Composition and process for removing arsenic and selenium from aqueous solution
    75.
    发明申请
    Composition and process for removing arsenic and selenium from aqueous solution 失效
    从水溶液中除去砷和硒的组成和工艺

    公开(公告)号:US20030155303A1

    公开(公告)日:2003-08-21

    申请号:US10266240

    申请日:2002-10-08

    Abstract: The invention is a new composition and process for lanthanum oxide concentrate that is used to significantly reduce arsenic and/or selenium concentration levels in aqueous solutions. The lanthanum oxide concentrate is a mixture of lanthanum oxide and one or more oxides from the following group: neodymium oxide, cerium oxide, parseodymiun oxide, strontium oxide, calcium oxide and sodium oxide. The process of manufacture comprises the steps of sintering the lanthanum oxide concentrate, then washing the resultant media. The process of use is the contact of the lanthanum oxide concentrate with an aqueous solution containing arsenic and/or selenium whereby the lanthanum oxide concentrate removes at least a portion of the arsenic and/or selenium from the aqueous solution.

    Abstract translation: 本发明是用于显着降低水溶液中砷和/或硒浓度水平的氧化镧浓缩物的新组合物和方法。 氧化镧浓缩物是氧化镧和一种或多种来自下列组分的氧化物的混合物:氧化钕,氧化铈,氧化镝,氧化锶,氧化钙和氧化钠。 制造方法包括烧结氧化镧浓缩物,然后洗涤所得的介质的步骤。 使用的过程是氧化镧浓缩物与含有砷和/或硒的水溶液的接触,由此氧化镧浓缩物从水溶液中除去至少一部分砷和/或硒。

    Hydrous composite cerium-phosphorus oxide for immobilization of
strontium ions in solution
    79.
    发明授权
    Hydrous composite cerium-phosphorus oxide for immobilization of strontium ions in solution 失效
    用于在溶液中固定锶离子的水性复合铈 - 磷氧化物

    公开(公告)号:US5573673A

    公开(公告)日:1996-11-12

    申请号:US404097

    申请日:1995-03-14

    CPC classification number: B01J20/02 B01J20/0207 B01J20/0292 G21F9/12

    Abstract: Disclosed is a novel hydrous composite oxide of cerium (IV) and phosphorus characterized by the specified chemical composition and the unique X-ray diffractometric pattern, which is useful as an adsorbent or immobilizing agent of strontium ions in an aqueous solution such as radioactive wastes from atomic power plants. The composite oxide prepared by the precipitation reaction of a Ce (IV) salt in an aqueous solution and phosphoric acid can be imparted with an increased adsorption capacity for strontium ions when the precipitates are heat-treated under hydrothermal conditions at up to 300.degree. C. Immobilization of strontium ions adsorbed on the adsorbent can be more complete when the adsorbent bearing strontium ions is dried and subjected to a heat treatment at a temperature of 200.degree. C. or higher.

    Abstract translation: 公开了一种铈(Ⅳ)和磷的新型含水复合氧化物,其特征在于具有特定的化学成分和独特的X射线衍射图谱,其可用作锶离子在水溶液中的吸附剂或固定剂,例如放射性废物 原子能发电厂。 当在高达300℃的水热条件下对沉淀物进行热处理时,通过Ce(IV)盐在水溶液中的沉淀反应制备的复合氧化物可以赋予锶离子增加的吸附能力。 当吸附剂负载锶离子干燥并在200℃或更高的温度下进行热处理时,吸附在吸附剂上的锶离子的固定可以更完整。

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