Image-forming method and developer
    4.
    发明授权
    Image-forming method and developer 失效
    图像形成方法和开发者

    公开(公告)号:US07141358B2

    公开(公告)日:2006-11-28

    申请号:US10902139

    申请日:2004-07-30

    申请人: Hiroyuki Nagase

    发明人: Hiroyuki Nagase

    IPC分类号: G03F7/30 G03F7/32

    CPC分类号: G03F7/322

    摘要: A developer comprising at least one carbonate, at least one hydrogen carbonate and at least one alkali silicate, wherein the ratio of the total molar concentration “a” of the carbonate and the hydrogen carbonate to the molar concentration “b” of the SiO2 component present in the alkali silicate: “a/b” ranges from 1:0.3 to 1:2, the total molar concentration of “a” and “b”: “a+b” ranges from 0.1 to 2 mole/L, and the pH value thereof ranges from 9 to 13; and an image-forming method which comprises the steps of imagewise exposing a negative-working image-forming material which comprises a substrate provided thereon with an image-recording layer comprising an infrared light absorber, a polymerization initiator, an ethylenically unsaturated bond-containing monomer and a polymer binder, and then developing the imagewise exposed image-forming material with the foregoing developer.

    摘要翻译: 包含至少一种碳酸盐,至少一种碳酸氢盐和至少一种碱金属硅酸盐的显影剂,其中碳酸盐和碳酸氢盐的总摩尔浓度“a”与SiO

    Method for preparing lithographic printing plate
    5.
    发明授权
    Method for preparing lithographic printing plate 失效
    平版印刷版的制备方法

    公开(公告)号:US06756183B2

    公开(公告)日:2004-06-29

    申请号:US10222903

    申请日:2002-08-19

    申请人: Hiroyuki Nagase

    发明人: Hiroyuki Nagase

    IPC分类号: G03F730

    CPC分类号: G03F7/322

    摘要: A method for preparing a lithographic printing plate comprising the steps of imagewise exposing, to light, a presensitized plate for use in making a lithographic printing plate, which comprises a grained and anodized substrate provided thereon with a photopolymerizable light-sensitive layer containing a compound having at least one addition-polymerizable ethylenically unsaturated double bond and a titanocene type initiator; and then developing the light-exposed presensitized plate using a developer which comprises a surfactant and a weak acid or a salt thereof having a dissociation constant pka ranging from 10 to 13, and has a pH value ranging from 11.5 to 12.8. The method exhibits excellent development performance, and gives good results to the resultant printing plate in terms of printing durability and scumming. In addition, the change in pH value of the developer is so small that the stable development can be ensured for a long period of time.

    摘要翻译: 一种制备平版印刷版的方法,包括以下步骤:成像曝光用于制备平版印刷版的预敏化板,其包括在其上设置有可光聚合的感光层的光致聚合光敏层,所述光致聚合光敏层含有具有 至少一种可加成聚合的烯属不饱和双键和二茂钛型引发剂; 然后使用包含表面活性剂和弱酸或其盐的解离常数pka为10〜13的显影剂显影出曝光的未敏化平版,并具有11.5〜12.8的pH值。 该方法表现出优异的显影性能,并且在印刷耐久性和浮渣方面对得到的印版具有良好的结果。 此外,显影剂的pH值的变化如此之小,以至于可以长期确保稳定的显影。

    Silver halide light-sensitive material comprising support, hardening
layer and light-sensitive layer
    6.
    发明授权
    Silver halide light-sensitive material comprising support, hardening layer and light-sensitive layer 失效
    卤化银感光材料,包括支撑体,硬化层和感光层

