公开(公告)号：US20090227814A1

公开(公告)日：2009-09-10

申请号：US12392122

申请日：2009-02-25

Applicant: Masahiro HOSHINO ,  Nobufumi Watanabe ,  Keisuke Sugita

Inventor： Masahiro HOSHINO ,  Nobufumi Watanabe ,  Keisuke Sugita

IPC: C07C35/08 ,  C07C45/33

CPC classification number: B01J35/1061 ,  B01J23/38 ,  B01J23/70 ,  B01J23/75 ,  B01J29/0308 ,  B01J35/1023 ,  B01J35/1028 ,  B01J37/0018 ,  B01J37/033 ,  B01J37/10 ,  B01J2229/32 ,  C07C29/50 ,  C07C45/33 ,  C07C2601/14 ,  C07C35/08 ,  C07C49/403

Abstract: An object of the present invention is to provide a method capable of producing a cycloalkanol and/or a cycloalkanone with a favorable selectivity coefficient by oxidizing a cycloalkane with a favorable conversion ratio.Disclosed is a method for producing a cycloalkanol and/or a cycloalkanone, which comprises oxidizing a cycloalkane with oxygen in the presence of a mesoporous silica which contains at least one transition metal and has been also subjected to contact treatment with an amine and/or ammonia. Preferably, a crystal obtained by mixing a compound containing the metal, a silicon compound, a structure-directing agent and water is subjected to contact treatment with an amine and/or ammonia and then fired to obtain a mesoporous silica, and a cycloalkane is oxidized with oxygen in the presence of the mesoporous silica.

Abstract translation: 本发明的目的是提供一种通过以良好的转化率氧化环烷烃，能够制备具有良好选择性系数的环烷醇和/或环烷酮的方法。 公开了一种制备环烷醇和/或环烷酮的方法，其包括在含有至少一种过渡金属的介孔二氧化硅的存在下用氧氧化环烷烃，并且还已经用胺和/或氨进行接触处理 。 优选将通过混合含有金属，硅化合物，结构导向剂和水的化合物得到的晶体与胺和/或氨进行接触处理，然后烧制以获得介孔二氧化硅，并且环烷烃被氧化 在介孔二氧化硅存在下用氧气。

公开(公告)号：US20090048094A1

公开(公告)日：2009-02-19

申请号：US11837852

申请日：2007-08-13

Applicant: Zbigniew Ring ,  Hong Yang

Inventor： Zbigniew Ring ,  Hong Yang

IPC: B01J29/068

CPC classification number: B01J29/068 ,  B01J29/084 ,  B01J29/74 ,  B01J29/7407 ,  B01J29/80 ,  B01J29/90 ,  B01J2229/126 ,  B01J2229/186 ,  B01J2229/32 ,  B01J2229/42 ,  C07C5/10 ,  C07C2529/12 ,  C07C2529/74 ,  Y02P20/584 ,  C07C13/48

Abstract: A sulfur resistant catalyst is taught having noble metal nano-particles contained in a zeolite cage having a final pore size of between about 2.9 Å and about 3.5 Å. The zeolite cage is either directly synthesized, or the final pore size of the zeolite cage is reduced by post-treatments selected from chemical vapour deposition, chemical liquid deposition, cation exchange and combinations thereof to allow passage of hydrogen molecules into the cage while excluding organic sulfur molecules. Disassociated hydrogen species from reaction with the noble metal spill over through the zeolite pores to induce hydrogenation and to regenerate neighboring catalyst supports. A method is also taught for producing a sulfur resistant catalyst having noble metal nano-particles. The method involves either synthesizing a zeolite cage having a final pore size of between about 2.9 Å and about 3.5 Å or reducing the size of pores in the zeolite cage by a post treatment selected from chemical vapour deposition, chemical liquid deposition, cation exchange and combinations thereof.

