公开(公告)号：US6011170A

公开(公告)日：2000-01-04

申请号：US142688

申请日：1999-04-22

申请人： Takeshi Kondo ,  Akira Nishiyama ,  Noboru Ueyama ,  Hiroshi Murao ,  Hajime Manabe ,  Yasuyoshi Ueda

发明人： Takeshi Kondo ,  Akira Nishiyama ,  Noboru Ueyama ,  Hiroshi Murao ,  Hajime Manabe ,  Yasuyoshi Ueda

IPC分类号： C07C319/14 ,  C07C323/58 ,  C07C323/59 ,  C07C321/04

CPC分类号： C07C319/14 ,  C07B2200/07 ,  Y02P20/55

摘要： This invention relates to a method comprising reacting an amino acid derivative of the following general formula (I); ##STR1## (wherein R.sup.1 represents an amino-protective group; R.sup.0 represents hydrogen or, taken together with R.sup.1, represents an amino-protecting group; R.sup.2 represents a carboxy-protecting group; X represents a leaving group) with a thiol compound of the following general formula (II):R.sup.3 SH (II)(wherein R.sup.3 represents an alkyl group of 1 to 7 carbon atoms, an aryl group of 6 to 10 carbon atoms, or an aralkyl group of 7 to 10 carbon atoms) to give a cysteine derivative of the following general formula (III): ##STR2## (wherein R.sup.0, R.sup.1, R.sup.2, and R.sup.3 are as defined above), wherein the reaction is conducted in the presence of a base and water in an organic reaction solvent.

摘要翻译： PCT No.PCT / JP98 / 00101 Sec。 371日期1999年4月22日 102（e）日期1999年4月22日PCT提交1998年1月14日PCT公布。 第WO98 / 30538号公报 日期：1998年7月16日本发明涉及使下述通式（I）的氨基酸衍生物反应的方法。 （其中R 1表示氨基保护基; R 0表示氢或与R 1一起表示氨基保护基; R 2表示羧基保护基; X表示离去基团）与下列通式的硫醇化合物反应 （II）：R3SH（II）（其中R3表示1〜7个碳原子的烷基，6〜10个碳原子的芳基或7〜10个碳原子的芳烷基），得到 以下通式（III）：（其中R 0，R 1，R 2和R 3如上定义），其中反应在有机反应溶剂中在碱和水的存在下进行。

公开(公告)号：US06407281B1

公开(公告)日：2002-06-18

申请号：US09600253

申请日：2000-08-25

申请人： Yasuyoshi Ueda ,  Hiroshi Murao ,  Takeshi Kondo ,  Noboru Ueyama ,  Hajime Manabe ,  Kenji Yoneda ,  Akira Nishiyama

发明人： Yasuyoshi Ueda ,  Hiroshi Murao ,  Takeshi Kondo ,  Noboru Ueyama ,  Hajime Manabe ,  Kenji Yoneda ,  Akira Nishiyama

IPC分类号： C07C32100

CPC分类号： C07C319/28 ,  C07B2200/07 ,  C07C319/20 ,  Y02P20/55 ,  C07C323/59

摘要： A process for producing optically active cysteine derivatives with high optical purity and good quality which is economically advantageous and is high in productivity even on a commercial scale is provided. A process for producing an optically active cysteine derivative which comprises synthesizing a D-form or L-form optically active cysteine derivative of the general formula (2) shown below (R1 represents an amino-protecting group of the urethane or acyl type, R0 represents a hydrogen atom or, taken together with R1, an amino-protecting group, R2 represents an alkyl, aryl or aralkyl group, R3 represents a univalent organic group and * represents the position of an asymmetric carbon) by reacting the corresponding D-form or L-form optically active amino acid derivative of the general formula (1) shown below with an alcohol of the general formula (3) shown below and a strong acid and/or a thionyl halide and recovering the above cysteine derivative (2) from the reaction mixture, the procedural series from reaction to recovery being carried out under conditions such that the medium contacting the above optically active cysteine derivative (2) is within the range from acidic to weakly basic to thereby recover the above cysteine derivative (2) from the reaction mixture while suppressing the decomposition and racemization thereof.

