公开(公告)号：US20160304421A1

公开(公告)日：2016-10-20

申请号：US15090027

申请日：2016-04-04

Applicant: HONEYWELL INTERNATIONAL INC.

Inventor： Yuon Chiu ,  Stephen A. Cottrell ,  Hsueh Sung Tung ,  Haluk Kopkalli ,  Gustavo Cerri

IPC: C07C17/25 ,  B01J19/14 ,  B01J7/00 ,  B01J19/00 ,  C07C17/354 ,  C07C17/38

CPC classification number: C07C17/25 ,  B01J7/00 ,  B01J19/0046 ,  B01J19/14 ,  B01J2219/00452 ,  B01J2219/0059 ,  B01J2219/00594 ,  B01J2219/0072 ,  B01J2219/00759 ,  C07C17/23 ,  C07C17/354 ,  C07C17/38 ,  C07C21/18 ,  C07C19/08

Abstract: A method for producing 1,1,1,2-tetrafluoropropene and/or 1,1,1,2,3-pentafluoropropene using a single set of four unit operations, the unit operations being (1) hydrogenation of a starting material comprising hexafluoropropene and optionally recycled 1,1,1,2,3-pentafluoropropene; (2) separation of the desired intermediate hydrofluoroalkane, such as 1,1,1,2,3,3-hexafluoropropane and/or 1,1,1,2,3-pentafluoropropane; (3) dehydrofluorination of the intermediate hydrofluoroalkane to produce the desired 1,1,1,2-tetrafluoropropene and/or 1,1,1,2,3-pentafluoropropene, followed by another separation to isolate the desired product and, optionally, recycle of the 1,1,1,2,3-pentafluoropropene.

Abstract translation: 使用单组四个单元操作制备1,1,1,2-四氟丙烯和/或1,1,1,2,3-五氟丙烯的方法，单元操作是（1）将包含六氟丙烯的原料氢化 和任选的再循环的1,1,1,2,3-五氟丙烯; （2）所需中间体氢氟烷烃如1,1,1,2,3,3-六氟丙烷和/或1,1,1,2,3-五氟丙烷的分离; （3）中间体氢氟烷烃的脱氟化氢以产生所需的1,1,1,2-四氟丙烯和/或1,1,1,2,3-五氟丙烯，然后进行另一次分离以分离所需产物，并且任选地再循环 的1,1,1,2,3-五氟丙烯。

公开(公告)号：US20160296904A1

公开(公告)日：2016-10-13

申请号：US15034863

申请日：2014-11-19

Applicant: UNIVERSITY OF WASHINGTON THROUGH ITS CENTER FOR COMMERCIALIZATION ,  UOP LLC

Inventor： Carl KNOWLEN ,  Arthur T. MATTICK ,  Carl J. STEVENS ,  Robert CERFF ,  Viggo HANSEN

IPC: B01J7/00 ,  B01J19/10 ,  C10G15/08 ,  B01J12/00

CPC classification number: B01J7/00 ,  B01J12/00 ,  B01J12/005 ,  B01J19/10 ,  B01J19/26 ,  B01J2219/00087 ,  B01J2219/00123 ,  B01J2219/00135 ,  B01J2219/00159 ,  B01J2219/0218 ,  B01J2219/0883 ,  C07C2/78 ,  C10G15/08 ,  C10G31/06 ,  C07C11/24

Abstract: Apparatuses and associated methods for forming olefins from saturated hydrocarbon feedstock are disclosed herein. In one embodiment, a carrier gas is introduced at a supersonic velocity to a feedstock injector section. A feedstock gas is introduced tot he carrier gas stream using feedstock injectors that are offset in the streamwise direction one from another. The upstream feedstock injectors are positioned to inject feedstock gas to create plumes that improve penetration depth of the feedstock gas and reduce pressure losses at the downstream feedstock injectors. The feedstock gas can be regeneratively preheated by cooling the convergent-divergent nozzle. Water, steam and/or hydrogen gas can be injected into the apparatus for cooling the throat of the convergent-divergent nozzle.

