公开(公告)号：US09315736B2

公开(公告)日：2016-04-19

申请号：US14094487

申请日：2013-12-02

Applicant: Energia Technologies, Inc.

Inventor： Krishniah Parimi ,  Thien Duyen Thi Nguyen

IPC: B01J8/00 ,  B01J8/02 ,  B01J8/04 ,  B01J19/00 ,  B01J19/24 ,  C10G3/00 ,  C10G47/00 ,  C10L1/00 ,  C10L1/04 ,  B01J23/44 ,  B01J23/755 ,  B01J35/00 ,  B01J37/02 ,  B01J37/16 ,  B01J21/00 ,  B01J21/18 ,  B01J23/00 ,  B01J23/38 ,  B01J23/40 ,  B01J23/70 ,  B01J23/74 ,  B01J23/745 ,  B01J35/02 ,  B01J37/00

CPC classification number: C10G3/50 ,  B01J8/0457 ,  B01J19/2485 ,  B01J21/18 ,  B01J23/44 ,  B01J23/755 ,  B01J35/0013 ,  B01J37/0217 ,  B01J37/0221 ,  B01J37/16 ,  B01J2219/00006 ,  B01J2219/0004 ,  B01J2219/248 ,  C10G3/42 ,  C10G3/44 ,  C10G3/45 ,  C10G3/46 ,  C10G3/47 ,  C10G3/48 ,  C10G3/49 ,  C10G3/54 ,  C10G47/00 ,  C10G2300/1011 ,  C10G2400/02 ,  C10G2400/04 ,  C10G2400/08 ,  C10L1/04 ,  Y02P30/20

Abstract: Presented are one or more aspects and/or one or more embodiments of catalysts, methods of preparation of catalyst, methods of deoxygenation, and methods of fuel production.

Abstract translation: 提出的催化剂的一个或多个方面和/或一个或多个实施方案，催化剂的制备方法，脱氧方法和燃料生产方法。

公开(公告)号：US09314759B2

公开(公告)日：2016-04-19

申请号：US14168099

申请日：2014-01-30

Applicant: Steven Xuqi Song ,  Donald Leroy Kuehne ,  Abdenour Kemoun ,  Bruce Edward Reynolds

Inventor： Steven Xuqi Song ,  Donald Leroy Kuehne ,  Abdenour Kemoun ,  Bruce Edward Reynolds

IPC: B01J8/00 ,  B01J8/02 ,  B01J19/00 ,  B01J19/24 ,  B01J19/30 ,  B01J8/06 ,  B01J8/22 ,  B01J8/44 ,  C10G45/02 ,  C10G45/16 ,  C10G45/22 ,  C10G47/26 ,  C10G49/12 ,  B01J8/18 ,  C10G45/00 ,  C10G47/00 ,  C01G49/00

CPC classification number: B01J8/06 ,  B01J8/005 ,  B01J8/007 ,  B01J8/1827 ,  B01J8/22 ,  B01J8/226 ,  B01J8/44 ,  B01J2208/00176 ,  B01J2208/00929 ,  B01J2208/025 ,  B01J2208/026 ,  B01J2219/0004 ,  C10G45/02 ,  C10G45/16 ,  C10G45/22 ,  C10G47/26 ,  C10G49/12

Abstract: An apparatus is disclosed for the hydroconversion of hydrocarbon feedstock with a hydrogen gas at elevated temperature and pressure with the use of a catalyst. The apparatus is a reactor vessel with a grid plate distributor for improved gas liquid distribution. The distributor comprises a grid plate and a bubble cap assembly with a plurality of tubular risers extending through the grid plate. Each tubular riser has an upper section above the grid plate and a lower section below the grid plate, the lower section terminated with an open bottom end for ingress of the hydrogen gas and hydrocarbon feedstock, the upper section having a closed top terminated with a housing cap. Each tubular riser has at least a vertical slot and a least a laterally placed opening sufficiently sized such that in operation, the liquid level in the zone below the grid plate is above the vertical slot and below the laterally placed opening.

