METHOD FOR PRODUCING IONOMER-COATED, CATALYST-SUPPORTING CARBON NANOTUBES
    92.
    发明申请
    METHOD FOR PRODUCING IONOMER-COATED, CATALYST-SUPPORTING CARBON NANOTUBES 有权
    用于生产离子涂覆的催化支持碳纳米管的方法

    公开(公告)号:US20140322453A1

    公开(公告)日:2014-10-30

    申请号:US14354718

    申请日:2012-10-31

    发明人: Ryoichi Namba

    IPC分类号: C01B31/02

    摘要: Disclosed is a method for producing ionomer-coated, catalyst-supporting carbon nanotubes, the method comprising: a step of preparing catalyst-supporting carbon nanotubes on at least one surface of a substrate; a step of preparing a first ionomer solution; an ionomer coating step of bringing the catalyst-supporting carbon nanotubes into contact with the first ionomer solution and coating the catalyst-supporting carbon nanotubes with the ionomer; and a drying step of drying the ionomer-coated, catalyst-supporting carbon nanotubes, wherein the method comprises an ionomer removal step in which, when the ionomer that is unevenly attached in a thickness direction of a layer comprising the ionomer-coated, catalyst-supporting carbon nanotubes, the ionomer that is relatively largely found in and attached to the tip end of the carbon nanotubes rather than other parts thereof, is removed after the ionomer coating step and before the drying step.

    摘要翻译: 公开了一种用于生产离聚物涂覆的催化剂负载型碳纳米管的方法,该方法包括:在基材的至少一个表面上制备催化剂负载的碳纳米管的步骤; 制备第一离聚物溶液的步骤; 离子键体涂布步骤,使催化剂负载的碳纳米管与第一离聚物溶液接触并用离聚物涂布催化剂负载的碳纳米管; 以及干燥步骤,干燥所述离聚物涂覆的催化剂负载型碳纳米管,其中所述方法包括离聚物除去步骤,其中当所述离子交联聚合物沿着包含所述离聚物涂覆的催化剂涂覆的层的厚度方向不均匀地附着时, 支撑碳纳米管时,在离聚物涂布步骤之后和干燥步骤之前,除去相对大量发现并附着在碳纳米管的末端而不是其它部分的离聚物。

    METHOD OF PREPARING PRECIOUS METAL NITRIDE NANOPARTICLE COMPOSITIONS
    94.
    发明申请
    METHOD OF PREPARING PRECIOUS METAL NITRIDE NANOPARTICLE COMPOSITIONS 审中-公开
    制备优质金属氮化物纳米材料组合物的方法

    公开(公告)号:US20130210610A1

    公开(公告)日:2013-08-15

    申请号:US13372956

    申请日:2012-02-14

    摘要: A method of preparing a precious metal nitride nanoparticle composition, includes the step of ionizing nitrogen in the gas phase to create an active nitrogen species as a plasma. An atomic metal species of the precious metal is provided in the gas phase. The active nitrogen species in the gas phase is contacted with the atomic metal species of the precious metal in the gas phase to form a precious metal nitride. The precious metal nitride is deposited on the support. Precious metal nanoparticle compositions are also disclosed.

    摘要翻译: 制备贵金属氮化物纳米颗粒组合物的方法包括在气相中电离氮气以产生作为等离子体的活性氮物质的步骤。 在气相中提供贵金属的原子金属种类。 气相中的活性氮物质与气相中的贵金属的原子金属物质接触以形成贵金属氮化物。 贵金属氮化物沉积在载体上。 还公开了贵金属纳米颗粒组合物。

    Metal catalyst carriers and catalyst members made therefrom
    98.
    发明授权
    Metal catalyst carriers and catalyst members made therefrom 有权
    金属催化剂载体和由其制成的催化剂构件

    公开(公告)号:US08062990B2

    公开(公告)日:2011-11-22

    申请号:US10612658

    申请日:2003-07-02

    IPC分类号: B01J23/10 B01J23/26

    摘要: A pliable refractory metal carrier (46) may have coated thereon an anchor layer (47) to improve adherence to the carrier (46) of a catalytic coating (48). The conformable catalyst member (26, 82, 82′, 126, 226, 326) may be bent to conform to a curved or bent exhaust pipe (20, 220, 320) within which it is mounted. The pliable metal carrier may be in the form of a tube such as carrier (46) having perforations (54) formed therein, or it may be a metal strip (76) which is folded into accordion pleats (80) and has perforations (78) formed therein. The perforations (54, 78) serve to permit the passage of exhaust gas therethrough. A series of interior closures (58) and annular baffles (60) may be provided to import a serpentine flow path to gases flowed through an exhaust pipe (22) containing a conformable catalyst member (226) therein. A mounting member (68) may be supplied to fasten one end of the conformable catalyst member (226) to the discharge end of an exhaust pipe (220).

