Process for producing aromatic amines
    73.
    发明授权
    Process for producing aromatic amines 失效
    生产芳香胺的方法

    公开(公告)号:US5808157A

    公开(公告)日:1998-09-15

    申请号:US511165

    申请日:1995-08-04

    CPC分类号: C07C209/36

    摘要: Aromatic amines are produced by hydrogenation of the associated aromatic nitro compounds in the gas phase over fixed catalysts. The catalysts contain active hydrogenation metals on supports. The reaction is conducted at a pressure of 2-50 bar and at a temperature in the range 250.degree.-500.degree. C. under adiabatic conditions. A circulating gas is passed over the catalyst, which circulating gas contains 3-150 moles of hydrogen, 2-100 moles of the amino groups to be formed per mole of nitro groups, and 2 to 6 moles of water per amino group equivalent. The amine and water formed, as well as a purification stream, are separated from the circulating gas. Thereafter the circulating gas is enriched with volatilised aromatic nitro compound and fresh hydrogen and recycled.

    摘要翻译: 通过在气相中通过固定催化剂氢化相关联的芳族硝基化合物来生产芳族胺。 催化剂在载体上含有活性氢化金属。 反应在绝热条件下,在2-50巴的压力和250-500℃的温度下进行。 循环气体通过催化剂,循环气体含有3-150摩尔氢,每摩尔硝基形成2-100摩尔氨基和每个氨基当量2-6摩尔水。 所形成的胺和水以及净化物流与循环气体分离。 此后,循环气体富含挥发的芳​​香硝基化合物和新鲜氢气并再循环。

    Catalyst and method of preparing the catalyst
    76.
    发明授权
    Catalyst and method of preparing the catalyst 失效
    催化剂和制备催化剂的方法

    公开(公告)号:US5286700A

    公开(公告)日:1994-02-15

    申请号:US964268

    申请日:1992-10-21

    摘要: The catalyst according to the present invention can be utilized effectively as an ozone decomposing catalyst for catalytically decomposing to eliminate ozone contained in a gas or as an ozone deodorizing catalyst for decomposing offensive odor ingredients contained in a gas by catalytic oxidation under the pretense of ozone, and it comprises a composition containing Mn oxide, metal Pd and/or Pd oxide as the essential ingredients formed as a thin film on a support. Further, the performance of the catalyst can be improved by using Mn oxide and Pd as the essential ingredient and using an alumina sol as a binder upon preparation.

    摘要翻译: 根据本发明的催化剂可以有效地用作臭氧分解催化剂,用于催化分解以消除气体中所含的臭氧,或作为臭氧除臭催化剂,用于通过在臭氧的假装下通过催化氧化分解气体中含有的恶臭成分, 并且其包含在载体上形成为薄膜的作为必需成分的Mn氧化物,金属Pd和/或Pd氧化物的组合物。 此外,通过使用Mn氧化物和Pd作为必需成分,并且在制备时使用氧化铝溶胶作为粘合剂,可以提高催化剂的性能。

    Process for the production of catalyzers and catalyzers for the removal
of polluting components from the exhaust gases of internal combustion
engines
    78.
    发明授权
    Process for the production of catalyzers and catalyzers for the removal of polluting components from the exhaust gases of internal combustion engines 失效
    用于生产用于从内燃机排气中去除污染组分的催化剂和催化剂的方法

    公开(公告)号:US4818744A

    公开(公告)日:1989-04-04

    申请号:US126970

    申请日:1987-10-15

    摘要: The invention relates to a process for the production of a catalyzer and a catalyzer for the removal of polluting components from exhaust gases of internal combustion engines, particularly Otto-engines, by using carrier materials provided with catalytically effective metallic compounds. The catalyzer is not only simple and cost-effective to produce but also is very efficient at removing polluting components from exhaust gases, can be operated with leaded gasoline and has a comparatively long life components of the catalyzer include approx. 22-26% by weight of cobalt oxide, approx. 8-15% by weight manganous oxide, approx. 4-6% by weight copper oxide, approx. 25-35% by weight clay, and approx. 27-35% by weight talc. All these components are first premixed together in a dry powder form, homogenized and brought to the desired final particle size. Subsequently the powder mixture to be plastified is agitaled in a mixer and granulated through a sieve resultant granulate is then pressed into molds to be dried at approx. 50-150 degrees C and then burned at a temperature of approx. 850-900 degrees C.

    摘要翻译: PCT No.PCT / EP87 / 00115 Sec。 371日期:1987年10月15日 102(e)日期1987年10月15日PCT 1987年2月26日PCT PCT。 公开号WO87 / 05231 日本1987年9月11日。本发明涉及一种生产催化剂和催化剂的方法,用于通过使用提供有催化有效金属的载体材料来除去内燃机废气中的污染组分,特别是奥托发动机 化合物。 催化剂不仅生产简单且经济高效,而且从废气中除去污染成分也非常有效,可以用含铅汽油进行操作,催化剂的使用寿命比较长。 22-26重量%的氧化钴,约 8-15重量%的氧化锰,约 4-6%重量的氧化铜,约 25-35%(重量)粘土, 27-35%滑石粉。 所有这些组分首先以干粉形式预混合在一起,均化并达到所需的最终粒度。 随后将待塑化的粉末混合物在混合器中搅拌并通过筛子造粒得到的颗粒然后压制成模具以在约 50-150摄氏度,然后在约 850-900摄氏度