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    Process for the catalytic oxidation of aromatic compounds
    2.
    发明授权
    Process for the catalytic oxidation of aromatic compounds 失效
    芳香族化合物的催化氧化方法

    公开(公告)号：US5616734A

    公开(公告)日：1997-04-01

    申请号：US378231

    申请日：1995-01-25

    申请人： Wolfgang A. Herrmann ,  Joao D. G. Correia ,  Richard Fischer ,  Waldemar Adam ,  Jianhua Lin ,  Chantu R. Saha-Moller ,  Masao Shimizu

    发明人： Wolfgang A. Herrmann ,  Joao D. G. Correia ,  Richard Fischer ,  Waldemar Adam ,  Jianhua Lin ,  Chantu R. Saha-Moller ,  Masao Shimizu

    IPC分类号： B01J31/12 ,  C07B61/00 ,  C07C27/00 ,  C07C37/60 ,  C07C39/07 ,  C07C39/225 ,  C07C46/04 ,  C07C46/06 ,  C07C50/02 ,  C07C50/10 ,  C07C50/28 ,  C07C51/285 ,  C07C63/331 ,  C07D311/74 ,  C07C50/04

    CPC分类号： C07C46/04 ,  C07C37/60 ,  C07C46/06 ,  C07C50/10

    摘要： The invention relates to the use of compounds of the formula IR.sup.1.sub.a Re.sub.b O.sub.c (I),where a is from 1 to 6, b is from 1 to 4 and c is from 1 to 14 and the sum of a, b and c is in accordance with the valence of from 5 to 7 of the rhenium, with the proviso that c is not greater than 3.multidot.b, and where R.sup.1 is identical or different and is an aliphatic hydrocarbon radical having from 1 to 10 carbon atoms, an aromatic hydrocarbon radical having from 6 to 10 carbon atoms or an arylalkyl radical having from 7 to 9 carbon atoms, with the radicals R.sup.1 being able, if desired, to be identically or differently substituted independently of one another and, in the case of .sigma.-bonded radicals, at least one hydrogen atom still being bonded to the carbon atom in the .alpha. position, as catalysts for the oxidation of electron-rich aromatic compounds and their derivatives and to a process for the oxidation of electron-rich aromatic compounds which comprises oxidizing electron-rich C.sub.6 -C.sub.22 -aryl compounds and their derivatives in the presence of a catalyst of the formula I and a peroxide-containing compound.

    摘要翻译： 本发明涉及式Ⅰ化合物R1aRebOc（Ⅰ）的用途，其中a为1至6，b为1至4，c为1至14，a，b和c的和为 铼的价数为5至7，条件是c不大于3xb，并且其中R1相同或不同，是具有1至10个碳原子的脂族烃基，具有从 6至10个碳原子或具有7至9个碳原子的芳基烷基，如果需要，基团R1能够彼此相同或不同地取代，并且在σ-键合基团的情况下，至少 一个氢原子仍然与α位上的碳原子键合，作为用于氧化富含电子的芳族化合物及其衍生物的催化剂，以及氧化富含电子的芳族化合物的方法，其包括将富含电子的C6- C22-芳基化合物及其衍生物 在式I催化剂和含过氧化物的化合物存在下进行。

    Use of organorhenium compounds for the oxidation of multiple C--C-bonds, oxidation processes based theron and novel organorhenium compounds
    3.
    发明授权
    Use of organorhenium compounds for the oxidation of multiple C--C-bonds, oxidation processes based theron and novel organorhenium compounds 失效
    用于多种C-C氧化物氧化的有机化合物的使用，基于其和新型有机化合物的氧化方法

    公开(公告)号：US5155247A

    公开(公告)日：1992-10-13

    申请号：US470086

    申请日：1990-01-25

    申请人： Wolfgang A. Herrmann ,  Dieter M. Fritz-Meyer-Weg ,  Werner Wagner ,  Josef G. Kuchler ,  Georg Weichselbaumer ,  Richard Fischer

    发明人： Wolfgang A. Herrmann ,  Dieter M. Fritz-Meyer-Weg ,  Werner Wagner ,  Josef G. Kuchler ,  Georg Weichselbaumer ,  Richard Fischer