Abstract translation: 公开了一种使用催化剂在升高的温度和压力下用氢气加氢转化烃原料的装置。 该装置是具有用于改善气体液体分布的格栅分配器的反应器容器。 分配器包括格栅板和气泡盖组件，其具有延伸穿过格栅板的多个管状立管。 每个管状提升管具有在格栅板上方的上部部分和在格栅板下方的下部分，下部部分终止于用于进入氢气和烃原料的开口底端，上部部分具有封闭的顶部，其与壳体 帽。 每个管状提升管具有至少一个垂直狭槽和至少一个横向放置的开口，其尺寸足够大，使得在操作中，格栅板下方的区域中的液位高于垂直槽并在横向放置的开口下方。

公开(公告)号：US09266730B2

公开(公告)日：2016-02-23

申请号：US13801538

申请日：2013-03-13

Applicant: Steve Kresnyak

Inventor： Steve Kresnyak

IPC: C10G9/00 ,  C10G45/02 ,  C10G45/58 ,  C01B3/34 ,  C01B3/48 ,  C10G47/00 ,  C10K1/08 ,  C10K1/32 ,  C10K3/04 ,  C10K3/06 ,  C10G1/04 ,  C10G2/00

CPC classification number: C01B3/34 ,  C01B3/48 ,  C01B2203/0233 ,  C01B2203/0244 ,  C01B2203/025 ,  C01B2203/0405 ,  C01B2203/043 ,  C01B2203/0485 ,  C01B2203/062 ,  C01B2203/063 ,  C01B2203/1052 ,  C01B2203/1058 ,  C01B2203/1064 ,  C01B2203/107 ,  C10G1/045 ,  C10G2/32 ,  C10G9/00 ,  C10G9/007 ,  C10G45/02 ,  C10G45/58 ,  C10G47/00 ,  C10G2300/203 ,  C10G2300/302 ,  C10G2300/308 ,  C10G2400/02 ,  C10G2400/04 ,  C10K1/08 ,  C10K1/32 ,  C10K3/04 ,  C10K3/06

Abstract: A bitumen and heavy oil upgrading process and system is disclosed for the synthesis of hydrocarbons, an example of which is synthetic crude oil (SCO). The process integrates Fischer-Tropsch technology with gasification and hydrogen rich gas stream generation. The hydrogen rich gas generation is conveniently effected using singly or in combination a hydrogen source, a hydrogen rich vapor from hydroprocessing and the Fischer-Tropsch process, a steam methane reformer (SMR) and autothermal reformer (ATR) or a combination of SMR/ATR. The feedstock for upgrading is distilled and the bottoms fraction is gasified and converted in a Fischer-Tropsch reactor. A resultant hydrogen lean syngas is then exposed to the hydrogen rich gas stream to optimize the formation of, for example, the synthetic crude oil. Partial upgrading and the commensurate benefits is detailed as well. A system for effecting the processes is also characterized in the specification.

Abstract translation: 公开了一种用于合成烃的沥青和重油改质方法和体系，其中一个实例是合成原油（SCO）。 该工艺将费 - 托技术与气化和富氢气流生成相结合。 富氢气体的生成可以单独或组合使用氢源，来自加氢处理的富氢蒸气和费 - 托法，蒸汽甲烷重整器（SMR）和自热重整器（ATR）或SMR / ATR的组合 。 将升级的原料蒸馏并将底部馏分气化并在费 - 托反应器中转化。 然后将所得的贫氢合成气暴露于富氢气流中以优化例如合成原油的形成。 部分升级和相应的好处也是详细的。 实施方法的系统的特征还在本说明书中。

公开(公告)号：US20160040198A1

公开(公告)日：2016-02-11

申请号：US14886983

申请日：2015-10-19

Applicant: Calysta, Inc.

Inventor： Joshua A. Silverman ,  Sol M. Resnick ,  Michael Mendez

IPC: C12P7/64 ,  C10G47/00 ,  C10L1/04 ,  C10G3/00

CPC classification number: C12P7/6409 ,  C10G3/00 ,  C10G3/50 ,  C10G47/00 ,  C10G2300/1014 ,  C10L1/02 ,  C10L1/04 ,  C10L2200/0469 ,  C10L2270/02 ,  C10L2270/04 ,  C10L2290/26 ,  C12N1/16 ,  C12N1/20 ,  C12N9/1029 ,  C12N9/16 ,  C12N9/93 ,  C12N15/52 ,  C12N15/74 ,  C12P5/00 ,  C12P7/6463 ,  C12P7/649 ,  C12R1/01 ,  C12Y203/01039 ,  C12Y301/02 ,  C12Y602/01003 ,  C12Y604/01002 ,  Y02E50/13 ,  Y02E50/343 ,  Y02P20/52 ,  Y02P30/20

Abstract: The present disclosure relates to bioengineering approaches for producing biofuel and, in particular, to the use of a C1 metabolizing microorganism reactor system for converting C1 substrates, such as methane or methanol, into biomass and subsequently into biofuels, bioplastics, or the like.