摘要翻译： 提供一种制造光学活性半胱氨酸衍生物的方法，该方法具有高光学纯度和良好的质量，其在经济上是有利的并且即使在商业规模下也具有高生产率。1.一种光学活性半胱氨酸衍生物的制备方法，其包括合成D型或L型 （2）的光学活性半胱氨酸衍生物（R1表示氨基甲酸酯或酰基型氨基保护基，R 0表示氢原子，或与R 1一起形成氨基保护基，R2表示 烷基，芳基或芳烷基，R 3表示一价有机基团，*表示不对称碳的位置），通过使下述通式（1）的相应的D型或L型光学活性氨基酸衍生物与 如下所示的通式（3）的醇和强酸和/或亚硫酰卤并从反应混合物中回收上述半胱氨酸衍生物（2），程序 在与上述光学活性半胱氨酸衍生物（2）接触的介质在酸性至弱碱性的范围内，从反应混合物中回收上述半胱氨酸衍生物（2）的条件下进行反应回收的ural系列，同时抑制 其分解和外消旋化。

公开(公告)号：US06472544B1

公开(公告)日：2002-10-29

申请号：US09509998

申请日：2000-08-16

申请人： Noriyuki Kizaki ,  Yukio Yamada ,  Yoshihiko Yasohara ,  Akira Nishiyama ,  Makoto Miyazaki ,  Masaru Mitsuda ,  Takeshi Kondo ,  Noboru Ueyama ,  Kenji Inoue

发明人： Noriyuki Kizaki ,  Yukio Yamada ,  Yoshihiko Yasohara ,  Akira Nishiyama ,  Makoto Miyazaki ,  Masaru Mitsuda ,  Takeshi Kondo ,  Noboru Ueyama ,  Kenji Inoue

IPC分类号： C07D31906

CPC分类号： C07D319/06 ,  C07B2200/07 ,  C07C67/343 ,  C07C253/30 ,  C12P7/62 ,  C07C69/716 ,  C07C255/21

摘要： This invention provides a process for producing optically active 2-[6-(hydroxymethyl)-1,3-dioxan-4-yl]acetic acid derivatives, which are of value as intermediates of drugs, from inexpensive starting materials without using any special equipment such as that required for super-low temperature reactions. A process for producing optically active 2-[6-(hydroxymethyl)-1,3-dioxan-4-yl]acetic acid derivatives which comprises reacting an acetic acid derivative at a temperature of not less than −30° C. with an enolate prepared by permitting either a base or a metal having a valency of 0 to act on the derivative to produce a hydroxyoxohexanoic acid derivative, reducing this compound with the aid of a strain of microorganism to provide a halomethyldioxanylacetic acid derivative, treating this compound with an acetalizing agent in the presence of an acid catalyst to provide a halomethyldioxanylacetic acid derivative, reacted with an acyloxylating agent to provide a acyloxymethyldioxanylacetic acid derivative, and subjecting this compound to solvolysis in the presence of a base.

摘要翻译： 本发明提供了从廉价起始原料生产具有价值作为药物中间体的光学活性的2- [6-（羟甲基）-1,3-二恶烷-4-基]乙酸衍生物的方法，而不使用任何特殊设备 例如超低温反应所需的方法。一种制备光学活性的2- [6-（羟甲基）-1,3-二恶烷-4-基]乙酸衍生物的方法，其包括在不是的温度下使乙酸衍生物反应 小于-30℃，通过使碱金属或化合价为0的金属作用于衍生物以制备羟基氧代己酸衍生物而制备的烯醇化物，借助于微生物菌株还原该化合物以提供 卤甲基二恶烷基乙酸衍生物，在酸催化剂存在下用缩醛化剂处理该化合物，得到卤代甲基二恶烷基乙酸衍生物，与酰氧基化剂反应，得到酰氧基甲基二恶烷基乙酸 在碱的存在下，将该化合物施用于溶剂分解。

