公开(公告)号：US20170137739A1

公开(公告)日：2017-05-18

申请号：US15352784

申请日：2016-11-16

Applicant: TRENT UNIVERSITY

Inventor： Suresh Narine ,  Laziz Bouzidi ,  Latchmi Raghunanan

IPC: C10M129/72 ,  C10M105/04 ,  C07C69/67 ,  C10L10/08 ,  C10L1/19 ,  C07C69/73 ,  C10M101/02 ,  C10M129/76

CPC classification number: C10M129/72 ,  C07C69/67 ,  C07C69/675 ,  C07C69/73 ,  C10L1/1905 ,  C10L1/191 ,  C10L10/08 ,  C10L2200/0476 ,  C10L2270/026 ,  C10M101/02 ,  C10M105/04 ,  C10M105/38 ,  C10M105/40 ,  C10M105/42 ,  C10M129/76 ,  C10M2203/003 ,  C10M2203/022 ,  C10M2203/1006 ,  C10M2205/0285 ,  C10M2207/282 ,  C10M2207/283 ,  C10M2207/2835 ,  C10M2207/289 ,  C10M2207/2895 ,  C10M2207/30 ,  C10M2207/301 ,  C10M2209/102 ,  C10M2209/1023 ,  C10N2230/02 ,  C10N2230/64 ,  C10N2240/02 ,  C10N2240/04

Abstract: The disclosure generally provides branched diester compounds having exceptional low-temperature and flow properties. The disclosure also provides uses of the branched diester compounds in lubricant compositions, for example, as a base oil, and in other applications where their low-temperature and flow properties can be employed beneficially. The disclosure also provides efficient and green methods for making the branched diester compounds.In certain embodiments, a vegetable oil-based diester (1,6-hexyldioleate) was branched with propanoic acid (C3) using a green synthetic approach involving solvent-free and catalyst-free epoxide ring opening followed by in situ normal esterification. A total of three branched ester derivatives possessing varied numbers of internal protruding branched ester groups and hydroxyl groups were obtained. All of the pure branched derivatives were comprised of mixtures of positional isomers and/or stereoisomers. Differential scanning calorimetry (DSC) showed that regardless of the composition inhomogeneity of each branched derivative, crystallization was suppressed completely in all of the branched compounds, and they all demonstrated glass transitions below −65° C.Without being bound by any theory, it is believed that this unique thermal behavior is attributed to the internal protruding branched moieties and hydroxyl groups, which dramatically slowed down mass transfer starting with the least branched compound (2-branched derivative). The viscosity of the branched compounds was one order of magnitude larger than that of the starting di ester due to the increased branching and increased resistance to flow associated with hydrogen bonding introduced by the OH groups. Overall, these branched diesters demonstrated superior low temperature and flow properties comparable to existing non-sustainable commercial lubricants and analogous biobased materials which makes them suitable alternatives for use in lubricant formulations particularly in high performance industrial gear and bearing lubricants.

公开(公告)号：US20170066985A1

公开(公告)日：2017-03-09

申请号：US15356870

申请日：2016-11-21

Applicant: 21ST CENTURY R & D, LLC

Inventor： JOHN RISSIO

IPC: C10L1/02 ,  C10M109/02

CPC classification number: C10L1/026 ,  C10L1/023 ,  C10L1/1817 ,  C10L1/191 ,  C10L10/14 ,  C10L2200/0423 ,  C10L2200/0446 ,  C10L2200/0469 ,  C10L2200/0476 ,  C10L2270/023 ,  C10L2270/026 ,  C10M109/02 ,  C10M159/00 ,  C10M2207/24 ,  C10M2207/40 ,  C10N2230/64 ,  C10N2240/10 ,  C10N2270/00 ,  Y02E50/13 ,  C10N2260/06

Abstract: A bio-organic composition includes residues of a fatty acid glyceride-containing composition, residues of a first epoxide or glycol, and the residues of a second epoxide. The fatty acid glyceride-containing composition is characterized by the viscosity at room temperature. The first epoxide or glycol and second epoxides are present in a sufficient amount that the room temperature viscosity of the bio-organic composition is lower than the room temperature viscosity of the vegetable oil prior to formulation and/or the first epoxide or glycol and second epoxides are present in a sufficient amount that the pour point of the bio-organic composition is lower than the pour point of the fatty acid glyceride-containing composition prior to formulation.

