公开(公告)号：US09757688B2

公开(公告)日：2017-09-12

申请号：US14641255

申请日：2015-03-06

申请人： Sidel Systems USA Inc.

发明人： Parthosarothy K. Mukherji

IPC分类号： B01D53/62 ,  F23J15/02 ,  B01D53/14 ,  F23J15/04

CPC分类号： B01D53/62 ,  B01D53/1475 ,  B01D53/1493 ,  B01D2251/404 ,  B01D2251/602 ,  B01D2251/606 ,  B01D2252/205 ,  F23J15/04 ,  F23J2215/50 ,  F23J2219/40 ,  Y02A50/2342 ,  Y02C10/04 ,  Y02C10/06 ,  Y02E20/326

摘要： A method of capturing carbon dioxide emitted by a power plant includes providing a reactor vessel having a shell with a top and a bottom, introducing an exhaust gas stream into the reactor vessel, the exhaust gas stream containing carbon dioxide, whereby the exhaust gas stream rises toward the top of the reactor vessel. The method includes introducing an organic sorbent solution into the reactor vessel near the top of the reactor vessel so that the organic sorbent solution falls toward the bottom of the reactor vessel, mixing the rising exhaust gas stream with the falling organic sorbent solution to precipitate calcium carbonate, and removing the calcium carbonate from the bottom of the reactor vessel, whereby the calcium carbonate includes the carbon dioxide from the exhaust gas stream.

公开(公告)号：US20170100618A1

公开(公告)日：2017-04-13

申请号：US15315858

申请日：2015-06-03

申请人： SOLVAY SA

发明人： Rasik H. RAYTHATHA ,  David Jean Lucien SAVARY

IPC分类号： A62D3/33 ,  F23J15/00 ,  B01D53/80 ,  B09B3/00 ,  B01D53/50 ,  B01D53/64

CPC分类号： A62D3/33 ,  A62D2101/08 ,  A62D2101/24 ,  A62D2101/43 ,  B01D53/508 ,  B01D53/64 ,  B01D53/80 ,  B01D53/83 ,  B01D53/8693 ,  B01D2251/304 ,  B01D2251/402 ,  B01D2251/404 ,  B01D2251/60 ,  B01D2251/602 ,  B01D2251/604 ,  B01D2251/606 ,  B01D2257/302 ,  B01D2257/60 ,  B01D2258/0283 ,  B09B3/0008 ,  B09B3/0041 ,  B09B2220/06 ,  C04B18/08 ,  C04B20/1085 ,  F23J15/003 ,  F23J2215/60 ,  Y02W30/92 ,  C04B20/023

摘要： A treatment method for stabilizing at least a portion of at least one heavy metal contained in a sodic fly ash to reduce leachability, wherein the sodic fly ash is provided by a process whereby a sodium-based sorbent is injected in a combustion flue gas to remove pollutants therefrom. The treatment method comprises contacting the sodic fly ash with at least one water-soluble source of silicate and at least one additive comprising calcium and/or magnesium. The material obtained from the contacting step is preferably dried. The additive may be selected from the group consisting of lime kiln dust, fine limestone, quicklime, hydrated lime, dolomitic lime, dolomite, selectively calcined dolomite, hydrated dolomite, magnesium hydroxide, magnesium carbonate, magnesium oxide, and any mixture thereof. A particularly preferred additive comprises lime kiln dust and/or dolomitic lime. The heavy metal to be stabilized in the sodic fly ash may comprise selenium and/or arsenic.

公开(公告)号：US20170014750A1

公开(公告)日：2017-01-19

申请号：US15301099

申请日：2015-07-08

申请人： HITACHI CHEMICAL COMPANY, LTD.

发明人： Kouhei YOSHIKAWA ,  Masato KANEEDA ,  Hidehiro NAKAMURA ,  Toshiaki SHIRASAKA

IPC分类号： B01D53/04 ,  B01D53/82 ,  B01D53/26 ,  B01J38/02 ,  B01D53/96 ,  B01D53/047 ,  B01J20/06 ,  B01J20/18 ,  B01D53/62 ,  B01D53/34

CPC分类号： B01D53/0438 ,  B01D53/04 ,  B01D53/0454 ,  B01D53/0462 ,  B01D53/047 ,  B01D53/06 ,  B01D53/261 ,  B01D53/30 ,  B01D53/346 ,  B01D53/62 ,  B01D53/81 ,  B01D53/82 ,  B01D53/96 ,  B01D2251/602 ,  B01D2253/108 ,  B01D2253/1124 ,  B01D2257/504 ,  B01D2257/80 ,  B01D2258/0283 ,  B01D2259/4009 ,  B01D2259/40096 ,  B01D2259/402 ,  B01J20/04 ,  B01J20/06 ,  B01J20/08 ,  B01J20/10 ,  B01J20/18 ,  B01J20/20 ,  B01J23/10 ,  B01J35/1019 ,  B01J37/031 ,  B01J37/08 ,  B01J38/02 ,  Y02A50/2342 ,  Y02C10/04 ,  Y02C10/08