公开(公告)号：US06903225B2

公开(公告)日：2005-06-07

申请号：US10242453

申请日：2002-09-13

申请人： Noriyuki Kizaki ,  Yukio Yamada ,  Yoshihiko Yasohara ,  Akira Nishiyama ,  Makoto Miyazaki ,  Masaru Mitsuda ,  Takeshi Kondo ,  Noboru Ueyama ,  Kenji Inoue

发明人： Noriyuki Kizaki ,  Yukio Yamada ,  Yoshihiko Yasohara ,  Akira Nishiyama ,  Makoto Miyazaki ,  Masaru Mitsuda ,  Takeshi Kondo ,  Noboru Ueyama ,  Kenji Inoue

IPC分类号： C07C67/343 ,  C07C253/30 ,  C07C255/21 ,  C07D319/06 ,  C12P7/62 ,  C12P1/04 ,  C12P17/06

CPC分类号： C07D319/06 ,  C07B2200/07 ,  C07C67/343 ,  C07C253/30 ,  C12P7/62 ,  C07C69/716 ,  C07C255/21

摘要： This invention provides a process for producing optically active 2-[6-(hydroxymethyl)-1,3-dioxan-4-yl]acetic acid derivatives, which are of value as intermediates of drugs, from inexpensive starting materials without using any special equipment such as that required for super-low temperature reactions.A process for producing optically active 2-[6-(hydroxymethyl)-1,3-dioxan-4-yl]acetic acid derivatives which comprises reacting an acetic acid derivative at a temperature of not less than −30° C. with an enolate prepared by permitting either a base or a metal having a valency of 0 to act on the derivative to produce a hydroxyoxohexanoic acid derivative, reducing this compound with the aid of a strain of microorganism to provide a halomethyldioxanylacetic acid derivative, treating this compound with an acetalizing agent in the presence of an acid catalyst to provide a halomethyl-dioxanylacetic acid derivative, reacted with an acyloxylating agent to provide a acyloxymethyldioxanylacetic acid derivative, and subjecting this compound to solvolysis in the presence of a base.

摘要翻译： 本发明提供了从廉价起始原料生产具有价值作为药物中间体的光学活性的2- [6-（羟甲基）-1,3-二恶烷-4-基]乙酸衍生物的方法，而不使用任何特殊设备 例如超低温反应所需的。 一种制备光学活性的2- [6-（羟基甲基）-1,3-二恶烷-4-基]乙酸衍生物的方法，其包括使不饱和-30℃的乙酸衍生物与烯醇化物 通过使碱金属或0价金属作用于衍生物以制备羟基己酸衍生物而制备，借助于微生物菌株还原该化合物以提供卤代甲基二恶烷基乙酸衍生物，用缩醛化处理该化合物 在酸催化剂存在下，提供卤代甲基 - 二恶烷基乙酸衍生物，与酰氧基化剂反应，得到酰氧基甲基二恶烷基乙酸衍生物，并在碱的存在下使其溶解。

公开(公告)号：US09556513B2

公开(公告)日：2017-01-31

申请号：US13818050

申请日：2011-07-27

申请人： Wataru Iwaya ,  Takeshi Kondo

发明人： Wataru Iwaya ,  Takeshi Kondo

IPC分类号： C23C14/48 ,  B29C59/14 ,  B05D7/04 ,  B05D1/00 ,  C08J7/04 ,  C08J7/12

CPC分类号： C23C14/48 ,  B05D1/62 ,  B05D7/04 ,  B05D2252/02 ,  B29C59/14 ,  B29C2059/147 ,  C08J7/045 ,  C08J7/047 ,  C08J7/123 ,  C08J2367/02 ,  C08J2433/12 ,  C08J2483/16 ,  Y10T428/31667

