公开(公告)号：US11410846B2

公开(公告)日：2022-08-09

申请号：US17094563

申请日：2020-11-10

Applicant: Taiwan Semiconductor Manufacturing Company, Ltd.

Inventor： Shich-Chang Suen ,  Li-Chieh Wu ,  Chi-Jen Liu ,  He Hui Peng ,  Liang-Guang Chen ,  Yung-Chung Chen

IPC: H01L21/02 ,  H01L21/28 ,  H01L21/311 ,  H01L21/768 ,  H01L21/288 ,  H01L29/66

Abstract: The present disclosure provides a method for forming an integrated circuit (IC) structure. The method includes providing a metal gate (MG), an etch stop layer (ESL) formed on the MG, and a dielectric layer formed on the ESL. The method further includes etching the ESL and the dielectric layer to form a trench. A surface of the MG exposed in the trench is oxidized to form a first oxide layer on the MG. The method further includes removing the first oxide layer using a H3PO4 solution.

公开(公告)号：US20210391208A1

公开(公告)日：2021-12-16

申请号：US16902203

申请日：2020-06-15

Applicant: TAIWAN SEMICONDUCTOR MANUFACTURING COMPANY LTD.

Inventor： Ji Cui ,  Fu-Ming Huang ,  Ting-Kui Chang ,  Tang-Kuei Chang ,  Chun-Chieh Lin ,  Wei-Wei Liang ,  Chi-Hsiang Shen ,  Ting-Hsun Chang ,  Li-Chieh Wu ,  Hung Yen ,  Chi-Jen Liu ,  Liang-Guang Chen ,  Kei-Wei Chen

IPC: H01L21/768 ,  C09G1/02 ,  C09K3/14

Abstract: A method for CMP includes following operations. A metal layer is received. A CMP slurry composition is provided in a CMP apparatus. The CMP slurry composition includes at least a first oxidizer and a second oxidizer different from each other. The first oxidizer is oxidized to form a peroxidant by the second oxidizer. A portion of the metal layer is oxidized to form a first metal oxide by the peroxidant. The first metal oxide is re-oxidized to form a second metal oxide by the second oxidizer.

公开(公告)号：US20210082688A1

公开(公告)日：2021-03-18

申请号：US17094563

申请日：2020-11-10

Applicant: Taiwan Semiconductor Manufacturing Company, Ltd.

Inventor： Shich-Chang Suen ,  Li-Chieh Wu ,  Chi-Jen Liu ,  He Hui Peng ,  Liang-Guang Chen ,  Yung-Chung Chen

IPC: H01L21/02 ,  H01L21/28 ,  H01L21/311 ,  H01L21/768 ,  H01L29/40 ,  H01L21/288

Abstract: The present disclosure provides a method for forming an integrated circuit (IC) structure. The method includes providing a metal gate (MG), an etch stop layer (ESL) formed on the MG, and a dielectric layer formed on the ESL. The method further includes etching the ESL and the dielectric layer to form a trench. A surface of the MG exposed in the trench is oxidized to form a first oxide layer on the MG. The method further includes removing the first oxide layer using a H3PO4 solution.

公开(公告)号：US10937691B2

公开(公告)日：2021-03-02

申请号：US16559336

申请日：2019-09-03

Applicant: Taiwan Semiconductor Manufacturing Company, Ltd.

Inventor： Chia Hsuan Lee ,  Chun-Wei Hsu ,  Chia-Wei Ho ,  Chi-Hsiang Shen ,  Li-Chieh Wu ,  Jian-Ci Lin ,  Chi-Jen Liu ,  Yi-Sheng Lin ,  Yang-Chun Cheng ,  Liang-Guang Chen ,  Kuo-Hsiu Wei ,  Kei-Wei Chen

IPC: H01L21/02 ,  H01L21/768 ,  H01L21/3105 ,  C09G1/02

Abstract: Methods of forming a slurry and methods of performing a chemical mechanical polishing (CMP) process utilized in manufacturing semiconductor devices, as described herein, may be performed on semiconductor devices including integrated contact structures with ruthenium (Ru) plug contacts down to a semiconductor substrate. The slurry may be formed by mixing a first abrasive, a second abrasive, and a reactant with a solvent. The first abrasive may include a first particulate including titanium dioxide (TiO2) particles and the second abrasive may include a second particulate that is different from the first particulate. The slurry may be used in a CMP process for removing ruthenium (Ru) materials and dielectric materials from a surface of a workpiece resulting in better WiD loading and planarization of the surface for a flat profile.

