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公开(公告)号:US20180078898A1
公开(公告)日:2018-03-22
申请号:US15712187
申请日:2017-09-22
发明人: Paul ANDERSEN , Hai-Ying CHEN , Kevin DOURA , Joseph FEDEYKO
CPC分类号: B01D53/864 , B01D53/944 , B01D53/9459 , B01D53/9468 , B01D53/9472 , B01D2255/1021 , B01D2255/1023 , B01D2255/1026 , B01D2255/106 , B01D2255/2065 , B01D2255/20715 , B01D2255/2092 , B01D2255/902 , B01D2255/9022 , B01D2255/9032 , B01D2255/9155 , B01D2257/702 , B01D2257/7025 , B01D2258/012 , B01J21/04 , B01J21/066 , B01J21/12 , B01J23/38 , B01J23/40 , B01J23/42 , B01J23/44 , B01J23/462 , B01J23/52 , B01J23/63 , B01J29/00 , B01J29/06 , B01J35/0006 , B01J35/04 , B01J37/0244 , B01J37/0246 , B01J37/0248 , F01N3/0835 , F01N3/103 , F01N3/106 , F01N2370/02 , F01N2370/04 , F01N2510/063 , F01N2510/068 , F01N2510/0682 , F01N2510/0684 , F01N2570/12 , F01N2570/145 , Y02A50/2322 , Y02C20/10 , Y02T10/20
摘要: An oxidation catalyst is described for treating hydrocarbons in an exhaust gas produced by an internal combustion engine, wherein the oxidation catalyst comprises a region disposed on a substrate, wherein the region comprises ruthenium (Ru) supported on a support material comprising a refractory oxide.
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公开(公告)号:US20230265772A1
公开(公告)日:2023-08-24
申请号:US18169595
申请日:2023-02-15
发明人: Kevin DOURA , John KILMARTIN , Jing LU , Nicholas MCNAMARA , Thomas YEH
CPC分类号: F01N3/208 , B01D53/945 , B01D53/9454 , B01D53/9477 , B01D53/9495 , B01J21/04 , B01J23/10 , B01J23/462 , F01N3/101 , F01N3/108 , F01N3/2803 , F01N3/2839 , B01D2255/1026 , B01D2255/904 , B01D2255/908 , B01D2255/9155 , F01N2610/04 , F01N2610/1406 , F01N2610/1453 , F01N2900/1402
摘要: The present invention relates to a system for ammonia combustion and exhaust gas treatment, the system comprising: an internal combustion engine for combusting ammonia; and an exhaust system comprising an intake for receiving an exhaust gas from the combustion engine, an upstream injector for adding hydrogen gas to the exhaust gas and a downstream catalyst article, wherein the downstream catalyst article comprises a three-way catalyst (TWC) composition. The invention further relates to a method for the treatment of an exhaust gas from an ammonia internal combustion engine.
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公开(公告)号:US20210094022A1
公开(公告)日:2021-04-01
申请号:US16948587
申请日:2020-09-24
发明人: Paul Joseph ANDERSEN , Ferdinand BAER , Maria Theresia BRANDMAIR , Kevin DOURA , Heike KREUDER , Desiree DURAN MARTIN
IPC分类号: B01J23/847 , B01J23/44 , B01J21/04 , B01J23/02 , B01J23/10 , B01J23/34 , B01J23/00 , B01J35/04 , B01D53/94 , B01J29/70
摘要: A multi-function catalyst article for treating both NO and carbon monoxide emissions in a flow of a combustion exhaust gas from a stationary emission source comprises a honeycomb monolith substrate comprising one or more channels which are open at both ends and extend along an axial length thereof and through which, in use, a combustion exhaust gas flows, which catalyst article comprising a catalyst composition comprising a combination of a first, vanadium-containing SCR catalyst component and a second component which is a compound of a transition metal comprising copper, manganese, cobalt, molybdenum, nickel or cerium or a mixture of any two or more thereof and optionally a third, crystalline molecular sieve component.
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4.
公开(公告)号:US20190383174A1
公开(公告)日:2019-12-19
申请号:US16465600
申请日:2017-11-29
发明人: Paul ANDERSEN , Kevin DOURA , Cindy KHALAF , David REPP , Thomas YEH
摘要: A method of extending the useful life of an aged selective catalytic reduction (SCR) catalyst bed, which catalyses the conversion of oxides of nitrogen (NOx) to dinitrogen (N2) in the presence of a nitrogenous reductant, in the exhaust gas after treatment system of a stationary source of NOx so that the exhaust gas emitted to atmosphere from the system continues to meet proscribed limits for both NOx and ammonia emissions, which method comprising the step of retrofitting an additional honeycomb substrate monolith or a plate-type substrate comprising a catalyst (ASC) for converting ammonia in exhaust gas also containing oxygen to nitrogen and water downstream of the aged SCR catalyst bed, wherein the kNOx of the honeycomb substrate monolith comprising the catalyst for converting ammonia in exhaust gas also containing oxygen to nitrogen and water is greater than or equal to 80 m/hr between 300 and 400° C. inclusive, wherein kNOx of a sample of the catalyst, which has been aged at 450° C. in 10% H2O (as steam) in air for 48 hours, is determined by a SCR activity test in a laboratory scale reactor using a gas composition of 50 ppm CO, 30 ppm NO, 36 ppm NH3, 15% O2, 8% water, 3% CO2, balance N2.