    IPC分类号： B01J31/16 ,  B01J31/18 ,  B01J31/22 ,  C07B61/00 ,  C07C27/00 ,  C07C29/48 ,  C07C31/20 ,  C07C35/14 ,  C07C45/28 ,  C07C67/31 ,  C07C69/675 ,  C07D301/12 ,  C07D303/04 ,  C07D303/08 ,  C07D303/32 ,  C07D303/42 ,  C07D303/48 ,  C07F13/00

    CPC分类号： C07F13/00 ,  B01J31/1658 ,  B01J31/1805 ,  B01J31/181 ,  C07C29/48 ,  C07C45/28 ,  C07C67/31 ,  C07D301/12 ,  C07D303/04 ,  C07D303/08 ,  C07D303/32 ,  C07D303/42 ,  C07D303/48 ,  B01J2231/72 ,  B01J2531/74 ,  C07C2101/14

    摘要： Compounds of the formula(R.sup.11 Re).sub.k O.sub.1 R.sup.12 .sub.m .multidot.L.sub.n (III)in whichR.sup.11 is a hydrocarbon group which is bonded to the rhenium via a carbon atom to which at least one hydrogen atom is still attached,R.sup.12 is aliphatic hydrocarbon radical which may contain silicon bridge atoms, or is an unsubstituted or substituted phenyl radical,L is a ligand which is bonded to the rhenium metal via one to three oxygen and/or nitrogen atoms, and theindex k is 1 or 2, the index 1 is an integer from 1 to three times k, the index m is zero or an integer from 1 to twice k, and the index n is an integer from 1 to three times k, and in which the indices k, l, m and n are selected such that their combination satisfies the 5-, 6- or 7-valence of rhenium.The invention also provides compounds of the formula(polymer).sub.f .multidot.(CH.sub.3 ReO.sub.3).sub.8 (VI)in which the rhenium compound CH.sub.3 ReO.sub.3 is bonded to the polymer via amine or amide nitrogen in the polymer. It further provides for the use of compounds of the formula R.sup.1.sub.a Re.sub.b O.sub.c (I) in which a is 1 to 6, b is 1 to 4 and c is 1 to 14 and the total of a, b and c is such that the 5-valence to 7-valence of rhenium is satisfied, with the proviso that c is not greater than three times b, and in which R.sup.1 represents an optionally fluorinated hydrocarbon, or of compounds of the formula (R.sup.11 Re).sub.k O.sub.l R.sup.12.sub.m .multidot.L.sub.n (III) or (polymer).sub.f .multidot.(CH.sub.3 ReO.sub.3).sub.g (VI), as catalysts for the oxidation of multiple C--C bonds and also provides processes of this type.

    摘要翻译： 其中R 11是通过至少一个氢原子连接的碳原子与铼键合的烃基的式（R 11 Re）kO 1 R 12 mxLn（III）的化合物，R 12是可以含有硅桥的脂族烃基 原子，或是未取代或取代的苯基，L是通过1-3个氧和/或氮原子与铼金属键合的配体，并且指数k为1或2，指数1为1的整数 到三次k，索引m为零或1至2k的整数，索引n为1至3倍k的整数，并且其中索引k，l，m和n被选择为使得它们 组合满足铼的5-，6-或7-价。 本发明还提供了通过聚合物中的胺或酰胺氮将铼化合物CH 3 ReO 3与聚合物结合的式（聚合物）fx（CH 3 ReO 3）8（VI）的化合物。 它进一步提供了使用式为R1aRebOc（Ⅰ）的化合物，其中a为1至6，b为1至4，c为1至14，a，b和c的总和为5价 满足铼的7价，条件是c不大于3倍，其中R1表示任意氟化的烃，或式（R11Re）kOlR12mxLn（Ⅲ）或（聚合物）fx的化合物 （CH3ReO3）g（VI）作为多个CC键氧化的催化剂，也提供了这种类型的工艺。

    Reactivation of water-soluble hydroformylation catalysts
    4.
    发明授权
    Reactivation of water-soluble hydroformylation catalysts 失效
    水溶性加氢甲酰化催化剂的再活化

