公开(公告)号：US20190314838A1

公开(公告)日：2019-10-17

申请号：US16451702

申请日：2019-06-25

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Adam J. Meuler ,  Nicholas L. Untiedt ,  Stephen C.P. Joseph ,  Thomas P. Klun ,  Naiyong Jing ,  Paul B. Armstrong ,  David A. Gzik ,  Cheryl L.S. Elsbernd

IPC: B05B7/24 ,  C09D127/18 ,  C09D7/63 ,  C09D7/61 ,  C09D5/00 ,  C09D7/62

Abstract: Presently described are components of a spray application system. At least one component comprises a liquid repellent surface layer. The liquid repellent surface (e.g. layer) may comprise a porous layer and a lubricant impregnated into pores of the porous layer; a fluoropolymer; a fluorochemical material and an organic polymeric binder; or a fluorochemical material melt additive and a thermoplastic polymeric material component. The component is typically a liquid reservoir, a liquid reservoir liner, a lid for a liquid reservoir or liner, or a combination thereof. In some embodiments, the component comprises a thermoplastic polymeric material. In some favored embodiments, the component is a removable liquid reservoir or liner. In some favored embodiments, the component is a collapsible liquid reservoir or liner. The spray application system typically further comprises a gravity-fed spray gun. Also described are spray application systems, methods of using a spray application system, as well as methods of making a component of a spray application system wherein the component has a liquid repellent surface.

公开(公告)号：US10227426B2

公开(公告)日：2019-03-12

申请号：US15532856

申请日：2015-12-04

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Yu Yang ,  Jason M. Kehren ,  Suresh S. Iyer ,  William M. Lamanna ,  Thomas P. Klun ,  Jeffrey A. Peterson

IPC: C08F210/02 ,  C09D123/08

Abstract: Antistatic polymers include divalent segments represented by the formula wherein R1 represents an alkyl group having from 6 to 18 carbon atoms, R2 and R3 represent alkyl groups having from 1 to 4 carbon atoms, and R4 represents an alkylene group having from 2 to 8 carbon atoms. Methods of making antistatic polymers are also disclosed.

公开(公告)号：US20180236756A1

公开(公告)日：2018-08-23

申请号：US15753027

申请日：2016-08-18

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Robert S. Clough ,  Joseph C. Spagnola ,  Christopher S. Lyons ,  Mark D. Weigel ,  Thomas P. Klun

IPC: B32B27/36 ,  B32B27/30 ,  C08L67/07 ,  C08K5/053

CPC classification number: B32B27/36 ,  B32B27/08 ,  B32B27/308 ,  B32B2255/10 ,  B32B2255/20 ,  C08F222/10 ,  C08K5/053 ,  C08L67/07 ,  C08L2203/16 ,  C08L2203/204

Abstract: A composite article includes a multilayer barrier assembly bonded to a substrate, and a top polymer layer bonded to the multilayer barrier assembly opposite the substrate. The multilayer barrier assembly comprises a base polymer layer and a base inorganic barrier layer. The base polymer layer comprises a polymerized reaction product of polymerizable components comprising at least one di(meth)acrylate represented by the formula: Formula (I) Each R1 independently represents H or methyl; each R2 independently represents an alkyl group having from 1 to 4 carbon atoms; x=0, 1, 2, 3, or 4; and z=0, 1, 2, 3, or 4, with the provisos that at least one of x and z is not zero and 1≤x+z≤4. Methods of making the same are also disclosed.

公开(公告)号：US20180236755A1

公开(公告)日：2018-08-23

申请号：US15753034

申请日：2016-08-18

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Robert S. Clough ,  Joseph C. Spagnola ,  Christopher S. Lyons ,  Mark D. Weigel ,  Thomas P. Klun

IPC: B32B27/30 ,  C08J7/04 ,  C08L33/06

CPC classification number: B32B27/308 ,  B32B2255/10 ,  B32B2255/20 ,  C08J7/045 ,  C08J2367/02 ,  C08J2433/12 ,  C08L33/06 ,  C08L2203/16 ,  C08L2203/204

Abstract: A composite article comprises a substrate, base polymer layer, an inorganic barrier layer, and top polymer layer. The base polymer layer is disposed on the substrate, and includes a polymerized reaction product of components comprising at least 60 percent by weight of at least one di(meth)acrylate represented by the formula wherein: each R1 is independently H or methyl; and each R2 independently represents an alkyl group having from 1 to 4 carbon atoms, or two R2 groups may together form an alkylene group having from 2 to 7 carbon atoms. An inorganic barrier layer is bonded to the base polymer layer. The top polymer layer is disposed on the inorganic barrier layer opposite the substrate, wherein the top polymer layer comprises a polymerized reaction product of components comprising at least 60 percent by weight of a cycloaliphatic (meth)acrylate having from 13 to 24 carbon atoms.

