摘要:
Disclosed are: an exhaust gas purification catalyst which is capable of achieving a higher NOx removal ratio in comparison to conventional exhaust gas purification catalysts; and an exhaust gas purification apparatus which uses the exhaust gas purification catalyst. An exhaust gas purification catalyst comprises: a first catalyst layer that contains Pt and has NOx capturing ability; a second catalyst layer that contains a zeolite that has HC capturing ability; and an intermediate layer that is provided between the first catalyst layer and the second catalyst layer and has NOx reducing ability. The intermediate layer contains, as a main component, at least one oxide selected from the group consisting of CeO2, ZrO2 and complex oxides containing Ce and Zr, and also contains one or both of Rh and Pd. Also specifically disclosed is an exhaust gas purification apparatus which uses the exhaust gas purification catalyst.
摘要:
Provided is a fuel reforming device, which can produce and supply a reformed gas in quick response to a demand for the reformed gas and which is so inexpensive as can be suitably mounted on a vehicle. The fuel reforming device feeds a material to a reforming catalyst and produces the reformed gas under a pressure higher than the atmospheric pressure. The fuel reforming device comprises a material supply means for supplying the material to the reforming catalyst, a reforming means having the reforming catalyst, for reforming the material supplied from the material supply means, to produce the reformed gas, and a run control means for controlling the run of the fuel reforming device. The run control means includes a stop mode, in which the drive of the material supply means is stopped to stop the production of the reformed gas, a reform mode, in which the material supply means is driven to produce the reformed gas, and a standby mode, in which the material supply means is driven and in which the temperature of the reforming catalyst is held within a predetermined range while producing the reformed gas as little as possible, so that the standby mode can shift instantly to the reform mode.
摘要:
An exhaust gas purification system equipped, from an upstream side toward downstream side through which an exhaust gas flows, with a plasma reactor and a catalyst unit charged with a catalyst acting on NOx in the exhaust gas in this order, and equipped with a reducing agent supplying device to supply a reducing agent at an upstream side of the plasma reactor, wherein the catalyst has an NO2 adsorptive catalyst layer and an NO2 selective reduction catalyst layer contacting the NO2 adsorptive catalyst layer.
摘要:
An exhaust gas purification device for an internal combustion engine, in which a catalyst installed in an exhaust passage is quickly heated to the activation temperature of the catalyst. The exhaust gas purification device has a NOx purification catalyst (33) for adsorbing or occluding NOx in exhaust gas and reducing the NOx, a catalytic converter (31) installed at that position of an exhaust pipe (4) which is upstream of the NOx purification catalyst (33), a fuel reformer (50) installed separately from the exhaust pipe (4), producing a reformed gas, and supplying the reformed gas, as a reducing gas, into the exhaust pipe (4) from an introduction opening (14) formed in that portion of the exhaust pipe (4) which is upstream of the NOx purification catalyst (33) and the catalytic converter (31), and an ECU (40) which, while the exhaust gas air-fuel ratio is being set to be lean, supplies the reducing gas into the exhaust pipe (4) and controls at least one of a throttle valve (9), an EGR valve (13), and a turbocharger (8) to regulate the flow rate of the exhaust gas flowing in the exhaust pipe (4).
摘要:
Provided is an exhaust gas cleaner by which nitrogen oxides contained in an exhaust gas can be efficiently removed in a wide temperature range from a low temperature. The exhaust gas cleaner (10) is for use in purifying the exhaust gas discharged from an internal combustion engine (15) in which fuel is fed under periodical rich or lean conditions and burned. The cleaner (10) comprises: a reforming means (11) which generates a reforming gas comprising hydrogen and carbon monoxide; a means of low-temperature oxidation (12) which contains palladium and which thereby can oxidize and adsorb nitrogen oxides at low temperatures and oxidize the hydrogen and carbon monoxide; and a purifying means (13) which under lean conditions adsorbs nitrogen oxides and which under rich conditions releases the adsorbed nitrogen oxides and removes the released nitrogen oxides with the hydrogen and carbon monoxide present in the channel. By contriving the layout of the reforming means (11), means of low-temperature oxidation (12), and purifying means (13), nitrogen oxides contained in an exhaust gas can be removed in a wide temperature range from a low temperature.