摘要： The invention is a formed article including a gas barrier layer, the gas barrier layer including a surface layer part that is formed of a material that includes at least a carbon atom, an oxygen atom, and a silicon atom, the surface layer part having a carbon atom content rate of more than 0 and not more than 70%, an oxygen atom content rate of 10 to 70%, a nitrogen atom content rate of 0 to 35%, and a silicon atom content rate of 20 to 55%, based on a total content rate of carbon atoms, oxygen atoms, nitrogen atoms, and silicon atoms; a method for producing the formed article; an electronic device member including the formed article; and an electronic device comprising the electronic device member. The formed article of the invention exhibits an excellent gas barrier capability, excellent transparency, and excellent bending resistance. The method for producing a formed article of the invention can efficiently, safely, and conveniently produce the formed article of the invention. The electronic device member of the invention may suitably be used for electronic devices such as displays and solar cells.

摘要翻译： 本发明是一种包含气体阻隔层的成形制品，所述阻气层包括由至少包含碳原子，氧原子和硅原子的材料形成的表面层部分，所述表面层部分具有 碳原子含有率大于0且不超过70％，氧原子含量率为10〜70％，氮原子含量率为0〜35％，硅原子含有率为20〜55％，基于 碳原子，氧原子，氮原子和硅原子的总含量比; 一种生产成形品的方法; 包括所述成形制品的电子装置构件; 以及包括电子设备构件的电子设备。 本发明的成型体具有优异的阻气性，优异的透明性和优异的耐弯曲性。 本发明的成型体的制造方法能够有效，安全，方便地制造本发明的成型体。 本发明的电子设备构件可以适用于诸如显示器和太阳能电池的电子设备。

公开(公告)号：US09357642B2

公开(公告)日：2016-05-31

申请号：US13685972

申请日：2012-11-27

申请人： Katsumi Mizuno ,  Kazuhiko Konomi ,  Yutaka Natsume ,  Ryo Miyakoshi ,  Takeshi Kondo

发明人： Katsumi Mizuno ,  Kazuhiko Konomi ,  Yutaka Natsume ,  Ryo Miyakoshi ,  Takeshi Kondo

IPC分类号： H05K1/03 ,  B32B15/04 ,  H05K1/05

CPC分类号： H05K1/0373 ,  B32B15/04 ,  B32B2457/08 ,  H05K1/056 ,  H05K2201/0141 ,  H05K2201/0209 ,  Y10T428/31681

摘要： A circuit board laminate includes a metal substrate, an insulation layer disposed on the metal substrate, and a metal foil disposed on the insulation layer. A metal-based circuit board includes a metal substrate, an insulation layer disposed on the metal substrate, and a circuit pattern disposed on the insulation layer. The insulation layer contains a liquid crystal polyester and 50% by volume or more of an inorganic filler. The inorganic filler is made of boron nitride and at least one of aluminum nitride and aluminum oxide. A proportion of boron nitride in the inorganic filler is within a range of 35 to 80% by volume.

摘要翻译： 电路板层叠体包括金属基板，设置在金属基板上的绝缘层和设置在绝缘层上的金属箔。 金属基电路板包括金属基板，设置在金属基板上的绝缘层和布置在绝缘层上的电路图案。 绝缘层含有液晶聚酯和50体积％以上的无机填料。 无机填料由氮化硼和氮化铝和氧化铝中的至少一种制成。 无机填料中的氮化硼的比例在35〜80体积％的范围内。

公开(公告)号：US08890400B2

公开(公告)日：2014-11-18

申请号：US12993610

申请日：2009-05-18

申请人： Satoshi Naganawa ,  Takashi Morioka ,  Naoki Taya ,  Takeshi Kondo ,  Kazue Saito ,  Yuko Iwamoto ,  Shinichi Hoshi ,  Yumiko Matsubayashi

发明人： Satoshi Naganawa ,  Takashi Morioka ,  Naoki Taya ,  Takeshi Kondo ,  Kazue Saito ,  Yuko Iwamoto ,  Shinichi Hoshi ,  Yumiko Matsubayashi

