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    Catalyst for decomposition of sulfur trioxide and hydrogen production process
    12.
    发明授权
    Catalyst for decomposition of sulfur trioxide and hydrogen production process 有权
    三氧化硫分解催化剂和氢气生产工艺

    公开(公告)号：US08940270B2

    公开(公告)日：2015-01-27

    申请号：US13997473

    申请日：2011-12-27

    申请人： Shinichi Takeshima ,  Masato Machida

    发明人： Shinichi Takeshima ,  Masato Machida

    IPC分类号： B01J23/847 ,  B01J23/26 ,  C01B3/06 ,  B01J23/22

    CPC分类号： B01J23/8472 ,  B01J23/22 ,  B01J23/26 ,  B01J29/0333 ,  B01J29/0341 ,  B01J35/002 ,  B01J35/1061 ,  B01J35/109 ,  B01J37/0201 ,  B01J37/0205 ,  B01J37/0242 ,  C01B3/068 ,  Y02A50/2348 ,  Y02E60/36

    摘要： To provide a sulfur trioxide decomposition catalyst, particularly, a sulfur trioxide decomposition catalyst capable of lowering the temperature required when producing hydrogen by an S—I cycle process.A sulfur trioxide decomposition catalyst comprising a composite oxide of vanadium and at least one metal selected from the group consisting of transition metal and rare earth elements is provided. Also, a sulfur dioxide production process comprising decomposing sulfur trioxide into sulfur dioxide and oxygen by using the sulfur trioxide decomposition catalyst above, is provided. Furthermore, a hydrogen production process, wherein the reaction of decomposing sulfur trioxide into sulfur dioxide and oxygen by an S—I cycle process is performed by the above-described sulfur dioxide production process, is provided.

    摘要翻译： 提供一种三氧化硫分解催化剂，特别是能够降低通过S-I循环过程产生氢气所需的温度的三氧化硫分解催化剂。 提供了包含钒和选自过渡金属和稀土元素中的至少一种金属的复合氧化物的三氧化硫分解催化剂。 此外，还提供了通过使用上述三氧化硫分解催化剂将三氧化硫分解成二氧化硫和氧气的二氧化硫生产方法。 另外，通过上述二氧化硫的制造方法进行氢过程，其中通过S-I循环过程将三氧化硫分解成二氧化硫和氧的反应进行。

    METHOD FOR PRODUCING FATTY ACID ALKYL ESTERS AND/OR GLYCERIN
    19.
    发明申请
    METHOD FOR PRODUCING FATTY ACID ALKYL ESTERS AND/OR GLYCERIN 审中-公开
    生产脂肪酸乙酯和/或甘氨酸的方法

    公开(公告)号：US20090069586A1

    公开(公告)日：2009-03-12

    申请号：US11816754

    申请日：2006-02-20

    申请人： Tomoharu Oku ,  Toshimitsu Moriguchi ,  Takeo Akatsuka ,  Masanori Nonoguchi

    发明人： Tomoharu Oku ,  Toshimitsu Moriguchi ,  Takeo Akatsuka ,  Masanori Nonoguchi

    IPC分类号： C11C1/02 ,  C07C31/22 ,  C01G23/04 ,  C01G25/02 ,  C01B33/00

    CPC分类号： B01J23/002 ,  B01J21/063 ,  B01J21/066 ,  B01J23/06 ,  B01J23/34 ,  B01J23/8472 ,  B01J35/002 ,  B01J37/08 ,  B01J2523/00 ,  C07C67/03 ,  C11C3/003 ,  C07C69/52 ,  C07C69/24 ,  B01J2523/31 ,  B01J2523/47 ,  B01J2523/41 ,  B01J2523/72 ,  B01J2523/847 ,  B01J2523/48 ,  B01J2523/842 ,  B01J2523/27 ,  B01J2523/845 ,  B01J2523/55

    摘要： To provide: a production method using a catalyst which can substantially suppress leaching of active metal components and exhibit high activity for both reactions of transesterification of glycerides and esterification of free fatty acids each contained in a fat or oil; and the catalyst. A method for producing fatty acid alkyl esters and/or glycerin comprising a step of bringing a fat or oil into contact with an alcohol in the presence of a catalyst, wherein the catalyst is at least one catalyst selected from the group consisting of the following (I) to (V): (I) a metal oxide having an ilmenite structure and/or a slyrankite structure; (II) an oxide containing a metallic element belonging to the Group 12 and a metallic element belonging to the Group 4; (III) a mixed oxide containing a metallic element belonging to the Group 12 and a tetravalent transition metallic element; (IV) a metal oxide containing zirconium and at least one metallic element selected from the group consisting of metallic elements belonging to the Groups 4, 5 and 8; and (V) a metal oxide containing anatase type titanium oxide and/or rutile type titanium oxide, and the metal oxide containing a sulfur component of 700 ppm or less.