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公开(公告)号:US20220219145A1
公开(公告)日:2022-07-14
申请号:US17647358
申请日:2022-01-07
发明人: Kevin DOURA
IPC分类号: B01J23/42 , B01J21/12 , B01J21/06 , B01J37/03 , B01J37/04 , B01J37/08 , B01J35/04 , B01J37/02 , B01J35/10 , B01D53/94 , F01N3/28
摘要: The present invention relates to a method of preparing a catalyst article comprising steps: (a) preparing a washcoat composition by combining at least the following components: a support material comprising a mixed oxide, a mixture of oxides or a molecular sieve comprising (i) alumina and (ii) silica and/or zirconia; a metal oxide sol comprising at least one of titania, silica or zirconia; a liquid medium; (b) applying the washcoat composition to a substrate to form a washcoating; and (c) drying and/or calcining the washcoating; wherein the method further comprises a step of impregnating the support material with a platinum group metal component. The prepared catalyst article may be suitable for the treatment of emissions from an internal combustion engine or a gas turbine, for example, the treatment of carbon monoxide and/or formaldehyde emissions from a natural gas fueled internal combustion engine or gas turbine.
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6.
公开(公告)号:US20170341022A1
公开(公告)日:2017-11-30
申请号:US15607936
申请日:2017-05-30
发明人: Paul ANDERSEN , Kevin DOURA
CPC分类号: B01D53/8637 , B01D53/565 , B01D53/75 , B01D53/8628 , B01D53/9418 , B01D53/944 , B01D53/9477 , B01D2251/2062 , B01D2255/102 , B01D2255/1021 , B01D2255/2061 , B01D2255/20707 , B01D2255/20715 , B01D2255/20761 , B01D2255/30 , B01D2255/50 , B01D2258/012 , B01D2258/018 , B01D2258/0233 , B01D2258/0241 , B01D2258/025 , B01D2258/0283 , B01D2258/0291 , B01J21/04 , B01J21/063 , B01J21/066 , B01J21/12 , B01J23/42 , B01J23/63 , B01J29/072 , B01J29/763 , B01J35/0006 , B01J35/04 , B01J37/0201 , B01J37/0215 , B01J37/0246 , B01J2229/186 , B01J2229/42 , B01J2523/00 , F01N3/0842 , F01N3/085 , F01N3/105 , F01N2610/02 , Y02C20/10 , Y02E20/14 , B01J2523/36 , B01J2523/41 , B01J2523/48 , B01J2523/828
摘要: A method of selectively catalysing the reduction of oxides of nitrogen (NOx) including nitrogen monoxide in an exhaust gas of a stationary source of NOx emissions also containing oxides of sulfur (SOx) comprising the steps of passively oxidising nitrogen monoxide to nitrogen dioxide (NO2) over an oxidation catalyst comprising a platinum group metal so that a NO2/NOx content is from 40-60%; introducing a nitrogenous reductant into the exhaust gas; and contacting exhaust gas having the 40-60% NO2/NOx content and containing the nitrogenous reductant with a selective catalytic reduction (SCR) catalyst comprising an aluminosilicate zeolite promoted with copper.
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公开(公告)号:US20150352492A1
公开(公告)日:2015-12-10
申请号:US14726924
申请日:2015-06-01
发明人: Paul Joseph ANDERSEN , Kevin DOURA
IPC分类号: B01D53/86 , B01J23/10 , B01J37/08 , B01J23/889 , B01J29/72 , B01J37/02 , B01J35/00 , B01J21/04
CPC分类号: B01D53/8634 , B01D53/9436 , B01D2255/2065 , B01D2255/20715 , B01D2255/2073 , B01D2255/20738 , B01D2255/20761 , B01D2255/2092 , B01D2255/407 , B01D2255/502 , B01D2255/65 , B01D2255/9022 , B01D2255/9032 , B01D2257/406 , B01J21/04 , B01J23/10 , B01J23/83 , B01J23/8892 , B01J29/14 , B01J29/24 , B01J29/46 , B01J29/68 , B01J29/7215 , B01J29/7615 , B01J29/763 , B01J29/85 , B01J35/0006 , B01J35/023 , B01J37/0036 , B01J37/0244 , B01J37/0246 , B01J37/038 , B01J37/08
摘要: An ammonia slip catalyst having an SCR catalyst and an oxidation catalyst comprising at least two metals, each of which is selected from a specific group, and a substrate upon which at least oxidation catalyst is located is described. The ammonia slip catalyst can have dual layers, with one of the layers containing an SCR catalyst, a second layer containing the oxidation catalyst with comprises at least two metals, each of which is selected from a specific group, and the ammonia slip catalyst does not contain a platinum group metal. Methods of making and using the ammonia slip catalyst to reduce ammonia slip are described.