    公开(公告)号:US5882838A

    公开(公告)日:1999-03-16

    申请号:US943122

    申请日:1997-10-03

    CPC分类号: G03F7/0285

    摘要: A silver halide light-sensitive material comprises a support, a hardening layer and a light-sensitive layer. The hardening layer contains an ethylenically unsaturated polymerizable compound or an ethylenically unsaturated cross-linkable polymer. The light-sensitive layer contains silver halide and a hydrophilic polymer. The hardening layer or the light-sensitive layer contains a reducing agent. An adhesive layer or the light-sensitive layer contains a water-soluble synthetic polymer. The adhesive layer is provided between the hardening layer and the light-sensitive layer. The water-soluble synthetic polymer comprises a repeating unit represented by the formula (I) in an amount of at least 50 mol %: ##STR1## in which each of n1 and n2 is an integer of 10 to 5,000; each of R.sup.1 and R.sup.2 is hydrogen, an alkyl group or an aryl group; X is --O--R.sup.4 --O-- or --NR.sup.5 --; R.sup.4 is an alkylene group, an alkyleneoxyalkylene group, an arylene group or an aralkylene group; R.sup.5 is an alkyl group or an aryl group; Y.sup.1 is --CO-- or --CONH--; Y.sup.2 is --CO-- or --NHCO--; and R.sup.3 is an alkylene group, an alkenylene group, an arylene group or an aralkylene group.

    摘要翻译: 卤化银感光材料包括载体,硬化层和感光层。 硬化层含有烯属不饱和的可聚合化合物或烯属不饱和的可交联聚合物。 感光层含有卤化银和亲水性聚合物。 硬化层或感光层含有还原剂。 粘合剂层或感光层含有水溶性合成聚合物。 粘合剂层设置在硬化层和感光层之间。 水溶性合成聚合物包含由式(I)表示的重复单元,其量为至少50摩尔%:其中n1和n2各自为10至5000的整数; R 1和R 2各自为氢,烷基或芳基; X是-O-R 4 -O-或-NR 5 - ; R4是亚烷基,亚烷基氧亚烷基,亚芳基或亚芳基; R5是烷基或芳基; Y1是-CO-或-CONH-; Y2是-CO-或-NHCO-; 并且R 3是亚烷基,亚烯基,亚芳基或亚芳烷基。

    Method for forming images
    7.
    发明申请
    Method for forming images 有权
    图像形成方法

    公开(公告)号:US20050112496A1

    公开(公告)日:2005-05-26

    申请号:US10973918

    申请日:2004-10-27

    申请人: Hiroyuki Nagase

    发明人: Hiroyuki Nagase

    摘要: The present invention relates to a method for forming images which comprises imagewise exposing a photopolymerizable image-forming material comprising a substrate provided thereon with an image-recording layer which comprises a specific photopolymerization initiator system, a polymerizable compound carrying at least one ethylenically unsaturated group and a binder polymer and then developing the imagewise exposed material with a developer containing at least one carbonate and at least one hydrogen carbonate and a specific surfactant in an amount ranging from 1.0 to 10% by weight, and having a specific pH and a specific electrical conductivity. The image-forming method permits the achievement of a sufficient developing ability even at a relatively low pH at which the image-forming material is not damaged so much and the preparation of a printing plate having good printing durability.

    摘要翻译: 本发明涉及一种用于形成图像的方法,该方法包括将包含其上设置有基材的基材的可光聚合成像材料成像曝光,所述图像记录层包含特定光聚合引发剂体系,携带至少一个烯键式不饱和基团的可聚合化合物和 粘合剂聚合物,然后用含有至少一种碳酸酯和至少一种碳酸氢盐和特定表面活性剂的显影剂显影成像曝光的材料,其量为1.0至10重量%,并且具有特定的pH和比电导率 。 图像形成方法即使在图像形成材料没有被损坏太多的相对低的pH下也能够获得足够的显影能力,并且制备具有良好印刷耐久性的印刷版。

    Image-forming method and developer
    8.
    发明申请
    Image-forming method and developer 失效
    图像形成方法和开发者

    公开(公告)号:US20050026092A1

    公开(公告)日:2005-02-03

    申请号:US10902139

    申请日:2004-07-30

    申请人: Hiroyuki Nagase

    发明人: Hiroyuki Nagase

    CPC分类号: G03F7/322

    摘要: The present invention provides a developer comprising at least one carbonate, at least one hydrogen carbonate and at least one alkali silicate, wherein the ratio of the total molar concentration “a” of the carbonate and the hydrogen carbonate to the molar concentration “b” of the SiO2 component present in the alkali silicate: “a/b” ranges from 1:0.3 to 1:2, the total molar concentration of “a” and “b”:“a+b” ranges from 0.1 to 2 mole/L, and the pH value thereof ranges from 9 to 13; and an image-forming method which comprises the steps of imagewise exposing a negative-working image-forming material which comprises a substrate provided thereon with an image-recording layer comprising an infrared light absorber, a polymerization initiator, an ethylenically unsaturated bond-containing monomer and a polymer binder, and then developing the imagewise exposed image-forming material with the foregoing developer. The developer and image-forming method can ensure sufficient developing properties or a satisfactory developing ability at a low pH wherein the image-forming material is hardly damaged. Accordingly, they permit the simultaneous achievement of good printing durability and a good developing ability of an image-forming material. Further, the developing activity of the developer is not hardly reduced due to the action of carbon dioxide and therefore, it does not suffer from a problem originated from the scum formed during development.

