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    Photocurable compositions with dispersed carbon-coated metal particles
    1.
    发明授权
    Photocurable compositions with dispersed carbon-coated metal particles 有权
    具有分散的碳涂覆金属颗粒的可光固化组合物

    公开(公告)号：US09434852B2

    公开(公告)日：2016-09-06

    申请号：US14514492

    申请日：2014-10-15

    申请人： Eastman Kodak Company

    发明人： Karen M. Kosydar ,  Gary L. Slater ,  Mary Christine Brick ,  Christine Joanne Landry-Coltrain

    IPC分类号： C09D11/52 ,  C09D11/102 ,  C09D11/037 ,  C09D11/101

    CPC分类号： C09D11/52 ,  C09D11/037 ,  C09D11/101 ,  C09D11/102 ,  C09D11/104

    摘要： A non-aqueous photocurable composition contains dispersed carbon-coated metal particles in an amount of at least 10 weight %, and the dispersed carbon-coated metal particles have a median diameter of less than 0.6 μm. These particles are dispersed with a particle dispersing agent that has a weight average molecular weight (Mw) of at least 2,000 and up to and including 100,000 and comprises nitrogen-containing units. Such compositions include an organic diluent as well as suitable photocurable components that can be used for example in acid-catalyzed or free radical chemistries. When the non-aqueous photocurable composition contains up to and including 25 weight % of the dispersed carbon-coated metal particles, it exhibits no visual settling when subjected to a settling test of at least 24 hours at 20° C. The non-aqueous photocurable compositions can be used to provide photocured metallic patterns for various devices that have a touch screen display.

    摘要翻译： 非水性光固化性组合物含有至少10重量％的分散的碳涂覆的金属颗粒，分散的碳涂覆的金属颗粒的中值粒径小于0.6μm。 这些颗粒用重均分子量（Mw）至少为2,000并且至多包括100,000并且包括含氮单元的颗粒分散剂分散。 这样的组合物包括有机稀释剂以及可用于例如酸催化或自由基化学物质中的合适的可光固化组分。 当非水性光固化剂组合物含有至多并且包含25重量％的分散的碳涂覆的金属颗粒时，当在20℃进行至少24小时的沉降试验时，其表现出没有视觉沉降。非水可光固化 可以使用组合物为具有触摸屏显示器的各种装置提供光固化金属图案。

    Laser-engraveable elements
    3.
    发明授权
    Laser-engraveable elements 有权
    激光雕刻元件

    公开(公告)号：US09381698B2

    公开(公告)日：2016-07-05

    申请号：US14848554

    申请日：2015-09-09

    申请人： Eastman Kodak Company

    发明人： Anna C. Greene ,  Christine Joanne Landry-Coltrain ,  Steven Evans

    IPC分类号： F21V9/04 ,  F21V9/06 ,  G02B5/22 ,  G02B5/26 ,  B29C59/16 ,  B41C1/05 ,  C08K9/04 ,  B29C35/08 ,  B29C73/16 ,  C08K5/02 ,  C08L27/12 ,  D06M15/277 ,  B82Y30/00 ,  B29K27/18 ,  B29L7/00

    CPC分类号： B29C59/16 ,  B29K2027/18 ,  B29L2007/001 ,  B41C1/05 ,  B82Y30/00 ,  C08K9/04

    摘要： A laser-engraveable layer is used in a laser-engraveable element to provide relief images. The resulting laser-engraved elements can take various forms and can be used to apply various inks to receiver materials in an imagewise fashion. The laser-engraveable element has a thermally crosslinked laser-engraveable layer containing a crosslinked elastomeric fluoropolymer and a fluoro-functionalized near-infrared radiation absorber. The crosslinked fluoropolymer has a glass transition temperature of less than and including 0° C. and the crosslinked laser-engraveable layer is formed from a reactive fluoropolymer composition comprising a reactive fluoropolymer, the fluoro-functionalized near-infrared radiation absorber, and a compound that causes crosslinking of the reactive fluoropolymer during thermal curing. The reactive fluoropolymer can have a reactive group selected from the group consisting of: poly(tetrafluoroethylene oxide-co-difluoromethylene oxide) α,ω-diol bis(2,3-dihydroxypropyl ether), poly(tetrafluoroethylene oxide-co-difluoromethylene oxide) α,ω-diol, ethoxylated poly(tetrafluoroethylene oxide-co-difluoromethylene oxide) α,ω-diol, and a multifuncational (meth)acrylate end-functionalized derivative of one of such compounds.

