Sn-based plated steel sheet
    2.
    发明授权

    公开(公告)号:US11859289B2

    公开(公告)日:2024-01-02

    申请号:US17772079

    申请日:2019-12-19

    摘要: To provide a Sn-based plated steel sheet excellent in yellowing resistance, coating film adhesiveness, and sulfurization blackening resistance without performing the conventional chromate treatment.
    A Sn-based plated steel sheet of the present invention includes: a steel sheet; a Sn-based plating layer located on at least one surface of the steel sheet; and a coating layer located on the Sn-based plating layer, wherein: the Sn-based plating layer contains 0.10 to 15.00 g/m2 of Sn per side in terms of metal Sn; the coating layer contains a Zr oxide and a Mn oxide; a content of the Zr oxide is 0.20 to 50.00 mg/m2 per side in terms of metal Zr; a content of the Mn oxide in terms of metal Mn is 0.01 to 0.50 times on a mass basis relative to the content of the Zr oxide in terms of metal Zr; and a depth position A where an element concentration of Mn is maximum is located on a side closer to a surface of the coating layer than a depth position B where an element concentration of Zr is maximum, and a distance in a depth direction between the depth position A and the depth position B is 2 nm or more in an element analysis in the depth direction by XPS.

    TREATED SUBSTRATES
    3.
    发明公开
    TREATED SUBSTRATES 审中-公开

    公开(公告)号:US20230203699A1

    公开(公告)日:2023-06-29

    申请号:US18169148

    申请日:2023-02-14

    摘要: Methods for treating a substrate are disclosed. The substrate is deoxidized and then immersed in an electrodepositable pretreatment composition comprising a lanthanide series element and/or a Group IIIB metal, an oxidizing agent, and a metal-complexing agent to deposit a coating from the electrodepositable pretreatment composition onto a surface of the substrate. Optionally, the electrodepositable pretreatment composition may comprise a surfactant. A coating from a spontaneously depositable pretreatment composition comprising a Group IIIB and/or Group IVB metal may be deposited on the substrate surface prior to electrodepositing a coating from the electrodepositable pretreatment composition. Following electrodeposition of the electrodepositable pretreatment composition, the substrate optionally may be contacted with a sealing composition comprising phosphate and a Group IIIB and/or IVB metal. Substrates treated according to the methods also are disclosed.

    METHOD OF PRODUCING SURFACE-TREATED STEEL SHEET AND SURFACE-TREATED STEEL SHEET

    公开(公告)号:US20220205124A1

    公开(公告)日:2022-06-30

    申请号:US17594502

    申请日:2020-02-18

    IPC分类号: C25D9/08 C25D9/06 C23C28/00

    摘要: A method of producing a surface-treated steel sheet, comprising: subjecting a steel sheet having a Sn coating or plating layer to an anodic electrolytic treatment in an alkaline aqueous solution to form a Sn oxide layer; and then subjecting the steel sheet to a cathodic electrolytic treatment in an aqueous solution containing zirconium ions to form a layer containing zirconium oxide, wherein the Sn coating or plating layer has a Sn coating weight of 0.1 g/m2 to 20.0 g/m2, the Sn oxide layer has, at a point in time when the Sn oxide layer is formed, a reduction current peak within a potential range of −800 mV to −600 mV and an electric quantity of a reduction current in the potential range of 1.5 mC/cm2 to 10.0 mC/cm2, and the layer containing zirconium oxide has a Zr coating weight of 0.1 mg/m2 to 50.0 mg/m2.

    BATHLESS METAL-COMPOSITE ELECTROPLATING
    8.
    发明申请

    公开(公告)号:US20200325589A1

    公开(公告)日:2020-10-15

    申请号:US16379237

    申请日:2019-04-09

    IPC分类号: C25D5/02 C25D9/02 C25D9/08

    摘要: A bathless method for plating a conductive material with composite particles or with high surface coverage. The setup for the bathless electro-plating includes a cathode, a composite mixture, a membrane, and an anode. The cathode is a conductive material. The composite mixture comprises a metal salt, an acid, and a composite material. The composite mixture is applied to the cathode. A hydrophilic membrane is applied to the composite mixture. An anode, with oxidizing properties, is applied to the membrane. A current is applied to the bathless setup. Upon removing the current and composite mixture from the cathode, a metal-based composite coating remains on the cathode.