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1.发明授权Crystallized silicon-containing material with hierarchical and organized porosity 失效结晶含硅材料具有分层和有组织的孔隙度公开(公告)号：US08623508B2
公开(公告)日：2014-01-07
申请号：US12676750
申请日：2008-08-29
CPC分类号： C01B37/005 , C01B37/02 , C01B39/00
摘要： Material with hierarchical and organized porosity in the microporosity and mesoporosity domains, consisting of at least two elementary spherical particles, each one of said particles comprising a matrix based on silicon oxide, mesostructured, having a mesopore diameter ranging between 1.5 and 30 nm and exhibiting microporous and crystallized walls of thickness ranging between 1 and 60 nm, said elementary spherical particles having a maximum diameter of 200 microns. The preparation of said material is also described.
摘要翻译： 在微孔和中孔结构域中具有分层和有组织的孔隙度的材料，由至少两个基本球形颗粒组成，所述颗粒中的每一个包含基于氧化硅的基质，介孔结构的，具有介于1.5和30nm之间的中孔直径并且表现出微孔 和厚度范围在1至60nm之间的结晶壁，所述基本球形颗粒的最大直径为200微米。 还描述了所述材料的制备。
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2.发明授权Amorphous silicon-containing material with hierarchical and organized porosity 有权无定形含硅材料具有分层和有组织的孔隙度公开(公告)号：US08236419B2
公开(公告)日：2012-08-07
申请号：US12676759
申请日：2008-08-19
IPC分类号： B32B5/66
CPC分类号： C01B37/02 , C01B33/46 , C01B39/02 , Y10T428/2982 , Y10T428/2991 , Y10T428/2993
摘要： Material with hierarchical porosity consisting of at least two elementary spherical particles, each one of said particles comprising a matrix based on silicon oxide, mesostructured, having a mesopore diameter ranging between 1.5 and 30 nm and exhibiting amorphous and microporous walls of thickness ranging between 1.5 and 50 nm, said elementary spherical particles having a maximum diameter of 200 microns. The matrix based on silicon oxide can contain aluminium. The preparation of said material is also described.
摘要翻译： 具有由至少两个基本球形颗粒组成的分层孔隙的材料，每个所述颗粒包含基于氧化硅的介孔结构的基体，其具有介于1.5和30nm之间的中孔直径，并且具有范围在1.5和1.5之间的无定形和微孔壁 所述基本球形颗粒的最大直径为200微米。 基于氧化硅的基体可以含有铝。 还描述了所述材料的制备。
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3.发明申请AMORPHOUS SILICON-CONTAINING MATERIAL WITH HIERARCHICAL AND ORGANIZED POROSITY 有权具有分层和有组织的多孔性的非晶含硅材料公开(公告)号：US20100291387A1
公开(公告)日：2010-11-18
申请号：US12676759
申请日：2008-08-19
CPC分类号： C01B37/02 , C01B33/46 , C01B39/02 , Y10T428/2982 , Y10T428/2991 , Y10T428/2993
摘要： Material with hierarchical porosity consisting of at least two elementary spherical particles, each one of said particles comprising a matrix based on silicon oxide, mesostructured, having a mesopore diameter ranging between 1.5 and 30 nm and exhibiting amorphous and microporous walls of thickness ranging between 1.5 and 50 nm, said elementary spherical particles having a maximum diameter of 200 microns. The matrix based on silicon oxide can contain aluminium. The preparation of said material is also described.
摘要翻译： 具有由至少两个基本球形颗粒组成的分层孔隙的材料，每个所述颗粒包含基于氧化硅的介孔结构的基体，其具有介于1.5和30nm之间的中孔直径，并且具有范围在1.5和1.5之间的无定形和微孔壁 所述基本球形颗粒的最大直径为200微米。 基于氧化硅的基体可以含有铝。 还描述了所述材料的制备。
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4.发明申请CRYSTALLIZED SILICON-CONTAINING MATERIAL WITH HIERARCHICAL AND ORGANIZED POROSITY 失效具有分层和有组织的多孔性的结晶含硅材料公开(公告)号：US20100297002A1
公开(公告)日：2010-11-25
申请号：US12676750
申请日：2008-08-29
IPC分类号： C01B39/02
CPC分类号： C01B37/005 , C01B37/02 , C01B39/00
摘要： Material with hierarchical and organized porosity in the microporosity and mesoporosity domains, consisting of at least two elementary spherical particles, each one of said particles comprising a matrix based on silicon oxide, mesostructured, having a mesopore diameter ranging between 1.5 and 30 nm and exhibiting microporous and crystallized walls of thickness ranging between 1 and 60 nm, said elementary spherical particles having a maximum diameter of 200 microns. The preparation of said material is also described.