公开(公告)号：US20160002541A1

公开(公告)日：2016-01-07

申请号：US14852248

申请日：2015-09-11

Applicant: RES USA, LLC

Inventor： Mark Ibsen ,  Sergio Mohedas ,  Frank Hogsett ,  Mark Bohn ,  Harold A. Wright

IPC: C10G2/00 ,  C10G45/00 ,  C10G47/00 ,  C10G45/58

CPC classification number: B03C1/02 ,  B01J8/005 ,  B01J8/007 ,  B01J8/22 ,  B01J8/228 ,  B01J35/0033 ,  B03C1/288 ,  B03C1/30 ,  B03C2201/18 ,  C10G2/33 ,  C10G2/332 ,  C10G2/342 ,  C10G45/00 ,  C10G45/58 ,  C10G47/00

Abstract: A method for converting synthesis gas into liquid hydrocarbons by introducing a synthesis gas feed into a Fischer-Tropsch system that includes a catalytic reactor fluidly connected with at least two slurry loops, the reactor comprising at least as many reactor product outlets and slurry return inlets as slurry loops; each slurry loop comprising a separation system comprising at least one separator, an inlet of each separator fluidly connected to a reactor product outlet via a slurry offtake, and an outlet of each separator fluidly connected to a slurry return inlet via a slurry return; separating concentrated catalyst slurry from the reaction product via the slurry loops; removing liquid hydrocarbon product from each separator; and returning concentrated catalyst slurry to the catalytic reactor via the slurry returns and slurry return inlets. A system for converting synthesis gas into liquid hydrocarbons via the method is also disclosed.

Abstract translation: 通过将合成气进料引入费 - 托系统中来将合成气转化成液体烃的方法，所述费 - 托系统包括与至少两个浆液回路流体连接的催化反应器，所述反应器至少包含反应器产物出口和浆料返回入口 浆液回路; 每个浆料回路包括分离系统，该分离系统包括至少一个分离器，每个分离器的入口经由浆料出口流体连接到反应器产物出口，以及每个分离器的出口通过浆料回流器流体连接到浆料返回入口; 通过浆料循环从反应产物中分离浓缩的催化剂浆料; 从每个分离器去除液体烃产物; 并通过浆料返回和浆料返回入口将浓缩的催化剂浆料返回到催化反应器。 还公开了一种通过该方法将合成气转化为液态烃的系统。

公开(公告)号：US09206363B2

公开(公告)日：2015-12-08

申请号：US13597598

申请日：2012-08-29

Applicant: Hyung Suk Woo ,  Jane Chi-ya Cheng ,  Teh C. Ho ,  Stephen Harold Brown ,  Richard Charles Dougherty ,  David Thomas Ferrughelli ,  Federico Barrai

Inventor： Hyung Suk Woo ,  Jane Chi-ya Cheng ,  Teh C. Ho ,  Stephen Harold Brown ,  Richard Charles Dougherty ,  David Thomas Ferrughelli ,  Federico Barrai

IPC: C10G47/00 ,  C10G53/02 ,  C10G53/04 ,  C10G65/12 ,  C10G47/02 ,  C10G45/04 ,  C10G49/02 ,  C10G49/22 ,  C10G67/04 ,  B01J37/20 ,  B01J23/74 ,  B01J35/02 ,  B01J37/02 ,  B01J23/883 ,  B01J23/888 ,  B01J35/10

CPC classification number: C10G45/00 ,  B01J23/74 ,  B01J23/883 ,  B01J23/8885 ,  B01J35/023 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1061 ,  B01J37/0201 ,  B01J37/0207 ,  B01J37/20 ,  C10G45/02 ,  C10G45/04 ,  C10G45/32 ,  C10G45/44 ,  C10G45/58 ,  C10G47/00 ,  C10G47/02 ,  C10G49/02 ,  C10G49/22 ,  C10G67/0454 ,  C10G67/049 ,  C10G2300/1037 ,  C10G2300/107 ,  C10G2300/1077 ,  C10G2300/202 ,  C10G2300/205 ,  C10G2300/206 ,  C10G2300/301 ,  C10G2300/4006 ,  C10G2300/4012 ,  C10G2300/4018 ,  C10G2300/4081 ,  C10G2300/44 ,  C10L1/04

Abstract: Heavy oil feeds are hydroprocessed in the presence of a solvent under conditions that provide a variety of benefits. The solvent can be an added solvent or a portion of the liquid effluent from hydroprocessing. The processes allow for lower pressure processing of heavy oil feeds for extended processing times or extended catalyst lifetimes be reducing or mitigating the amount of coke formation on the hydroprocessing catalyst.

