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公开(公告)号:US11541647B2
公开(公告)日:2023-01-03
申请号:US17054214
申请日:2019-04-25
Applicant: Toray Industries, Inc.
Inventor: Hirohito Uchida , Takashi Isozaki , Yu Abe , Takashi Funatomi
Abstract: A white polyester film is described that includes at least a layer including, as a main component, a polyester resin (A), a thermoplastic resin (B) incompatible with the polyester resin (A), and an inorganic particle (C), where the white polyester film achieves high reflectance and a concealing property without increasing the thickness of the reflective film, the layer including voids in which the thermoplastic resin (B) functions as nuclei, wherein in a vertical section of the white film, NB2/NB1×100 (%) is 15% or more, wherein NB1 represents the number of the nuclei of the thermoplastic resin (B), and NB2 represents the number of the sections of the thermoplastic resin (B), the sections including the inorganic particle (C) inside.
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公开(公告)号:US20150072140A1
公开(公告)日:2015-03-12
申请号:US14389144
申请日:2013-02-07
Applicant: TORAY INDUSTRIES, INC.
Inventor: Kazuyoshi Ota , Yu Abe , Yasushi Takada
CPC classification number: B32B27/16 , B32B27/08 , B32B27/26 , B32B27/308 , B32B27/36 , B32B37/182 , B32B38/0008 , B32B38/0012 , B32B2037/243 , B32B2038/0028 , B32B2250/02 , B32B2250/24 , B32B2255/10 , B32B2307/4026 , B32B2307/412 , B32B2307/516 , B32B2307/518 , B32B2307/536 , B32B2307/584 , B32B2307/732 , B32B2309/02 , B32B2367/00 , B32B2457/20 , B32B2457/208 , Y10T428/269
Abstract: Provided is a multilayer film, in which a resin layer obtained using a resin (α) is provided on at least one surface of a polyester film, and which satisfies the conditions (I)-(IV) described below. (I) The resin layer has a thickness of 80-500 nm. (II) The resin layer has a pencil hardness of F or higher. (III) The multilayer film has a haze of 3.0% or less. (IV) The resin (α) is a resin that is obtained by heating a resin composition, which contains a resin (A) that has a hydroxyl group and an acryloyl group and a melamine compound (B) that has a methylol group, at 150° C. or higher. This multilayer film has a transparent resin layer that has a predominantly thin thickness of 500 nm or less, while having high hardness and excellent oligomer precipitation inhibiting properties.
Abstract translation: 提供一种多层膜,其中在聚酯膜的至少一个表面上提供使用树脂(α)获得的树脂层,并满足下述条件(I) - (IV)。 (I)树脂层的厚度为80〜500nm。 (II)树脂层的铅笔硬度为F以上。 (III)多层膜的雾度为3.0%以下。 (Ⅳ)树脂(α)是将含有羟基和丙烯酰基的树脂(A)和具有羟甲基的三聚氰胺化合物(B))的树脂组合物加热得到的树脂 150℃以上。 该多层膜具有主要薄膜厚度为500nm以下的透明树脂层,同时具有高硬度和优异的低聚物沉淀抑制性能。
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公开(公告)号:US11851542B2
公开(公告)日:2023-12-26
申请号:US17259430
申请日:2019-07-01
Applicant: Toray Industries, Inc.
Inventor: Haruki Aono , Tadahiko Iwaya , Keiko Sawamoto , Yu Abe
CPC classification number: C08J7/0427 , B05D3/12 , B05D5/08 , B05D7/04 , C09D5/20 , B05D2201/04 , B05D2502/00 , B05D2503/00 , B05D2504/00 , C08J2367/00 , C08J2433/08 , C08J2463/00 , C08J2475/06
Abstract: A laminated film has a resin layer on at least one surface of a polyester film, in which the resin layer is on at least one surface layer, the water contact angle of the resin layer is 85°-100°, inclusive, and |H2-H1|≤1.0 (%) is satisfied, H1 (%) being the haze of the laminated film and H2 (%) being the haze of the laminated film after being immersed in a solvent and subjected to a rub test. This laminated film has excellent coating and releasability properties with respect to ceramic slurry.
