Method of sulfonation of block polymers
    91.
    发明授权
    Method of sulfonation of block polymers 有权
    嵌段聚合物的磺化方法

    公开(公告)号:US09587106B2

    公开(公告)日:2017-03-07

    申请号:US14486604

    申请日:2014-09-15

    Applicant: Stepan Company

    Abstract: Improved methods for preparing sulfonated block polymers with acyl sulfates in non-halogenated aliphatic solvents are provided. The methods include the sulfonation of a precursor block polymer with an acyl sulfate in a reaction mixture further comprising at least one non-halogenated aliphatic solvent to form a sulfonated block polymer, wherein the initial concentration of the precursor block polymer is in the range of from about 0.1 wt % to a concentration that is below the limiting concentration of the precursor block polymer based on the total weight of the reaction mixture. A sulfonation degree of greater than about 1.0 milliequivalent sulfonic acid per gram sulfonated block polymer can be achieved substantially free of polymer precipitation and free of disabling gelation.

    Abstract translation: 提供了在非卤代脂族溶剂中制备具有酰基硫酸盐的磺化嵌段聚合物的改进方法。 所述方法包括在还含有至少一种非卤代脂族溶剂的反应混合物中使用酰基硫酸酯磺化前体嵌段聚合物以形成磺化嵌段聚合物,其中前体嵌段聚合物的初始浓度范围为 约0.1重量%至低于前体嵌段聚合物的极限浓度的浓度,基于反应混合物的总重量。 可以实现大于约1.0毫当量磺酸/克磺化嵌段聚合物的磺化度,基本上不含聚合物沉淀并且没有失效的凝胶化。

    Hybrid pressure sensitive adhesive
    95.
    发明授权
    Hybrid pressure sensitive adhesive 有权
    混合压敏粘合剂

    公开(公告)号:US09421736B2

    公开(公告)日:2016-08-23

    申请号:US13239815

    申请日:2011-09-22

    Abstract: A hybrid pressure sensitive adhesive (PSA) composition includes (i) a solvent phase comprising a first acrylic PSA dissolved in an organic solvent, an alcohol, and optionally water; and (ii) an emulsion phase comprising a second, emulsified acrylic PSA. In another aspect, a metalized film laminate includes a metalized film layer, a hybrid PSA layer, and an ink-containing polymeric film layer. The two-phase hybrid PSA system effectively addresses both metal tear and ink pick problems associated with conventional metalized film laminates.

    Abstract translation: 混合压敏粘合剂(PSA)组合物包括(i)溶剂相,其包含溶解在有机溶剂中的第一丙烯酸PSA,醇和任选的水; 和(ii)包含第二乳化丙烯酸PSA的乳液相。 另一方面,金属化膜层叠体包括金属化膜层,复合粘合剂层和含油墨的聚合物膜层。 两相混合PSA系统有效地解决了与常规金属化薄膜层压板相关的金属撕裂和油墨拾取问题。

    POLYMER PARTICLE, POLYMER DISPERSION, METHOD FOR PRODUCING SAID POLYMER DISPERSION, COATING MATERIAL PRODUCED FROM SAID POLYMER DISPERSION, AND COATED ARTICLE
    96.
    发明申请
    POLYMER PARTICLE, POLYMER DISPERSION, METHOD FOR PRODUCING SAID POLYMER DISPERSION, COATING MATERIAL PRODUCED FROM SAID POLYMER DISPERSION, AND COATED ARTICLE 有权
    聚合物颗粒,聚合物分散体,生产聚合物分散体的方法,由聚合物分散体制得的涂料,和涂层物品

    公开(公告)号:US20150376390A1

    公开(公告)日:2015-12-31

    申请号:US14767754

    申请日:2014-02-14

    Abstract: The present invention relates to: a polymer particle in which a urethane resin (A1) and an acrylic polymer (B1) are included in a single particle, said polymer particle having a gel fraction of 10% or more as measured using N,N-dimethylformamide (DMF) as a solvent; a polymer particle in which a urethane resin (A2) having a sulfonic acid group and an acrylic polymer (B2) are included in a single particle, said polymer particle having a surface acid value of 0.1 to 19 mgKOH/g as measured by a potentiometric titration method; and a method for producing a polymer dispersion. According to the present invention, it becomes possible to provide: a polymer dispersion which has excellent polymerization stability and can have an excellent coating viscosity property and excellent storage stability when used in a coating material; a method for producing the polymer dispersion; and a polymer particle contained in the polymer dispersion. It also becomes possible to provide: a coating material which enables the formation of a coating film that can have excellent water resistance and solvent resistance even when the drying conditions include a low temperature and a shorter drying time; and a coated material which has the coating material applied thereon.

    Abstract translation: 本发明涉及:在单粒子中含有聚氨酯树脂(A1)和丙烯酸类聚合物(B1)的聚合物粒子,所述聚合物粒子的凝胶分数为10%以上,使用N,N- 二甲基甲酰胺(DMF)作为溶剂; 在单个颗粒中包含具有磺酸基的聚氨酯树脂(A2)和丙烯酸类聚合物(B2)的聚合物颗粒,所述聚合物颗粒的表面酸值为0.1〜19mgKOH / g,通过电位计 滴定法 和聚合物分散体的制造方法。 根据本发明,可以提供:聚合稳定性优异且在涂布材料中使用时具有优异的涂布粘度特性和优异的保存稳定性的聚合物分散体; 聚合物分散体的制造方法; 和聚合物分散体中所含的聚合物颗粒。 也可以提供:即使干燥条件包括低温和较短的干燥时间,也能够形成能够形成具有优异的耐水性和耐溶剂性的涂膜的涂料。 以及其上涂覆有涂料的涂布材料。