Abstract translation: 生物有机组合物包括含脂肪酸甘油酯的组合物的残留物，第一环氧化物或二醇的残基和第二环氧化物的残基。 含脂肪酸甘油酯的组合物的特征在于在室温下的粘度。 第一环氧化物或乙二醇和第二环氧化物以足够的量存在，使得生物有机组合物的室温粘度低于制剂前植物油的室温粘度和/或第一环氧化物或二醇和第二环氧化物 存在的量足以使生物有机组合物的倾点低于配制前含脂肪酸甘油酯的组合物的倾点。

公开(公告)号：US20160311755A1

公开(公告)日：2016-10-27

申请号：US15103119

申请日：2014-12-05

Applicant: THE LUBRIZOL CORPORATION

Inventor： Mark J. McGuiness

IPC: C07C69/75 ,  C23F11/12 ,  B05D7/00 ,  C09D5/08

CPC classification number: C07C69/75 ,  B05D7/00 ,  C07C69/40 ,  C07C69/593 ,  C07C211/63 ,  C07C215/40 ,  C07C217/08 ,  C07C2601/14 ,  C09D5/086 ,  C10L1/191 ,  C10L10/04 ,  C10M129/74 ,  C10M129/76 ,  C10M133/06 ,  C10M133/08 ,  C10M133/46 ,  C10M2207/282 ,  C10M2207/283 ,  C10M2207/289 ,  C10M2207/401 ,  C10M2215/02 ,  C10M2215/04 ,  C10M2215/042 ,  C10M2215/224 ,  C10N2230/12 ,  C10N2240/10 ,  C23F11/10 ,  C23F11/128 ,  C23F11/143

Abstract: A corrosion-inhibiting composition includes a diluent and a mixture of organic salts of half ester-half acids of a dioic acid with of a glyceride group with a fatty acyl residue. Included are organic salts of glyceride-cyclic carboxylic acid anhydride adducts.

Abstract translation: 腐蚀抑制组合物包括稀酸盐和二酸与甘油酯基与脂肪酰基残基的半酯半酸的有机盐的混合物。 包括甘油酯 - 环状羧酸酐加成物的有机盐。

公开(公告)号：US20150329794A1

公开(公告)日：2015-11-19

申请号：US14713585

申请日：2015-05-15

Applicant: SeaChange Group LLC

Inventor： George N. Harakas ,  Scott J. Eaton ,  Richard W. Kimball ,  Brandon G. Braley ,  Robert C. Ring

IPC: C10L10/14 ,  C10L10/02 ,  C10L1/12 ,  C10L10/08 ,  C10L1/18 ,  C10L1/32

CPC classification number: C10L1/328 ,  C10L1/12 ,  C10L1/125 ,  C10L1/18 ,  C10L1/1811 ,  C10L1/1824 ,  C10L1/1826 ,  C10L1/1852 ,  C10L1/191 ,  C10L1/1915 ,  C10L1/1985 ,  C10L1/2286 ,  C10L1/231 ,  C10L10/02 ,  C10L10/08 ,  C10L10/14 ,  C10L2200/0469 ,  C10L2200/0476 ,  C10L2230/22 ,  C10L2250/06 ,  C10L2250/084 ,  C10L2270/026 ,  F02M25/00

Abstract: The invention provides fuel mixtures containing biodiesel oil, glycerol, glycerol soluble compounds, surfactants and additives. The fuel mixtures are uniform, remain suspended in solution, and are resistant to phase separation. Upon combustion, the mixtures generate reduced CO, CO2, SOx, NOx and particulate matter emissions compared to petroleum fuels and offer improved engine performance over petroleum and water mixtures.