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公开(公告)号:US20210277197A1
公开(公告)日:2021-09-09
申请号:US17259430
申请日:2019-07-01
Applicant: Toray Industries, Inc.
Inventor: Haruki Aono , Tadahiko Iwaya , Keiko Sawamoto , Yu Abe
Abstract: A laminated film has a resin layer on at least one surface of a polyester film, in which the resin layer is on at least one surface layer, the water contact angle of the resin layer is 85°-100°, inclusive, and |H2−H1|≤1.0 (%) is satisfied, H1 (%) being the haze of the laminated film and H2 (%) being the haze of the laminated film after being immersed in a solvent and subjected to a rub test. This laminated film has excellent coating and releasability properties with respect to ceramic slurry.
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公开(公告)号:US20150191621A1
公开(公告)日:2015-07-09
申请号:US14408897
申请日:2013-06-19
Applicant: TORAY INDUSTRIES, INC.
Inventor: Yu Abe , Masami Ogata , Yasushi Takada
IPC: C09D133/26
CPC classification number: C09D133/26 , B32B27/36 , C08F2220/343 , C08G18/6229 , C08G18/6254 , C08G18/706 , C08J7/042 , C08J2367/02 , C08J2467/02 , C08J2475/14 , C09D175/04 , G02B1/105 , G02B1/14 , Y10T428/31533 , Y10T428/31565 , C08F220/14 , C08F2220/1808 , C08F220/58
Abstract: The purpose of the present invention is to provide a laminated polyester film which has excellent translucency and excellent suppression of an iris-like pattern (interference fringe), i.e., excellent visibility, when a hard coat layer is laminated; has excellent initial adhesion to the hard coat layer, adhesiveness at high temperatures and high humidity (wet heat-resistant adhesion), and UV-resistant adhesion (adhesion after UV irradiation); and has excellent adhesion when immersed in boiling water (boiling-resistant adhesion) and boiling-resistant translucency. This objective is achieved by a laminated polyester film having a resin layer (X) on at least one surface of a polyester film, wherein the resin layer (X) is formed from a coating composition comprising an acrylic/urethane copolymer resin (a) and a polyester resin (b) having a naphthalene backbone, and the film haze change amount (ΔHz) before and after a boiling treatment test (ΔHz=the film haze after the boiling treatment test−the film haze before the boiling treatment test) is less than 3.0%.
Abstract translation: 本发明的目的是提供一种叠层聚酯薄膜,当层压硬涂层时,其具有优异的半透明度和优异的抑制虹膜状图案(干涉条纹),即优异的可视性; 对硬涂层具有优异的初始粘合性,在高温和高湿度下的粘合性(耐湿热粘合性)和耐UV粘合性(UV照射后的粘合性); 并且当浸入沸水(耐沸腾粘附)和耐沸石半透明度时具有优异的附着力。 该目的通过在聚酯膜的至少一个表面上具有树脂层(X)的层压聚酯膜来实现,其中树脂层(X)由包含丙烯酸/氨基甲酸酯共聚物树脂(a)和 具有萘主链的聚酯树脂(b)和沸腾处理试验前后的膜雾度变化量(&Dgr; Hz)(&Dgr; Hz =沸腾处理试验后的膜雾度 - 沸腾处理前的膜雾度 测试)小于3.0%。
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公开(公告)号:US20150086777A1
公开(公告)日:2015-03-26
申请号:US14384063
申请日:2013-03-07
Applicant: TORAY Industries, Inc.
