摘要:
Disclosed is a novel compound represented by formula (1) below. In the formula, A represents an optionally substituted aromatic hydrocarbon ring or aromatic heterocyclic group, B represents a group including a chain of one to four pieces of one or more groups selected from groups represented by specific formulae (B-1) to (B-13) (such as —C═C— or —N═N—, specifically see the description), R1 to R3 each represent an optionally substituted hydrocarbon or hydrocarbonoxy group, at least one of R1 to R3 represents an optionally substituted hydrocarbonoxy group, R4 and R5 each represent an optionally substituted hydrocarbon group, R4 and R5 may be linked together to form a ring, and R4 and R5 may be each independently linked with A to form a ring.
摘要:
The photoelectric conversion device described herein includes a working electrode having a dye-supported metal oxide electrode in which a dye is supported on a metal oxide layer. The dye includes a structure represented by general formula (I) wherein A is a structure having a maximum absorption wavelength λmax of 350 to 500 nm in a methanol solution; B is a cyanine skeleton having a maximum absorption wavelength λmax of 500 to 700 nm in a methanol solution; Z1 is any one divalent linking group selected from —CONR—, —NRCO—, —SO2NR—, and —NRSO2—; R in Z1 is a hydrogen atom, an alkyl group having 1 to 8 carbon atoms, or an arylalkyl group having 7 to 20 carbon atoms; Y1 and Y2 are each independently an alkylene group having 1 to 8 carbon atoms, or a single bond, and may be the same or different; r is 1 or 2; m and n are each independently an integer of 0 to 2; and (m+n) is 1 or more.
摘要:
Provided are a polymerizable liquid crystal composition, a coating material, a medium, and a polarizing device each produced using a polymerizable liquid crystal compound and a colorant and each capable of producing polarized light suitable for polarizing devices, and also a novel naphtholactam derivative, a novel coumarin derivative, a novel Nile Red derivative, and a novel anthracene derivative each suitable for use as the colorant. Specifically provided are a polymerizable liquid crystal composition containing (A) at least one liquid crystal compound having a polymerizable functional group, (B) at least one colorant, and (C) a polymerization initiator, and a novel naphtholactam derivative of formula (IV′), a novel coumarin derivative of formula (VI′), a novel Nile Red derivative of formula (VII′), and a novel anthracene derivative of formula (VIII′) each suitable for use as the colorant (B).
摘要:
The photoelectric conversion device described herein includes a working electrode having a dye-supported metal oxide electrode in which a dye is supported on a metal oxide layer. The dye includes a structure represented by general formula (I) wherein A is a structure having a maximum absorption wavelength λmax of 350 to 500 nm in a methanol solution; B is a cyanine skeleton having a maximum absorption wavelength λmax of 500 to 700 nm in a methanol solution; Z1 is any one divalent linking group selected from —CONR—, —NRCO—, —SO2NR—, and —NRSO2—; R in Z1 is a hydrogen atom, an alkyl group having 1 to 8 carbon atoms, or an arylalkyl group having 7 to 20 carbon atoms; Y1 and Y2 are each independently an alkylene group having 1 to 8 carbon atoms, or a single bond, and may be the same or different; r is 1 or 2; m and n are each independently an integer of 0 to 2; and (m+n) is 1 or more.
摘要:
A photoelectric conversion device capable of improving conversion efficiency is provided. The photoelectric conversion device includes a work electrode, a counter electrode, and an electrolyte-containing layer. In the work electrode, a metal oxide semiconductor layer supporting a dye is provided. The dye contains a cyanine compound. The cyanine compound has heterocyclic skeletons containing indolenine skeletons bonded with both ends of a methine chain, an anchor group introduced to a nitrogen atom contained in the indolenine skeletons, and a phenanthrene skeleton contained in one of the heterocyclic skeletons. In the case where light enters the dye, electron injection efficiency to the metal oxide semiconductor layer is improved.