公开(公告)号：US09982160B2

公开(公告)日：2018-05-29

申请号：US14419303

申请日：2013-03-01

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Thomas P. Klun ,  Alan K. Nachtigal ,  Joseph C. Spagnola ,  Mark A. Roehrig ,  Jennifer K. Schnobrich ,  Guy D. Joly ,  Christopher S. Lyons

IPC: C09D133/14 ,  C09D143/04 ,  C07F7/18 ,  H01L51/00 ,  H01L51/52 ,  H01L51/44 ,  H01L51/10 ,  B05D3/06 ,  B32B27/30 ,  C08J7/04 ,  B05D1/00 ,  B05D3/10 ,  C08K3/34 ,  C09D135/02 ,  C23C14/08 ,  C23C14/34 ,  C23C16/40 ,  C23C16/44 ,  C08F130/08 ,  C09J133/14

CPC classification number: C09D143/04 ,  B05D1/60 ,  B05D3/067 ,  B05D3/068 ,  B05D3/101 ,  B32B27/308 ,  B32B2250/04 ,  B32B2307/7242 ,  B32B2307/7244 ,  C07F7/1804 ,  C08F130/08 ,  C08J7/045 ,  C08J2333/12 ,  C08K3/34 ,  C09D133/14 ,  C09D135/02 ,  C09J133/14 ,  C23C14/08 ,  C23C14/34 ,  C23C16/40 ,  C23C16/44 ,  H01L51/004 ,  H01L51/107 ,  H01L51/448 ,  H01L51/5253 ,  Y10T428/1064 ,  Y10T428/31507 ,  Y10T428/31551 ,  Y10T428/31609 ,  Y10T428/31663

Abstract: Urea (multi)-(meth)acrylate (multi)-silane precursor compounds, synthesized by reaction of (meth)acrylated materials having isocyanate functionality with aminosilane compounds, either neat or in a solvent, and optionally with a catalyst, such as a tin compound, to accelerate the reaction. Also described are articles including a substrate, a base (co)polymer layer on a major surface of the substrate, an oxide layer on the base (co)polymer layer; and a protective (co)polymer layer on the oxide layer, the protective (co)polymer layer including the reaction product of at least one urea (multi) (meth)acrylate (multi)-silane precursor compound synthesized by reaction of (meth)acrylated materials having isocyanate functionality with aminosilane compounds. The substrate may be a (co)polymer film or an electronic device such as an organic light emitting device, electrophoretic light emitting device, liquid crystal display, thin film transistor, or combination thereof. Methods of making the urea (multi)-(meth)acrylate (multi)-silanes and their use in composite films and electronic devices are described.

公开(公告)号：US20180030281A1

公开(公告)日：2018-02-01

申请号：US15728321

申请日：2017-10-09

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Thomas P. Klun ,  Brandt K. Carter ,  Michael K. Gerlach ,  Mahfuza B. Ali ,  Mark J. Pellerite ,  Thomas M. Snyder ,  William M. Lamanna

IPC: C09D4/00 ,  C08F220/30

CPC classification number: C09D4/00 ,  C08F220/30 ,  C08F222/1006 ,  Y10T428/24355 ,  Y10T428/269 ,  Y10T428/31504 ,  Y10T428/31609 ,  Y10T428/31721 ,  Y10T428/31931 ,  Y10T428/31935

Abstract: An optical device having a first optical member, a second optical member, and an antistatic layer disposed between the first optical member and the second optical member wherein the antistatic layer contains the reaction product of a mixture comprising at least one polymerizable onium salt having an anion and at least one non-onium polymerizable monomer, oligomer, or polymer.

公开(公告)号：US09803042B2

公开(公告)日：2017-10-31

申请号：US15226306

申请日：2016-08-02

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Thomas P. Klun ,  Mahfuza B. Ali ,  Richard J. Pokorny ,  Daniel R. Cremons ,  Michelle L. Toy

IPC: C09D129/10 ,  C08F220/36 ,  C09D4/00 ,  C09D5/00 ,  C08F22/10 ,  C09D133/16 ,  C09D7/12

CPC classification number: C08F220/36 ,  C08F22/10 ,  C09D4/00 ,  C09D5/00 ,  C09D7/65 ,  C09D133/16

Abstract: Additives comprising a low surface energy group and one or more hydroxyl groups are described.