Abstract translation: 本文公开了用于从饱和烃原料形成烯烃的装置和相关方法。 在一个实施例中，以超音速将载气引入原料喷射器部分。 使用在流动方向上彼此偏移的原料喷射器将原料气体引入到载气流中。 定位上游原料注入器以注入原料气体以产生提高原料气体的渗透深度并减少下游原料喷射器处的压力损失的羽流。 原料气体可以通过冷却会聚发散喷嘴再生预热。 水，蒸汽和/或氢气可以注入到用于冷却会聚发散喷嘴的喉部的设备中。

公开(公告)号：US20160279587A1

公开(公告)日：2016-09-29

申请号：US15033749

申请日：2014-10-30

Applicant: NIPPON SHOKUBAI CO., LTD.

Inventor： Yuuji SHIMASAKI

IPC: B01J7/00 ,  C07C51/25 ,  C07D301/08 ,  B01J8/06 ,  C07C37/58

CPC classification number: B01J7/00 ,  B01J8/067 ,  B01J19/30 ,  B01J2208/065 ,  B01J2219/30223 ,  B01J2219/30226 ,  B01J2219/30253 ,  B01J2219/30408 ,  B01J2219/30416 ,  C07C37/58 ,  C07C51/252 ,  C07D301/08 ,  C07D307/60

Abstract: In a fixed-bed flow reaction using a multitubular heat exchange type reactor, an object of the present invention is to provide a novel packing for a reaction tube, which can control the reaction ratio in the vicinity of the reaction tube inlet, reduce the load unevenly placed on the catalyst in the reaction region, and distribute the load on the entire catalyst layer, a heat exchange type reactor, and a reaction method using the reaction tube. The packing for a reaction tube of the present invention is characterized in that the volume is continuously or step-by-step decreased from one end part or midway toward the other end part.

Abstract translation: 在使用多管式热交换型反应器的固定床流动反应器中，本发明的目的是提供一种用于反应管的新型填料，其可以控制反应管入口附近的反应比，减少负载 不均匀地放置在反应区域中的催化剂上，并且将负载分布在整个催化剂层上，热交换型反应器和使用反应管的反应方法。 本发明的反应管的填料的特征在于，其体积从一个端部或中途向另一端部连续地或逐步地减小。

公开(公告)号：US20160272493A1

公开(公告)日：2016-09-22

申请号：US15166735

申请日：2016-05-27

Applicant: Shrikar Chakravarti ,  Raymond Francis Drnevich ,  Minish M. Shah ,  Ines C. Stuckert

Inventor： Shrikar Chakravarti ,  Raymond Francis Drnevich ,  Minish M. Shah ,  Ines C. Stuckert

IPC: C01B3/38 ,  B01J19/00 ,  B01J7/00

CPC classification number: C01B3/386 ,  B01J8/009 ,  B01J8/0457 ,  B01J8/0496 ,  B01J2208/0053 ,  B01J2219/00006 ,  B01J2219/00495 ,  B01J2219/00745 ,  C01B3/26 ,  C01B3/382 ,  C01B3/384 ,  C01B13/0251 ,  C01B2203/0233 ,  C01B2203/0244 ,  C01B2203/0261 ,  C01B2203/04 ,  C01B2203/0495 ,  C01B2203/0833 ,  C01B2203/0838 ,  C01B2203/0883 ,  C01B2203/1205 ,  C01B2203/1235 ,  C01B2203/127 ,  C01B2203/142 ,  C01B2203/80

Abstract: A method and system for producing a synthesis gas in an oxygen transport membrane based reforming system is disclosed that carries out an air heated pre-reforming process, a primary reforming process, a secondary reforming process.

Abstract translation: 公开了一种在氧传输膜基重整系统中生产合成气的方法和系统，其进行空气加热预重整工艺，初级重整工艺，二次重整工艺。

公开(公告)号：US20160272492A1

公开(公告)日：2016-09-22

申请号：US15033997

申请日：2014-11-06

Applicant: WATT FUEL CELL CORP.

