公开(公告)号：US09079174B2

公开(公告)日：2015-07-14

申请号：US13723616

申请日：2012-12-21

Applicant: Total Raffinage Marketing ,  IFP Energies Nouvelles

Inventor： Laurent Simon ,  Bertrand Guichard ,  Gregory Lapisardi ,  Hugues Dulot ,  Valentina De Grandi ,  Delphine Minoux ,  Jean Pierre Dath

IPC: C10G47/02 ,  C10G47/18 ,  C10G47/20 ,  B01J31/04 ,  B01J37/00 ,  B01J29/076 ,  B01J31/34 ,  B01J37/20 ,  B01J37/26 ,  B01J37/28 ,  B01J37/02 ,  B01J29/16 ,  B01J29/78 ,  B01J29/064 ,  B01J31/02 ,  B01J35/00 ,  B01J27/188 ,  B01J27/19

CPC classification number: B01J31/34 ,  B01J27/188 ,  B01J27/19 ,  B01J29/064 ,  B01J29/076 ,  B01J29/166 ,  B01J29/7815 ,  B01J31/0209 ,  B01J31/04 ,  B01J35/002 ,  B01J37/0009 ,  B01J37/0203 ,  B01J37/0205 ,  B01J37/20 ,  B01J37/26 ,  B01J37/28 ,  B01J2229/42 ,  C10G47/20

Abstract: The invention concerns a catalyst containing a support comprising at least one binder and at least one zeolite having at least one series of channels the opening of which is defined by a ring containing 12 oxygen atoms, said catalyst comprising phosphorus, at least one C1-C4 dialkyl succinate, acetic acid and a hydrodehydrogenating function comprising at least one element from group VI B and at least one element from group VIII, the Raman spectrum of the catalyst comprising bands at 990 and/or 974 cm-1, characteristic of at least one Keggin heteropolyanion, the characteristic bands of said succinate and the characteristic principal band of acetic acid at 896 cm-1. The invention also concerns the process for preparing the catalyst and its use in hydroconversion.

Abstract translation: 本发明涉及一种含有载体的催化剂，其包括至少一种粘合剂和至少一种沸石，该沸石具有至少一个通道，其开口由含有12个氧原子的环所限定，所述催化剂包含磷，至少一个C 1 -C 4 琥珀酸二烷基酯，乙酸和脱氢功能，其包含来自VIB族的至少一种元素和来自VIII族的至少一种元素，催化剂的拉曼光谱包括990和/或974cm -1处的带，其特征在于至少一种 Keggin杂多阴离子，所述琥珀酸的特征带和896cm-1乙酸的特征主带。 本发明还涉及制备催化剂的方法及其在加氢转化中的用途。

公开(公告)号：US10711206B2

公开(公告)日：2020-07-14

申请号：US16169341

申请日：2018-10-24

Applicant: IFP Energies Nouvelles

Inventor： Hugues Dulot ,  Aline Grezaud ,  Jean-Philippe Heraud

IPC: C10G49/24 ,  C10G65/12 ,  C10G45/38 ,  C10G45/52 ,  C10G45/54 ,  C10G2/00 ,  C10L1/08 ,  B01J23/883 ,  B01J37/18 ,  C10G45/62 ,  C10G45/64 ,  B01J23/42 ,  C10G47/18 ,  C10G45/08 ,  B01J21/12

Abstract: Method for starting up a method for producing kerosene and diesel fuel from hydrocarbon compounds produced by Fischer-Tropsch synthesis.The start-up method employs catalytic reaction of Fischer-Tropsch synthesis with a synthesis gas for producing a heavy hydrocarbon fraction and a light hydrocarbon fraction, a reduction (RE) reducing a hydrotreatment catalyst by ensuring contact with a gas comprising hydrogen, bringing the heavy hydrocarbon fraction into contact with the hydrotreatment catalyst (DM). During the step for ensuring contact, the temperature (TEMP) of the catalyst is increased to a temperature of between 260° C. and 360° C. Then, (TR) bringing a mixture comprising the heavy hydrocarbon fraction and the light hydrocarbon fraction into contact with the hydrotreatment catalyst is carried out.

