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1.发明授权Oxide-based superconductor, a process for preparing the same and a wire material of comprising the same 失效基于氧化物的超导体，其制备方法和包含该超导体的线材
公开(公告)号：US5545610A
公开(公告)日：1996-08-13
申请号：US115056
申请日：1993-09-02
申请人： Kazutoshi Higashiyama , Toshiya Doi , Takesi Ozawa , Seizi Takeuchi , Tomoichi Kamo , Shinpei Matsuda , Yutaka Yoshida
发明人： Kazutoshi Higashiyama , Toshiya Doi , Takesi Ozawa , Seizi Takeuchi , Tomoichi Kamo , Shinpei Matsuda , Yutaka Yoshida
CPC分类号： H01L39/248 , Y10S428/93 , Y10S505/704 , Y10S505/733 , Y10S505/74 , Y10S505/783
摘要： An oxide-based superconductor ccmprising Tl, Pb, Sr, Ca and Cu or Tl, Pb, Ba, Sr, Ca and Cu, prepared by subjecting a low melting point composition comprising the superconductor-constituting elements and a solid composition comprising the superconductor-constituting elements, prepared in advance, to reaction under melting conditions for the low melting point composition, has distinguished current pass characteristics in a high magnetic field due to improvement of electric contact among grains through reduction of non-superconductor phase, increase in crystal grain sizes (reduction of crystal boundaries), orientation of crystal and cleaning of crystal boundaries.
摘要翻译： 通过对包含超导体构成元素的低熔点组合物和包含超导体构成元素的固体组合物进行处理而制备的通过对包含超导体构成元素的低熔点组合物进行制备的Tl，Pb，Sr，Ca和Cu或Tl，Pb，Ba，Sr，Ca和Cu的氧化物基超导体， 预先制备的用于低熔点组合物的熔融条件下的反应的组成元素由于非超导体相的还原而改善晶粒之间的电接触而导致高磁场中的电流通过特性，晶粒尺寸的增加 （晶体边界的减少），晶体取向和晶界的清洗。
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2.发明授权
公开(公告)号：US5508256A
公开(公告)日：1996-04-16
申请号：US264767
申请日：1994-06-23
申请人： Teruo Kumagai , Tsuneyuki Kanai , Atsuko Soeta , Takaaki Suzuki , Kazutoshi Higashiyama , Tomoichi Kamo , Shinpei Matsuda , Kunihiro Maeda , Akira Okayama , Hideyo Kodama , Akira Yoshinari , Yoshimi Yanai
发明人： Teruo Kumagai , Tsuneyuki Kanai , Atsuko Soeta , Takaaki Suzuki , Kazutoshi Higashiyama , Tomoichi Kamo , Shinpei Matsuda , Kunihiro Maeda , Akira Okayama , Hideyo Kodama , Akira Yoshinari , Yoshimi Yanai
CPC分类号： H01L39/248 , C30B11/00 , C30B13/00 , C30B29/225 , H01L39/126 , H01L39/2419 , Y10S505/729 , Y10S505/737 , Y10S505/74 , Y10S505/776 , Y10S505/78 , Y10S505/782
摘要： A method of producing a high-temperature oxide superconducting material, which comprises the steps of (a) preparing a material corresponding to an oxide superconductor of the perovskite type structure consisting essentially of a first member selected from the group consisting yttrium, lanthanoids, thallium and bismuth; at least one alkaline earth metal; copper; and oxygen and (b) heating the material in the presence of an alkali metal selected from the group consisting of potassium, sodium, rubidium and cesium to a temperature around the melting point of the alkali metal or to a higher temperature for a time sufficient to effect grain growth in the superconductor material, thereby to produce the superconductor containing the alkali metal in an amount not larger than 4 mole % based on the first member.
