Abstract:
Interconnect structures with copper conductors being at least substantially free of internal seams or voids are obtained employing an electroplating copper bath containing dissolved cupric salt wherein the concentration of the salt is at least about 0.4 molar and up to about 0.5 molar concentration of an acid. Also provided are copper damascene structures having an aspect ratio of greater than about 3 and a width of less than about 0.275 μm and via openings filled with electroplated copper than is substantially free of internal seams or voids.
Abstract:
Semiconductor structures having improved dopant configurations are obtained by use of barrier layers containing silicon, nitrogen, and oxygen atoms and having a thickness of about 5 to 50 Å. A doped semiconductor structure with controlled dopant configuration can be formed by: (a) providing a first semiconductor material region, (b) forming an interface layer comprising silicon, oxygen, and nitrogen on the first region, (c) forming a second semiconductor material region on the interface layer, the second semiconductor material region being on an opposite side of the interface layer from the first semiconductor material region, (d) providing a dopant in the second region, and (e) heating the first and second regions whereby at least a portion of the dopant diffuses from the second region through the interface layer to the first region.
Abstract:
A method for controlling dopant outdiffusion within an integrated circuit is disclosed. The method includes providing a substrate, forming a trench in the substrate, and forming a first doped layer in the trench. The first doped layer has a first dopant concentration. The method further includes forming a dopant diffusion control structure above the first doped layer. The dopant diffusion control structure includes silicon nitride (Si.sub.x N.sub.y) disposed in grain boundaries of the first doped layer. The method also includes forming a second layer above the dopant diffusion control structure. The second layer has a second dopant concentration lower than the first dopant concentration. Forming the dopant diffusion control structure includes, in one example, forming a first oxide layer over the first doped silicon layer, nitridizing the first oxide layer, thereby forming an oxynitride (SiO.sub.x N.sub.y) layer and causing the silicon nitride to migrate into the grain boundaries, and removing the oxynitride layer, thereby exposing the silicon nitride at the grain boundaries at an interface of the first doped layer.
Abstract translation:公开了一种用于控制集成电路内的掺杂物扩散扩散的方法。 该方法包括提供衬底,在衬底中形成沟槽,以及在沟槽中形成第一掺杂层。 第一掺杂层具有第一掺杂浓度。 该方法还包括在第一掺杂层之上形成掺杂剂扩散控制结构。 掺杂剂扩散控制结构包括设置在第一掺杂层的晶界中的氮化硅(SixNy)。 该方法还包括在掺杂剂扩散控制结构上方形成第二层。 第二层具有低于第一掺杂剂浓度的第二掺杂剂浓度。 在一个示例中,形成掺杂剂扩散控制结构包括在第一掺杂硅层上形成第一氧化物层,对第一氧化物层进行氮化,从而形成氧氮化物(SiO x N y)层并使氮化硅迁移到晶界, 并去除氧氮化物层,从而在第一掺杂层的界面处的晶界暴露氮化硅。
Abstract:
A method of preventing surface decomposition of a III-V compound semiconductor is provided. The method includes forming a silicon film having a thickness from 10 Å to 400 Å on a surface of an III-V compound semiconductor. After forming the silicon film onto the surface of the III-V compound semiconductor, a high performance semiconductor device including, for example, a MOSFET, can be formed on the capped/passivated III-V compound semiconductor. During the MOSFET fabrication, a high k dielectric can be formed on the capped/passivated III-V compound semiconductor and thereafter, activated source and drain regions can be formed into the III-V compound semiconductor.
Abstract:
A method for forming a trench structure is provided for a semiconductor and/or memory device, such as an DRAM device. In one embodiment, the method for forming a trench structure includes forming a trench in a semiconductor substrate, and exposing the sidewalls of the trench to an arsenic-containing gas to adsorb an arsenic containing layer on the sidewalls of the trench. A material layer is then deposited on the sidewalls of the trench to encapsulate the arsenic-containing layer between the material layer and sidewalls of the trench.
Abstract:
A method for forming a trench structure is provided for a semiconductor and/or memory device, such as an DRAM device. In one embodiment, the method for forming a trench structure includes forming a trench in a semiconductor substrate, and exposing the sidewalls of the trench to an arsenic-containing gas to adsorb an arsenic containing layer on the sidewalls of the trench. A material layer is then deposited on the sidewalls of the trench to encapsulate the arsenic-containing layer between the material layer and sidewalls of the trench.
Abstract:
An interconnect structure of the single or dual damascene type and a method of forming the same, which substantially reduces the surface oxidation problem of plating a conductive material onto a noble metal seed layer are provided. In accordance with the present invention, a hydrogen plasma treatment is used to treat a noble metal seed layer such that the treated noble metal seed layer is highly resistant to surface oxidation. The inventive oxidation-resistant noble metal seed layer has a low C content and/or a low nitrogen content.
Abstract:
A method of substantially reducing and/or eliminating the amount of defects and/or impurities that amass at interfacial surfaces that are present in a multilayer structure is provided. Specifically, the method improves the efficiency of a forming gas anneal by providing a multilayer structure having a catalytic layer formed thereon or buried therein which allows for a significant increase in the amount of hydrogen or deuterium which can be incorporated into the structure. The method is also conducted at a low temperature (on the order of about 400° C. or less). Multilayer structures are also provided which include an annealed multilayer structure having at least one interfacial surface present therein. The at least one material interface contains a region of hydrogen or deuterium which substantially reduces defects and impurities present at the at least one interface.
Abstract:
A method for cleaning an oxidized diffusion barrier layer, in accordance with the present invention, includes providing a conductive diffusion barrier layer employed for preventing oxygen and metal diffusion therethrough and providing a wet chemical etchant including hydrofluoric acid. The diffusion barrier layer is etched with the wet chemical etchant to remove oxides from the diffusion barrier layer such that by employing the wet chemical etchant linear electrical behavior is achieved through the diffusion barrier layer.
Abstract:
The preferred embodiment provides a method for fabricating field effect transistors that have different threshold voltages without requiring excessive masking and other fabrication steps. In particular, the method facilitates the formation of FETs with different threshold voltages by doping the gate dielectric with various amounts of ions. This provides a built in potential in the gate dielectric proportional to the amount of ions in the gate dielectric. This potential changes the threshold voltage of the FET. Thus, by selectively doping the gate dielectric with ions the threshold voltage of a FET can be changed. The selective doping of many FETs to many different threshold voltages can be done with only one additional masking step. Thus, the present invention provides the ability to form FETs having different threshold voltages without requiring excessive process complexity.