公开(公告)号：US20180133706A1

公开(公告)日：2018-05-17

申请号：US15569783

申请日：2016-03-11

Applicant: IFP Energies Nouvelles

Inventor： Pierre-Louis CARRETTE

IPC: B01J31/04 ,  C10G45/12 ,  B01J27/19 ,  B01J21/04 ,  B01J29/06 ,  B01J31/34 ,  B01J35/00 ,  B01J37/02

Abstract: The invention relates to a catalyst comprising a support based on alumina or silica or silica-alumina, at least one element of group VIII, at least one element of group VIB and γ-ketovaleric acid. The invention also relates to the process for the preparation of said catalyst and the use thereof in a hydrotreatment and/or hydrocracking process.

公开(公告)号：US09683180B2

公开(公告)日：2017-06-20

申请号：US14554242

申请日：2014-11-26

Applicant: IFP ENERGIES NOUVELLES

Inventor： Magalie Roy-Auberger ,  Emmanuelle Guillon ,  Aline Grezaud

IPC: C10G65/02 ,  C10G65/04 ,  C10G45/08 ,  C10G65/12 ,  C10G69/04 ,  B01J37/02 ,  B01J27/19 ,  B01J35/00 ,  C10G65/00

CPC classification number: C10G65/04 ,  B01J27/19 ,  B01J35/002 ,  B01J37/0203 ,  B01J37/0207 ,  C10G45/08 ,  C10G65/12 ,  C10G69/04 ,  C10G2300/1074 ,  C10G2300/202

Abstract: A process for the hydrotreatment of a vacuum distillate type hydrocarbon feed containing nitrogen-containing compounds is described, comprising a first step in which the feed is brought into contact with a catalyst in its oxide form, then a second step in which the feed is brought into contact with a dried catalyst comprising at least one organic compound containing oxygen and/or nitrogen.

公开(公告)号：US20170120229A1

公开(公告)日：2017-05-04

申请号：US15318561

申请日：2015-06-09

Applicant: IFP Energies Nouvelles

Inventor： Malika BOUALLEG ,  Bertrand GUICHARD

IPC: B01J27/19 ,  C10G65/04 ,  B01J21/04 ,  B01J37/04 ,  B01J37/03 ,  B01J37/00 ,  B01J37/02 ,  B01J37/08 ,  C10G45/08 ,  B01J35/10

CPC classification number: B01J27/19 ,  B01J21/04 ,  B01J23/28 ,  B01J23/70 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1028 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1061 ,  B01J35/1071 ,  B01J35/1076 ,  B01J35/109 ,  B01J37/0063 ,  B01J37/009 ,  B01J37/0201 ,  B01J37/0236 ,  B01J37/031 ,  B01J37/036 ,  B01J37/04 ,  B01J37/08 ,  B01J37/10 ,  B01J37/20 ,  C01F7/34 ,  C01F7/441 ,  C10G45/08 ,  C10G45/14 ,  C10G45/18 ,  C10G65/04 ,  C10G2300/107 ,  C10G2300/1077 ,  C10G2300/202 ,  C10G2300/205

Abstract: A hydroconversion catalyst with a bimodal pore structure: an oxide matrix predominantly of calcined aluminium; a hydro-dehydrogenative active phase of at least one group VIII metal being at least partly commixed within the said oxide matrix mainly made up of calcined aluminium, an SBET specific surface greater than 100 m2/g, a mesoporous median diameter in volume between 12 and 25 nm inclusive, a macroporous median diameter in volume between 250 and 1500 nm inclusive, a mesoporous volume as measured by mercury intrusion porosimeter greater than or equal to 0.55 ml/g and a total measured pore volume by mercury porosimetry greater than or equal to 0.70 ml/g; a method for preparing a residue catalyst for hydroconversion/hydroprocessing by commixing the active phase with a particular alumina, the use of the catalyst in hydroproces sing, including hydroproces sing heavy feeds.

公开(公告)号：US09498772B2

公开(公告)日：2016-11-22

申请号：US14091137

申请日：2013-11-26

Applicant: Saudi Arabian Oil Company

Inventor： Miao Sun ,  Wei Xu

IPC: C10L10/10 ,  C10L1/04 ,  C07C2/18 ,  C07C2/14 ,  B01J27/19

CPC classification number: B01J27/19 ,  B01J2523/00 ,  C07C2/14 ,  C07C2/18 ,  C07C2523/04 ,  C07C2523/28 ,  C07C2527/19 ,  C10L1/04 ,  C10L10/10 ,  C10L2200/0423 ,  C10L2200/043 ,  C10L2200/0438 ,  C10L2200/0446 ,  C10L2270/023 ,  C10L2270/026 ,  C10L2270/04 ,  C07C9/16 ,  B01J2523/15 ,  B01J2523/51 ,  B01J2523/68

Abstract: The present invention relates to unsupported metal (e.g., cesium) substituted heteropolyacid catalyst compositions useful for the production of butene dimers and/or oligomers from a mixed butenes feed, in which, under mild conditions, all isomers of mixed butenes produce highly branched C8 and C8+ olefins.