Abstract translation: 本发明提供了含有生物柴油，甘油，甘油可溶性化合物，表面活性剂和添加剂的燃料混合物。 燃料混合物是均匀的，保持悬浮在溶液中，并且耐相分离。 在燃烧时，与石油燃料相比，混合物产生的CO，CO2，SOx，NOx和颗粒物质排放量减少，并提供比石油和水混合物更好的发动机性能。

公开(公告)号：US20150275121A1

公开(公告)日：2015-10-01

申请号：US14682527

申请日：2015-04-09

Applicant: Gordon K. Goldman

Inventor： Gordon K. Goldman

IPC: C10M137/04 ,  C10M129/38 ,  C10M129/16 ,  C10M101/02

CPC classification number: C10M137/04 ,  C09K8/524 ,  C10G29/20 ,  C10G2300/1033 ,  C10G2300/1085 ,  C10G2300/206 ,  C10G2300/208 ,  C10G2300/302 ,  C10G2300/304 ,  C10G2300/308 ,  C10G2300/802 ,  C10G2400/04 ,  C10G2400/10 ,  C10L1/143 ,  C10L1/1616 ,  C10L1/1802 ,  C10L1/1852 ,  C10L1/1881 ,  C10L1/19 ,  C10L1/191 ,  C10L1/1963 ,  C10L1/1985 ,  C10L1/203 ,  C10L1/224 ,  C10L1/232 ,  C10L1/238 ,  C10L1/2641 ,  C10L10/04 ,  C10L10/08 ,  C10L10/14 ,  C10L10/16 ,  C10M101/02 ,  C10M129/16 ,  C10M129/38 ,  C10M141/10 ,  C10M2203/1006 ,  C10M2203/1025 ,  C10M2203/1065 ,  C10M2203/1085 ,  C10M2205/17 ,  C10M2205/173 ,  C10M2205/20 ,  C10M2207/046 ,  C10M2207/125 ,  C10M2207/126 ,  C10M2207/281 ,  C10M2207/40 ,  C10M2207/402 ,  C10M2209/084 ,  C10M2209/104 ,  C10M2211/042 ,  C10M2215/08 ,  C10M2215/223 ,  C10M2223/04 ,  C10M2223/041 ,  C10N2220/023 ,  C10N2230/02 ,  C10N2230/18 ,  C10N2230/24 ,  C10M2209/108

Abstract: A chemical composition of matter comprising a wax plasticizing agent (plasticizer) tributoxyethyl phosphate, a mixture of selected long chain fatty acids (preferably C10 to C22), and a mixture of selected low-surface tension surfactants, which when added in solution to crude oil or refined products has been shown to lower both the B.S. & W. (rag layer) and the coefficient of friction of crude oils and refined products. This chemical composition of matter is particularly useful as a wax liquefaction, dispersant, and solubilization agent for asphaltene and paraffins in crude oil and refined products. The reduction in the co-efficient of friction resulting from the addition of this product to crude oil will allow crude oil to pump through pipelines with a minimum amount of resistance due to friction (drag).

Abstract translation: 包含蜡增塑剂（增塑剂）磷酸三丁氧基乙酯，选择的长链脂肪酸（优选C10至C22）的混合物的物质的化学组成和选择的低表面张力表面活性剂的混合物，其在溶液中加入到原油中 或已经显示精制产品降低了BS ＆W.（碎布层）和原油和精制产品的摩擦系数。 这种物质的化学组成特别适用于原油和精炼产品中的沥青质和石蜡的蜡液化，分散剂和增溶剂。 由于将该产品加入原油而导致的摩擦系数的降低将允许原油由于摩擦（阻力）而以最小量的阻力泵送通过管道。

公开(公告)号：US09133409B2

公开(公告)日：2015-09-15

申请号：US12551087

申请日：2009-08-31

Applicant: Dries Muller ,  Pedro Lopes ,  Mark Brewer ,  Erik Kelderman ,  David Broere

Inventor： Dries Muller ,  Pedro Lopes ,  Mark Brewer ,  Erik Kelderman ,  David Broere

IPC: C07C53/00 ,  C10L10/16 ,  C10L1/14 ,  C10L1/188 ,  C10L1/238 ,  C10L10/08 ,  C10L10/14 ,  C11C3/00 ,  C11C3/02 ,  C10L1/16 ,  C10L1/19 ,  C10L1/222 ,  C10L1/224 ,  C10L1/232

CPC classification number: C10L10/16 ,  C10L1/143 ,  C10L1/1608 ,  C10L1/1616 ,  C10L1/1881 ,  C10L1/1883 ,  C10L1/1885 ,  C10L1/1886 ,  C10L1/1888 ,  C10L1/19 ,  C10L1/1905 ,  C10L1/191 ,  C10L1/2222 ,  C10L1/2225 ,  C10L1/224 ,  C10L1/232 ,  C10L1/2381 ,  C10L10/08 ,  C10L10/14 ,  C11C3/003 ,  C11C3/02 ,  Y02E50/13 ,  Y02T50/678

Abstract: The present invention relates to methods of improving the low temperature storage and performance properties of fatty acids and/or derivatives thereof, as well as compositions containing fatty acids and/or derivatives thereof having superior lower temperature storage and performance properties.