    摘要翻译： 激光雕刻层用于激光雕刻元件以提供浮雕图像。 所得到的激光雕刻元件可以采取各种形式，并且可以用于以成像方式将各种油墨应用于接收器材料。 可激光雕刻元件具有含有交联的弹性体含氟聚合物和氟官能化的近红外辐射吸收体的热交联激光可雕刻层。 交联的含氟聚合物的玻璃化转变温度低于0℃，交联的可激光雕刻层由包含反应性氟聚合物，氟官能化的近红外辐射吸收剂的反应性含氟聚合物组合物形成， 导致热固化期间反应性含氟聚合物的交联。 反应性含氟聚合物可以具有选自：聚（四氟乙烯氧化物 - 共二氧化环氧乙烷）α，ω-二醇双（2,3-二羟丙基醚），聚（四氟乙烯氧化物 - 共二氟亚甲基氧化物） α，ω-二醇，乙氧基化聚（四氟乙烯氧化物 - 共二氧环氧乙烷）α，ω-二醇和这些化合物之一的多官能（甲基）丙烯酸酯末端官能化衍生物。

    LASER-ENGRAVEABLE ELEMENTS
    4.
    发明申请
    LASER-ENGRAVEABLE ELEMENTS 有权
    激光可雕刻的元素

    公开(公告)号：US20150375446A1

    公开(公告)日：2015-12-31

    申请号：US14848554

    申请日：2015-09-09

    申请人： Eastman Kodak Company

    发明人： Anna C. Greene ,  Christine Joanne Landry-Coltrain ,  Steven Evans

    IPC分类号： B29C59/16 ,  C08K9/04

    CPC分类号： B29C59/16 ,  B29K2027/18 ,  B29L2007/001 ,  B41C1/05 ,  B82Y30/00 ,  C08K9/04

    摘要： A laser-engraveable layer is used in a laser-engraveable element to provide relief images. The resulting laser-engraved elements can take various forms and can be used to apply various inks to receiver materials in an imagewise fashion. The laser-engraveable element has a thermally crosslinked laser-engraveable layer containing a crosslinked elastomeric fluoropolymer and a fluoro-functionalized near-infrared radiation absorber. The crosslinked fluoropolymer has a glass transition temperature of less than and including 0° C. and the crosslinked laser-engraveable layer is formed from a reactive fluoropolymer composition comprising a reactive fluoropolymer, the fluoro-functionalized near-infrared radiation absorber, and a compound that causes crosslinking of the reactive fluoropolymer during thermal curing. The reactive fluoropolymer can have a reactive group selected from the group consisting of: poly(tetrafluoroethylene oxide-co-difluoromethylene oxide) α,ω-diol bis(2,3-dihydroxypropyl ether), poly(tetrafluoroethylene oxide-co-dilfluoromethylene oxide) α,ω-diol, ethoxylated poly(tetrafluoroethylene oxide-co-difluoromethylene oxide) α,ω-diol, and a multifuncational (meth)acrylate end-functionalized derivative of one of such compounds.

    摘要翻译： 激光雕刻层用于激光雕刻元件以提供浮雕图像。 所得到的激光雕刻元件可以采取各种形式，并且可以用于以成像方式将各种油墨应用于接收器材料。 可激光雕刻元件具有含有交联的弹性体氟聚合物和氟官能化的近红外辐射吸收体的热交联激光可雕刻层。 交联的含氟聚合物的玻璃化转变温度低于0℃，交联的可激光雕刻层由包含反应性氟聚合物，氟官能化的近红外辐射吸收剂的反应性含氟聚合物组合物形成， 导致热固化期间反应性含氟聚合物的交联。 反应性含氟聚合物可以具有选自：聚（四氟乙烯氧化物 - 共二氧化环氧乙烷）α，ω-二醇双（2,3-二羟基丙基醚），聚（四氟乙烯氧化物 - 共 - 二氟环氧乙烷） α，ω-二醇，乙氧基化聚（四氟乙烯氧化物 - 共二氧环氧乙烷）α，ω-二醇和这些化合物之一的多官能（甲基）丙烯酸酯末端官能化衍生物。

    Preparation of patterned or electrically-conductive articles
    7.
    发明授权
    Preparation of patterned or electrically-conductive articles 有权
    图案化或导电制品的制备