摘要翻译： 一种生产高温氧化物超导材料的方法，其包括以下步骤：（a）制备相应于钙钛矿型结构的氧化物超导体的材料，所述氧化物超导体主要由选自钇，镧系元素，铊和 铋; 至少一种碱土金属; 铜; 和氧和（b）在选自钾，钠，铷和铯的碱金属存在下将材料加热到约碱金属熔点的温度或更高的温度，持续足够的时间 在超导体材料中产生晶粒生长，由此产生含有碱金属的超导体，其量不得大于基于第一成员的4摩尔％。
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公开(公告)号：US06316391B1
公开(公告)日：2001-11-13
申请号：US09536043
申请日：2000-03-27
IPC分类号： H01B1200
CPC分类号： H01L39/2454 , H01F6/06 , H01L39/143
摘要： The present invention provides superconductors capable of being used at temperatures to which the superconductor can be cooled in liquid nitrogen and of carrying current in a high critical current density in a magnetic field, and superconducting apparatuses employing the superconductors and more advantageous in costs than the conventional superconducting apparatuses. A superconducting wire is formed by combining a metallic body of a cubic aggregate structure and an oxide superconducting substance. The present invention provides superconductors, superconducting wires, superconducting magnets and applied superconducting apparatuses having a high superconducting critical current density. The applied super conducting apparatuses employing the superconductors or the superconducting wires in accordance with the present invention are able to operate when cooled in liquid nitrogen-and can be manufactured at costs lower than those of the conventional superconducting apparatuses.
摘要翻译： 本发明提供了能够在超导体可以在液氮中冷却并在磁场中以高临界电流密度承载电流的温度下使用的超导体，以及使用超导体的超导装置，并且比常规的成本更有利 超导装置。 通过组合立方体聚集体结构的金属体和氧化物超导物质来形成超导线。 本发明提供具有高超导临界电流密度的超导体，超导线，超导磁体和应用的超导装置。 使用根据本发明的超导体或超导线的应用的超导传导装置能够在液氮中冷却时操作，并且可以以比常规超导装置的成本低的成本制造。
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4.发明申请公开(公告)号：US20050031930A1
公开(公告)日：2005-02-10
申请号：US10921268
申请日：2004-08-19
CPC分类号： H01M8/1027 , C08G75/23 , C08G2650/02 , C08J5/2256 , C08J2381/06 , C08L81/06 , H01M4/881 , H01M8/1032 , H01M2300/0082 , Y02P70/56
摘要： An object of the present invention is to provide a highly durable solid polymer electrolyte that has a deterioration resistance equal to or higher than that of the fluorine-containing solid polymer electrolytes or a deterioration resistance sufficient for practical purposes, and can be produced at a low cost. According to the present invention, there is provided a solid polymer electrolyte comprising a polyether ether sulfone that is used as an electrolyte and has sulfoalkyl groups bonded to its aromatic rings and represented by the general formula —(CH2)n—SO3H.
摘要翻译： 本发明的目的是提供一种具有等于或高于含氟固体聚合物电解质的耐劣化性的耐久性高的固体聚合物电解质或用于实际目的的耐劣化性，并且可以在低 成本。 根据本发明，提供了一种固体聚合物电解质，其包含聚醚醚砜，其用作电解质并具有与其芳环键合且由通式 - （CH 2）n -SO 3 H表示的磺基烷基。
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5.发明授权Solid polymer electrolyte, a membrane using thereof, a solution for coating electrode catalyst, a membrane/electrode assembly, and a fuel cell 有权固体聚合物电解质，使用其的膜，用于涂覆电极催化剂的溶液，膜/电极组件和燃料电池公开(公告)号：US07553574B2
公开(公告)日：2009-06-30
申请号：US11176373
申请日：2005-07-08
CPC分类号： C08J5/2256 , C08J2371/12 , C08J2381/04 , C08J2381/06 , H01M4/8605 , H01M4/92 , H01M8/1004 , H01M8/1025 , H01M8/1027 , H01M8/1032 , H01M2300/0082 , Y02P70/56
摘要： A solid polymer electrolyte is made up of a polymer compound having a hydrocarbon aromatic group in the backbone thereof and including a side chain expressed by FORMULA 1: CH2nSO3H FORMULA 1 wherein “n” is 1, 2, 3, 4, 5, or 6. The solid polymer electrolyte may be incorporated into a membrane and may be used in a solution for covering an electrode catalyst.