Abstract translation: 教导了一种耐硫催化剂，其具有包含在最终孔径为约2.9至约Å的沸石笼中的贵金属纳米颗粒。 沸石保持架是直接合成的，或者通过选自化学气相沉积，化学液体沉积，阳离子交换及其组合的后处理来减少沸石笼的最终孔径，以允许氢分子进入笼中，同时排除有机物 硫分子。 与贵金属反应的脱相氢物质通过沸石孔溢出，以引起氢化并再生邻近的催化剂载体。 还教导了一种制备具有贵金属纳米颗粒的耐硫酸催化剂的方法。 该方法包括通过选自化学气相沉积，化学气相沉积，阳离子交换和组合的后处理来合成具有约2.9至约3.5埃的最终孔径的沸石笼或减小沸石笼中的孔的尺寸 其中。

公开(公告)号：US20090036714A1

公开(公告)日：2009-02-05

申请号：US12184461

申请日：2008-08-01

Applicant: Masahiro HOSHINO ,  Nobufumi Watanabe

Inventor： Masahiro HOSHINO ,  Nobufumi Watanabe

IPC: C07C45/27 ,  C07C35/08

CPC classification number: C07C29/50 ,  B01J29/0333 ,  B01J35/0066 ,  B01J2229/32 ,  C07C45/33 ,  C07C2601/14 ,  C12C11/02 ,  C07C35/08 ,  C07C49/403

Abstract: An object of the present invention is to provide a process capable of producing cycloalkanol and/or cycloalkanone with a favorable selectivity by oxidizing cycloalkane with a favorable conversion.Disclosed is a process for producing cycloalkanol and/or cycloalkanone, which comprises oxidizing cycloalkane with oxygen in the presence of mesoporous silica, wherein (1) the mesoporous silica contains at least one transition metal, and (2) a ratio of total volume of mesoporous silica particles having a particle diameter of 20 μm or less to total volume of entire mesoporous silica particles is 25% or more in the mesoporous silica.

Abstract translation: 本发明的目的是提供一种通过以良好的转化率氧化环烷烃，以良好的选择性制备环烷醇和/或环烷酮的方法。 公开了一种制备环烷醇和/或环烷酮的方法，其包括在介孔二氧化硅存在下用氧氧化环烷烃，其中（1）介孔二氧化硅含有至少一种过渡金属，和（2）介孔中的总体积比 在介孔二氧化硅中，粒径为20μm以下的二氧化硅粒子的总体积的总体积为25％以上。

公开(公告)号：US20080228007A1

公开(公告)日：2008-09-18

申请号：US12048258

申请日：2008-03-14

Applicant: Masahiro HOSHINO ,  Tatsuya Suzuki ,  Hajime Ishida

Inventor： Masahiro HOSHINO ,  Tatsuya Suzuki ,  Hajime Ishida

IPC: C07C45/32

CPC classification number: C07C29/50 ,  B01J23/22 ,  B01J23/26 ,  B01J23/34 ,  B01J23/44 ,  B01J23/462 ,  B01J23/745 ,  B01J23/75 ,  B01J29/0308 ,  B01J29/041 ,  B01J37/0209 ,  B01J2229/32 ,  C07C45/33 ,  C07C2601/14 ,  C07C49/403 ,  C07C35/08

Abstract: An object of the present invention is to provide a method capable of producing cycloalkanol and/or cycloalkanone with a favorable selectivity by oxidizing cycloalkane with a favorable conversion.A cycloalkanol and/or cycloalkanone are produced by oxidizing cycloalkane with oxygen in the presence of mesoporous silica which contains at least one metal selected from metals of Groups 5 to 10 of the Periodic Table and which is also subjected to a contact treatment with an organosilicon compound. The metal is preferably at least one metal selected from the group consisting of vanadium, chromium, manganese, iron, cobalt, ruthenium and palladium, and the mesoporous silica is preferably MCM-41 type mesoporous silica.