IPC分类号： H01J1/62 ,  H01J63/04 ,  H05B33/10 ,  C09K11/02 ,  H05B33/14 ,  H05B33/20

CPC分类号： H05B33/10 ,  C09K11/02 ,  C09K11/584 ,  H05B33/14 ,  H05B33/20

摘要： The present invention provides a luminescent composition which is capable of providing an inorganic electroluminescent sheet with a high productivity at low costs in an efficient manner, and has a desired light transmittance (transparency) when no electric voltage is applied thereto, an inorganic electroluminescent sheet obtained from the luminescent composition which can be mass-produced, and a process for producing the inorganic electroluminescent sheet. The present invention relates to a luminescent composition including an inorganic electroluminescent substance and a binder resin, wherein a content of the inorganic electroluminescent substance is not less than 0.5 part by mass and less than 100 parts by mass on the basis of 100 parts by mass of the binder resin; and an inorganic electroluminescent sheet including at least a first transparent substrate, a first transparent electrode, an inorganic electroluminescent layer, a first transparent electrode and a second transparent substrate which are successively laminated in this order, wherein the inorganic electroluminescent layer is formed from the above luminescent composition, and the inorganic electroluminescent sheet has a light transmittance of 60% or more as measured at a wavelength of 550 nm under a non-light emitting condition.

摘要翻译： 本发明提供一种发光组合物，其能够以低成本有效地提供高生产率的无机电致发光片，并且当不施加电压时具有期望的透光率（透明度），获得的无机电致发光片 从可以大量生产的发光组合物和无机电致发光片的制造方法。 本发明涉及包含无机电致发光物质和粘合剂树脂的发光组合物，其中无机电致发光物质的含量不小于0.5质量份且小于100质量份，基于100质量份 粘合剂树脂; 以及至少包括依次层叠的第一透明基板，第一透明电极，无机电致发光层，第一透明电极和第二透明基板的无机电致发光片，其中无机电致发光层由上述形成 发光组合物，无机电致发光片在非发光条件下的波长550nm下的透光率为60％以上。

公开(公告)号：US08846200B2

公开(公告)日：2014-09-30

申请号：US13823688

申请日：2011-09-16

申请人： Masaharu Ito ,  Takeshi Kondo ,  Yuta Suzuki

发明人： Masaharu Ito ,  Takeshi Kondo ,  Yuta Suzuki

IPC分类号： B32B9/04 ,  B32B27/00 ,  C08J7/04 ,  C08J7/18 ,  C23C14/14 ,  C23C14/20 ,  G02F1/1333 ,  H01L51/44 ,  C23C14/48 ,  C09D5/00 ,  C08J7/12 ,  H01L51/52

CPC分类号： C09D5/00 ,  C08J7/047 ,  C08J7/123 ,  C08J2369/00 ,  C08J2381/06 ,  C08J2483/16 ,  C23C14/48 ,  G02F1/133305 ,  H01L51/448 ,  H01L51/5253 ,  H01L2251/5338 ,  Y02E10/549 ,  Y02P70/521 ,  Y10T428/31667

摘要： The present invention provides a gas barrier film including a base layer, and a gas barrier layer that is provided on at least one side of the base layer, the base layer including a resin having a glass transition temperature (Tg) of more than 130° C., the gas barrier layer being formed of a material that includes at least an oxygen atom and a silicon atom, a surface layer part of the gas barrier layer having an oxygen atom content rate of 60 to 75%, a nitrogen atom content rate of 0 to 10%, and a silicon atom content rate of 25 to 35%, based on a total content rate of oxygen atoms, nitrogen atoms, and silicon atoms, and the surface layer part of the gas barrier layer having a film density of 2.4 to 4.0 g/cm3. Also provided are a process for producing the same, an electronic device member that includes the gas barrier film, and an electronic device that includes the electronic device member. The gas barrier film of the invention exhibits an excellent gas barrier capability, excellent transparency, excellent bending resistance, and excellent heat resistance.