摘要:
A control system controls a hybrid vehicle having an engine for rotating a drive axle, an electric motor for assisting the engine in rotating the drive axle and converting kinetic energy of the drive axle into electric energy in a regenerative mode, and an electric energy storage unit connected through a drive control circuit to the electric motor, for storing electric energy. The control system has a regenerative quantity determining unit which includes first, second, and third first regenerative quantity establishing units. The first regenerative quantity establishing unit establishes a first regenerative quantity for the electric motor based on a vehicle speed of the hybrid vehicle when the supply of fuel to the engine is stopped upon deceleration of the hybrid vehicle. The second regenerative quantity establishing unit establishes a second regenerative quantity for the electric motor based on a remaining capacity of the electric energy storage unit. The third regenerative quantity establishing unit establishes a third regenerative quantity for the electric motor based on a temperature of the drive control circuit. A pumping loss controlling unit controls pumping losses of the engine based on the first, second, and third regenerative quantities.
摘要:
A control system for a hybrid vehicle including an internal combustion engine, a drive shaft driven by the engine, a generator for converting kinetic energy of the drive shaft to electrical energy to generate electric power, and an electrical storage device for storing electrical energy output from the generator, wherein idling of the engine is detected. An amount of electrical energy to be regenerated by the generator during the idling of the engine is calculated. An output from the generator is calculated based on the amount of electrical energy to be regenerated by the generator. An amount of intake air supplied to the engine is controlled in a manner such that the amount of intake air to be supplied to the engine is increased when the generator regenerates electrical energy during the idling of the engine. And an air-fuel ratio of a mixture supplied to the engine is controlled to a leaner value than a stoichiometric value during the idling of the engine.
摘要:
A control system is provided in an internal combustion engine in which a valve timing such as an opening time point and lift amount of an intake valve can be switched to a low-speed or high-speed valve timing within a lean-burn control range established in accordance with the operational state, such as an intake pipe internal absolute pressure and an engine revolution number of the engine, wherein an air-fuel ratio of an air-fuel mixture supplied to the internal combustion engine is enriched for a predetermined time when the valve timing is switched from the low-speed valve timing to the high-speed valve timing while carrying out a lean-burn control. Thus, even when the valve timing is switched over to the high-speed valve timing, the lean-burn control is carried out to prevent a misfiring or an unstable combustion state caused when the valve timing is switched during the lean-burn control, thereby providing a reduction in emission and an enhancement in drivability, while enhancing the specific fuel consumption.
摘要:
A method of determining the deterioration of an oxygen concentration sensor for an internal combustion engine. The oxygen concentration sensor includes at least one oxygen concentration sensor element having an oxygen-pumping element and a cell element each composed of a member of a solid electrolytic material having oxygen ion-conductivity, and a pair of electrodes having the member interposed therebetween, and a current-detecting resistance serially connected to the oxygen-pumping element to form a series circuit. A voltage having a magnitude corresponding to a difference between a voltage produced between the electrodes of the cell element and a predetermined reference voltage is applied to the series circuit, and pumping current is detected from a voltage developed across the current-detecting resistance. The predetermined reference voltage is changed from a first predetermined value to a second predetermined value, followed by detecting a difference between a value of said pumping current detected when the predetermined reference voltage assumes the first predetermined value and a value of the pumping current detected when the predetermined reference voltage assumes the second predetermined value. It is determined that there is deterioration in the oxygen concentration sensor when the difference is equal to or greater than a predetermined reference value.
摘要:
An oxygen concentration detecting device includes at least one oxygen concentration detecting element formed by an oxygen-pumping element and a cell element, composed of an oxygen ion-conductive wall, separating a pair of electrodes. The oxygen-pumping element and cell element define a gas diffusion chamber. A current detecting resistance forms a series circuit with the oxygen-pumping element. A voltage applying circuit applies to the series circuit an output voltage corresponding to the difference between a voltage between the electrodes of the cell element and a first reference voltage. An output detecting circuit outputs a voltage signal corresponding to a value of pumping current flowing through the resistance. An operational amplifier has a non-inverting input terminal supplied with a second reference voltage, an inverting input terminal connected to one end of the resistance, and an output terminal connected to the other end of the resistance. The output detecting circuit detects a first voltage at the one end of the resistance and a second voltage at the other end and outputs the voltage signal corresponding to the difference between the detected first and second voltages. The output detecting circuit corrects the voltage signal based upon the first and second voltages which are obtained in a state where no pumping current is supplied to the resistance. Electrodes of the oxygen-pumping element and the cell element are connected together within the gas diffusion chamber or within the basic body of the sensor body.