公开(公告)号：US20200043786A1

公开(公告)日：2020-02-06

申请号：US16450665

申请日：2019-06-24

Applicant: Taiwan Semiconductor Manufacturing Company, Ltd.

Inventor： Li-Chieh Wu ,  Kuo-Hsiu Wei ,  Kei-Wei Chen ,  Tang-Kuei Chang ,  Chia Hsuan Lee ,  Jian-Ci Lin

IPC: H01L21/768 ,  H01L21/321 ,  H01L23/532 ,  H01L23/535 ,  C09G1/04

Abstract: A structure and a formation method of a semiconductor device are provided. The method includes forming a conductive feature over a semiconductor substrate and forming a dielectric layer over the conductive feature. The method also includes forming an opening in the dielectric layer to expose the conductive feature. The method further includes forming a conductive material to overfill the opening. In addition, the method includes thinning the conductive material using a chemical mechanical polishing process. A slurry used in the chemical mechanical polishing process includes an iron-containing oxidizer that oxidizes a portion of the conductive material.

公开(公告)号：US20170221700A1

公开(公告)日：2017-08-03

申请号：US15492034

申请日：2017-04-20

Applicant: Taiwan Semiconductor Manufacturing Company, Ltd.

Inventor： Shich-Chang Suen ,  Li-Chieh Wu ,  Chi-Jen Liu ,  He Hui Peng ,  Liang-Guang Chen ,  Yung-Chung Chen

IPC: H01L21/02 ,  H01L21/288 ,  H01L21/768 ,  H01L21/311

CPC classification number: H01L21/02068 ,  H01L21/02063 ,  H01L21/0234 ,  H01L21/28079 ,  H01L21/28132 ,  H01L21/288 ,  H01L21/31105 ,  H01L21/31111 ,  H01L21/31116 ,  H01L21/76804 ,  H01L21/76814 ,  H01L21/76831 ,  H01L21/76877 ,  H01L21/76895 ,  H01L29/401 ,  H01L29/66545

Abstract: The present disclosure provides a method for forming an integrated circuit (IC) structure. The method includes providing a metal gate (MG), an etch stop layer (ESL) formed on the MG, and a dielectric layer formed on the ESL. The method further includes etching the ESL and the dielectric layer to form a trench. A surface of the MG exposed in the trench is oxidized to form a first oxide layer on the MG. The method further includes removing the first oxide layer using a H3PO4 solution.

公开(公告)号：US09449841B2

公开(公告)日：2016-09-20

申请号：US14134914

申请日：2013-12-19

Applicant: Taiwan Semiconductor Manufacturing Company, Ltd.

Inventor： Shich-Chang Suen ,  Chi-Jen Liu ,  Ying-Liang Chuang ,  Li-Chieh Wu ,  Liang-Guang Chen ,  Ming-Liang Yen

IPC: H01L21/02 ,  H01L21/321 ,  H01L29/66 ,  H01L21/67

CPC classification number: H01L21/28123 ,  B24B37/20 ,  H01L21/02074 ,  H01L21/3212 ,  H01L21/67051 ,  H01L29/66545

Abstract: The present disclosure provides a method of fabricating a semiconductor device. The method includes providing a semiconductor structure including a metal gate (MG) layer formed to fill in a trench between two adjacent interlayer dielectric (ILD) regions; performing a chemical mechanical polishing (CMP) process using a CMP system to planarize the MG layer and the ILD regions; and cleaning the planarized MG layer using a O3/DIW solution including ozone gas (O3) dissolved in deionized water (DIW). The MG layer is formed on the ILD regions.

Abstract translation: 本公开提供了制造半导体器件的方法。 该方法包括提供包括形成为填充两个相邻层间电介质（ILD）区域之间的沟槽的金属栅极（MG）层的半导体结构; 使用CMP系统进行化学机械抛光（CMP）处理以使MG层和ILD区域平坦化; 以及使用溶解在去离子水（DIW）中的包含臭氧气体（O 3）的O 3 / DIW溶液清洗平坦化的MG层。 MG层形成在ILD区域上。

公开(公告)号：US09209272B2

公开(公告)日：2015-12-08

申请号：US14024247

申请日：2013-09-11

Applicant: Taiwan Semiconductor Manufacturing Company, Ltd.