公开(公告)号：US09441135B2

公开(公告)日：2016-09-13

申请号：US14381382

申请日：2013-05-30

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Thomas P. Klun ,  Mahfuza B. Ali ,  Richard J. Pokorny ,  Daniel R. Cremons ,  Michelle L. Toy

IPC: C08F22/10 ,  C09D133/16 ,  C09D4/00 ,  C09D5/00

CPC classification number: C08F220/36 ,  C08F22/10 ,  C09D4/00 ,  C09D5/00 ,  C09D7/65 ,  C09D133/16

Abstract: Coating compositions are described comprising a non-ionic surfactant and an additive wherein the additive comprises a low surface energy group and one or more hydroxyl groups. The cured coating can exhibit reduced fingerprint visibility and low cellulose surface attraction. Also described are copolymer compositions useful as additives.

Abstract translation: 描述了包含非离子表面活性剂和添加剂的涂料组合物，其中所述添加剂包含低表面能基团和一个或多个羟基。 固化的涂层可以显示降低的指纹可见性和低纤维素表面吸引力。 还描述了可用作添加剂的共聚物组合物。

公开(公告)号：US09377563B2

公开(公告)日：2016-06-28

申请号：US14097396

申请日：2013-12-05

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Encai Hao ,  Zai-Ming Qiu ,  Yu Yang ,  Thomas P. Klun

IPC: G02B1/10 ,  C09D171/02 ,  C09D133/16 ,  C08G65/00 ,  C08G65/332 ,  C08G65/333 ,  C08J7/04 ,  C09D133/02 ,  C08L71/02

CPC classification number: G02B1/14 ,  C08G65/007 ,  C08G65/3322 ,  C08G65/33351 ,  C08G2650/48 ,  C08J7/045 ,  C08J7/047 ,  C08J2433/16 ,  C08L71/02 ,  C08L2205/05 ,  C09D133/02 ,  C09D133/16 ,  C09D171/02 ,  G02B1/10 ,  G02B1/105 ,  Y10T428/31511 ,  Y10T428/3154 ,  Y10T428/31544 ,  C08L2666/22 ,  C08L2666/04

Abstract: Presently described are articles, such as optical displays and protective films, comprising a (e.g. light transmissive) substrate having a surface layer comprising the reaction product of a mixture comprising a non-fluorinated binder precursor (e.g. of a hardcoat composition) and at least one polymerizable perfluoropolyether polymer. The resulting cured surface layer can advantageously exhibit low lint attraction in combination with low surface energy. Also described are one-step and two-step methods of synthesizing perfluoropolyether polymers having polymerizable ethylenically unsaturated groups.

Abstract translation: 目前描述的是诸如光学显示器和保护膜的物品，其包括具有表面层（例如透光性）的基材，该表面层包含包含非氟化粘合剂前体（例如硬涂层组合物）的混合物的反应产物和至少一种 可聚合的全氟聚醚聚合物。 所得到的固化表面层可以有利地表现出与低表面能结合的低绒毛吸引力。 还描述了合成具有可聚合烯属不饱和基团的全氟聚醚聚合物的一步和两步法。

公开(公告)号：US20160145458A1

公开(公告)日：2016-05-26

申请号：US14900185

申请日：2014-06-26

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Christopher B. Walker, JR. ,  John C. Clark ,  Tatsuo Fukushi ,  Thomas P. Klun ,  Vivek Krishnan ,  Alexander J. Kugel ,  Lan H. Liu ,  Jingjing Ma ,  Steven J. McMan

IPC: C09D127/18 ,  C09D127/16 ,  C09D127/12 ,  C09D127/20

Abstract: There is provided an article comprising at least a first surface having a fluorine-containing polymeric binder resin layer and a plurality of microspheres partially embedded in a first major surface of the binder resin layer and adhered thereto; wherein the fluorine-containing polymer is derived in part from at least one partially fluorinated, or non-fluorinated, monomer; and wherein the article exhibits a stain resistance to yellow mustard at elevated temperature and humidity as measured by the change in b* of less than 50. There are also provided such articles wherein the fluorine-containing polymer is derived in part from at least one partially fluorinated, or non-fluorinated, monomer; and wherein the fluorine content along the polymeric backbone of the fluorine-containing polymer is from about 27% to 72% by weight. There are also provided such articles wherein the article is a thermoformable article exhibiting chemical resistance according to ASTM D5402-06.

Abstract translation: 提供一种制品，其至少包括具有含氟聚合物粘合剂树脂层的第一表面和部分地嵌入粘合剂树脂层的第一主表面并粘合到其上的多个微球; 其中所述含氟聚合物部分地衍生自至少一种部分氟化的或非氟化的单体; 并且其中所述制品在通过b *的变化小于50测量的高温和湿度下对黄芥子具有耐污染性。还提供了这样的制品，其中所述含氟聚合物部分地衍生自部分 氟化或非氟化的单体; 并且其中沿着含氟聚合物的聚合物主链的氟含量为约27％至72％重量。 还提供了这样的制品，其中制品是根据ASTM D5402-06具有耐化学性的热成型制品。