摘要： A CO2 removal device includes: a CO2 capturing material which captures H2O and CO2 in a gas; a reaction container which contains the CO2 capturing material; an H2O measuring unit for measuring the concentration of H2O in the gas; an H2O concentration adjustment device which adjusts the concentration of H2O on the basis of information obtained by the H2O measuring unit; a gas introduction path introducing the gas into the reaction container from the H2O concentration adjustment device and bringing the gas into contact with the CO2 capturing material; a first gas discharge path discharging the gas from the reaction container after the gas has been brought into contact with the CO2 capturing material; and a second gas discharge path discharging the gas that has been desorbed from the CO2 capturing material from the reaction container. The CO2 removal device allows for the reduction of energy consumption in removing CO2.

摘要翻译： CO 2去除装置包括：捕获气体中的H 2 O和CO 2的CO 2捕获材料; 含有CO 2捕获材料的反应容器; 用于测量气体中H 2 O浓度的H 2 O测量单元; H 2 O浓度调节装置，其基于由H 2 O测量单元获得的信息来调节H 2 O的浓度; 从H 2 O浓度调节装置将气体引入反应容器并使气体与CO 2捕获材料接触的气体导入路径; 在所述气体与所述CO 2捕获材料接触之后，从所述反应容器排出气体的第一气体排出路径; 以及将从CO 2捕获材料解吸的气体从反应容器排出的第二气体排出路径。 CO2去除装置可以减少去除二氧化碳的能源消耗。

公开(公告)号：US20160325226A1

公开(公告)日：2016-11-10

申请号：US15108968

申请日：2014-12-30

申请人： BEIJING SJ ENVIRONMENTAL PROTECTION AND NEW MATERIAL CO., LTD.

发明人： Liying Li ,  Wenwen SONG ,  Wenjun MAO ,  Zhimin ZHANG ,  Boshu LIU ,  Zhenyi Liu

IPC分类号： B01D53/80 ,  B01J21/16 ,  B01J23/78 ,  B01J37/00 ,  B01J37/04 ,  B01J20/30 ,  B01J37/06 ,  B01J20/12 ,  B01J20/04 ,  B01J20/08 ,  B01J20/02 ,  B01D53/48 ,  B01J37/08

CPC分类号： B01D53/80 ,  B01D53/485 ,  B01D2251/602 ,  B01D2257/308 ,  B01J20/0229 ,  B01J20/041 ,  B01J20/08 ,  B01J20/12 ,  B01J20/3007 ,  B01J20/3014 ,  B01J20/3071 ,  B01J20/3078 ,  B01J20/3085 ,  B01J21/04 ,  B01J21/063 ,  B01J21/16 ,  B01J23/78 ,  B01J37/0009 ,  B01J37/0036 ,  B01J37/031 ,  B01J37/04 ,  B01J37/06 ,  B01J37/08 ,  B01J37/088

摘要： Provided is a high-concentration carbonyl sulfide conversion-absorption type desulfurizer for use at medium-low temperature and preparation method thereof. The desulfurizer comprises 50%-75% magnetic iron oxide red (Fe21.333O32), 5%-10% alkali metal oxide (K2O), 5-35% anatase TiO2, and 5-10% shaping binder. The method of preparing the desulfurizer comprises: uniformly mixing a metatitanic acid prepared using ferrous sulfate recycled as a by-product from titanium dioxide production with K2CO3, calcining to activate at 500° C.-700° C., mixing with the magnetic iron oxide red and binder, roll molding at room temperature to form balls which are dried at 100° C.-150° C. to obtain the desulfurizer. The desulfurizer has a hydrolysis conversion of carbonyl sulfide higher than 99%, and has a higher sulfur capacity more than 25%.