Abstract translation: 在提供各种益处的条件下，在溶剂存在下将重油进料加氢处理。 溶剂可以是加氢处理的添加溶剂或一部分液体流出物。 该方法允许重油进料的较低压力处理用于延长的处理时间或延长的催化剂寿命来减少或减轻加氢处理催化剂上焦炭形成的量。

公开(公告)号：US20150275112A1

公开(公告)日：2015-10-01

申请号：US14439328

申请日：2013-10-30

Applicant: IFP ENERGIES NOUVELLES ,  AXENS ,  BIONEXT ,  COMMISSARIAT A L'ENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES ,  SOFIPROTEOL ,  THYSSENKRUPP UHDE GMBH ,  TOTAL RAFFINAGE CHIMIE

Inventor： Guillaume Boissonnet ,  Michael Hecquet ,  Priscilla Avenier ,  Laurent Bournay ,  David Chiche ,  Jean-Philippe Heraud ,  Anne Claire Lucquin ,  Norbert Ullrich ,  Stéphane Fedou ,  Julien Rousseau ,  Raphael Lemaire ,  Jean-Christophe Viguie

IPC: C10K3/04 ,  C10G45/00 ,  C10G47/00 ,  C10J3/46 ,  C10K3/06 ,  C10K1/00 ,  C10K1/10 ,  C10K1/34 ,  C10K1/20 ,  C10G2/00 ,  C10J3/48

CPC classification number: C10K3/04 ,  B01J20/06 ,  B01J20/18 ,  B01J20/20 ,  B01J2220/603 ,  C10G2/30 ,  C10G2/32 ,  C10G45/00 ,  C10G47/00 ,  C10G2300/1011 ,  C10J3/00 ,  C10J3/466 ,  C10J3/485 ,  C10J2200/09 ,  C10J2300/0906 ,  C10J2300/0909 ,  C10J2300/0916 ,  C10J2300/0959 ,  C10J2300/1659 ,  C10J2300/1846 ,  C10K1/004 ,  C10K1/005 ,  C10K1/006 ,  C10K1/007 ,  C10K1/101 ,  C10K1/20 ,  C10K1/34 ,  C10K3/06 ,  C10L9/083 ,  Y02E50/15 ,  Y02E50/32 ,  Y02P20/125 ,  Y02P20/145 ,  Y02P20/52 ,  Y02P30/10 ,  Y02P30/20

Abstract: The present invention concerns an integrated process for the production of liquid hydrocarbons starting from a feed containing at least one fraction of biomass and optionally at least one fraction of another feed, said process comprising at least one pre-treatment step, a gasification step, a step for conditioning synthesis gas, a water scrubbing step, a step for eliminating acid gases, a final purification step, and a catalytic Fischer-Tropsch synthesis reaction step.

Abstract translation: 本发明涉及从含有至少一部分生物质和任选的至少一个其它进料部分的进料开始生产液体烃的综合方法，所述方法包括至少一个预处理步骤，气化步骤， 用于调节合成气的步骤，水洗步骤，消除酸性气体的步骤，最终纯化步骤和催化费 - 托合成反应步骤。

公开(公告)号：US09133401B2

公开(公告)日：2015-09-15

申请号：US12733054

申请日：2008-05-26

Applicant: Mohan Singh Rana ,  Jorge Ancheyta Juárez ,  Patricia Rayo Mayoral ,  Samir Kumar Maity

Inventor： Mohan Singh Rana ,  Jorge Ancheyta Juárez ,  Patricia Rayo Mayoral ,  Samir Kumar Maity

IPC: B01J21/04 ,  B01J23/652 ,  B01J23/882 ,  C10G45/08 ,  B01J23/56 ,  B01J23/86 ,  B01J23/85 ,  B01J23/887 ,  B01J35/10 ,  C10G47/00 ,  C10G65/04 ,  C10G65/12

CPC classification number: B01J23/885 ,  B01J21/04 ,  B01J23/56 ,  B01J23/652 ,  B01J23/85 ,  B01J23/862 ,  B01J23/864 ,  B01J23/866 ,  B01J23/882 ,  B01J23/887 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1061 ,  B01J37/08 ,  C10G45/08 ,  C10G47/00 ,  C10G65/04 ,  C10G65/12 ,  C10G2300/107 ,  C10G2300/1077 ,  C10G2300/202 ,  C10G2300/205

Abstract: An improved catalyst for hydrodemetallization of heavy crude oils and residua is disclosed. The catalyst is adopted for fixed bed hydroprocessing units. The invention is characterized for having a large pore diameter catalyst principally for hydrodemetallization of heavy oil and residue in a first reactor of a multi-reactor process. The catalyst has high demetallizing activity and high metal deposition capacity which results in good stability with time on stream (TOS). The hydrorefining catalyst is obtained by kneading a porous starting powder principally composed of gamma-alumina and having a pore capacity of 0.3-0.6 ml/g or larger and a mean pore diameter of 10 to 26 nm, extrudating and calcining, and after that supported with active metals component of elements belonging to groups VIIIB and VIB of the periodic table.