    公开(公告)号：US09505942B2

    公开(公告)日：2016-11-29

    申请号：US14311453

    申请日：2014-06-23

    申请人： Eastman Kodak Company

    发明人： Christine Joanne Landry-Coltrain ,  Charles Leo Bauer ,  James Stephen Honan ,  Brian Andrew Schell ,  Richard Thomas Kane

    IPC分类号： C09D113/02 ,  C09D5/00 ,  C23C18/16

    CPC分类号： C09D113/02 ,  C09D5/002 ,  C09D5/24 ,  C23C18/1608 ,  C23C18/1641 ,  Y10T428/24917

    摘要： A first polymer latex and second polymer latex can be mixed to form a dried primer layer on a substrate to adhere patterned materials having fine lines. The first polymer latex comprises a first polymer and a first surfactant such that a dried coating of the first polymer latex has a surface polarity of at least 50%. The second polymer latex comprises a second polymer and a second surfactant such that a dried coating of the second polymer latex has a surface polarity of less than or equal to 27%. Moreover, a dried coating of the mixture has a surface polarity of at least 15% and up to and including 50%. Primed substrates are useful for preparing electrically-conductive articles having electrically-conductive fine lines directly on a dried primer layer by applying a patterned material to a substrate. Such articles can be used as touch screen displays in various electronic devices.

    摘要翻译： 可以将第一聚合物胶乳和第二聚合物胶乳混合以在基材上形成干燥的底漆层以粘附具有细线的图案化材料。 第一聚合物胶乳包括第一聚合物和第一表面活性剂，使得第一聚合物胶乳的干燥涂层具有至少50％的表面极性。 第二聚合物胶乳包含第二聚合物和第二表面活性剂，使得第二聚合物胶乳的干燥涂层的表面极性小于或等于27％。 此外，该混合物的干燥涂层的表面极性至少为15％且至多且包括50％。 引发底物可用于通过将图案化材料施加到基底上而直接在干底漆层上制备具有导电细线的导电制品。 这些物品可以用作各种电子设备中的触摸屏显示器。

    PHOTOCURABLE COMPOSITIONS WITH DISPERSED CARBON-COATED METAL PARTICLES
    8.
    发明申请
    PHOTOCURABLE COMPOSITIONS WITH DISPERSED CARBON-COATED METAL PARTICLES 有权
    具有分散涂层的金属颗粒的光致抗蚀剂组合物

    公开(公告)号：US20160108269A1

    公开(公告)日：2016-04-21

    申请号：US14514492

    申请日：2014-10-15

    申请人： Eastman Kodak Company

    发明人： KAREN M. KOSYDAR ,  Gary L. Slater ,  Mary Christine Brick ,  Christine Joanne Landry-Coltrain

    IPC分类号： C09D11/52 ,  C09D11/102

    CPC分类号： C09D11/52 ,  C09D11/037 ,  C09D11/101 ,  C09D11/102 ,  C09D11/104

    摘要： A non-aqueous photocurable composition contains dispersed carbon-coated metal particles in an amount of at least 10 weight %, and the dispersed carbon-coated metal particles have a median diameter of less than 0.6 μm. These particles are dispersed with a particle dispersing agent that has a weight average molecular weight (Mw) of at least 2,000 and up to and including 100,000 and comprises nitrogen-containing units. Such compositions include an organic diluent as well as suitable photocurable components that can be used for example in acid-catalyzed or free radical chemistries. When the non-aqueous photocurable composition contains up to and including 25 weight % of the dispersed carbon-coated metal particles, it exhibits no visual settling when subjected to a settling test of at least 24 hours at 20° C. The non-aqueous photocurable compositions can be used to provide photocured metallic patterns for various devices that have a touch screen display.

    摘要翻译： 非水性光固化性组合物含有至少10重量％的分散的碳涂覆的金属颗粒，分散的碳涂覆的金属颗粒的中值粒径小于0.6μm。 这些颗粒用重均分子量（Mw）至少为2,000并且至多包括100,000并且包括含氮单元的颗粒分散剂分散。 这样的组合物包括有机稀释剂以及可用于例如酸催化或自由基化学物质中的合适的可光固化组分。 当非水性光固化剂组合物含有至多并且包含25重量％的分散的碳涂覆的金属颗粒时，当在20℃进行至少24小时的沉降试验时，其表现出没有视觉沉降。非水可光固化 可以使用组合物为具有触摸屏显示器的各种装置提供光固化金属图案。