Abstract translation: 本发明涉及改善脂肪酸和/或其衍生物的低温储存和性能的方法，以及含有具有优异的较低温度储存和性能特性的脂肪酸和/或其衍生物的组合物。

公开(公告)号：US20150184101A1

公开(公告)日：2015-07-02

申请号：US14571395

申请日：2014-12-16

Applicant: Marc-Andre Poirier ,  Alexander S. Lang

Inventor： Marc-Andre Poirier ,  Alexander S. Lang

IPC: C10L10/14 ,  C10L1/10

CPC classification number: C10L10/14 ,  C10L1/026 ,  C10L1/10 ,  C10L1/146 ,  C10L1/1608 ,  C10L1/1616 ,  C10L1/1824 ,  C10L1/1852 ,  C10L1/1855 ,  C10L1/191 ,  C10L1/1963 ,  C10L1/1966 ,  C10L1/1983 ,  C10L1/2383 ,  C10L1/2437 ,  C10L1/2475 ,  C10L2200/0476 ,  C10L2230/20 ,  C10L2250/04 ,  C10L2290/24 ,  C10L2300/20 ,  C10L2300/30 ,  Y02E50/13

Abstract: Embodiments of the invention provide a method of inhibiting precipitation of biodiesel fuel components. The method includes providing a biodiesel fuel composition; providing a copolymer comprising at least first and second polymer units, said first polymer units derived from a carboxylic acid anhydride and said second polymer units derived from an olefin; and blending said copolymer with the biodiesel fuel to form a treated fuel composition. Alternatively, instead of the copolymer, a dialkylene glycol additive can be provided. Embodiments of the invention provide a method of reducing the cold soak filter blocking tendency of a biodiesel fuel composition.

Abstract translation: 本发明的实施方案提供抑制生物柴油燃料组分沉淀的方法。 该方法包括提供生物柴油燃料组合物; 提供包含至少第一和第二聚合物单元的共聚物，所述第一聚合物单元衍生自羧酸酐，所述第二聚合物单元衍生自烯烃; 并将所述共聚物与生物柴油燃料混合以形成经处理的燃料组合物。 或者，代替共聚物，可以提供二烷撑二醇添加剂。 本发明的实施方案提供了降低生物柴油燃料组合物的冷浸过滤器阻塞倾向的方法。

公开(公告)号：US20150166920A1

公开(公告)日：2015-06-18

申请号：US14571919

申请日：2014-12-16

Applicant: SHELL OIL COMPANY

Inventor： Mark Lawrence BREWER

IPC: C10L10/14 ,  C10L10/12 ,  C10L1/10

CPC classification number: C10L10/14 ,  C10L1/14 ,  C10L1/1857 ,  C10L1/1883 ,  C10L1/189 ,  C10L1/19 ,  C10L1/1905 ,  C10L1/191 ,  C10L1/223 ,  C10L1/2286 ,  C10L1/232 ,  C10L10/12 ,  C10L2270/02

Abstract: A liquid fuel composition comprising a base fuel suitable for use in an internal combustion engine; one or more organic UV filter compounds; and one or more ester co-additive compounds provides improvements in terms of stability properties in an additive blend containing said one or more organic UV filter compounds and said one or more ester co-additive compounds, particularly at low temperatures, such as temperatures of 5° C. or lower.

Abstract translation: 一种液体燃料组合物，包括适用于内燃机的基础燃料; 一种或多种有机紫外线过滤剂化合物; 和一种或多种酯共添加剂化合物在含有所述一种或多种有机UV过滤剂化合物和所述一种或多种酯共添加剂化合物的添加剂共混物方面提供改进的稳定性，特别是在低温下，例如5 ℃以下。

公开(公告)号：US20150020440A1

公开(公告)日：2015-01-22

申请号：US14216810

申请日：2014-03-17

Applicant: Sylvatex, Inc.