    摘要翻译： 提供：使用能够基本上抑制活性金属成分的浸出的催化剂的制造方法，并且对于甘油酯的酯交换反应和脂肪或油中各自含有游离脂肪酸的酯化反应均表现出高活性; 和催化剂。 一种生产脂肪酸烷基酯和/或甘油的方法，包括在催化剂存在下使脂肪或油与醇接触的步骤，其中所述催化剂是选自下列的至少一种催化剂（ I）至（V）：（I）具有钛铁矿结构和/或硅藻土结构的金属氧化物; （II）含有属于第12族的金属元素的氧化物和属于第4族的金属元素; （III）含有属于第12族的金属元素和四价过渡金属元素的混合氧化物; （IV）含有锆的金属氧化物和选自属于第4,5,8族的金属元素的至少一种金属元素; 和（V）含有锐钛矿型氧化钛和/或金红石型氧化钛的金属氧化物，以及含有700ppm以下的硫成分的金属氧化物。

    Catalyst Bodies for Use in Fischer-Tropsch Reactions
    20.
    发明申请
    Catalyst Bodies for Use in Fischer-Tropsch Reactions 审中-公开
    用于费托反应的催化剂体

    公开(公告)号：US20090012189A1

    公开(公告)日：2009-01-08

    申请号：US12097267

    申请日：2006-12-14

    申请人： Arold Marcel Albert Routier ,  Franciscus Johannes Maria Schrauwen ,  Gerardus Petrus Niesen

    发明人： Arold Marcel Albert Routier ,  Franciscus Johannes Maria Schrauwen ,  Gerardus Petrus Niesen

    IPC分类号： C07C1/04 ,  B01J35/04

    CPC分类号： B01J35/023 ,  B01J8/22 ,  B01J19/2485 ,  B01J23/462 ,  B01J23/745 ,  B01J23/75 ,  B01J23/8472 ,  B01J23/8892 ,  B01J23/89 ,  B01J35/008 ,  B01J35/04 ,  B01J35/10 ,  B01J37/0221 ,  B01J2208/00672 ,  C07C1/0425 ,  C10G2/342

    摘要： The invention relates to a catalyst body comprising a Fischer-Tropsch catalyst or catalyst precursor and a porous body, said porous body being between 1-50 mm, preferably 1-30 mm in size, the catalyst body having an internal voidage between 50-95%. The invention further relates to a process comprising the steps of: (i) introducing the synthesis gas into the reactor; and (ii) contacting the synthesis gas with a non-stationary catalyst to catalytically convert the synthesis gas at an elevated temperature to obtain the normally gaseous, normally liquid, and optionally normally solid hydrocarbons from synthesis gas; wherein the catalyst of step (ii) is located on a plurality of porous bodies being 1-50 mm in size, preferably 1-30 mm in size, thus forming catalyst bodies, and wherein said catalyst bodies have an external voidage in situ in the reactor between 5-60%, and a porosity within the catalyst bodies between 50-95%. Use of catalyst bodies according to the invention provides an advantageous intermediate balance whereby such catalyst bodies are significantly easier (and therefore less costly) to separate from the products of the slurry reactor, but they are still able to be supported by the slurry, and are therefore still movable within the reactor vessel so as to seek the most even catalytic transfer and heat transfer, but without being fixed.

    摘要翻译： 本发明涉及包含费 - 托催化剂或催化剂前体和多孔体的催化剂体，所述多孔体的尺寸为1-50mm，优选为1-30mm，催化剂体的内部空隙率在50-95 ％。 本发明还涉及一种方法，其包括以下步骤：（i）将合成气引入反应器; 和（ii）使合成气与非固定催化剂接触以在升高的温度下催化转化合成气，以从合成气中获得通常为气态的，通常为液体的和任选的通常为固体的烃; 其中步骤（ii）的催化剂位于多个多孔体上，尺寸为1-50mm，优选为1-30mm，从而形成催化剂体，并且其中所述催化剂体在 反应器在5-60％之间，催化剂体内的孔隙率在50-95％之间。 根据本发明的催化剂体的使用提供了有利的中间平衡，其中这样的催化剂体与浆料反应器的产物分离显着更容易（因此成本更低），但它们仍然能够被浆料支撑，并且是 因此仍然可以在反应堆容器内移动，以便寻求最均匀的催化转移和热传递，但不固定。