Inventor： Caine M. Finnerty ,  Paul DeWald

IPC: C01B3/38 ,  B01J19/00 ,  B01J7/00

CPC classification number: C01B3/386 ,  B01J4/001 ,  B01J4/002 ,  B01J4/005 ,  B01J7/00 ,  B01J8/0285 ,  B01J8/065 ,  B01J8/067 ,  B01J8/1836 ,  B01J8/24 ,  B01J12/005 ,  B01J12/007 ,  B01J19/0013 ,  B01J19/0093 ,  B01J19/2415 ,  B01J19/2445 ,  B01J2208/00389 ,  B01J2208/00902 ,  B01J2208/00911 ,  B01J2219/00006 ,  B01J2219/00058 ,  B01J2219/00063 ,  B01J2219/00069 ,  B01J2219/00117 ,  B01J2219/00132 ,  B01J2219/00135 ,  B01J2219/00155 ,  B01J2219/00157 ,  B01J2219/00159 ,  B01J2219/002 ,  B01J2219/00213 ,  B01J2219/00234 ,  B01J2219/00585 ,  C01B2203/0233 ,  C01B2203/0244 ,  C01B2203/0261 ,  C01B2203/0844 ,  C01B2203/085 ,  C01B2203/1223 ,  C01B2203/1229 ,  C01B2203/1235 ,  C01B2203/1241 ,  C01B2203/1247 ,  C01B2203/141

Abstract: A multi-tubular chemical reactor (400) includes an igniter (435) for the initiation of gas phase exothermic reaction within the gas phase reaction zones (409) of the tubular reactor units (408). A method of carrying out a gas phase exothermic reaction within the multi-tubular chemical reactor comprising: introducing gaseous reactants into a tubular reactor unit (408); initiating with radiant heat an exothermic reaction of the gaseous reactants within the reactor unit; and transferring heat produced by the exothermic reaction occurring within the gas phase reaction zone of the reactor unit to the gas phase reaction zone of one or more adjacent reactor units (408), thereby initiating an exothermic reaction within at least one adjacent reactor unit (408) until in such manner an exothermic reaction has been initiated in each of the plurality of spaced-apart reactor units (408).

Abstract translation: 多管式化学反应器（400）包括用于在管状反应器单元（408）的气相反应区（409）内引发气相放热反应的点火器（435）。 一种在多管式化学反应器内进行气相放热反应的方法，包括：将气态反应物引入管式反应器单元（408）中; 用辐射热引发气体反应物在反应器单元内的放热反应; 以及将由反应器单元的气相反应区内发生的放热反应产生的热量转移到一个或多个相邻的反应器单元（408）的气相反应区，从而在至少一个相邻的反应器单元（408）内引发放热反应 ），直到以这种方式在多个间隔开的反应器单元（408）中的每一个中已经开始放热反应。

公开(公告)号：US20160268616A1

公开(公告)日：2016-09-15

申请号：US15162199

申请日：2016-05-23

Applicant: OHIO STATE INNOVATION FOUNDATION

Inventor： Liang-Shih FAN ,  Fanxing LI ,  Liang ZENG ,  Deepak SRIDHAR

IPC: H01M8/0612 ,  H01M8/1016 ,  C25B3/00 ,  H01M8/14 ,  C25B1/04 ,  B01J7/00 ,  H01M8/1007

CPC classification number: H01M8/0618 ,  B01J7/00 ,  C01B3/063 ,  C01B3/34 ,  C01B3/344 ,  C01B2203/0216 ,  C01B2203/0222 ,  C01B2203/0233 ,  C01B2203/0238 ,  C01B2203/066 ,  C01B2203/0827 ,  C01B2203/148 ,  C10J3/46 ,  C10J3/725 ,  C10J2300/0916 ,  C10J2300/093 ,  C10J2300/0959 ,  C10J2300/0993 ,  C10J2300/1612 ,  C10J2300/1646 ,  C10J2300/1678 ,  C10J2300/1807 ,  C10K1/003 ,  C10K1/024 ,  C10K3/026 ,  C25B1/04 ,  C25B3/00 ,  H01M8/0643 ,  H01M8/1007 ,  H01M8/1016 ,  H01M8/145 ,  H01M2008/1293 ,  H01M2008/147 ,  H01M2300/0051 ,  H01M2300/0071 ,  Y02E20/18 ,  Y02E20/185 ,  Y02E60/36 ,  Y02E60/366 ,  Y02E60/50 ,  Y02E60/525 ,  Y02E60/526 ,  Y02P20/134 ,  Y02P20/146 ,  Y02P70/56

Abstract: High efficiency electricity generation processes and systems with substantially zero CO2 emissions are provided. A closed looping between the unit that generates gaseous fuel (H2, CO, etc) and the fuel cell anode side is formed. In certain embodiments, the heat and exhaust oxygen containing gas from the fuel cell cathode side are also utilized for the gaseous fuel generation. The systems for converting fuel may comprise reactors configured to conduct oxidation-reduction reactions. The resulting power generation efficiencies are improved due to the minimized steam consumption for the gaseous fuel production in the fuel cell anode loop as well as the strategic mass and energy integration schemes.