Inventor： Virginia M. Klausmeier ,  Kristen L. Aramthanapon

IPC: C10L1/32

CPC classification number: C10L1/328 ,  C10L1/026 ,  C10L1/10 ,  C10L1/1266 ,  C10L1/1824 ,  C10L1/1881 ,  C10L1/191 ,  C10L1/231 ,  C10L10/04 ,  C10L10/08 ,  C10L10/12 ,  C10L2200/0446 ,  C10L2250/084 ,  C10L2250/086 ,  C10L2270/026 ,  C10L2290/24 ,  C10L2290/60 ,  Y02E50/13

Abstract: A fuel composition for use in internal-combustion engines has a fuel component, an alcohol component, a water component, a microemulsion blend, and a cetane-enhancer component. The microemulsion blend includes at least one of lower grade fatty acid derivatives being present in an amount effective for the fuel, alcohol, and water components to form a microemulsion blend. The emulsifier is present in an amount effective for the biodiesel fuel, alcohol, water, and emulsifier to form an emulsion.

Abstract translation: 用于内燃机的燃料组合物具有燃料成分，醇成分，水成分，微乳液混合物和十六烷基增强剂成分。 微乳液共混物包括至少一种低级脂肪酸衍生物以对于燃料，醇和水组分有效的量存在以形成微乳液共混物。 乳化剂以对生物柴油燃料，醇，水和乳化剂有效的量存在以形成乳液。

公开(公告)号：US20140318004A1

公开(公告)日：2014-10-30

申请号：US14129652

申请日：2012-06-29

Applicant: Jens Mogens Nielsen ,  Maja Duelund ,  Allan Torben Bech

Inventor： Jens Mogens Nielsen ,  Maja Duelund ,  Allan Torben Bech

IPC: C10L1/19

CPC classification number: C10L1/19 ,  C10L1/191 ,  C10L1/328 ,  C10L2230/14 ,  C10L2250/084

Abstract: The present invention provides a fuel composition comprising: (a) a fuel; and (b) a polyglycerol ester of a fatty acid; wherein the polyglycerol composition used to form the polyglycerol ester of a fatty acid comprises a mixture of diglycerol in an amount of 11.0 to 34.0 weight % based on the combined weight of the polyglycerols; triglycerol in an amount of 9.5 to 24.5 weight % based on the combined weight of the polyglycerols; tetraglycerol in an amount of 6.0 to 21.0 weight % based on the combined weight of the polyglycerols; pentaglycerol in an amount of 3.5 to 19.0 weight % based on the combined weight of the polyglycerols; hexaglycerol in an amount of 6.0 to 13.5 weight % based on the combined weight of the polyglycerols; heptaglycerol in an amount of 5.0 to 13.0 weight % based on the combined weight of the polyglycerols; octaglycerol in an amount of 3.0 to 12.0 weight % based on the combined weight of the polyglycerols; nonaglycerol in an amount of 1.5 to 10.0 weight % based on the combined weight of the polyglycerols; decaglycerol in an amount of 0.0 to 8.0 weight % based on the combined weight of the polyglycerols; and unadecaglycerol in an amount of 0.0 to 7.0 weight % based on the combined weight of the polyglycerols.

Abstract translation: 本发明提供一种燃料组合物，其包括：（a）燃料; 和（b）脂肪酸的聚甘油酯; 其中用于形成脂肪酸的聚甘油酯的聚甘油组合物包含基于聚甘油的总重量为11.0至34.0重量％的二甘油的混合物; 基于聚甘油的总重量，9.5至24.5重量％的三甘油; 基于聚甘油的总重量，为6.0〜21.0重量％的四甘油; 基于聚甘油的总重量为3.5至19.0重量％的五甘油; 六甘油的量为6.0至13.5重量％，基于聚甘油的总重量; 基于聚甘油的总重量为5.0至13.0重量％的十七甘油; 基于聚甘油的总重量为3.0至12.0重量％的八甘油; 非甘油的量为1.5至10.0重量％，基于聚甘油的总重量; 十聚甘油的量为0.0-8.0重量％，基于聚甘油的总重量; 和非十八甘油的量为0.0-7.0重量％，基于聚甘油的总重量。