Dealuminated IM-5 zeolite
    1.
    发明授权
    Dealuminated IM-5 zeolite 失效
    脱铝IM-5沸石

    公开(公告)号:US5968475A

    公开(公告)日:1999-10-19

    申请号:US12190

    申请日:1998-01-23

    CPC分类号: C01B39/026 B01J2229/16

    摘要: The present invention relates to a dealuminated IM-5 zeolite and to any catalyst comprising that zeolite which is at least partially in its acid form. The invention also relates to the preparation of the catalyst and to the catalyst. Finally, the invention relates to the use of the zeolite in a hydrocarbon conversion process.

    摘要翻译: 本发明涉及脱铝的IM-5沸石和任何包含至少部分为其酸形式的沸石的催化剂。 本发明还涉及催化剂和催化剂的制备。 最后,本发明涉及沸石在烃转化方法中的应用。

    Homogeneous bed of catalyst and a process for transforming hydrocarbons into aromatic compounds using said bed
    5.
    发明授权
    Homogeneous bed of catalyst and a process for transforming hydrocarbons into aromatic compounds using said bed 有权
    催化剂的均相床和使用所述床将烃转化为芳族化合物的方法

    公开(公告)号:US08349760B2

    公开(公告)日:2013-01-08

    申请号:US10454837

    申请日:2003-06-05

    摘要: The invention concerns a homogeneous bed of particles of a catalyst, said catalyst comprising at least one amorphous matrix, at least one noble metal, at least one additional metal M and at least one halogen, and in which, for a catalyst particle, CPt is the local concentration of noble metal Pt; CM is the local concentration of additional metal M; CX is the local concentration of halogen; said catalyst being in the form of a homogeneous bed of particles, in which across the diameter of the particle, at least 70% of the values CPt/CM or CPt/CX differ from the mean local ratio by at most 30%, and in which the mole ratio M/Pt in the catalyst is in the range 1.8 to 6.

    摘要翻译: 本发明涉及催化剂颗粒的均匀床,所述催化剂包含至少一种无定形基质,至少一种贵金属,至少一种另外的金属M和至少一种卤素,其中,对于催化剂颗粒,CPt为 贵金属Pt的局部浓度; CM是附加金属M的局部浓度; CX是卤素的局部浓度; 所述催化剂是均匀的颗粒床形式,其中跨越颗粒的直径,CPt / CM或CPt / CX的值的至少70%与平均局部比率不同至多30%,并且在 催化剂中M / Pt的摩尔比在1.8至6的范围内。

    METHOD FOR PREPARING A MULTI-METAL CATALYST HAVING AN OPTIMIZED SITE PROXIMITY
    6.
    发明申请
    METHOD FOR PREPARING A MULTI-METAL CATALYST HAVING AN OPTIMIZED SITE PROXIMITY 审中-公开
    制备具有优化现场接近度的多金属催化剂的方法

    公开(公告)号:US20120178979A1

    公开(公告)日:2012-07-12

    申请号:US13381281

    申请日:2010-06-15

    摘要: The invention concerns a process for preparing a catalyst comprising at least one metal M from the platinum group, tin, a phosphorus promoter, a halogenated compound, a porous support and at least one promoter X1 selected from the group constituted by gallium, indium, thallium, arsenic, antimony and bismuth. The promoter or promoters X1 and the phosphorus are introduced during one or more sub-steps a1) or a2), the sub-step a1) corresponding to synthesis of the precursor of the main oxide and sub-step a2) corresponding to shaping the support. The tin is introduced during at least one of sub-steps a1) and a2). The product is dried and calcined before depositing at least one metal M from the platinum group. The ensemble is then dried in a stream of neutral gas or a stream of gas containing oxygen, and then is dried. The invention also concerns the use of a catalyst obtained by said process in catalytic reforming or aromatics production reactions.

    摘要翻译: 本发明涉及一种制备催化剂的方法,所述催化剂包含至少一种来自铂族的金属M,锡,磷促进剂,卤代化合物,多孔载体和至少一种选自镓,铟,铊 ,砷,锑和铋。 在一个或多个子步骤a1)或a2)期间引入启动子或启动子X1和磷,对应于主氧化物的前体的合成的子步骤a1)和对应于形成载体的子步骤a2) 。 在子步骤a1)和a2)中的至少一个中引入锡。 在从铂族中沉积至少一种金属M之前,将产物干燥并煅烧。 然后将所述组合体在中性气体流或含氧气流中干燥,然后干燥。 本发明还涉及通过所述方法在催化重整或芳烃生产反应中获得的催化剂的用途。

    Process for preparing aluminophosphate compounds and substituted
derivatives of the structural type VFI
    8.
    发明授权
    Process for preparing aluminophosphate compounds and substituted derivatives of the structural type VFI 失效
    制备结构型VFI的氨基磷酸酯化合物和取代衍生物的方法

    公开(公告)号:US5241093A

    公开(公告)日:1993-08-31

    申请号:US822852

    申请日:1992-01-21

    IPC分类号: B01J29/83 C01B37/04 C01B37/08

    CPC分类号: B01J29/83 C01B37/04 C01B37/08

    摘要: A process for preparing aluminophosphate compounds (and substituted derivatives) of the structural type VFI. This preparation process is characterized in that the speed of increase in temperature of the reaction mixture is greater than 250.degree. C./hour, the total time of heating of the reaction mixture, including the rise in temperature and the plateau heating, being less than one hour. The temperature of the plateau heating is between 100.degree. and 200.degree. C.The synthetic compounds in accordance with the invention possess(a) a general formula approximating to the following:1 Al.sub.2 O.sub.3 0.75-1.25 P.sub.2 O.sub.5 0-0.5 XO.sub.n/2 0-0.05 R y H.sub.2 OwhereX represents a heteroatom chosen from the group consisting of silicon, cobalt, magnesium and zinc;n is the degree of oxidation of the heteroatom X;y, the number of water molecules contained in the said compound, is greater than 0.001; andR is an organic compound chosen from the group consisting of secondary amines, tertiary amines, and quaternary ammonium salts and hydroxides;(b) an X-ray diffraction diagram as represented in Table I of the description.

    摘要翻译: 制备结构型VFI的磷酸铝化合物(和取代的衍生物)的方法。 该制备方法的特征在于,反应混合物的温度升高速度大于250℃/小时,反应混合物的总加热时间(包括温度升高和平台加热)小于 一小时。 平台加热的温度为100至200℃。根据本发明的合成化合物具有(a)接近于以下的通式:1 Al 2 O 3 0.75-1.25 P 2 O 5 0-0.5 XOn / 2 0-0.05 其中X表示选自硅,钴,镁和锌的杂原子; n是杂原子X的氧化度; y,所述化合物中含有的水分子数目大于0.001; 并且R是选自仲胺,叔胺和季铵盐和氢氧化物的有机化合物; (b)如说明书的表I所示的X射线衍射图。