Abstract translation: 提供了高效发电过程和基本上零二氧化碳排放的系统。 形成产生气体燃料（H2，CO等）的单元与燃料电池阳极侧之间的闭环。 在某些实施例中，来自燃料电池阴极侧的含有热和废气的含氧气体也用于产生气体燃料。 用于转化燃料的系统可以包括被配置为进行氧化还原反应的反应器。 由于燃料电池阳极回路中的气体燃料生产的最小蒸汽消耗以及战略质量和能量集成方案，所得到的发电效率得到改善。

公开(公告)号：US20160263541A1

公开(公告)日：2016-09-15

申请号：US15032318

申请日：2014-10-30

Applicant: LINDE AKTIENGESELLSCHAFT

Inventor： Sven Halang ,  Jens Buschmann ,  Ronald Meusel ,  Tomas Suchy ,  Andreas Mihm

IPC: B01J7/00 ,  C10J3/24 ,  C01B3/02

CPC classification number: B01J7/00 ,  C01B3/02 ,  C10B7/00 ,  C10B49/04 ,  C10B57/14 ,  C10J3/24 ,  C10J2200/152 ,  C10J2300/092 ,  C10J2300/0956

Abstract: A device for supplying gasification agent to a reactor of a low-temperature gasifier, the device having at least one nozzle block joined at a first end by a pipe connection in a wall of the reactor to a manifold. Each nozzle block is located inside the reactor and the manifold is located outside the reactor. Each nozzle block includes at least two nozzle openings.

Abstract translation: 一种用于将气化剂供应到低温气化器的反应器的装置，该装置具有至少一个喷嘴块，其在第一端通过反应器的壁中的管道连接到歧管。 每个喷嘴块位于反应器内部，歧管位于反应器外部。 每个喷嘴块包括至少两个喷嘴开口。

公开(公告)号：US20160257562A1

公开(公告)日：2016-09-08

申请号：US15030985

申请日：2014-10-24

Applicant: HALDOR TOPSØE A/S

Inventor： Troels Dahlgaard STUMMANN ,  Niels Ulrik ANDERSEN ,  Madhanakrishnan JANARDHANAN ,  Jens R. ROSTRUP-NIELSEN

IPC: C01B3/16 ,  C07C1/04 ,  C07C29/157 ,  C07C29/151 ,  C07C29/154 ,  C07C29/156 ,  B01J7/00 ,  C07C29/152

CPC classification number: C01B3/16 ,  B01J7/00 ,  B01J8/001 ,  B01J8/0453 ,  B01J8/0492 ,  B01J2219/185 ,  B01J2219/1943 ,  C01B2203/0283 ,  C01B2203/061 ,  C01B2203/062 ,  C01B2203/142 ,  C07C1/041 ,  C07C1/043 ,  C07C1/0435 ,  C07C1/044 ,  C07C29/1512 ,  C07C29/152 ,  C07C29/154 ,  C07C29/156 ,  C07C29/157 ,  C07C2523/06 ,  C07C2523/28 ,  C07C2523/72 ,  C07C2523/745 ,  C07C2523/75 ,  C07C2523/755

Abstract: The present disclosure relates to a reactor and a method of operation for an exothermal process being catalyzed by a catalytically active material receiving a reactant gas and providing a product gas, in which said exothermal process has a heat development having a potential for thermally degrading said catalytically active material, and which exothermal process operates at a temperature at which the reactants and at least 80% or all of the products are present as gases, said method comprising the steps of a) directing the reactant gas to a first zone of a material catalytically active in the exothermal process producing an first product gas, and b) directing the first product gas to a second zone of a material catalytically active in the exothermal process producing a product gas, with the option of fully or partially by-passing either said first zone or said second zone, while directing a non-condensing gas stream having a temperature at least 50° C. lower than the product gas to said by-passed zone, wherein the choice of by-passing said zone is made based on the time of operation or a process parameter reflecting the catalytic activity of the zone of catalytically active material which is not by-passed with the associated benefit of reducing the extent of thermal deactivation of the catalytically active material, and thus increasing the overall lifetime of the catalytically active material.