Abstract translation: 本发明的目的是提供一种通过以良好的转化率氧化环烷烃，以良好的选择性制备环烷醇和/或环烷酮的方法。 在含有至少一种选自元素周期表第5至10族金属的金属的介孔二氧化硅的存在下，用氧氧化环烷烃并且还与有机硅化合物进行接触处理来制备环烷醇和/或环烷酮 。 金属优选为选自钒，铬，锰，铁，钴，钌和钯中的至少一种金属，并且介孔二氧化硅优选为MCM-41型介孔二氧化硅。

公开(公告)号：US20070287875A1

公开(公告)日：2007-12-13

申请号：US11383660

申请日：2006-05-16

Applicant: TA YEN CHING ,  JEFFERY GEE ,  RUTHANN M. HICKOX

Inventor： TA YEN CHING ,  JEFFERY GEE ,  RUTHANN M. HICKOX

IPC: C07C5/25 ,  C07C5/23 ,  B01J29/04

CPC classification number: B01J21/08 ,  B01J29/0308 ,  B01J29/041 ,  B01J31/0209 ,  B01J31/0225 ,  B01J31/0231 ,  B01J31/0232 ,  B01J31/0274 ,  B01J31/0275 ,  B01J31/1633 ,  B01J35/1023 ,  B01J35/1028 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1061 ,  B01J2229/32 ,  C07C5/2562 ,  C07C2531/025 ,  C07C2531/04 ,  C07C11/02

Abstract: A process for selectively making 2-alkenes from a NAO using a mesoporous catalyst that has been surface modified with a Brönsted acid compound. The Brönsted acid compound has a reactive silane connector, an organic linking group, and a Brönsted acid group. The mesoporous catalyst has an average pore diameter in a range of about 12 to about 100 Angstroms and a surface area of between about 400 to about 1400 m2/gram.

Abstract translation: 使用已经用布朗斯台德酸化合物表面改性的介孔催化剂从NAO选择性制备2-烯烃的方法。 布朗斯台德酸化合物具有反应性硅烷连接剂，有机连接基团和布朗斯台德酸基团。 介孔催化剂的平均孔径在约12至约100埃的范围内，表面积为约400至约1400平方米/克。

公开(公告)号：US20070276146A1

公开(公告)日：2007-11-29

申请号：US11438388

申请日：2006-05-23

Applicant: Darbha Srinivas ,  Rajendra Srivastava ,  Paul Ratnasamy

Inventor： Darbha Srinivas ,  Rajendra Srivastava ,  Paul Ratnasamy

IPC: C07D317/08 ,  C07H19/19

CPC classification number: C07D317/36 ,  B01J29/0308 ,  B01J29/89 ,  B01J31/0237 ,  B01J31/0244 ,  B01J31/0254 ,  B01J31/068 ,  B01J2229/18 ,  B01J2229/32 ,  B01J2229/34 ,  B01J2231/34 ,  C07D317/38

Abstract: The present invention provides an adenine modified solid, ordered, mesoporous, bifunctional, organo-inorganic silica-based catalyst, its method of preparation and also a process for the production of cyclic carbonates of the formula hereinbelow wherein R═H, CH2Cl, CH3, C4H9, C6H11, C6H5

Abstract translation: 本发明提供腺嘌呤改性固体，有序，介孔，双功能，有机 - 无机二氧化硅基催化剂，其制备方法以及下式的环状碳酸酯的制备方法，其中RH，CH 2， C 1，CH 3，C 4 H 9，C 6 H 11， C 6，C 6 H 5

公开(公告)号：US20070102322A1

公开(公告)日：2007-05-10

申请号：US11267742

申请日：2005-11-04

Applicant: Li Wang

Inventor： Li Wang

IPC: C10G11/00 ,  B01J29/08 ,  B01J21/00 ,  B01J29/04

CPC classification number: C10G47/16 ,  B01J23/882 ,  B01J23/883 ,  B01J23/888 ,  B01J29/084 ,  B01J29/7007 ,  B01J29/80 ,  B01J37/0201 ,  B01J37/26 ,  B01J2229/32 ,  C10G47/20 ,  C10G2300/301 ,  C10G2300/4006 ,  C10G2300/4012 ,  C10G2400/08

Abstract: Increased yields of middle distillate and jet fuel and increased catalyst activity are obtained in a hydrocracking process by the use of a catalyst containing a beta zeolite and a Y zeolite having a unit cell size from 24.37 to 24.43 angstrom. The catalyst has a relatively high amount of Y zeolite relative to beta zeolite.