Inventor: Yu Abe , Masami Ogata , Yasushi Takada
IPC: C09D133/10 , B29D7/01
CPC classification number: C09D133/10 , B05D3/02 , B05D7/04 , B05D7/26 , B05D2201/02 , B05D2502/00 , B05D2508/00 , B29D7/01 , B29K2033/00 , B29K2033/04 , B29K2033/08 , B29K2033/12 , B29K2067/00 , B29K2105/0005 , B29K2105/256 , B29K2995/0051 , B32B27/08 , B32B27/20 , B32B27/30 , B32B27/308 , B32B27/36 , B32B2038/0028 , B32B2250/02 , B32B2250/24 , B32B2264/10 , B32B2264/102 , B32B2333/08 , B32B2333/12 , B32B2367/00 , B32B2457/202 , B32B2457/206 , B32B2457/208 , C08F220/18 , C08K3/013 , C08K5/0025 , C08K5/3415 , C08K5/34922 , C08K5/353 , C08K2003/2237 , C08K2003/2241 , C08K2003/2244 , C09D133/02 , C09D133/04 , C09D133/062 , C09D133/066 , C09D133/08 , C09D133/12 , C09D133/14 , C09D161/28 , C09D167/00 , C09D167/02 , C09D167/03 , Y10T428/265 , Y10T428/269 , Y10T428/31797 , Y10T428/31935 , C08F2220/1891 , C08F2220/1875 , C08F220/20
Abstract: The present invention provides a laminated film comprising a polyester film having a resin layer on at least one side thereof, wherein said resin layer contains at least metal oxide particles (A) having a number average particle diameter of 3 nm or more and 50 nm or less, and an acrylic resin (B), and a component (C1) derived from an oxazoline-based compound and/or a component (C2) derived from a melamine-based compound, and wherein said acrylic resin (B) contains a monomer unit (b1), a monomer unit (b2) and a monomer unit (b3).The present invention provides a laminated film which is excellent in transparency, suppression of interference pattern upon lamination of a high refractive index hard coat layer, adhesive property to a high refractive index hard coat layer, and adhesion under high temperature and high humidity conditions (adhesion under high temperature and high humidity conditions), at a low cost.
Abstract translation: 本发明提供一种层叠膜,其具有在至少一面具有树脂层的聚酯膜,其中,所述树脂层至少含有数均粒径为3nm以上且50nm以下的金属氧化物粒子(A),或 较少的丙烯酸类树脂(B)和衍生自恶唑啉系化合物的成分(C1)和/或由三聚氰胺类化合物衍生的成分(C2),其中所述丙烯酸树脂(B)含有单体 单体(b1),单体单元(b2)和单体单元(b3)。 本发明提供一种透明性优异的抑制,高折射率硬涂层层压时的干涉图案的抑制,高折射率硬涂层的粘合性,以及高温高湿条件下的粘合性(粘接性 在高温高湿条件下),成本低。
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公开(公告)号:US20210060914A1
公开(公告)日:2021-03-04
申请号:US17054214
申请日:2019-04-25
Applicant: Toray Industries, Inc.
Inventor: Hirohito Uchida , Takashi Isozaki , Yu Abe , Takashi Funatomi
Abstract: A white polyester film is described that includes at least a layer including, as a main component, a polyester resin (A), a thermoplastic resin (B) incompatible with the polyester resin (A), and an inorganic particle (C), where the white polyester film achieves high reflectance and a concealing property without increasing the thickness of the reflective film, the layer including voids in which the thermoplastic resin (B) functions as nuclei, wherein in a vertical section of the white film, NB2/NB1×100 (%) is 15% or more, wherein NB1 represents the number of the nuclei of the thermoplastic resin (B), and NB2 represents the number of the sections of the thermoplastic resin (B), the sections including the inorganic particle (C) inside.
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公开(公告)号:US09604435B2
公开(公告)日:2017-03-28
申请号:US14389144
申请日:2013-02-07
Applicant: TORAY INDUSTRIES, INC.