Abstract translation: 本发明涉及一种用于放热过程的反应器和操作方法，其由接收反应气体和提供产物气体的催化活性材料催化，其中所述放热方法具有热显影，其具有热降解所述催化作用 活性材料，并且该放热过程在反应物和至少80％或全部产物作为气体存在的温度下操作，所述方法包括以下步骤：a）将反应物气体引导到材料的第一区域， 活跃在放热过程中产生第一产物气体，以及b）将第一产物气体引导到放热过程中催化活性物质的第二区域，产生产物气体，其选择是完全或部分地旁路所述第一产物气体 区域或所述第二区域，同时将具有比产物气体低至少50℃的温度的非冷凝气流引导至sa 其中所述区域的旁路选择是基于操作时间或反映催化活性材料区域的催化活性的过程参数进行的，所述催化活性材料区域不被旁路以及减少的相关益处 催化活性材料的热失活的程度，从而增加催化活性材料的总体寿命。

公开(公告)号：US20160256841A1

公开(公告)日：2016-09-08

申请号：US15066173

申请日：2016-03-10

Applicant: SYK TECHNOLOGIES, LLC

Inventor： J.W. Randolph Miller ,  John J. Miller ,  Stephen H. Fairbanks

IPC: B01J7/00 ,  A61L2/20 ,  A61L2/00 ,  A61K33/00 ,  A61K9/00 ,  C01B21/24 ,  A61L2/26

CPC classification number: B01J7/00 ,  A61K9/0014 ,  A61K33/00 ,  A61L2/0005 ,  A61L2/20 ,  A61L2/26 ,  C01B21/24

Abstract: An apparatus for controlled delivery of nitric oxide. A pump draws air through an activated carbon filter and into a reaction chamber. The generation of nitric oxide occurs in the reaction chamber. A second pump draws the gas in the reaction chamber through a calcium hydroxide filter and delivers the nitric oxide through an orifice, or aperture, that controls the flow of nitric oxide delivered. The nitric oxide is filtered through a calcium hydroxide filter just prior to being made available for various nitric oxide therapies. Topical applications that provide a nitric oxide therapy to a surface are also provided.

Abstract translation: 用于一氧化氮控制递送的装置。 泵将空气通过活性炭过滤器吸入反应室。 在反应室中产生一氧化氮。 第二个泵通过氢氧化钙过滤器将反应室中的气体吸入，并将一氧化氮通过一个控制一氧化氮输送流量的孔或孔。 在一氧化氮过滤器刚好被用于各种一氧化氮治疗之前，一氧化氮被过滤。 还提供了向表面提供一氧化氮治疗的局部应用。

公开(公告)号：US20160256840A1

公开(公告)日：2016-09-08

申请号：US15032401

申请日：2014-09-22

Applicant: DOW GLOBAL TECHNOLOGIES LLC

Inventor： Matthew Pretz ,  Don F. Shaw ,  Richard E. Walter

IPC: B01J7/00

CPC classification number: B01J7/00 ,  B01J8/0055 ,  B01J8/008 ,  B01J8/18 ,  B01J2208/00557 ,  B04C5/24 ,  B04C11/00

Abstract: A cyclonic reactor vessel comprising: a primary cyclonic separation device disposed within the shell and having an outlet; a plurality of secondary cyclones, said secondary cyclones being disposed within the shell, and each of said secondary cyclones having a body, an inlet and an outlet; wherein the outlet of the primary cyclonic separation device is connected to the inlet of at least one secondary cyclone; a first plenum having a skirt and a floor forming a sealed annular chamber within the shell; a second plenum having a smaller volume than a volume of the first plenum; and a secondary cyclone support system minimizing or eliminating mechanical thermal stresses; and wherein the outlets of the plurality of secondary cyclones are fluidly connected to the second plenum is provided.

Abstract translation: 一种旋风反应堆容器，包括：主旋转分离装置，其设置在壳体内并具有出口; 多个第二旋风分离器，所述第二旋风分离器设置在壳体内，并且每个所述次级旋风分离器具有主体，入口和出口; 其中所述主旋风分离装置的出口连接到至少一个次级旋风分离器的入口; 第一增压室具有裙部和底板，在壳体内形成密封的环形室; 具有比第一增压室的体积小的体积的第二增压室; 以及最小化或消除机械热应力的次级旋风支撑系统; 并且其中提供多个次级旋风分离器的出口流体连接到第二增压室。