摘要翻译： 本发明提供了一种阻气膜，其包括基底层和设置在基底层的至少一侧的阻气层，所述基底层包括玻璃化转变温度（Tg）大于130°的树脂 气体阻隔层由至少包含氧原子和硅原子的材料形成，阻气层的氧原子含有率为60〜75％的表层部分，氮原子含有率 为0〜10％，硅原子含有率为25〜35％，基于氧原子，氮原子和硅原子的总含有率，阻气层的表层部分的膜密度为 2.4〜4.0g / cm 3。 还提供了制造该方法的方法，包括阻气膜的电子器件部件和包括该电子器件部件的电子器件。 本发明的阻气膜表现出优异的阻气性，优异的透明性，优异的耐弯曲性和优异的耐热性。

公开(公告)号：US08482245B2

公开(公告)日：2013-07-09

申请号：US12933206

申请日：2009-03-19

申请人： Takeshi Kondo ,  Katsutoshi Miyazaki

发明人： Takeshi Kondo ,  Katsutoshi Miyazaki

IPC分类号： H02P27/04

CPC分类号： B60L11/1861 ,  B60L11/005 ,  B60W2510/244 ,  H01M10/44 ,  H02M3/1582 ,  Y02T10/7005 ,  Y02T10/7022 ,  Y02T10/7044 ,  Y02T10/705

摘要： A power conversion device in which an inverter for controlling a load is connected to an alternating current power system, and arranged to perform an electric power assist by connecting a direct-current power assist device having a chopper and a charge device to a direct-current circuit of the inverter. The device including a setting section to set charge and discharge target values in accordance with a sensed value of the direct-current voltage of the inverter; a charge control section to perform a charge control based on the charge target value; a discharge control section to perform a discharge control based on the discharge target value; and an instantaneous-low high-speed-compensation section to estimate an electric power corresponding to a direct-current sensed voltage of the inverter, and to output a value to the discharge control section which is obtained by dividing the estimated value by the direct-current sensed voltage.

摘要翻译： 一种电力转换装置，其中用于控制负载的逆变器连接到交流电力系统，并且被布置成通过将具有斩波器和充电装置的直流辅助装置连接到直流电来执行电力辅助 逆变器电路。 所述装置包括根据所述逆变器的直流电压的感测值来设定充放电目标值的设定部; 充电控制部，其基于所述充电目标值进行充电控制; 放电控制部，其基于所述放电目标值进行放电控制; 以及用于估计与逆变器的直流感测电压相对应的电力的瞬时低速高速补偿部，并且通过将所述估计值除以所述直流输出而获得的所述放电控制部输出值， 电流检测电压。

公开(公告)号：US20130068136A1

公开(公告)日：2013-03-21

申请号：US13634713

申请日：2011-03-28

申请人： Wataru Iwaya ,  Takeshi Kondo

发明人： Wataru Iwaya ,  Takeshi Kondo

IPC分类号： C09D1/00 ,  C23C14/48

CPC分类号： C09D1/00 ,  C08G77/62 ,  C08J7/04 ,  C08J2367/02 ,  C08J2483/16 ,  C08K3/346 ,  C08K2201/008 ,  C09D183/16 ,  C23C14/48 ,  G02F1/133305

摘要： Provided a formed article comprising a layer that includes a polysilazane compound and a clay mineral, and having a water vapor transmission rate at a temperature of 40° C. and a relative humidity of 90% of 6.0 g/m2/day or less. Also provided are a method for producing the formed article, an electronic device member including the formed article, and an electronic device including the electronic device member. The formed article exhibiting an excellent gas barrier capability, excellent transparency, and excellent bending resistance, a method for producing the formed article, and an electronic device member, or the like, comprising the formed article are provided.

摘要翻译： 提供一种成型体，其包括含有聚硅氮烷化合物和粘土矿物的层，并且在40℃的温度和90％的相对湿度为6.0g / m 2 /天以下的水蒸气透过率。 还提供了一种用于生产成型物品的方法，包括成形物品的电子设备构件和包括该电子设备构件的电子设备。 提供了具有优异的阻气性，优异的透明性和优异的抗弯曲性的成型体，成型体的制造方法以及电子器件部件等。