High performance alloys with improved metal dusting corrosion resistance
    41.
    发明申请
    High performance alloys with improved metal dusting corrosion resistance 有权
    具有改善金属除尘耐腐蚀性能的高性能合金

    公开(公告)号:US20060257675A1

    公开(公告)日:2006-11-16

    申请号:US11126007

    申请日:2005-05-10

    IPC分类号: B32B15/04 B32B9/00

    摘要: Alloy compositions which are resistant to metal dusting corrosion are provided by the present invention. Also provided are methods for preventing metal dusting on metal surfaces exposed to carbon supersaturated environments. The alloy compositions include an alloy (PQR), and a multi-layer oxide film on the surface of the alloy (PQR). The alloy (PQR) includes a metal (P) selected from the group consisting of Fe, Ni, Co, and mixtures thereof, an alloying metal (Q) comprising Cr, Mn, and either Al, Si, or Al/Si, and an alloying element (R). When the alloying metal (Q) includes Al, the multi-layer oxide film on the surface of the alloy includes at least three oxide layers. When the alloying metal (Q) includes Si, the multi-layer oxide film on the surface of the alloy (PQR) includes at least four oxide layers. When the alloying metal (Q) includes Al and Si, the multi-layer oxide film on the surface of the alloy (PQR) includes at least three oxide layers. The multi-layer oxide film is formed in situ during use of the alloy composition in a carbon supersaturated metal dusting environment. Advantages exhibited by the disclosed alloy compositions include improved metal dusting corrosion resistance at high temperatures in carbon-supersaturated environments having relatively low oxygen partial pressures. The disclosed alloy compositions are suitable for use as the inner surfaces in reactor systems and refinery apparatus.

    摘要翻译: 耐金属粉尘腐蚀的合金组合物由本发明提供。 还提供了防止金属表面暴露于碳过饱和环境的金属粉尘的方法。 合金组合物包括合金(PQR)和合金表面上的多层氧化膜(PQR)。 合金(PQR)包括选自Fe,Ni,Co及其混合物的金属(P),包含Cr,Mn以及Al,Si或Al / Si的合金金属(Q),以及 合金元素(R)。 当合金金属(Q)包括Al时,合金表面上的多层氧化物膜包括至少三个氧化物层。 当合金金属(Q)包含Si时,合金表面上的多层氧化物膜(PQR)包括至少四个氧化物层。 当合金金属(Q)包括Al和Si时,合金表面上的多层氧化物膜(PQR)包括至少三个氧化物层。 在碳过饱和金属粉尘环境中的合金组合物的使用期间,多层氧化物膜原位形成。 所公开的合金组合物显示的优点包括在具有相对低的氧分压的碳过饱和环境中的高温下改善的金属粉尘耐腐蚀性。 所公开的合金组合物适用于反应器系统和炼油设备中的内表面。

    Porous pyrolysis reactor materials and methods
    43.
    发明授权
    Porous pyrolysis reactor materials and methods 有权
    多孔热解反应器的材料及方法

    公开(公告)号:US08932534B2

    公开(公告)日:2015-01-13

    申请号:US12623046

    申请日:2009-11-20

    摘要: In one aspect, the invention includes a reactor apparatus for pyrolyzing a hydrocarbon feedstock, said apparatus including: a reactor component comprising a refractory material in oxide form, the refractory material having a melting point of no less than 2060° C. and which remains in oxide form when exposed to a gas having carbon partial pressure of 10−22 bar and oxygen partial pressure of 10−10 bar, at a temperature of 1200° C.; wherein said refractory material has no less than 4 vol % formed porosity, measured at 20° C., based upon the bulk volume of said refractory material. In another embodiment, the refractory material has total porosity in the range of from 4 to 60 vol %.