摘要翻译： 提供了用于中低温的高浓度硫化羰转化吸收型脱硫剂及其制备方法。 脱硫剂包括50％-75％的磁性氧化铁红（Fe21.333O32），5％-10％的碱金属氧化物（K2O），5-35％的锐钛型TiO 2和5-10％的成型粘合剂。 制备脱硫剂的方法包括：将以二氧化钛生产的副产物再循环的硫酸亚铁制备的偏钛酸与K 2 CO 3均匀混合，煅烧以在500℃-700℃下活化，与磁性氧化铁 红色和粘合剂，在室温下成型，形成在100℃-150℃下干燥以获得脱硫剂的球。 脱硫剂具有高于99％的羰基硫化物的水解转化率，硫含量高于25％。

公开(公告)号：US20160279569A1

公开(公告)日：2016-09-29

申请号：US15034542

申请日：2014-11-06

申请人： ThyssenKrupp Industrial Solutions AG

发明人： Timo STENDER ,  Melanie FLAßPÖHLER ,  Kathrin ROHLOFF

IPC分类号： B01D53/86 ,  C04B7/36 ,  C04B7/43 ,  B01D53/90 ,  B01D53/06

CPC分类号： B01D53/8656 ,  B01D53/06 ,  B01D53/10 ,  B01D53/8653 ,  B01D53/90 ,  B01D2251/602 ,  B01D2257/302 ,  B01D2257/404 ,  B01D2257/502 ,  B01D2257/702 ,  B01D2258/0233 ,  C04B7/364 ,  C04B7/365 ,  C04B7/43 ,  C04B7/436

摘要： A method for cleaning bypass gases of the cement or mineral industry includes cooling down a removed bypass gas from a cement or mineral processing plant to a temperature of between 500° C. and 150° C., and coarsely dedusting the bypass gas, the dust burden being reduced by 30 to 95%. After the dedusting step, the gaseous constituents contained in the partly dedusted bypass gas are reduced in a reducing step. The partly dedusted bypass gas is further finely dedusted. The gaseous constituents reducing step includes at least a catalytic reduction of one or more of nitrogen oxides, hydrocarbons, and carbon monoxide.

摘要翻译： 用于清洁水泥或矿物工业的旁路气体的方法包括将去除的旁路气体从水泥或矿物加工设备冷却至500℃至150℃的温度，并将旁路气体，灰尘 负担减少了30％至95％。 在除尘步骤之后，包含在部分除尘旁通气体中的气态组分在还原步骤中减少。 部分除尘旁路气体进一步细分除尘。 气态成分还原步骤至少包括一种或多种氮氧化物，烃类和一氧化碳的催化还原。

公开(公告)号：US20160243498A1

公开(公告)日：2016-08-25

申请号：US15025783

申请日：2015-01-22

申请人： MITSUBISHI HITACHI POWER SYSTEMS, LTD.

发明人： Naoyuki Kamiyama ,  Seiji Kagawa ,  Toshihiro Fukuda ,  Tetsu Ushiku

IPC分类号： B01D53/50 ,  F23L15/04 ,  F23J15/04 ,  B01D53/56 ,  B01D53/64

CPC分类号： B01D53/50 ,  B01D53/501 ,  B01D53/56 ,  B01D53/64 ,  B01D53/75 ,  B01D53/869 ,  B01D2251/404 ,  B01D2251/602 ,  B01D2251/604 ,  B01D2251/606 ,  B01D2257/302 ,  B01D2257/404 ,  F23J15/003 ,  F23J15/04 ,  F23J15/06 ,  F23J2215/10 ,  F23J2215/20 ,  F23J2219/10 ,  F23J2219/60 ,  F23L15/04 ,  Y02A50/2348 ,  Y02E20/348

摘要： Provided are: an NOx removal unit to remove nitrogen oxide; an air preheater on a downstream side of the NOx removal unit to recover heat; a precipitator on a downstream side of the air preheater to remove ash dust; a gas-liquid contact type desulfurization unit on a downstream side of the precipitator to remove sulfur oxide; an SO3 removing agent supply unit to supply an SO3 removing agent at a supply unit on an upstream side of the precipitator; and a wet state processing unit between the air preheater and the supply unit to supply water to a flue gas to be made into a wet state; the wet state processing unit having a stand-up portion, a partition unit and a droplet supply unit.

摘要翻译： 提供：除去氮氧化物的NOx去除单元; 在NOx去除单元的下游侧的空气预热器，用于回收热量; 在空气预热器的下游侧具有除尘器以除灰尘; 在除尘器的下游侧的气液接触型脱硫单元，以除去硫氧化物; SO 3去除剂供给单元，其在所述除尘器的上游侧的供给单元供给SO 3除去剂; 以及空气预热器和供给单元之间的湿态处理单元，用于向待制成湿态的烟道气供水; 湿状态处理单元具有支撑部分，分隔单元和液滴供应单元。

公开(公告)号：US09192890B2

公开(公告)日：2015-11-24

申请号：US14336645

申请日：2014-07-21

申请人： Babcock & Wilcox Power Generation Group, Inc.