摘要翻译： 固体聚合物电解质由其主链中具有烃芳族基团的高分子化合物构成，并且包括由式1表示的侧链：<？在线公式描述=“在线式”末端=“铅” ？>
CH2
nSO3H FORMULA 1 <？in-line-formula description =“In-line Formulas”end =“tail”？>其中“ n“为1,2,3,4,5或6.固体聚合物电解质可以结合到膜中，并且可以用于覆盖电极催化剂的溶液中。
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6.发明申请Solid polymer electrolyte, a membrane using thereof, a solution for coating electrode catalyst, a membrane/electrode assembly, and a fuel cell 有权固体聚合物电解质，使用其的膜，用于涂覆电极催化剂的溶液，膜/电极组件和燃料电池公开(公告)号：US20050271922A1
公开(公告)日：2005-12-08
申请号：US11176373
申请日：2005-07-08
IPC分类号： C08J5/18 , C08G65/38 , C08G65/40 , C08G75/02 , C08G75/20 , C08G75/23 , C08J5/22 , H01B1/06 , H01B1/12 , H01M4/86 , H01M4/88 , H01M4/92 , H01M8/02 , H01M8/10
CPC分类号： C08J5/2256 , C08J2371/12 , C08J2381/04 , C08J2381/06 , H01M4/8605 , H01M4/92 , H01M8/1004 , H01M8/1025 , H01M8/1027 , H01M8/1032 , H01M2300/0082 , Y02P70/56
摘要： A solid polymer electrolyte is made up of a polymer compound having a hydrocarbon aromatic group in the backbone thereof and including a side chain expressed by FORMULA 1: CH2nSO3H FORMULA 1 wherein “n” is 1, 2, 3, 4, 5, or 6. The solid polymer electrolyte may be incorporated into a membrane and may be used in a solution for covering an electrode catalyst.
摘要翻译： 固体聚合物电解质由其主链中具有烃芳族基团的高分子化合物构成，并且包括由式1表示的侧链：<？在线公式描述=“在线式”末端=“铅” “>
CH
3 1 <？in-line-formula description =“In-line formula”end =“tail”？>其中“n”是1,2,3,4,5或6.固体聚合物电解质可以结合到 膜，并且可以用于覆盖电极催化剂的溶液中。
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7.发明授权公开(公告)号：US07541107B2
公开(公告)日：2009-06-02
申请号：US10921268
申请日：2004-08-19
CPC分类号： H01M8/1027 , C08G75/23 , C08G2650/02 , C08J5/2256 , C08J2381/06 , C08L81/06 , H01M4/881 , H01M8/1032 , H01M2300/0082 , Y02P70/56
摘要： An object of the present invention is to provide a highly durable solid polymer electrolyte that has a deterioration resistance equal to or higher than that of the fluorine-containing solid polymer electrolytes or a deterioration resistance sufficient for practical purposes, and can be produced at a low cost. According to the present invention, there is provided a solid polymer electrolyte comprising a polyether ether sulfone that is used as an electrolyte and has sulfoalkyl groups bonded to its aromatic rings and represented by the general formula —(CH2)n—SO3H.
摘要翻译： 本发明的目的是提供一种具有等于或高于含氟固体聚合物电解质的耐劣化性的耐久性高的固体聚合物电解质或用于实际目的的耐劣化性，并且可以在低 成本。 根据本发明，提供了一种固体聚合物电解质，其包含聚醚醚砜，其用作电解质并具有与其芳环键合且由通式 - （CH 2）n -SO 3 H表示的磺基烷基。
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公开(公告)号：US20060292417A1
公开(公告)日：2006-12-28
申请号：US11176397
申请日：2005-07-08
IPC分类号： H01M8/10
CPC分类号： C08J5/2256 , C08J2371/12 , C08J2381/04 , C08J2381/06 , H01M4/8605 , H01M4/92 , H01M8/1004 , H01M8/1025 , H01M8/1027 , H01M8/1032 , H01M2300/0082 , Y02P70/56
摘要： A solid polymer electrolyte is made up of a polymer compound having a hydrocarbon aromatic group in the backbone thereof and including a side chain expressed by FORMULA 1: wherein “n” is 1, 2, 3, 4, 5, or 6. The solid polymer electrolyte may be incorporated into a membrane and may be used in a solution for covering an electrode catalyst.