摘要翻译: 描述了具有SCR催化剂和氧化催化剂的氨滑动催化剂,其包含至少两种选自特定基团的金属和至少氧化催化剂所在的基材。 氨滑动催化剂可以具有双层,其中一层包含SCR催化剂,含有氧化催化剂的第二层包含至少两种金属,每种金属选自特定基团,氨滑移催化剂不 含有铂族金属。 描述了制造和使用氨滑移催化剂以减少氨滑移的方法。
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公开(公告)号:US20230074001A1
公开(公告)日:2023-03-09
申请号:US17820012
申请日:2022-08-16
发明人: Silvia ALCOVE CLAVE , Kevin DOURA , Joseph FEDEYKO
IPC分类号: B01J23/00 , F24F8/167 , F24F8/95 , B01J21/02 , B01J23/72 , B01J23/83 , B01J23/78 , B01J23/889 , B01D53/86
摘要: The present invention relates to a method for the treatment of an exhaust gas comprising carbon monoxide (CO) and/or one or more volatile organic compounds (VOCs) using a PGM-free catalyst article comprising a mixed oxide of Mn, Cu, Mg, Al and La. The present invention also relates to an HVAC system comprising a PGM-free catalyst article.
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9.
公开(公告)号:US20180078926A1
公开(公告)日:2018-03-22
申请号:US15712271
申请日:2017-09-22
发明人: Hai-Ying CHEN , Kevin DOURA , Joseph FEDEYTKO , Janet FISHER , John KILMARTIN
CPC分类号: B01J23/8926 , B01D53/9418 , B01D53/9436 , B01D53/944 , B01D2251/2062 , B01D2255/1021 , B01D2255/1026 , B01D2255/20715 , B01D2255/20761 , B01D2255/2092 , B01D2255/9022 , B01D2255/9032 , B01D2255/904 , B01J21/04 , B01J21/063 , B01J21/08 , B01J21/12 , B01J23/42 , B01J23/462 , B01J23/72 , B01J23/745 , B01J35/0006 , F01N3/103 , F01N3/106 , F01N3/2066 , F01N3/2086 , F01N3/28 , F01N2510/06 , F01N2510/068 , F01N2510/0682 , F01N2510/0684 , F01N2570/145 , F01N2570/18 , F01N2610/02 , Y02A50/2325 , Y02A50/2344 , Y02C20/10
摘要: An ammonia slip catalyst (ASC) comprising a first SCR catalyst, an oxidation catalyst comprising ruthenium or a Ru mixture, such as a Pt and Ru mixture, on a support comprising a rutile phase and a substrate is described. In some configurations, the ASC comprises a second oxidation catalyst. In other configurations, the ASC comprises a second oxidation catalyst and a third oxidation catalyst. The ASC's are useful for selective catalytic reduction (SCR) of NOx in exhaust gases and in reducing the amount of ammonia slip. Methods for producing such articles are described. Methods of using the ammonia slip catalyst in an SCR process, where the amount of ammonia slip is reduced, are also described.
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公开(公告)号:US20180078900A1
公开(公告)日:2018-03-22
申请号:US15712178
申请日:2017-09-22
发明人: Paul ANDERSEN , Hai-Ying CHEN , Kevin DOURA , Joseph FEDEYKO , John KILMARTIN
CPC分类号: B01D53/9427 , B01D53/9418 , B01D53/944 , B01D53/9459 , B01D2255/1021 , B01D2255/1026 , B01D2255/2065 , B01D2255/20707 , B01D2255/20715 , B01D2255/2092 , B01D2255/30 , B01D2255/407 , B01D2255/9022 , B01D2255/9032 , B01D2255/915 , B01D2255/9155 , B01J21/04 , B01J21/063 , B01J21/066 , B01J21/08 , B01J23/42 , B01J23/462 , B01J35/0006 , B01J35/04 , B01J37/0201 , B01J37/0248 , F01N3/103 , F01N3/106 , F01N2370/02 , F01N2570/145 , Y02A50/2325 , Y02A50/2344 , Y02C20/10 , Y02T10/24
摘要: An oxidation catalyst is described for treating an exhaust gas produced by a diesel engine. The oxidation catalyst comprises a washcoat region disposed on a substrate, wherein the washcoat region comprises a mixture of: platinum (Pt) supported on a first support material; and ruthenium (Ru).
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