Abstract translation: 通过使用含有β沸石的催化剂和具有24.37至24.43埃的晶胞尺寸的Y沸石，在加氢裂化过程中获得了中间馏分和喷气燃料的产率提高和催化剂活性的增加。 催化剂相对于β沸石具有相对高量的Y沸石。

公开(公告)号：US07094941B2

公开(公告)日：2006-08-22

申请号：US10319307

申请日：2002-12-14

Applicant: Jagannath Das ,  Anand Bhimrao Halgeri

Inventor： Jagannath Das ,  Anand Bhimrao Halgeri

IPC: C07C15/00

CPC classification number: C07C2/66 ,  B01J29/04 ,  B01J29/87 ,  B01J37/0009 ,  B01J37/0209 ,  B01J2229/12 ,  B01J2229/32 ,  C07C2/864 ,  C07C15/00

Abstract: A repeated “soak and dry” selectivation process for preparing a modified metallosilicate catalyst composite is disclosed comprising of a mixture of amorphous silica, alumina and a pore size controlled metallosilicate useful for alkylaromatic conversion. The process comprises (a) contacting an intermediate pore metallosilicate with an organosilicon compound in a solvent for a specific duration and then recovering the solvent, (b) combining the organosilicon compound treated metallosilicate with water and then drying the catalyst, (c), repeating the steps a) and b) above and (d) calcining the catalyst in an oxygen containing atmosphere sufficient to remove the organic material and deposit siliceous matter on the metallosilicate. In a another embodiment, when the organosilicon compound is water soluble, step (b) may be avoided.

公开(公告)号：US07084087B2

公开(公告)日：2006-08-01

申请号：US10691358

申请日：2003-10-22

Applicant: Zhiping Shan ,  Peter Wilhelm Gerhard Waller ,  Bowden George Maingay ,  Philip J. Angevine ,  Jacobus Cornelis Jansen ,  Chuen Y. Yeh ,  Thomas Maschmeyer ,  Frits M. Dautzenberg ,  Leonardo Marchese ,  Heloise de Oliveira Pastore

Inventor： Zhiping Shan ,  Peter Wilhelm Gerhard Waller ,  Bowden George Maingay ,  Philip J. Angevine ,  Jacobus Cornelis Jansen ,  Chuen Y. Yeh ,  Thomas Maschmeyer ,  Frits M. Dautzenberg ,  Leonardo Marchese ,  Heloise de Oliveira Pastore