发明人： Eric M Warren ,  Jeb W Gayheart ,  Anthony A Silva

IPC分类号： B01D53/50 ,  B01D53/81 ,  B01D53/83 ,  B01D53/86

CPC分类号： B01D53/508 ,  B01D53/505 ,  B01D53/8631 ,  B01D53/869 ,  B01D2251/404 ,  B01D2251/602 ,  B01D2251/604 ,  B01D2251/606 ,  B01D2257/2045 ,  B01D2258/0283 ,  F23J15/003 ,  F23J15/006 ,  F23J2215/20 ,  F23J2217/101 ,  F23J2217/102 ,  F23J2219/10 ,  F23J2219/60

摘要： An integrated sorbent injection, heat recovery, and flue gas desulfurization system is disclosed. A dry sorbent is injected into the flue gas upstream of the air heater. This reduces the acid dew point temperature, permitting additional heat energy to be captured when the flue gas passes through the air heater. The flue gas then passes through a desulfurization unit and through a baghouse, where solids are captured. The capture of additional heat energy permits the overall boiler efficiency to be increased while safely operating at a lower flue gas temperature. The integrated system consumes no greater quantity of sorbent than conventional methods but provides the benefit of improved plant heat rate.

摘要翻译： 公开了一种综合的吸附剂注入，热回收和烟道气脱硫系统。 将干燥的吸附剂注入到空气加热器上游的烟道气中。 这降低了酸露点温度，允许在烟道气通过空气加热器时捕获额外的热能。 然后，烟道气通过脱硫单元并通过捕集固体的袋屋。 捕获额外的热能允许总体锅炉效率提高，同时在较低的烟道气温度下安全运行。 该集成系统比常规方法消耗的吸附剂数量不大，但提供改善植物热量的益处。

公开(公告)号：US20150322357A1

公开(公告)日：2015-11-12

申请号：US14803462

申请日：2015-07-20

申请人： Calix Limited

发明人： Mark Geoffrey Sceats ,  Julian Westley Dinsdale

IPC分类号： C10K1/00 ,  C10L3/10 ,  C10K1/32 ,  C10K3/00 ,  C10K1/26

CPC分类号： C10K1/005 ,  B01D53/62 ,  B01D2251/402 ,  B01D2251/404 ,  B01D2251/602 ,  B01D2253/1124 ,  B01D2253/304 ,  B01D2257/504 ,  B01J20/041 ,  B01J20/28004 ,  B01J20/3204 ,  B01J20/3433 ,  B01J20/3483 ,  B01J2220/42 ,  C01B3/16 ,  C01B3/384 ,  C01B32/50 ,  C01B2203/0233 ,  C01B2203/0425 ,  C01B2203/0475 ,  C01B2203/0822 ,  C01B2203/0827 ,  C01B2203/1241 ,  C01B2203/84 ,  C01B2203/86 ,  C10K1/26 ,  C10K1/32 ,  C10K1/34 ,  C10K3/00 ,  C10K3/04 ,  C10L3/08 ,  C10L3/104 ,  C10L2290/12 ,  C10L2290/542 ,  Y02C10/04 ,  Y02C10/08 ,  Y02P20/128 ,  Y02P20/152 ,  Y02P30/30

摘要： A method and system for processing an input fuel gas and steam to produce separate CO2 and output fuel gas streams. The method comprises the steps of using a decarboniser segment for reacting at least a solid sorbent reacts with the fuel gas and steam to remove carbon from the input fuel gas and to produce the output fuel gas stream in an exhaust gas from the decarboniser; using a calciner segment for reacting the solid sorbent from the decarboniser segment therein to release the CO2 into the CO2 gas stream; wherein CO2 partial pressures and temperatures in the decarboniser and calciner segments respectively are controlled such that the temperature in the decarboniser segment is higher than the temperature in the calciner.

摘要翻译： 一种用于处理输入燃料气体和蒸汽以产生单独的CO 2并输出燃料气流的方法和系统。 所述方法包括以下步骤：使用脱碳段进行反应，使至少一种固体吸附剂与燃料气体和蒸汽反应，以从输入燃料气体中除去碳，并产生来自脱碳装置的排气中的输出燃料气流; 使用煅烧段将来自其中的脱碳碳段的固体吸附剂反应以将CO 2释放到CO 2气流中; 其中控制脱碳装置和煅烧炉段中的CO 2分压和温度，使得脱碳分段中的温度高于煅烧炉中的温度。