Inventor： Chi-Jen Liu ,  Li-Chieh Wu ,  Shich-Chang Suen ,  Liang-Guang Chen

IPC: H01L21/00 ,  H01L29/66 ,  H01L21/02 ,  H01L21/28 ,  H01L29/49 ,  H01L29/51

CPC classification number: H01L29/66545 ,  H01L21/02074 ,  H01L21/28088 ,  H01L21/28123 ,  H01L21/3212 ,  H01L21/76802 ,  H01L21/76805 ,  H01L21/76829 ,  H01L21/76831 ,  H01L21/76895 ,  H01L29/4966 ,  H01L29/517 ,  H01L29/665 ,  H01L29/6659

Abstract: A method includes forming a dummy gate of a transistor at a surface of a wafer, removing the dummy gate, and filling a metallic material into a trench left by the removed dummy gate. A Chemical Mechanical Polish (CMP) is then performed on the metallic material, wherein a remaining portion of the metallic material forms a metal gate of the transistor. After the CMP, a treatment is performed on an exposed top surface of the metal gate using an oxidation-and-etching agent comprising chlorine and oxygen.

Abstract translation: 一种方法包括在晶片的表面上形成晶体管的虚拟栅极，去除虚拟栅极，并将金属材料填充到由去除的虚拟栅极留下的沟槽中。 然后对金属材料进行化学机械抛光（CMP），其中金属材料的剩余部分形成晶体管的金属栅极。 在CMP之后，使用包含氯和氧的氧化 - 蚀刻剂在金属栅极的暴露的顶表面上进行处理。

公开(公告)号：US20150179432A1

公开(公告)日：2015-06-25

申请号：US14134914

申请日：2013-12-19

Applicant: Taiwan Semiconductor Manufacturing Company, Ltd.

Inventor： Shich-Chang Suen ,  Chi-Jen Liu ,  Ying-Liang Chuang ,  Li-Chieh Wu ,  Liang-Guang Chen ,  Ming-Liang Yen

IPC: H01L21/02 ,  H01L21/306

CPC classification number: H01L21/28123 ,  B24B37/20 ,  H01L21/02074 ,  H01L21/3212 ,  H01L21/67051 ,  H01L29/66545

Abstract: The present disclosure provides a method of fabricating a semiconductor device. The method includes providing a semiconductor structure including a metal gate (MG) layer formed to fill in a trench between two adjacent interlayer dielectric (ILD) regions; performing a chemical mechanical polishing (CMP) process using a CMP system to planarize the MG layer and the ILD regions; and cleaning the planarized MG layer using a O3/DIW solution including ozone gas (O3) dissolved in deionized water (DIW). The MG layer is formed on the ILD regions.

Abstract translation: 本公开提供了制造半导体器件的方法。 该方法包括提供包括形成为填充两个相邻层间电介质（ILD）区域之间的沟槽的金属栅极（MG）层的半导体结构; 使用CMP系统进行化学机械抛光（CMP）处理以使MG层和ILD区域平坦化; 以及使用溶解在去离子水（DIW）中的包含臭氧气体（O 3）的O 3 / DIW溶液清洗平坦化的MG层。 MG层形成在ILD区域上。

公开(公告)号：US11658065B2

公开(公告)日：2023-05-23

申请号：US16902203

申请日：2020-06-15

Applicant: TAIWAN SEMICONDUCTOR MANUFACTURING COMPANY LTD.

Inventor： Ji Cui ,  Fu-Ming Huang ,  Ting-Kui Chang ,  Tang-Kuei Chang ,  Chun-Chieh Lin ,  Wei-Wei Liang ,  Chi-Hsiang Shen ,  Ting-Hsun Chang ,  Li-Chieh Wu ,  Hung Yen ,  Chi-Jen Liu ,  Liang-Guang Chen ,  Kei-Wei Chen

IPC: H01L21/768 ,  C09K3/14 ,  C09G1/02 ,  H01L21/321

CPC classification number: H01L21/7684 ,  C09G1/02 ,  C09K3/1463 ,  C09K3/1481 ,  H01L21/3212 ,  H01L21/76877

Abstract: A method for CMP includes following operations. A metal layer is received. A CMP slurry composition is provided in a CMP apparatus. The CMP slurry composition includes at least a first oxidizer and a second oxidizer different from each other. The first oxidizer is oxidized to form a peroxidant by the second oxidizer. A portion of the metal layer is oxidized to form a first metal oxide by the peroxidant. The first metal oxide is re-oxidized to form a second metal oxide by the second oxidizer.