摘要翻译： 在微孔和中孔结构域中具有分层和有组织的孔隙度的材料，由至少两个基本球形颗粒组成，所述颗粒中的每一个包含基于氧化硅的基质，介孔结构的，具有介于1.5和30nm之间的中孔直径并且表现出微孔 和厚度范围在1至60nm之间的结晶壁，所述基本球形颗粒的最大直径为200微米。 还描述了所述材料的制备。
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5.发明申请SPHERICAL MATERIAL BASED ON HETEROPOLYANIONS TRAPPED IN A MESOSTRUCTURED OXIDE MATRIX AND USE THEREOF AS CATALYST IN HYDROCARBON REFINING PROCESSES 审中-公开基于在结构化氧化物基质中捕获的异黄酮的球形材料及其作为烃类精炼工艺中的催化剂的用途公开(公告)号：US20140005031A1
公开(公告)日：2014-01-02
申请号：US13995508
申请日：2011-12-15
申请人： Alexandra Chaumonnot , Clement Sanchez , Cedric Boissiere , Frederic Colbeau-Justin , Karin Marchand , Elodie Devers , Audrey Bonduelle , Denis Uzio , Antoine Daudin , Bertrand Guichard , Denis Uzio , Antoine Daudin
发明人： Alexandra Chaumonnot , Clement Sanchez , Cedric Boissiere , Frederic Colbeau-Justin , Karin Marchand , Elodie Devers , Audrey Bonduelle , Denis Uzio , Antoine Daudin , Bertrand Guichard , Denis Uzio , Antoine Daudin
IPC分类号： B01J27/199 , B01J27/19 , B01J27/188 , B01J23/882
CPC分类号： B01J27/199 , B01J23/882 , B01J27/186 , B01J27/188 , B01J27/19 , B01J29/0333 , B01J29/0341 , B01J29/041 , B01J29/044 , B01J29/045 , B01J35/002 , B01J35/006 , B01J35/023 , B01J35/1019 , B01J35/1042 , B01J35/1057 , B01J35/1061 , B01J37/0045 , B01J37/033 , B01J37/10 , B01J37/20 , C01B37/00 , C01B37/005 , C01B37/02 , C01B39/04 , C01B39/06 , C10G3/45 , C10G3/46 , C10G3/48 , C10G3/49 , C10G3/50 , C10G45/06 , C10G47/12 , C10G2300/1011 , C10G2300/104 , C10G2300/1044 , C10G2300/1055 , C10G2300/202 , C10G2300/301 , C10G2400/02 , C10G2400/04 , C10G2400/06 , C10L1/04 , C10L1/06 , C10L1/08 , Y02P30/10 , Y02P30/20
摘要： Inorganic material having at least two elementary spherical particles, each of said spherical metallic particles: a polyoxometallate with formula (XxMmOyHh)q−, where H is hydrogen, O is oxygen, X is phosphorus, silicon, boron, nickel or cobalt and M is one or more vanadium, niobium, tantalum, molybdenum, tungsten, iron, copper, zinc, cobalt and nickel, x is 0, 1, 2 or 4, m is 5, 6, 7, 8, 9, 10, 11, 12 or 18, y is 17 to 72, h is 0 to 12 and q is 1 to 20.
