摘要:
The present invention relates to a dealuminated IM-5 zeolite and to any catalyst comprising that zeolite which is at least partially in its acid form. The invention also relates to the preparation of the catalyst and to the catalyst. Finally, the invention relates to the use of the zeolite in a hydrocarbon conversion process.
摘要:
The invention concerns a NU-86 zeolite comprising silicon and at least one element T selected from the group formed by aluminium, iron, gallium and boron, preferably aluminium, characterized in that element T has been extracted from the framework, and in that it has a global Si/T atomic ratio of more than about 20. Element T is extracted from the zeolitic framework (or network) by means of at least one heat treatment, optionally carried out in the presence of steam, followed by at least one acid attack using at least one solution of a mineral or organic acid, or by direct acid attack. The invention also concerns a catalyst comprising the zeolite which is at least partially in its acid form, and the use of the catalyst for the conversion of hydrocarbons, in particular for the oligomerization of olefins.
摘要:
The present invention relates to the use of a catalyst comprising a Y zeolite with a faujasite structure combined with a NU-86 zeolite which is dealuminated and at least partially in its acid form and a matrix which is normally amorphous or of low crystallinity in a process for catalytic cracking of petroleum feeds.
摘要:
The present invention relates to the use of a catalyst comprising an IM-5 zeolite which has optionally been dealuminated and is at least partially in its acid form and a matrix which is normally amorphous or of low crystallinity, and optionally a Y zeolite with a faujasite structure, in a process for catalytic cracking of petroleum feeds.
摘要:
The invention concerns a homogeneous bed of particles of a catalyst, said catalyst comprising at least one amorphous matrix, at least one noble metal, at least one additional metal M and at least one halogen, and in which, for a catalyst particle, CPt is the local concentration of noble metal Pt; CM is the local concentration of additional metal M; CX is the local concentration of halogen; said catalyst being in the form of a homogeneous bed of particles, in which across the diameter of the particle, at least 70% of the values CPt/CM or CPt/CX differ from the mean local ratio by at most 30%, and in which the mole ratio M/Pt in the catalyst is in the range 1.8 to 6.
摘要:
The invention concerns a process for preparing a catalyst comprising at least one metal M from the platinum group, tin, a phosphorus promoter, a halogenated compound, a porous support and at least one promoter X1 selected from the group constituted by gallium, indium, thallium, arsenic, antimony and bismuth. The promoter or promoters X1 and the phosphorus are introduced during one or more sub-steps a1) or a2), the sub-step a1) corresponding to synthesis of the precursor of the main oxide and sub-step a2) corresponding to shaping the support. The tin is introduced during at least one of sub-steps a1) and a2). The product is dried and calcined before depositing at least one metal M from the platinum group. The ensemble is then dried in a stream of neutral gas or a stream of gas containing oxygen, and then is dried. The invention also concerns the use of a catalyst obtained by said process in catalytic reforming or aromatics production reactions.
摘要:
The invention concerns a process for preparing a catalyst comprising at least one metal from group VIII, rhenium or iridium and a sulphur-containing support, said catalyst having a sodium content which is strictly less than 50 ppm by weight and a sulphur content in the range 1500 to 3000 ppm by weight. The invention also concerns the use of said catalyst in a catalytic reforming reaction.
摘要:
A process for preparing aluminophosphate compounds (and substituted derivatives) of the structural type VFI. This preparation process is characterized in that the speed of increase in temperature of the reaction mixture is greater than 250.degree. C./hour, the total time of heating of the reaction mixture, including the rise in temperature and the plateau heating, being less than one hour. The temperature of the plateau heating is between 100.degree. and 200.degree. C.The synthetic compounds in accordance with the invention possess(a) a general formula approximating to the following:1 Al.sub.2 O.sub.3 0.75-1.25 P.sub.2 O.sub.5 0-0.5 XO.sub.n/2 0-0.05 R y H.sub.2 OwhereX represents a heteroatom chosen from the group consisting of silicon, cobalt, magnesium and zinc;n is the degree of oxidation of the heteroatom X;y, the number of water molecules contained in the said compound, is greater than 0.001; andR is an organic compound chosen from the group consisting of secondary amines, tertiary amines, and quaternary ammonium salts and hydroxides;(b) an X-ray diffraction diagram as represented in Table I of the description.
摘要翻译:制备结构型VFI的磷酸铝化合物(和取代的衍生物)的方法。 该制备方法的特征在于,反应混合物的温度升高速度大于250℃/小时,反应混合物的总加热时间(包括温度升高和平台加热)小于 一小时。 平台加热的温度为100至200℃。根据本发明的合成化合物具有(a)接近于以下的通式:1 Al 2 O 3 0.75-1.25 P 2 O 5 0-0.5 XOn / 2 0-0.05 其中X表示选自硅,钴,镁和锌的杂原子; n是杂原子X的氧化度; y,所述化合物中含有的水分子数目大于0.001; 并且R是选自仲胺,叔胺和季铵盐和氢氧化物的有机化合物; (b)如说明书的表I所示的X射线衍射图。
摘要:
The invention concerns a catalyst composed of at least one halogen, at least one metal from group VIII and a formed support of gamma alumina and optionally eta alumina, the catalyst being characterized in that the smallest average dimension of said support is in the range 0.8 mm to 2 mm and in that the halogen content is in the range 4.5% to 15% by weight. The invention also concerns the preparation of said catalyst, preferably with chlorination (in the case where the halogen is chlorine) in the presence of CCl.sub.4 or CHCl.sub.3. The invention also concerns the use of the catalyst for the isomerisation of normal C.sub.4 -C.sub.6 paraffins.