    摘要翻译: 本发明提供了包含至少一种碳酸酯,至少一种碳酸氢盐和至少一种碱金属硅酸盐的显影剂,其中碳酸盐和碳酸氢盐的总摩尔浓度“a”与摩尔浓度“b”的比率 碱性硅酸盐中存在的SiO 2成分:“a / b”为1:0.3〜1:2,“a”和“b”:“a + b”的总摩尔浓度为0.1〜2摩尔/ L ,pH值在9〜13的范围内。 以及一种图像形成方法,其包括以下步骤:成像曝光负片成像材料的步骤,所述负成像材料包括其上设置有包含红外光吸收剂,聚合引发剂,含烯键式不饱和键的单体的图像记录层的基材 和聚合物粘合剂,然后用上述显影剂显影成像曝光的图像形成材料。 显影剂和成像方法可以确保在低pH下具有足够的显影性能或令人满意的显影能力,其中成像材料几乎不被损坏。 因此,它们允许同时实现良好的印刷耐久性和成像材料的良好显影能力。 此外,由于二氧化碳的作用,显影剂的显影活性几乎不降低,因此不会产生在显影时形成的浮渣的问题。

    Image-forming method and developer
    10.
    发明授权
    Image-forming method and developer 有权
    图像形成方法和开发者

    公开(公告)号:US07101657B2

    公开(公告)日:2006-09-05

    申请号:US10899123

    申请日:2004-07-27

    申请人: Hiroyuki Nagase

    发明人: Hiroyuki Nagase

    IPC分类号: G03F7/32 G03F7/30

    摘要: An image-forming member excellent in the developing ability and printing durability can be obtained and images can be formed without being accompanied by any accumulation of scum in a developing bath used, by developing an image-forming material, in particular, a negative-working image-forming material which comprises a substrate provided thereon with an image-recording layer comprising an infrared light absorber, a polymerization initiator, an ethylenically unsaturated bond-containing monomer and a binder polymer, using a developer which comprises at least one carbonate and at least one hydrogen carbonate, and at least one surfactant selected from the group consisting of nonionic aromatic ether type surfactants represented by the following general formula (1): X—Y—O-(A)n-(B)m—H (wherein X represents an aromatic group; Y represents a single bond or an alkylene group having 1 to 10 carbon atoms; A and B represent groups different from one another and each represents either —CH2CH2O— or —CH2CH(CH3)O—; m and n are 0 or an integer ranging from 1 to 100, respectively, provided that n and m cannot simultaneously represent 0 and that when either n or m is 0, n and m cannot represent 1) and anionic surfactants in an amount ranging from 1.0 to 10% by weight; and which has a pH value ranging from 8.5 to 11.5 and an electrical conductivity x falling within the range: 30

    摘要翻译: 可以获得显影性能和印刷耐久性优异的成像构件,并且通过显影图像形成材料,特别是负面工作的图像形成材料,可以形成图像,而不伴随所使用的显影浴中的浮渣积累 图像形成材料,其包括其上设置有包含红外光吸收剂,聚合引发剂,含烯属不饱和键的单体和粘合剂聚合物的图像记录层的基材,使用包含至少一种碳酸酯和至少 一种碳酸氢盐和至少一种选自由以下通式(1)表示的非离子芳族醚型表面活性剂的表面活性剂:XYO-(A)N - (B) m H(其中X表示芳族基团; Y表示单键或碳原子数1〜10的亚烷基; A和B表示彼此不同的基团,各自表示 或-CH 2 CH 2 CH 2(CH 3 CH 3)O-或-CH 2 CH(CH 3 CH 3)O-; m和n分别为0或1至100的整数,条件是n和m不能同时表示0,当n或m为0时,n和m不能表示1)和阴离子表面活性剂,其量为 1.0〜10重量% pH值范围为8.5〜11.5,导电率x在30