    公开(公告)号：US5466644A

    公开(公告)日：1995-11-14

    申请号：US378861

    申请日：1995-01-19

    申请人： Werner Konkol ,  Helmut Bahrmann ,  Wolfgang A. Herrmann ,  Christian Kohlpaintner

    发明人： Werner Konkol ,  Helmut Bahrmann ,  Wolfgang A. Herrmann ,  Christian Kohlpaintner

    IPC分类号： B01J27/185 ,  B01J27/28 ,  B01J31/24 ,  B01J31/40 ,  B01J38/48 ,  C07B61/00 ,  C07C27/20 ,  C07C27/22 ,  C07C45/50 ,  C07C45/85 ,  C07C47/02 ,  B01J38/62

    CPC分类号： B01J31/4046 ,  B01J31/20 ,  B01J31/2404 ,  B01J31/2447 ,  C07C45/50 ,  C07C45/85 ,  B01J2231/321 ,  B01J2531/822 ,  B01J2531/96 ,  Y02P20/584

    摘要： A process for regenerating a water-soluble hydroformylation catalyst system comprising a coupler rhodium hydrogen-carbonyl complex of rhodium and compounds of the formula ##STR1## wherein Ar.sup.1 and Ar.sup.2 and Ar.sup.3 are individually phenyl or naphthyl, Y.sup.1, Y.sup.2 and Y.sup.3 are individually selected from the group consisting of alkyl and alkoxy of 1 to 4 carbon atoms, halogen, --OH, --CN, --NO.sub.2 and R.sup.1 R.sup.2 N--, R.sup.1 and R.sup.2 are individually alkyl of 1 to 4 carbon atoms, X.sup.1, X.sup.2 and X.sup.3 are individually carboxylate (--COO.sup.-) or sulfonate (--SO.sub.3.sup.-), m.sub.1, m.sub.2 and m.sub.3 are individually integers of 0 to 3, at least one of m.sub.1, m.sub.2 or m.sub.3 being equal to or greater than 1, and n.sub.1, n.sub.2 and n.sub.3 are individually integers of 0 to 5 and if appropriate in excess comprising adding maleic acid, fumaric acid or olefinically unsaturated compounds of formula ##STR2## wherein X is selected from the group consisting of O, S, -- ##STR3## or ##STR4## and R.sup.3, R.sup.4 and R.sup.5 are individually hydrogen, or alkyl or aryl to an aqueous solution of the catalyst system in an amount sufficient to remove sulfonated or carboxylated alkyl-arylphosphanes.

    摘要翻译： 一种再生水溶性加氢甲酰化催化剂体系的方法，其包含铑的偶合铑氢 - 羰基络合物和其中Ar1和Ar2和Ar3各自独立地为苯基或萘基，Y1，Y2和Y3的式I化合物的化合物， 由1-4个碳原子的烷基和烷氧基组成的组，卤素，-OH，-CN，-NO 2和R 1 R 2 N - ，R 1和R 2分别是1至4个碳原子的烷基，X 1，X 2和X 3分别是羧酸酯 （-COO-）或磺酸盐（-SO3-），m1，m2和m3分别为0-3的整数，m1，m2或m3中的至少一个等于或大于1，n1，n2和n3分别为 单独的整数为0至5，如果适当，过量包括加入马来酸，富马酸或烯属不饱和的式II化合物，其中X选自O，S， - IMAGE或IMAGE，和 R3，R4和R5分别是氢，或烷基或芳基与催化剂的水溶液 t系统，其量足以除去磺化或羧化的烷基 - 芳基磷烷。

    Ruthenium complexes, process for preparation thereof, and processes for producing open-ring polymer of cycloolefins and hydrogenation products thereof by using the complex as catalyst
    5.
    发明授权
    Ruthenium complexes, process for preparation thereof, and processes for producing open-ring polymer of cycloolefins and hydrogenation products thereof by using the complex as catalyst 失效
    钌络合物，其制备方法以及通过使用络合物作为催化剂制备环烯烃的开环聚合物及其氢化产物的方法