    摘要翻译: 在一个方面,本发明包括用于热解烃原料的反应器装置,所述装置包括:反应器组件,其包含氧化物形式的耐火材料,耐火材料的熔点不低于2060℃,并保持在 在1200℃的温度下暴露于碳分压为10-22巴,氧气分压为10-10巴的气体时,氧化物形式。 其中所述耐火材料具有基于所述耐火材料的体积体积在20℃下测量的不少于4体积%的孔隙率。 在另一个实施方案中,耐火材料具有4至60体积%的总孔隙率。

    Alumina forming bimetallic tube for refinery process furnaces and method of making and using
    44.
    发明授权
    Alumina forming bimetallic tube for refinery process furnaces and method of making and using 有权
    用于炼油工艺炉的氧化铝形成双金属管及其制造和使用方法

    公开(公告)号:US08877342B2

    公开(公告)日:2014-11-04

    申请号:US13446376

    申请日:2012-04-13

    摘要: Provided is a bimetallic tube for transport of hydrocarbon feedstocks in refinery process furnaces, and more particularly in furnace radiant coils, including: i) an outer tube layer being formed from stainless steels including chromium in the range of 15.0 to 26.0 wt. % based on the total weight of the stainless steel; ii) an inner tube layer being formed from an alumina forming bulk alloy including 5.0 to 10.0 wt. % of Al, 20.0 wt. % to 25.0 wt. % Cr, less than 0.4 wt. % Si, and at least 35.0 wt. % Fe with the balance being Ni, wherein the inner tube layer is formed plasma powder welding the alumina forming bulk alloy on the inner surface of the outer tube layer; and iii) an oxide layer formed on the surface of the inner tube layer, wherein the oxide layer is substantially comprised of alumina, chromia, silica, mullite, spinels, or mixtures thereof.

    摘要翻译: 本发明提供一种用于在精炼加工炉中更加特别是在炉内辐射线圈中输送烃原料的双金属管,包括:i)由不锈钢形成的外管层,该不锈钢包括15.0至26.0wt。 基于不锈钢总重量%; ii)内管层,其由包含5.0至10.0重量%的氧化铝形成块状合金形成。 %的Al,20.0wt。 %至25.0wt。 %Cr,小于0.4wt。 %Si,和至少35.0wt。 %Fe,余量为Ni,其中内管层形成等离子体粉末,将氧化铝形成体合金焊接在外管层的内表面上; 以及iii)形成在所述内管层的表面上的氧化物层,其中所述氧化物层基本上由氧化铝,氧化铬,二氧化硅,莫来石,尖晶石或其混合物组成。

    Stabilized Ceramic Composition, Apparatus and Methods of Using the Same
    50.
    发明申请
    Stabilized Ceramic Composition, Apparatus and Methods of Using the Same 有权
    稳定的陶瓷组合物,使用它的装置和方法

    公开(公告)号:US20100292522A1

    公开(公告)日:2010-11-18

    申请号:US12467752

    申请日:2009-05-18

    摘要: In one aspect, the invention includes a refractory material, said material comprising: (i) at least 20 wt. % of a first grain mode stabilized zirconia based upon the total weight of said material, said first grain mode having a D50 grain size in the range of from 5 to 2000 μm, said stabilized zirconia including a matrix oxide stabilizer; (ii) at least 1 wt. % of a second grain mode having a D50 grain size in the range of from 0.01 μm up to not greater than one-fourth the D50 grain size of said first grain mode zirconia, based upon the total weight of said material; and (iii) at least 1 wt. % of a preservative component within at least one of said first grain mode stabilized zirconia, said second grain mode stabilized zirconia, and an optional another grain mode; wherein after sintering, said material has porosity at 20° C. in the range of from 5 to 45 vol %.

    摘要翻译: 一方面,本发明包括耐火材料,所述材料包括:(i)至少20wt。 基于所述材料的总重量的第一晶粒模式稳定化氧化锆的%,所述第一晶粒模式具有在5至2000μm范围内的D50晶粒尺寸,所述稳定化氧化锆包括基体氧化物稳定剂; (ii)至少1wt。 基于所述材料的总重量,具有D50晶粒尺寸在0.01μm至不超过所述第一晶粒模式氧化锆的D50晶粒尺寸的四分之一范围内的第二晶粒模式的%。 和(iii)至少1wt。 所述第一晶粒模式稳定化氧化锆,所述第二晶粒模式稳定化氧化锆和任选的另一晶粒模式中的至少一种中的防腐剂组分% 其中烧结后,所述材料在20℃下的孔隙率为5-45体积%。