IPC: B01J29/06

CPC classification number: C10G11/04 ,  B01J21/06 ,  B01J21/12 ,  B01J23/26 ,  B01J23/38 ,  B01J23/44 ,  B01J23/50 ,  B01J23/52 ,  B01J29/005 ,  B01J29/0308 ,  B01J29/04 ,  B01J29/041 ,  B01J29/084 ,  B01J29/166 ,  B01J29/18 ,  B01J29/40 ,  B01J29/60 ,  B01J29/65 ,  B01J29/70 ,  B01J29/7007 ,  B01J29/80 ,  B01J29/85 ,  B01J29/87 ,  B01J29/88 ,  B01J29/89 ,  B01J35/002 ,  B01J35/1023 ,  B01J35/1028 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1061 ,  B01J35/108 ,  B01J37/0018 ,  B01J37/033 ,  B01J37/10 ,  B01J2229/183 ,  B01J2229/186 ,  B01J2229/32 ,  B01J2229/36 ,  B01J2229/42 ,  B01J2229/62 ,  C01B13/366 ,  C01B33/126 ,  C01B37/005 ,  C01B37/02 ,  C01P2006/12 ,  C01P2006/14 ,  C01P2006/16 ,  C07C2/66 ,  C07C45/46 ,  C07D215/227 ,  C07D301/06 ,  C07D301/10 ,  C10G2/332 ,  C10G11/05 ,  C10G27/04 ,  C10G29/205 ,  C10G45/00 ,  C10G45/04 ,  C10G45/12 ,  C10G45/60 ,  C10G45/62 ,  C10G45/64 ,  C10G45/68 ,  C10G47/00 ,  C10G47/14 ,  C10G47/16 ,  C10G49/02 ,  C10G49/08 ,  C10G50/00 ,  C10G2300/1096 ,  C10G2300/301 ,  C10G2300/4018 ,  C10G2400/04 ,  C10G2400/10 ,  C10G2400/30 ,  C07C15/073 ,  C07C49/84

Abstract: A catalytic material includes microporous zeolites supported on a mesoporous inorganic oxide support. The microporous zeolite can include zeolite Beta, zeolite Y (including “ultra stable Y”—USY), mordenite, Zeolite L, ZSM-5, ZSM-11, ZSM-12, ZSM-20, Theta-1, ZSM-23, ZSM-34, ZSM-35, ZSM-48, SSZ-32, PSH-3, MCM-22, MCM-49, MCM-56, ITQ-1, ITQ-2, ITQ-4, ITQ-21, SAPO-5, SAPO-11, SAPO-37, Breck-6, ALPO4-5, etc. The mesoporous inorganic oxide can be e.g., silica or silicate. The catalytic material can be further modified by introducing some metals e.g. aluminum, titanium, molybdenum, nickel, cobalt, iron, tungsten, palladium and platinum. It can be used as catalysts for acylation, alkylation, dimerization, oligomerization, polymerization, hydrogenation, dehydrogenation, aromatization, isomerization, hydrotreating, catalytic cracking and hydrocracking reactions.

Abstract translation: 催化材料包括负载在介孔无机氧化物载体上的微孔沸石。 微孔沸石可以包括沸石β，沸石Y（包括“超稳定Y”-USY），丝光沸石，沸石L，ZSM-5，ZSM-11，ZSM-12，ZSM-20，Theta-1，ZSM-23， ZSM-34，ZSM-35，ZSM-48，SSZ-32，PSH-3，MCM-22，MCM-49，MCM-56，ITQ-1，ITQ-2，ITQ-4，ITQ-21，SAPO- 5，SAPO-11，SAPO-37，Breck-6，ALPO 4 -5等。介孔无机氧化物可以是例如二氧化硅或硅酸盐。 催化材料可以通过引入一些金属进一步改性，例如 铝，钛，钼，镍，钴，铁，钨，钯和铂。 可用作酰化，烷基化，二聚，低聚，聚合，氢化，脱氢，芳构化，异构化，加氢处理，催化裂化和加氢裂化反应的催化剂。

公开(公告)号：US20060128555A1

公开(公告)日：2006-06-15

申请号：US11350156

申请日：2006-02-08

Applicant: Zhiping Shan ,  Peter Wilhelm ,  Bowden Maingay ,  Philip Angevine ,  Jacobus Jansen ,  Chuen Yeh ,  Thomas Maschmeyer ,  Frits Dautzenberg ,  Leonardo Marchese ,  Heloise Oliveira Pastore

Inventor： Zhiping Shan ,  Peter Wilhelm ,  Bowden Maingay ,  Philip Angevine ,  Jacobus Jansen ,  Chuen Yeh ,  Thomas Maschmeyer ,  Frits Dautzenberg ,  Leonardo Marchese ,  Heloise Oliveira Pastore