公开(公告)号：US09149766B2

公开(公告)日：2015-10-06

申请号：US14663520

申请日：2015-03-20

申请人： IHI CORPORATION

发明人： Toshiyuki Naito

IPC分类号： B01D53/00 ,  F25J1/00 ,  B01D53/75 ,  B01D53/34

CPC分类号： B01D53/75 ,  B01D53/002 ,  B01D53/261 ,  B01D53/265 ,  B01D53/346 ,  B01D53/501 ,  B01D53/56 ,  B01D53/60 ,  B01D53/68 ,  B01D53/78 ,  B01D2251/304 ,  B01D2251/402 ,  B01D2251/404 ,  B01D2251/602 ,  B01D2251/604 ,  B01D2251/606 ,  B01D2257/2045 ,  B01D2257/302 ,  B01D2257/404 ,  B01D2257/504 ,  B01D2257/602 ,  B01D2257/80 ,  B01D2258/0283 ,  C01B32/50 ,  F23J15/06 ,  F23J2215/50 ,  Y02E20/326 ,  Y02E20/344 ,  Y02P20/152

摘要： Impurities in exhaust gas from oxyfuel combustor are removed using simple equipment to reduce installation cost. Compressor-based impurity removal system for compressing exhaust gas mainly composed of carbon dioxide from combustor before supply to carbon dioxide liquefier for removal of impurities in exhaust gas has impurity separators with compressors for compressing exhaust gas from combustor stepwisely to target pressure for liquefaction of carbon dioxide and with aftercoolers for cooling exhaust gas compressed by compressors, water condensed by cooling being discharged as drain, and alkaline agent supply unit for supplying alkaline agent to at least upstream side of aftercooler in first impurity separator. Impurities in exhaust gas are discharged through drain including alkaline agent.

摘要翻译： 使用简单的设备除去来自含氧燃烧器的废气中的杂质，以降低安装成本。 用于压缩主要由二氧化碳组成的废气的废气排出系统，用于从二氧化碳液化器排出废气中的二氧化碳，用于除去废气中的杂质，其中包括具有压缩机的杂质分离器，用于逐步压缩来自燃烧器的废气到二氧化碳液化的目标压力 并且用于冷却由压缩机压缩的废气的后冷却器，通过冷却冷凝的水作为排放物排出，以及用于在第一杂质分离器中的至少后级冷却器的上游侧供应碱性试剂的碱剂供给单元。 排气中的杂质通过包括碱性剂在内的排水排出。

公开(公告)号：US09149765B2

公开(公告)日：2015-10-06

申请号：US14662446

申请日：2015-03-19

申请人： IHI Corporation

发明人： Toshiyuki Naito

IPC分类号： B01D53/00 ,  F25J1/00 ,  B01D53/75 ,  B01D53/34

CPC分类号： B01D53/75 ,  B01D53/002 ,  B01D53/346 ,  B01D53/60 ,  B01D53/78 ,  B01D53/79 ,  B01D2251/404 ,  B01D2251/602 ,  B01D2251/604 ,  B01D2251/606 ,  B01D2257/2045 ,  B01D2257/302 ,  B01D2257/404 ,  B01D2257/504 ,  B01D2257/602 ,  B01D2257/80 ,  B01D2258/0283 ,  C01B32/50 ,  F23J15/06 ,  F23J2215/50 ,  F23J2900/15061 ,  Y02E20/326 ,  Y02E20/344 ,  Y02P20/152

摘要： Provided are impurity separators which have compressors for supplying exhaust gas comprising carbon dioxide from oxyfuel combustor to target pressure stepwisely before supply to carbon dioxide liquefier and have aftercoolers for cooling exhaust gas compressed by the compressors stepwisely to target pressure, water condensed by cooling being discharged as drain; alkaline agent supply unit which supplies alkaline agent to upstream side of aftercooler in last impurity separator to discharge drain containing alkaline agent having removed impurities in exhaust gas from aftercooler in last impurity separator; and circulation line for supplying of drain from aftercooler in last impurity separator to upstream side of aftercooler in first impurity separator.

摘要翻译： 提供了一种杂质分离器，其具有用于在供应到二氧化碳液化器之前逐步地将来自氧燃料燃烧器的二氧化碳供给排气的排气的压缩机分阶段地进行压缩，并且具有用于将由压缩机压缩的废气逐步降低至目标压力的后冷却器，通过冷却冷凝的水以 排水; 碱性剂供给单元，其向最后的杂质分离器中的后冷却器的上游侧供给碱性试剂，以排出含有最后杂质分离器中的来自后冷却器的废气中除去杂质的碱性试剂; 以及用于在第一杂质分离器中将后一个杂质分离器中的后冷却器的排水供给到后冷器的上游侧的循环管线。