Abstract translation: 公开了一种改进的重质原油和残渣加氢脱金属催化剂。 固定床加氢处理装置采用催化剂。 本发明的特征在于具有大的孔径催化剂，主要用于在多反应器方法的第一反应器中重油和残余物的加氢脱金属。 催化剂具有高的脱金属活性和高的金属沉积能力，从而在流动时间（TOS）下产生良好的稳定性。 加氢精制催化剂是通过捏合主要由γ-氧化铝组成的多孔原料粉末，其孔容为0.3-0.6ml / g或更大，平均孔径为10-26nm，挤出和煅烧， 具有属于周期表第VIIIB族和VIB族的元素的活性金属组分。

公开(公告)号：US09127209B2

公开(公告)日：2015-09-08

申请号：US13836883

申请日：2013-03-15

Applicant: UOP LLC

Inventor： Mark Van Wees ,  David M. Bowman ,  Xin X. Zhu

IPC: C10G67/04 ,  C10G7/00 ,  C10G47/26 ,  C10G47/00 ,  C10G7/08

CPC classification number: C10G7/00 ,  C10G47/26 ,  C10G2400/04

Abstract: Two or three strippers are used to strip three hydroprocessed effluent streams, perhaps from a slurry hydrocracking reactor, separated by temperature instead of a single stripper to preserve separations previously made and conserving energy and reducing vessel size. A cold stripped stream may be taken as a diesel blending stock without further fractionation.

Abstract translation: 两个或三个剥离器用于剥离三个加氢处理的流出物流，可能来自浆料加氢裂化反应器，通过温度而不是单个汽提器分离，以保持先前制备的分离物并节约能量并减小容器大小。 可以将冷的汽提流作为柴油混合料而不进一步分馏。

公开(公告)号：US20150225233A1

公开(公告)日：2015-08-13

申请号：US14695522

申请日：2015-04-24

Applicant: lOGEN Corporation

Inventor： Brian Foody

IPC: C01B3/34 ,  C10G45/44 ,  G06Q50/06 ,  C10L1/04 ,  C12P5/02 ,  C01B3/36 ,  C10G47/00 ,  C10G45/02

CPC classification number: C01B3/34 ,  C01B3/36 ,  C01B2203/0211 ,  C01B2203/0216 ,  C01B2203/0222 ,  C01B2203/065 ,  C01B2203/1241 ,  C07C5/02 ,  C10G45/02 ,  C10G45/44 ,  C10G47/00 ,  C10G65/02 ,  C10G65/12 ,  C10G2400/02 ,  C10G2400/04 ,  C10G2400/08 ,  C10L1/04 ,  C10L3/08 ,  C10L3/10 ,  C10L3/101 ,  C10L2200/0469 ,  C10L2290/26 ,  C12P5/00 ,  C12P5/02 ,  C12P5/023 ,  G06Q30/018 ,  G06Q50/06 ,  Y02E50/13 ,  Y02E50/343 ,  Y02P30/10 ,  Y02P30/20 ,  Y02P80/21

Abstract: According to the present invention, organic material is converted to biogas through anaerobic digestion and the biogas is purified to yield a combustible fluid feedstock comprising methane. A fuel production facility utilizes or arranges to utilize combustible fluid feedstock to generate renewable hydrogen that is used to hydrogenate crude oil derived hydrocarbons in a process to make transportation or heating fuel. The renewable hydrogen is combined with crude oil derived hydrocarbons that have been desulfurized under conditions to hydrogenate the liquid hydrocarbon with the renewable hydrogen or alternatively, the renewable hydrogen can be added to a reactor operated so as to simultaneously desulfurize and hydrogenate the hydrocarbons. The present invention enables a party to receive a renewable fuel credit for the transportation or heating fuel.

Abstract translation: 根据本发明，通过厌氧消化将有机材料转化为沼气，并且净化沼气以产生包含甲烷的可燃流体原料。 燃料生产设备利用或安排利用可燃液体原料来产生可再生氢气，该可再生氢气在用于使运输或加热燃料的过程中氢化原油衍生的碳氢化合物。 可再生氢与原油衍生的烃组合，在已经脱硫的条件下，用可再生氢氢化液态烃，或者可再生氢可以加入反应器中，以同时使烃脱硫和氢化。 本发明使得一方能够为运输或加热燃料接收可再生燃料信用。