摘要翻译： 具有至少两个基本球形颗粒的无机材料，每个所述球形金属颗粒：具有式（XxMmOyHh）q-的多金属氧酸盐，其中H是氢，O是氧，X是磷，硅，硼，镍或钴，M是 一种或多种钒，铌，钽，钼，钨，铁，铜，锌，钴和镍，x为0,1,2或4，m为5,6,7,8,9,10,11,12 或18，y为17〜72，h为0〜12，q为1〜20。
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6.发明申请MESOSTRUCTURED ALUMINOSILICATE MATERIAL MADE OF SPHERICAL PARTICLES OF SPECIFIC SIZE 有权特殊尺寸的球形颗粒的结构化铝氧化物材料公开(公告)号：US20110105300A1
公开(公告)日：2011-05-05
申请号：US12935335
申请日：2009-02-26
CPC分类号： C01B39/04 , B01J20/18 , B01J20/28004 , B01J20/28019 , B01J20/28057 , B01J20/28083 , B01J21/12 , B01J29/041 , B01J35/1057 , B01J35/1061 , B01J35/109 , Y10T428/2991 , Y10T428/2993
摘要： A mesostructured aluminosilicate material is described, which consists of at least two elementary spherical particles, each one of said spherical particles consisting of a matrix based on silicon oxide and aluminium oxide, said matrix having a pore diameter ranging between 1.5 and 30 nm, a Si/Al molar ratio at least equal to 1 and amorphous walls of thickness ranging between 1 and 30 nm, said elementary spherical particles having a diameter D such that 10
摘要翻译： 描述了介质结构的硅铝酸盐材料，其由至少两个基本球形颗粒组成，每个所述球形颗粒由基于氧化硅和氧化铝的基体组成，所述基体的孔径范围为1.5至30nm，Si / Al摩尔比至少等于1，厚度范围在1至30nm之间的非晶壁，所述基本球形颗粒的直径D使得10
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公开(公告)号：US20090232720A1
公开(公告)日：2009-09-17
申请号：US12408437
申请日：2009-03-20
申请人： Alexandra Chaumonnot , Aurelie Coupe , Clement Sanchez , Patrick Euzen , Cedric Boissiere , David Grosso
发明人： Alexandra Chaumonnot , Aurelie Coupe , Clement Sanchez , Patrick Euzen , Cedric Boissiere , David Grosso
IPC分类号： C01B33/26
CPC分类号： B01J35/0013 , B01J29/041 , B01J35/023 , B01J35/10 , B01J35/1023 , B01J37/0045 , C01B39/02
摘要： A mesostructured aluminosilicate material is described, constituted by at least two spherical elementary particles, each of said spherical particles being constituted by a matrix based on silicon oxide and aluminium oxide, having a pore size in the range 1.5 to 30 nm, a Si/Al molar ratio of at least 1, having amorphous walls with a thickness in the range 1 to 20 nm, said spherical elementary particles having a maximum diameter of 10 μm. A process for preparing said material and its application in the fields of refining and petrochemistry are also described.
摘要翻译： 描述了由至少两个球形基本粒子构成的介孔结构的硅铝酸盐材料，每个所述球形颗粒由基于氧化硅和氧化铝的基体构成，孔径在1.5至30nm的范围内，Si / Al 摩尔比至少为1，具有厚度在1至20nm范围内的非晶壁，所述球形基本颗粒的最大直径为10μm。 还描述了制备所述材料的方法及其在精炼和石油化学领域的应用。
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公开(公告)号：US20090029847A1
公开(公告)日：2009-01-29
申请号：US11889891
申请日：2007-08-17
申请人： Patrick Euzen , Alexandra Chaumonnot , Aurelie Coupe , Clement Sanchez , Cedric Boissiere , David Grosso
发明人： Patrick Euzen , Alexandra Chaumonnot , Aurelie Coupe , Clement Sanchez , Cedric Boissiere , David Grosso
IPC分类号： B01J29/06
CPC分类号： C01B39/04 , B01J20/08 , B01J20/16 , B01J20/18 , B01J20/28007 , B01J20/28083 , B01J29/041 , B01J29/08 , B01J29/40 , B01J29/60 , B01J29/7007 , B01J29/80 , B01J2229/62 , B82Y30/00 , C01B39/48
摘要： A mesostructured material that consists of at least two elementary spherical particles, each of said particles comprising a mesostructured matrix based on aluminum oxide and having a pore size of between 1.5 and 30 nm, an aluminum oxide content that represents more than 46% by weight relative to the mass of said matrix, which has amorphous walls with a thickness of between 1 and 30 nm and whereby said elementary spherical particles have a maximum diameter of 10 μm, is described. Said mesostructured matrix can also contain silicon oxide. Each of the spherical particles of the mesostructured material can also contain zeolitic nanocrystals so as to form a material with a mixed porosity that is both mesostructured and zeolitic in nature. The preparation of said material is also described.