公开(公告)号：US09249364B2

公开(公告)日：2016-02-02

申请号：US13767072

申请日：2013-02-14

Applicant: IFP ENERGIES NOUVELLES

Inventor： Frédéric Feugnet ,  Francois Hugues ,  Natacha Touchais ,  Hugues Dulot ,  Annick Pucci

IPC: C10G69/12 ,  C07C1/00 ,  C07C2/12 ,  C10G11/04 ,  C10G11/05

CPC classification number: C10G69/126 ,  C07C1/00 ,  C07C2/12 ,  C10G11/04 ,  C10G11/05

Abstract: The present invention describes a process for converting a heavy feed which is flexible for the production of propylene, gasoline and middle distillate.The process uses a catalytic cracking unit and a unit for the oligomerization of C4 to C9 olefins. The process of the invention includes selective hydrogenation of the unrefined gasoline cut obtained from the catalytic cracking unit and separation between a light gasoline cut and a heavy gasoline cut, the light gasoline being directed to the oligomerization unit.

Abstract translation: 本发明描述了用于转化可用于生产丙烯，汽油和中间馏分的柔性的重料的方法。 该方法使用催化裂化装置和C4至C9烯烃低聚单元。 本发明的方法包括从催化裂化装置获得的未精制汽油馏分的选择氢化和轻汽油馏分与重汽油馏分之间的分离，轻汽油被引导至低聚单元。

公开(公告)号：US09546329B2

公开(公告)日：2017-01-17

申请号：US13661183

申请日：2012-10-26

Applicant: ENI S.P.A. ,  IFP ENERGIES NOUVELLES

Inventor： Christophe Bouchy ,  Aline Grezaud ,  Jean Philippe Heraud ,  Hugues Dulot ,  Vincenzo Calemma

IPC: C10G65/12 ,  C10G65/04 ,  B01J21/12 ,  B01J23/42 ,  B01J35/00 ,  B01J35/10 ,  B01J37/00 ,  B01J23/44

CPC classification number: C10G65/12 ,  B01J21/12 ,  B01J23/42 ,  B01J23/44 ,  B01J35/0066 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1061 ,  B01J35/108 ,  B01J37/0009 ,  C10G65/043 ,  C10G2300/1022 ,  C10G2300/1081 ,  C10G2300/202 ,  C10G2300/4006 ,  C10G2300/4012 ,  C10G2300/4018 ,  C10G2300/42 ,  C10G2400/04 ,  C10G2400/06 ,  C10G2400/08

Abstract: A process for the production of middle distillates from a paraffinic feedstock produced by Fischer-Tropsch synthesis comprising a limited content of molecules containing at least one oxygen atom. In the process, the feedstock is subjected to at least one hydrocracking/hydroisomerization stage in the presence of a hydrogen stream also containing a limited atomic oxygen content.

Abstract translation: 由费 - 托合成生产的石蜡原料生产中间馏分的方法，其包含含有至少一个氧原子的有限含量的分子。 在该方法中，原料在还含有有限原子氧含量的氢气流的存在下进行至少一个加氢裂化/加氢异构化阶段。

公开(公告)号：US09353320B2

公开(公告)日：2016-05-31

申请号：US13860850

申请日：2013-04-11

Applicant: ENI S.p.A. ,  IFP Energies nouvelles

Inventor： Aline Grezaud ,  Jean Philippe Heraud ,  Hugues Dulot ,  Christophe Bouchy ,  Vincenzo Calemma

IPC: C10G65/12 ,  C07C1/04 ,  C07C1/12 ,  B01J21/12 ,  B01J23/42 ,  B01J23/44 ,  B01J23/75 ,  B01J23/755 ,  B01J23/882 ,  B01J23/883 ,  B01J23/888 ,  B01J35/00 ,  B01J35/10 ,  B01J37/00 ,  B01J37/02 ,  C10G65/02 ,  C07C27/06 ,  C07C27/08 ,  C10G45/00 ,  C10G45/02

CPC classification number: C10G65/12 ,  B01J21/12 ,  B01J23/42 ,  B01J23/44 ,  B01J23/75 ,  B01J23/755 ,  B01J23/882 ,  B01J23/883 ,  B01J23/888 ,  B01J23/8885 ,  B01J35/0026 ,  B01J35/0066 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1061 ,  B01J37/0009 ,  B01J37/0201 ,  C07C1/0495 ,  C07C1/12 ,  Y02P20/52 ,  C07C9/04