摘要:
An exhaust purification device for an internal combustion engine is provided that can promote the reduction of NOx in a NOx purification catalyst from immediately after startup of the internal combustion engine. The exhaust purification device includes: a fuel reformer that is provided separately from exhaust plumbing 4, reforms fuel and produces a reducing gas that contains carbon monoxide, hydrogen and hydrocarbons, and supplies the reducing gas upstream of the NOx purification catalyst into the exhaust path; an exhaust gas temperature sensor 34 that detects a temperature TEX of the exhaust flowing in the exhaust plumbing 4; and a reformer control part 41 that starts supply of the reducing gas to the exhaust plumbing 4 by starting control of the fuel reformer 50 in a case where the temperature TEX thus detected by this exhaust gas temperature sensor 34 is no higher than a predetermined first determination temperature T1, and stops the supply of reducing gas to the exhaust plumbing 4 by stopping control of the fuel reformer 50 in a case where the temperature detected by the exhaust gas temperature sensor 34 is at least a second determination temperature T2, which is higher than the first determination temperature.
摘要:
An exhaust purification device for an internal combustion engine can achieve high NOx purifying performance independent of operating conditions of the engine. The exhaust purification device has a NOx purification catalyst (33) mounted in an exhaust pipe (4) of the internal combustion engine, adsorbing or occluding NOx in exhaust gas when the exhaust gas air/fuel ratio is made lean, and reducing the adsorbed or occluded NOx when the exhaust gas air/fuel ratio is made rich; a fuel reformer (50) mounted separately from the exhaust pipe (4), reforming fuel to produce a reducing gas containing hydrogen and carbon monoxide, and supplying the reducing gas into that part of the exhaust pipe (4) which is located upstream of the NOx purification catalyst (33); and enriching means for enriching the exhaust gas air/fuel ratio. When one or more of operating conditions are satisfied, the enriching means enriches the air/fuel ratio of mixed gas to be combusted in the engine and causes the fuel reformer (50) to supply the reducing gas into the exhaust pipe (4) to enrich the exhaust gas air/fuel ratio.
摘要:
Provided is an exhaust emission control device for an internal combustion engine capable of preventing NOx purification performance from degrading according to the operating condition. The exhaust emission control device comprises an NOx purification catalyst for adsorbing or occluding NOx in exhaust emissions and reducing the NOx, which is provided in an exhaust pipe (4), a catalyst converter (31) for continuously reducing the NOx in the exhaust emissions by using a reducing gas, which is provided in the exhaust pipe (4), a fuel reformer (50) for reforming fuel to manufacture a reformed gas containing hydrogen and carbon monoxide and supplying the reformed gas as the reducing gas from an introduction port (14) provided on the upstream side of the NOx purification catalyst (33) and the catalyst converter (31) of the exhaust pipe (4), which is provided separately from the exhaust pipe (4), an operating condition detecting means for detecting the operating condition of an engine, and an enriching means (40) for enriching the exhaust air-fuel ratio. The enriching means enriches the exhaust air-fuel ratio by supplying the reducing gas into the exhaust pipe (4) by using the fuel reformer (50) when the operating condition detected by the operating condition detecting means is a high-load operating condition.
摘要:
An exhaust gas purification system that is equipped, from an upstream side toward downstream side through which an exhaust gas flows, with a plasma reactor and a NOx selective reduction catalyst unit having a NOx selective reduction catalyst layer acting on the exhaust gas, and which system provides a reducing agent adding means adding a reducing agent to the exhaust gas at an upstream side of the plasma reactor, wherein the NOx selective reduction catalyst layer comprises nickel and a NOx selective reduction catalyst or wherein the NOx selective reduction catalyst layer contains γ-alumina that supports magnesium or wherein the NOx selective reduction catalyst unit comprises a first purification unit where an exhaust gas via the plasma reactor is introduced, and a second purification unit where an exhaust gas via the first purification unit is introduced.
摘要翻译:一种排气净化系统,其从排气流过的上游侧向下游侧配备有等离子体反应器和NO x x选择还原催化剂单元, 作用于废气的/ SUB>选择还原催化剂层,该系统提供在等离子体反应器的上游侧向排气添加还原剂的还原剂添加装置,其中NO x 选择性还原催化剂层包括镍和NO x选择性还原催化剂,或其中NO x选择性还原催化剂层含有支持镁的γ-氧化铝,或其中NO x 选择还原催化剂单元包括通过等离子体反应器引入废气的第一净化单元和经由第一净化单元引入排气的第二净化单元。