    摘要翻译: 柔性难熔金属载体(46)可以在其上涂覆有锚定层(47),以改善对催化涂层(48)的载体(46)的附着。 适配催化剂构件(26,82,82',126,226,326)可以被弯曲成符合安装在其中的弯曲或弯曲的排气管(20,220,320)。 柔性金属载体可以是管的形式,例如在其中形成有穿孔(54)的载体(46),或者它可以是折叠成折叠褶(80)并具有穿孔(78)的金属条(76) )。 穿孔(54,78)用于允许废气通过其中。 可以提供一系列内部封闭件(58)和环形挡板(60),以将蛇形流动路径导入通过其中包含适形催化剂构件(226)的排气管(22)流动的气体。 可以提供安装构件(68),以将适形催化剂构件(226)的一端固定到排气管(220)的排放端。

    STABILIZED PLATINUM CATALYST
    99.
    发明申请
    STABILIZED PLATINUM CATALYST 有权
    稳定的铂催化剂

    公开(公告)号:US20110143934A1

    公开(公告)日:2011-06-16

    申请号:US12867153

    申请日:2008-05-16

    摘要: A stabilized platinum nanoparticle has a core portion surrounded by a plurality of outer surfaces. The outer surfaces include terrace regions formed of platinum atoms, and edge and corner regions formed of atoms from a second metal. The stabilized nanoparticle may be formed by combining a platinum nanoparticle with a metal salt in a solution. Ions of the second metal react with platinum and replace platinum atoms on the nanoparticle. Platinum atoms from the edge and corner regions react with the second metal ions quicker than surface atoms from the terraces, due to a greater difference in electrode potential between the platinum atoms at the edge and corner regions, as compared to the second metal in the solution. The platinum nanoparticle may include surface defects, such as steps and kinks, which may also be replaced with atoms of the second metal. In an exemplary embodiment, the platinum nanoparticle is a cathode catalyst in an electro-chemical cell.

    摘要翻译: 稳定的铂纳米颗粒具有由多个外表面包围的芯部分。 外表面包括由铂原子形成的平台区域,以及由第二金属原子形成的边缘和拐角区域。 稳定的纳米颗粒可以通过将铂纳米颗粒与溶液中的金属盐组合而形成。 第二金属的离子与铂反应,并取代纳米颗粒上的铂原子。 由于与溶液中的第二金属相比,在边缘和拐角区域处的铂原子与边缘和角部区域上的铂原子之间的电极电位差异更大,所以来自边缘和角区域的铂原子与第二金属离子比来自梯田的表面原子更快地反应 。 铂纳米颗粒可以包括表面缺陷,例如步骤和扭结,其也可以被第二金属的原子替代。 在示例性实施方案中,铂纳米颗粒是电化学电池中的阴极催化剂。

    CARBON NANOTUBE AND METHOD FOR PRODUCING THE SAME
    100.
    发明申请
    CARBON NANOTUBE AND METHOD FOR PRODUCING THE SAME 审中-公开
    碳纳米管及其制造方法

    公开(公告)号:US20110064645A1

    公开(公告)日:2011-03-17

    申请号:US12635957

    申请日:2009-12-11

    摘要: The present invention provides a method for producing carbon nanotubes comprising (a) providing a substrate; (b) coating a catalyst layer on said substrate; (e) heating the substrate from step (b); (d) continuously supplying a carbon source to grow carbon nanotubes; (e) interrupting the supplement of the carbon source and supplying an oxidizing gas; and (f) resupplying the carbon source to make the carbon nanotubes obtained from step (d) to re-grow at a higher growth rate. The present invention also provides carbon nanotubes fabricated by the above-mentioned method. The carbon nanotubes have extremely excellent field emission properties.

    摘要翻译: 本发明提供一种碳纳米管的制造方法,其包括:(a)提供基材; (b)在所述衬底上涂覆催化剂层; (e)从步骤(b)加热基底; (d)连续供应碳源以生长碳纳米管; (e)中断碳源的补充并供应氧化气体; 和(f)再供给碳源以使从步骤(d)获得的碳纳米管以更高的生长速率再生长。 本发明还提供了通过上述方法制造的碳纳米管。 碳纳米管具有极好的场致发射特性。