Inventor: Kazuyoshi Ota , Yu Abe , Yasushi Takada
CPC classification number: B32B27/16 , B32B27/08 , B32B27/26 , B32B27/308 , B32B27/36 , B32B37/182 , B32B38/0008 , B32B38/0012 , B32B2037/243 , B32B2038/0028 , B32B2250/02 , B32B2250/24 , B32B2255/10 , B32B2307/4026 , B32B2307/412 , B32B2307/516 , B32B2307/518 , B32B2307/536 , B32B2307/584 , B32B2307/732 , B32B2309/02 , B32B2367/00 , B32B2457/20 , B32B2457/208 , Y10T428/269
Abstract: Provided is a multilayer film, in which a resin layer obtained using a resin (α) is provided on at least one surface of a polyester film, and which satisfies the conditions (I)-(IV) described below. (I) The resin layer has a thickness of 80-500 nm. (II) The resin layer has a pencil hardness of F or higher. (III) The multilayer film has a haze of 3.0% or less. (IV) The resin (α) is a resin that is obtained by heating a resin composition, which contains a resin (A) that has a hydroxyl group and an acryloyl group and a melamine compound (B) that has a methylol group, at 150° C. or higher. This multilayer film has a transparent resin layer that has a predominantly thin thickness of 500 nm or less, while having high hardness and excellent oligomer precipitation inhibiting properties.
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公开(公告)号:US09771491B2
公开(公告)日:2017-09-26
申请号:US14384063
申请日:2013-03-07
Applicant: TORAY Industries, Inc.
Inventor: Yu Abe , Masami Ogata , Yasushi Takada
IPC: B32B27/08 , B32B27/20 , B32B27/30 , B32B27/36 , B29D7/01 , B05D3/02 , B05D7/04 , B05D7/26 , C08K3/02 , C08K5/3415 , C08K5/3492 , C08K5/353 , C09D133/02 , C09D133/04 , C09D133/08 , C09D133/10 , C09D133/12 , C09D133/14 , C09D167/00 , C09D167/02 , C09D167/03 , C08F220/18 , C09D161/28 , B32B38/00 , B29K33/00 , B29K33/04 , C09D133/06 , C08K3/22 , C08K3/00 , C08K5/00 , B29K67/00 , B29K105/00
CPC classification number: C09D133/10 , B05D3/02 , B05D7/04 , B05D7/26 , B05D2201/02 , B05D2502/00 , B05D2508/00 , B29D7/01 , B29K2033/00 , B29K2033/04 , B29K2033/08 , B29K2033/12 , B29K2067/00 , B29K2105/0005 , B29K2105/256 , B29K2995/0051 , B32B27/08 , B32B27/20 , B32B27/30 , B32B27/308 , B32B27/36 , B32B2038/0028 , B32B2250/02 , B32B2250/24 , B32B2264/10 , B32B2264/102 , B32B2333/08 , B32B2333/12 , B32B2367/00 , B32B2457/202 , B32B2457/206 , B32B2457/208 , C08F220/18 , C08K3/013 , C08K5/0025 , C08K5/3415 , C08K5/34922 , C08K5/353 , C08K2003/2237 , C08K2003/2241 , C08K2003/2244 , C09D133/02 , C09D133/04 , C09D133/062 , C09D133/066 , C09D133/08 , C09D133/12 , C09D133/14 , C09D161/28 , C09D167/00 , C09D167/02 , C09D167/03 , Y10T428/265 , Y10T428/269 , Y10T428/31797 , Y10T428/31935 , C08F2220/1891 , C08F2220/1875 , C08F220/20
Abstract: The present invention provides a laminated film comprising a polyester film having a resin layer on at least one side thereof, wherein said resin layer contains at least metal oxide particles (A) having a number average particle diameter of 3 nm or more and 50 nm or less, and an acrylic resin (B), and a component (C1) derived from an oxazoline-based compound and/or a component (C2) derived from a melamine-based compound, and wherein said acrylic resin (B) contains a monomer unit (b1), a monomer unit (b2) and a monomer unit (b3). The present invention provides a laminated film which is excellent in transparency, suppression of interference pattern upon lamination of a high refractive index hard coat layer, adhesive property to a high refractive index hard coat layer, and adhesion under high temperature and high humidity conditions (adhesion under high temperature and high humidity conditions), at a low cost.
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