    NON-AQUEOUS DISPERSANT, COLOR MATERIAL DISPERSION LIQUID AND METHOD FOR PRODUCING THE SAME, COLOR RESIN COMPOSITION AND METHOD FOR PRODUCING THE SAME, COLOR FILTER, LIQUID CRYSTAL DISPLAY DEVICE, AND ORGANIC LIGHT-EMITTING DISPLAY DEVICE
    98.
    发明申请
    NON-AQUEOUS DISPERSANT, COLOR MATERIAL DISPERSION LIQUID AND METHOD FOR PRODUCING THE SAME, COLOR RESIN COMPOSITION AND METHOD FOR PRODUCING THE SAME, COLOR FILTER, LIQUID CRYSTAL DISPLAY DEVICE, AND ORGANIC LIGHT-EMITTING DISPLAY DEVICE 有权
    非水性分散剂,颜料分散液及其制造方法,颜料树脂组合物及其制造方法,彩色滤光片,液晶显示装置和有机发光显示装置

    公开(公告)号:US20150065658A1

    公开(公告)日:2015-03-05

    申请号:US14395278

    申请日:2013-04-26

    Abstract: The present invention is to provide: a non-aqueous dispersant which is excellent in dispersibility and dispersion stability and able to form a resin layer with excellent hydrolysis resistance; a color material dispersion liquid containing the non-aqueous dispersant; and a color resin composition containing the non-aqueous dispersant.Disclosed is a non-aqueous dispersant which is a polymer comprising at least one constitutional unit represented by the following general formula (I), wherein at least part of nitrogen sites of the constitutional units each form a salt with an acidic organophosphorous compound comprising one or more selected from the group consisting of organic phosphonic acid monoester compounds resulting from addition of a monofunctional epoxy compound or monofunctional oxetane compound to an organic phosphonic acid: Symbols shown in the general formula (I) are described in the Description.

    Abstract translation: 本发明提供:分散性和分散稳定性优异,能够形成耐水解性优异的树脂层的非水分散剂; 含有非水分散剂的着色材料分散液; 和含有非水分散剂的着色树脂组合物。 公开了一种非水分散剂,其是包含由以下通式(I)表示的至少一个结构单元的聚合物,其中所述结构单元的至少部分氮位点与酸性有机亚磷化合物形成盐,所述酸性有机亚磷化合物包含一个或多个 更优选由将单官能环氧化合物或单官能氧杂环丁烷化合物加成而成的有机膦酸单酯化合物与有机膦酸的组合。通式(I)所示的符号在说明书中有描述。

    Method of Sulfonation of Block Polymers
    99.
    发明申请
    Method of Sulfonation of Block Polymers 有权
    块状聚合物的磺化方法

    公开(公告)号:US20150005439A1

    公开(公告)日:2015-01-01

    申请号:US14486604

    申请日:2014-09-15

    Applicant: Stepan Company

    Abstract: Improved methods for preparing sulfonated block polymers with acyl sulfates in non-halogenated aliphatic solvents are provided. The methods include the sulfonation of a precursor block polymer with an acyl sulfate in a reaction mixture further comprising at least one non-halogenated aliphatic solvent to form a sulfonated block polymer, wherein the initial concentration of the precursor block polymer is in the range of from about 0.1 wt % to a concentration that is below the limiting concentration of the precursor block polymer based on the total weight of the reaction mixture. A sulfonation degree of greater than about 1.0 milliequivalent sulfonic acid per gram sulfonated block polymer can be achieved substantially free of polymer precipitation and free of disabling gelation.

    Abstract translation: 提供了在非卤代脂族溶剂中制备具有酰基硫酸盐的磺化嵌段聚合物的改进方法。 所述方法包括在还含有至少一种非卤代脂族溶剂的反应混合物中使用酰基硫酸酯磺化前体嵌段聚合物以形成磺化嵌段聚合物,其中前体嵌段聚合物的初始浓度范围为 约0.1重量%至低于前体嵌段聚合物的极限浓度的浓度,基于反应混合物的总重量。 可以实现大于约1.0毫当量磺酸/克磺化嵌段聚合物的磺化度,基本上不含聚合物沉淀并且没有失效的凝胶化。

    ADHESIVE RESIN COMPOSITION FOR SECONDARY BATTERY
    100.
    发明申请
    ADHESIVE RESIN COMPOSITION FOR SECONDARY BATTERY 有权
    用于二次电池的粘合树脂组合物

    公开(公告)号:US20140227603A1

    公开(公告)日:2014-08-14

    申请号:US14347108

    申请日:2012-09-24

    Inventor: Toshihiko Ogata

    Abstract: An adhesive resin composition for a secondary battery for bonding a separator for a secondary battery and an electrode for a secondary battery, wherein the composition comprises an adhesive resin, the adhesive resin contains the following (A) and (B), and the phase composed of (A) and (B) has a core shell heterophase structure and/or a sea-island heterophase structure: (A) a resin having a glass transition temperature of −30° C. to +20° C., (B) a resin having a glass transition temperature 20° C. to 200° C. higher than the glass transition temperature of (A).

    Abstract translation: 一种用于二次电池用隔膜和二次电池接合用二次电池用粘合树脂组合物,其中,所述组合物含有粘接性树脂,所述粘合树脂含有下述(A)和(B),所述相组成 (A)和(B)具有核壳异相结构和/或海岛异相结构:(A)玻璃化转变温度为-30℃至+ 20℃的树脂,(B) 玻璃化转变温度比(A)的玻璃化转变温度高20℃〜200℃的树脂。

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