    公开(公告)号：US07084222B2

    公开(公告)日：2006-08-01

    申请号：US10489921

    申请日：2002-09-19

    申请人： Masato Sakamoto ,  Seiji Okada ,  Yasuo Tsunogae ,  Shintaro Ikeda ,  Wolfgang A. Herrmann ,  Karl Oefele

    发明人： Masato Sakamoto ,  Seiji Okada ,  Yasuo Tsunogae ,  Shintaro Ikeda ,  Wolfgang A. Herrmann ,  Karl Oefele

    IPC分类号： C08F4/80 ,  C07F15/00

    CPC分类号： C07D239/04 ,  C07D233/02 ,  C07F15/0046 ,  C08G61/08

    摘要： The present invention relates to ruthenium complex compound wherein a heteroatom-containing carbene compound having a six-membered ring structure is bonded to ruthenium and a process for the preparation thereof; a process for producing ring-opened cyclic olefin polymer by subjecting a cyclic olefin to ring-opening metathesis polymerization in the presence of such a ruthenium complex compound; and a process for producing hydrogenated product of ring-opened cyclic olefin polymers by hydrogenating the carbon-carbon double bonds of the above ring-opened polymers. The invention gives hydrogenated product of ring-opened cyclic olefin polymers having physical properties different from those of hydrogenated product of ring-opened polymers of the prior art. Particularly, the use of dicyclopentadiene can give a hydrogenated product of ring-opened cyclic olefin polymer excellent in heat resistance, and this product can be advantageously used as parts or formed products for medical appliances or electrical components.

    摘要翻译： 本发明涉及具有六元环结构的含杂原子的卡宾化合物与钌结合的钌络合物及其制备方法， 在这种钌络合物的存在下，通过使环状烯烃进行开环易位聚合来制造开环式环烯烃聚合物的方法; 以及通过氢化上述开环聚合物的碳 - 碳双键来制备开环环烯烃聚合物的氢化产物的方法。 本发明提供了具有与现有技术的开环聚合物的氢化产物不同的物理性质的开环环烯烃聚合物的氢化产物。 特别地，二环戊二烯的使用可以得到耐热性优异的开环式环状烯烃聚合物的氢化物，该产品可有利地用作医疗器具或电子部件的部件或成形品。

    Complexes of lanthanides with heterocyclic carbenes
    10.
    发明授权
    Complexes of lanthanides with heterocyclic carbenes 失效
    镧系元素与杂环碳烯的络合物

    公开(公告)号：US5705619A

    公开(公告)日：1998-01-06

    申请号：US581398

    申请日：1995-12-29

    申请人： Wolfgang A. Herrmann

    发明人： Wolfgang A. Herrmann

    IPC分类号： C07C45/46 ,  C07F5/00 ,  C07F7/10

    CPC分类号： C07F5/00 ,  C07C45/46

    摘要： A complex of the formula �L.sub.a Ln.sub.b X.sub.c !.sup.n (A).sub.n wherein Ln is an ion in the oxidation state of 2, 3 or 4 of the lanthanide elements having the atomic numbers 21, 39 and from 57 to 71 in the Periodic Table of the Elements, with the exception of europium and promethium, as central atom, X.sup.(S) are monodentate or multidentate, charged or uncharged ligands bound to the central atom and L is a monocarbene or dicarbene ligand likewise bound to the central atom and which are derived from imidazole and/or pyrazole, A is a singly charged anion or the chemical equivalent of a multiple charged anion, b is an integer from 1 to 4, a is an integer from 1 to 4 . b and c is zero or an integer from 1 to 4.b and n is zero or an integer from 1 to 3.b having catalytic activity.

    摘要翻译： 式[LaLnbXc] n（A）n的络合物，其中Ln是氧化态的2,3或4族的镧系元素的离子，所述镧系元素在元素周期表中具有原子序数21,39和57至71 元素除了铕和ium之外，作为中心原子，X（S）是与中心原子结合的单齿或多齿，带电荷或不带电的配体，L是同样与中心原子结合的单碳烯或二烯属配体， A是单电荷阴离子或多电荷阴离子的化学等价物，b为1〜4的整数，a为1〜4的整数。 b和c为0或1至4.b的整数，n为0或具有催化活性的1至3b的整数。