：2014-08-05

申请号：US13401220

申请日：2012-02-21

申请人： Alexander Kastalsky

发明人： Alexander Kastalsky

IPC分类号： C23C16/00 ,  B05D5/00 ,  B05D1/32

CPC分类号： B01J37/344 ,  B01J23/06 ,  B01J23/745 ,  B01J23/755 ,  B01J35/0013 ,  B01J35/006 ,  B01J35/08 ,  B01J37/023 ,  B82Y30/00 ,  B82Y40/00

摘要： Two methods of producing nano-pads of catalytic metal for growth of single walled carbon nanotubes (SWCNT) are disclosed. Both methods utilize a shadow mask technique, wherein the nano-pads are deposited from the catalytic metal source positioned under the angle toward the vertical walls of the opening, so that these walls serve as a shadow mask.In the first case, the vertical walls of the photo-resist around the opening are used as a shadow mask, while in the second case the opening is made in a thin layer of the dielectric layer serving as a shadow mask. Both methods produce the nano-pad areas sufficiently small for the growth of the SWCNT from the catalytic metal balls created after high temperature melting of the nano-pads.

摘要翻译： 公开了制备用于单壁碳纳米管（SWCNT）生长的催化金属纳米垫的两种方法。 两种方法都采用荫罩技术，其中纳米垫从位于开口的垂直壁上的催化金属源沉积，使得这些壁用作荫罩。 在第一种情况下，围绕开口的光致抗蚀剂的垂直壁用作荫罩，而在第二种情况下，开口形成为用作荫罩的介电层的薄层。 两种方法都能使纳米焊盘区域足够小，以便在纳米焊盘高温熔化后产生的催化金属球中SWCNT的生长。

公开(公告)号：US20130341242A1

公开(公告)日：2013-12-26

申请号：US13925361

申请日：2013-06-24

申请人： Korea Institute of Energy Research

发明人： Jichan PARK ,  Heon JUNG ,  Hotae LEE ,  Jungil YANG ,  Donghyun CHUN ,  Sungjun HONG

IPC分类号： C07C1/04

CPC分类号： C07C1/044 ,  B01J23/745 ,  B01J27/22 ,  B01J35/1061 ,  B01J37/023 ,  B01J37/08 ,  C07C1/0445 ,  C07C2527/22 ,  C10G2/332 ,  C10G2300/703 ,  C10G2300/705

摘要： Iron/carbon (Fe/C) nanocomposite catalysts are prepared for Fischer-Tropsch synthesis reaction. A preparation method includes steps of mixing iron hydrate salts and a mesoporous carbon support to form a mixture, infiltrating the iron hydrate salts into the carbon support through melt infiltration of the mixture near a melting point of the iron hydrate salts, forming iron-carbide particles infiltrated into the carbon support through calcination of the iron hydrate salts infiltrated into the carbon support under a first atmosphere, and vacuum-drying the iron-carbide particles after passivation using ethanol. Using such catalysts, liquid hydrocarbons are produced.

摘要翻译： 制备铁/碳（Fe / C）纳米复合催化剂用于费 - 托合成反应。 一种制备方法包括混合铁水合物盐和介孔碳载体以形成混合物的步骤，通过在铁水合物盐的熔点附近熔融渗透混合物将铁水合物盐浸入碳载体中，形成碳化铁颗粒 通过在第一个气氛下渗入碳载体中的铁水合物盐的煅烧而渗透到碳载体中，并且使用乙醇钝化后对该碳化铁颗粒进行真空干燥。 使用这种催化剂，生产液态烃。