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9.发明授权公开(公告)号：US06893764B2
公开(公告)日：2005-05-17
申请号：US10208094
申请日：2002-07-31
CPC分类号： H01M8/1027 , C08G75/23 , C08G2650/02 , C08J5/2256 , C08J2381/06 , C08L81/06 , H01M4/881 , H01M8/1032 , H01M2300/0082 , Y02P70/56
摘要： An object of the present invention is to provide a highly durable solid polymer electrolyte that has a deterioration resistance equal to or higher than that of the fluorine-containing solid polymer electrolytes or a deterioration resistance sufficient for practical purposes, and can be produced at a low cost. According to the present invention, there is provided a solid polymer electrolyte comprising a polyether ether sulfone that is used as a electrolyte and has sulfoalkyl groups bonded to its aromatic rings and represented by the general formula —(CH2)n—SO3H.
摘要翻译： 本发明的目的是提供一种具有等于或高于含氟固体聚合物电解质的耐劣化性的耐久性高的固体聚合物电解质或用于实际目的的耐劣化性，并且可以在低 成本。 根据本发明，提供一种固体聚合物电解质，其包含聚醚醚砜，其用作电解质并具有与其芳环键合的磺基烷基，并由以下通式表示： - （CH 2） ）N 3 -SO 3。
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公开(公告)号：US06890673B2
公开(公告)日：2005-05-10
申请号：US10068837
申请日：2002-02-11
申请人： Kazutoshi Higashiyama , Masahiro Komachiya , Kiyoshi Hiyama , Tomoichi Kamo , Noriyuki Imada , Tetsurou Okano , Hiroyuki Kaku
发明人： Kazutoshi Higashiyama , Masahiro Komachiya , Kiyoshi Hiyama , Tomoichi Kamo , Noriyuki Imada , Tetsurou Okano , Hiroyuki Kaku
IPC分类号： C01B3/02 , B01J19/00 , C01B3/32 , C01B3/34 , C01B3/38 , G05B5/01 , H01M8/04 , H01M8/06 , H01M8/10
CPC分类号： B01J19/0013 , B01J2219/00063 , B01J2219/00164 , B01J2219/00198 , B01J2219/00202 , B01J2219/00213 , B01J2219/00231 , C01B3/32 , C01B3/323 , C01B3/34 , C01B3/382 , C01B3/386 , C01B2203/0233 , C01B2203/0244 , C01B2203/0261 , C01B2203/0283 , C01B2203/044 , C01B2203/047 , C01B2203/066 , C01B2203/0811 , C01B2203/0833 , C01B2203/0844 , C01B2203/085 , C01B2203/1052 , C01B2203/1064 , C01B2203/1223 , C01B2203/1241 , C01B2203/1258 , C01B2203/127 , C01B2203/1276 , C01B2203/1288 , C01B2203/141 , C01B2203/142 , C01B2203/16 , C01B2203/1604 , C01B2203/1619 , C01B2203/1628 , C01B2203/1685 , C01B2203/169 , C01B2203/1695 , C01B2203/82 , G05B5/01 , H01M8/0612 , H01M8/0662
摘要： For the stabilization of the reaction, especially, for maintaining reaction temperature, the feedback control by the feedback unit is performed for to the supply of air (, oxygen, or oxidizing agent), whereas other materials are supplied by the open-loop control according to the instruction of the flow selection unit which indicates a preset value depending on the required hydrogen production volume. In addition, the continuous flow setting unit capable of changing the flow continuously is employed for the supply system of the air, whereas the flow control of the other materials is performed by use of the discrete flow setting units each of which provides the discretized flow by use of the on-off combination of two or more on-off valves.
摘要翻译： 为了稳定反应，特别是为了维持反应温度，反馈单元的反馈控制被执行用于供应空气（，氧气或氧化剂），而其他材料通过开环控制提供，根据 涉及流量选择单元的指示，其指示取决于所需氢气产生量的预设值。 此外，能够连续地改变流量的连续流量设定单元用于空气的供给系统，而其他材料的流量控制通过使用离散流量设定单元进行，每个离散流量设定单元通过离散流量设定单元提供离散流量 使用两个或多个开关阀的开 - 关组合。
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