Precipitated silicas, a process for their preparation and their use in
vulcanizable rubber mixtures
    244.
    发明授权
    Precipitated silicas, a process for their preparation and their use in vulcanizable rubber mixtures 失效
    沉淀二氧化硅,其制备方法及其在可硫化橡胶混合物中的应用

    公开(公告)号:US5705137A

    公开(公告)日:1998-01-06

    申请号:US655035

    申请日:1996-05-29

    Abstract: Precipitated silicas, characterized in that they have a CTAB surface area (in accordance with ASTM D 3765-92) of 200 to 400 m.sup.2 /g, a DBP index (in accordance with ASTM D 2414) between 230 and 380 ml/100 g as powder and 180-250 g/100 g as granulate, a silanol group density (V.sub.2 -NaOH consumption) of 20 to 30 ml and the following macropore size distribution which is typical of the surface area range involved, determined by means of Hg porosimetry (DIN 66 133) for specific pore size intervals (incremental mode of application): ______________________________________ CTAB surface CTAB surface CTAB surface area range: area range: area range: 200-250 250-300 300-400 Pore size m.sup.2 /g m.sup.2 /g m.sup.2 /g interval �nm! Hg consumption in ml/g of silica ______________________________________ 10-20 0.27-0.49 0.35-0.50 0.32-0.42 20-30 0.22-0.32 0.15-0.30 0.17-0.22 30-40 0.15-0.21 0.12-0.17 0.12-0.15 40-50 0.11-0.16 0.09-0.12 0.08-0.11 50-60 0.08-0.12 0.06-0.10 0.06-0.09 ______________________________________

    Abstract translation: 沉淀二氧化硅,其特征在于它们具有200至400m 2 / g的CTAB表面积(根据ASTM D 3765-92),230至380ml / 100g之间的DBP指数(根据ASTM D 2414)为 粉末和180-250g / 100g作为颗粒,硅烷醇组密度(V2-NaOH消耗)为20至30ml,并且通过Hg孔隙率法(通过Hg孔隙率法测定)是典型的涉及的表面积范围的大孔分布 DIN 66 133)适用于特定孔径间隔(增量模式): - CTAB表面CTAB表面CTAB表面 - 面积范围:面积范围:面积范围: - 200-250 250-300 300-400 - 孔径m2 / g m2 / g m2 / g - 间隔[nm]汞消耗量,单位为ml / g二氧化硅 - 10-20 0.27-0.49 0.35-0.50 0.32-0.42 - 20-30 0.22-0.32 0.15-0.30 0.17-0.22 - 30-40 0.15- 0.21 0.12-0.17 0.12-0.15 - 40-50 0.11-0.16 0.09-0.12 0.08-0.11 - 50-60 0.08-0.12 0.06-0.10 0.06-0.09 -

    CONDUCTIVE RUBBER COMPOSITION FOR SENSING
    248.
    发明公开

    公开(公告)号:US20240343885A1

    公开(公告)日:2024-10-17

    申请号:US18292559

    申请日:2022-05-26

    Inventor: Tomohiro URATA

    CPC classification number: C08K3/04 C08K2201/001 C08K2201/006

    Abstract: The technical problem of the present disclosure is to provide a conductive rubber composition for sensing that has good responsiveness of changes in electrical resistance to strain and can accurately detect the occurrence of cracks. The solution is a conductive rubber composition for sensing, containing a rubber component and carbon black, wherein the rubber component contains 80% by mass or more of acrylonitrile-butadiene rubber, a product (A×B×C) of a cetyltrimethylammonium bromide (CTAB) adsorption specific surface area A (m2/g) of the carbon black, a compressed dibutyl phthalate (24M4DBP) absorption amount B (mL/100 g) of the carbon black, and a content C (parts by mass) of the carbon black per 100 parts by mass of the rubber component is 600,000 or more, and the cetyltrimethylammonium bromide (CTAB) adsorption specific surface area A of the carbon black is 110 m2/g or more.

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