摘要翻译： 由至少两个基本球形颗粒组成的介孔结构材料，每个所述颗粒包含基于氧化铝的孔结构基质，孔径在1.5至30nm之间，氧化铝含量相对于46重量％ 涉及具有1至30nm厚度的非晶壁的所述基体的质量，并且由此所述基本球形颗粒的最大直径为10um。 所述介孔结构的基质也可以含有氧化硅。 介孔结构材料的每个球形颗粒也可以含有沸石纳米晶体，以便形成具有混合孔隙率的材料，其本质上是介孔结构和沸石。 还描述了所述材料的制备。
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9.发明授权Inorganic material that has metal nanoparticles that are trapped in a mesostructured matrix 有权具有被捕获在介孔结构基质中的金属纳米颗粒的无机材料公开(公告)号：US08226740B2
公开(公告)日：2012-07-24
申请号：US11889890
申请日：2007-08-17
CPC分类号： C01B39/48 , B01J23/002 , B01J23/10 , B01J23/52 , B01J23/745 , B01J23/75 , B01J29/044 , B01J29/46 , B01J29/89 , B01J35/0013 , B01J35/10 , B01J35/1057 , B01J35/1061 , B01J35/1085 , B01J35/109 , B01J2229/18 , B01J2229/42 , B01J2523/00 , C01B37/02 , C01B39/04 , Y10S977/777 , Y10S977/779 , Y10T428/12042 , B01J2523/3706 , B01J2523/3712 , B01J2523/845 , B01J2523/41 , B01J2523/48 , B01J2523/31 , B01J2523/842
摘要： An inorganic material that consists of at least two elementary spherical particles, each of said spherical particles comprising metal nanoparticles that are between 1 and 300 nm in size and a mesostructured matrix with an oxide base of at least one element X that is selected from the group that consists of aluminum, titanium, tungsten, zirconium, gallium, germanium, tin, antimony, lead, vanadium, iron, manganese, hafnium, niobium, tantalum, yttrium, cerium, gadolinium, europium and neodymium is described, whereby said matrix has a pore size of between 1.5 and 30 nm and has amorphous walls with a thickness of between 1 and 30 nm, said elementary spherical particles having a maximum diameter of 10 μm. Said material can also contain zeolitic nanocrystals that are trapped within said mesostructured matrix.
摘要翻译： 由至少两个基本球形颗粒组成的无机材料，每个所述球形颗粒包含尺寸在1至300nm之间的金属纳米颗粒和具有至少一种元素X的氧化物碱的介孔结构基质，所述元素选自基团 描述了由铝，钛，钨，锆，镓，锗，锡，锑，铅，钒，铁，锰，铪，铌，钽，钇，铈，钆，铕和钕组成的组合物， 孔径在1.5和30nm之间，并且具有1至30nm厚度的非晶壁，所述基本球形颗粒的最大直径为10μm。 所述材料还可以含有被捕获在所述介孔结构基质内的沸石纳米晶体。
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公开(公告)号：US20060292054A1
公开(公告)日：2006-12-28
申请号：US11159384
申请日：2005-06-23
申请人： Alexandra Chaumonnot , Aurelie Coupe , Clement Sanchez , Patrick Euzen , Cedric Boissiere , David Grosso
发明人： Alexandra Chaumonnot , Aurelie Coupe , Clement Sanchez , Patrick Euzen , Cedric Boissiere , David Grosso
IPC分类号： C01B33/26
CPC分类号： B01J35/0013 , B01J29/041 , B01J35/023 , B01J35/10 , B01J35/1023 , B01J37/0045 , C01B39/02
摘要： A mesostructured aluminosilicate material is described, constituted by at least two spherical elementary particles, each of said spherical particles being constituted by a matrix based on silicon oxide and aluminium oxide, having a pore size in the range 1.5 to 30 nm, a Si/Al molar ratio of at least 1, having amorphous walls with a thickness in the range 1 to 20 nm, said spherical elementary particles having a maximum diameter of 10 μm. A process for preparing said material and its application in the fields of refining and petrochemistry are also described.
摘要翻译： 描述了由至少两个球形基本粒子构成的介孔结构的硅铝酸盐材料，每个所述球形颗粒由基于氧化硅和氧化铝的基体构成，孔径在1.5至30nm的范围内，Si / Al 摩尔比至少为1，具有厚度在1至20nm范围内的非晶壁，所述球形基本颗粒的最大直径为10μm。 还描述了制备所述材料的方法及其在精炼和石油化学领域的应用。
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