IPC: B01J29/06

CPC classification number: C10G11/04 ,  B01J21/06 ,  B01J21/12 ,  B01J23/26 ,  B01J23/38 ,  B01J23/44 ,  B01J23/50 ,  B01J23/52 ,  B01J29/005 ,  B01J29/0308 ,  B01J29/04 ,  B01J29/041 ,  B01J29/084 ,  B01J29/166 ,  B01J29/18 ,  B01J29/40 ,  B01J29/60 ,  B01J29/65 ,  B01J29/70 ,  B01J29/7007 ,  B01J29/80 ,  B01J29/85 ,  B01J29/87 ,  B01J29/88 ,  B01J29/89 ,  B01J35/002 ,  B01J35/1023 ,  B01J35/1028 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1061 ,  B01J35/108 ,  B01J37/0018 ,  B01J37/033 ,  B01J37/10 ,  B01J2229/183 ,  B01J2229/186 ,  B01J2229/32 ,  B01J2229/36 ,  B01J2229/42 ,  B01J2229/62 ,  C01B13/366 ,  C01B33/126 ,  C01B37/005 ,  C01B37/02 ,  C01P2006/12 ,  C01P2006/14 ,  C01P2006/16 ,  C07C2/66 ,  C07C45/46 ,  C07D215/227 ,  C07D301/06 ,  C07D301/10 ,  C10G2/332 ,  C10G11/05 ,  C10G27/04 ,  C10G29/205 ,  C10G45/00 ,  C10G45/04 ,  C10G45/12 ,  C10G45/60 ,  C10G45/62 ,  C10G45/64 ,  C10G45/68 ,  C10G47/00 ,  C10G47/14 ,  C10G47/16 ,  C10G49/02 ,  C10G49/08 ,  C10G50/00 ,  C10G2300/1096 ,  C10G2300/301 ,  C10G2300/4018 ,  C10G2400/04 ,  C10G2400/10 ,  C10G2400/30 ,  C07C15/073 ,  C07C49/84

Abstract: A catalytic material includes microporous zeolites supported on a mesoporous inorganic oxide support. The microporous zeolite can include zeolite Beta, zeolite Y (including “ultra stable Y”—USY), mordenite, Zeolite L, ZSM-5, ZSM-11, ZSM-12, ZSM-20, Theta-1, ZSM-23, ZSM-34, ZSM-35, ZSM-48, SSZ-32, PSH-3, MCM-22, MCM-49, MCM-56, ITQ-1, ITQ-2, ITQ-4, ITQ-21, SAPO-5, SAPO-11, SAPO-37, Breck-6, ALPO4-5, etc. The mesoporous inorganic oxide can be e.g., silica or silicate. The catalytic material can be further modified by introducing some metals e.g. aluminum, titanium, molybdenum, nickel, cobalt, iron, tungsten, palladium and platinum. It can be used as catalysts for acylation, alkylation, dimerization, oligomerization, polymerization, hydrogenation, dehydrogenation, aromatization, isomerization, hydrotreating, catalytic cracking and hydrocracking reactions.

Abstract translation: 催化材料包括负载在介孔无机氧化物载体上的微孔沸石。 微孔沸石可以包括沸石β，沸石Y（包括“超稳定Y”-USY），丝光沸石，沸石L，ZSM-5，ZSM-11，ZSM-12，ZSM-20，Theta-1，ZSM-23， ZSM-34，ZSM-35，ZSM-48，SSZ-32，PSH-3，MCM-22，MCM-49，MCM-56，ITQ-1，ITQ-2，ITQ-4，ITQ-21，SAPO- 5，SAPO-11，SAPO-37，Breck-6，ALPO 4 -5等。介孔无机氧化物可以是例如二氧化硅或硅酸盐。 催化材料可以通过引入一些金属进一步改性，例如 铝，钛，钼，镍，钴，铁，钨，钯和铂。 可用作酰化，烷基化，二聚，低聚，聚合，氢化，脱氢，芳构化，异构化，加氢处理，催化裂化和加氢裂化反应的催化剂。