Abstract: A method for producing middle distillates from a feedstock produced by Fischer-Tropsch synthesis and containing oxygenated compounds, including: a) a step of bringing the feedstock into contact with a hydrotreating catalyst allowing the methanation of the CO and CO2 contained in the feedstock or originating from the decomposition of the oxygenated compounds present in the feedstock, b) a step of hydroisomerization/hydrocracking of at least a part of the liquid and gaseous effluent originating from step a), in the presence of a hydroisomerization/hydrocracking catalyst, c) a step of gas/liquid separation of the effluent originating from step b) into a gaseous fraction comprising predominantly hydrogen and a hydroisomerized/hydrocracked liquid fraction, d) a step of fractionation of the liquid fraction separated in step c) to obtain at least one fraction of middle distillate, in which the hydrogen in step a) is obtained from the gaseous fraction separated in step c).

Abstract translation: 由费 - 托合成生产并含有氧化化合物的原料生产中间馏分的方法，包括：a）使原料与加氢处理催化剂接触的步骤，允许原料中所含的CO和CO 2的甲烷化或起始 来自原料中存在的含氧化合物的分解，b）在加氢异构化/加氢裂化催化剂存在下，来自步骤a）的至少一部分液体和气态流出物的加氢异构化/加氢裂化步骤，c） 将来自步骤b）的流出物气/液分离成主要包含氢气和加氢异构化/加氢裂化的液体馏分的气体馏分的步骤，d）在步骤c）中分离的液体馏分的分级步骤，以获得至少一个馏分 的中间馏分，其中步骤a）中的氢气是从步骤c）中分离的气体馏分得到的。

公开(公告)号：US09273255B2

公开(公告)日：2016-03-01

申请号：US13859789

申请日：2013-04-10

Applicant: ENI S.p.A. ,  IFP Energies nouvelles

Inventor： Jean-Philippe Heraud ,  Aline Grezaud ,  Hugues Dulot ,  Christophe Bouchy ,  Vincenzo Calemma

IPC: C10G65/12 ,  C07C5/02 ,  C07C1/04 ,  C07C1/12 ,  B01J21/12 ,  B01J23/46 ,  B01J23/755 ,  B01J23/882 ,  B01J23/883 ,  B01J23/888 ,  B01J35/00 ,  B01J35/10 ,  B01J37/00 ,  B01J37/02 ,  C10G65/02 ,  C07C27/06 ,  C07C27/08 ,  C10G45/00 ,  C10G45/02

CPC classification number: C10G65/12 ,  B01J21/12 ,  B01J23/462 ,  B01J23/464 ,  B01J23/755 ,  B01J23/882 ,  B01J23/883 ,  B01J23/888 ,  B01J23/8885 ,  B01J35/0026 ,  B01J35/0066 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1061 ,  B01J37/0009 ,  B01J37/0201 ,  C07C1/0465 ,  C07C1/12 ,  C07C5/02 ,  C07C9/04

Abstract: Production of middle distillates from a feedstock produced by Fischer-Tropsch synthesis and containing oxygenated compounds:a) catalytic hydrotreating; b) hydroisomerization/hydrocracking at least a part of liquid and gaseous effluent originating from a); c) gas/liquid separation of the stream from b) into a gaseous fraction comprising predominantly hydrogen, a hydroisomerized/hydrocracked organic liquid fraction and an aqueous fraction; d) fractionation of the organic liquid fraction in c) to obtain at least one fraction of middle distillates; and e) catalytic methanation of CO and CO2 on at least a part of said gaseous fraction in c) before hydrotreating a), and/or on at least a part of the liquid and gaseous effluent originating from a) in which the hydrogen in a) is obtained at least partly from the gaseous fraction separated in c).

Abstract translation: 由费 - 托合成生产含有氧化合物的原料生产中间馏分：a）催化加氢处理; b）加氢异构化/加氢裂化来自a）的至少一部分液体和气态流出物; c）将气流/液体从b）分离成主要包含氢气，加氢异构化/加氢裂化的有机液体馏分和水性馏分的气体馏分; d）有机液体馏分的分馏，c）得到至少一部分中间馏分; 和e）在加氢处理a）之前和/或在至少一部分源自a）的液体和气态流出物中，在c）中的至少一部分所述气态馏分中CO和CO 2的催化甲烷化，其中a） ）至少部分地由在c）中分离的气态馏分获得。