Abstract translation: 本发明涉及用于从混合丁烯进料生产丁烯二聚体和/或低聚物的无载体金属（例如铯）取代的杂多酸催化剂组合物，其中在温和条件下，混合丁烯的所有异构体产生高度支化的C8和 C8 +烯烃。

公开(公告)号：US09376636B2

公开(公告)日：2016-06-28

申请号：US13995800

申请日：2011-12-15

Applicant: Karin Marchand ,  Elodie Devers ,  Alexandra Chaumonnot ,  Audrey Bonduelle ,  Veronique Dufaud ,  Frederic Lefebvre ,  Manuela Bader ,  Susana Lopes Silva

Inventor： Karin Marchand ,  Elodie Devers ,  Alexandra Chaumonnot ,  Audrey Bonduelle ,  Veronique Dufaud ,  Frederic Lefebvre ,  Manuela Bader ,  Susana Lopes Silva

IPC: C10G45/04 ,  B01J27/186 ,  B01J27/188 ,  B01J27/19 ,  C10G45/10 ,  B01J29/03 ,  B01J35/00 ,  B01J35/10 ,  B01J37/03 ,  B01J37/10 ,  B01J37/20 ,  C10G45/06 ,  B01J27/195 ,  B01J27/198

CPC classification number: C10G45/10 ,  B01J27/186 ,  B01J27/188 ,  B01J27/19 ,  B01J29/0333 ,  B01J29/0341 ,  B01J35/002 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1057 ,  B01J35/1061 ,  B01J37/033 ,  B01J37/10 ,  B01J37/20 ,  B01J2229/20 ,  C10G45/04 ,  C10G45/06 ,  C10G2300/104 ,  C10G2300/1044 ,  C10G2300/202 ,  C10G2300/4018 ,  C10G2400/02

Abstract: A process of hydrodesulphuration of at least one gasoline cut implementing a catalyst comprising, in its oxide form, at least one metal from group VIB and/or at least one metal from group VIII of the periodic table, present in the form of at least one polyoxometalate of the formula (HhXxMmOy)q−, wherein X is an element selected from phosphorus, silicon, boron, nickel and cobalt, M is one or more element(s) selected from molybdenum, tungsten, nickel and cobalt, h is an integer from 0-12, x is an integer from 0-4, m is an integer 5, 6, 7, 8, 9, 10, 11, 12 and/or 18, y is an integer of 17-72 and q is an integer of 1-20, the polyoxometalates being present within a mesostructured silicon oxide matrix having a pore size of 1.5-50 nm and having amorphous walls of thickness 1-30 nm, the catalyst being sulphured before use in the process.

Abstract translation: 至少一种汽油切割加氢脱硫的方法，其实施催化剂，其以其氧化物形式包含至少一种以至少一种形式存在的来自VIB族组分和/或至少一种来自元素周期表Ⅷ族的金属的金属 式（HhXxMmOy）q-的多金属氧酸盐，其中X是选自磷，硅，硼，镍和钴的元素，M是选自钼，钨，镍和钴的一种或多种元素，h是整数 从0-12，x是0-4的整数，m是整数5,6,7,8,9,10,11,12和/或18，y是17-72的整数，q是 整数为1-20，多金属氧酸盐存在于孔径为1.5-50nm的介孔结构的氧化硅基质中，并且具有厚度为1-30nm的无定形壁，催化剂在该方法使用前被硫化。

公开(公告)号：US09254478B2

公开(公告)日：2016-02-09

申请号：US13391336

申请日：2010-08-24

Applicant: Sona Eijsbouts-Spickova ,  Marcel Adriaan Jansen

Inventor： Sona Eijsbouts-Spickova ,  Marcel Adriaan Jansen

IPC: B01J31/06 ,  B01J27/185 ,  B01J27/19 ,  B01J23/888 ,  B01J21/04 ,  B01J23/88 ,  B01J37/02 ,  B01J37/08 ,  C10G49/04 ,  B01J27/186

CPC classification number: B01J27/19 ,  B01J21/04 ,  B01J23/88 ,  B01J23/888 ,  B01J27/1853 ,  B01J37/0203 ,  B01J37/0213 ,  B01J37/0236 ,  B01J37/08 ,  C10G45/00 ,  C10G45/08 ,  C10G49/04

Abstract: This invention provides a process for forming a solution composition, which process comprises forming a primary solution by bringing together, in an aqueous medium, i) at least one phosphorus compound, ii) at least one Group VI metal compound, iii) at least one Group VIII metal compound, and iv) an additive which is a) tetraethylene glycol, b) polyethylene glycol having an average molecular weight in the range of about 200 to about 400, c) a mixture of tetraethylene glycol and polyethylene glycol having an average molecular weight in the range of about 200 to about 400, or d) a mixture of (1) tetraethylene glycol and/or polyethylene glycol having an average molecular weight in the range of about 200 to about 400 and (2) one or more of monoethylene glycol, diethylene glycol, and triethylene glycol. The molar ratio of additive to the total moles of Group VI metal and Group VIII metal is above 0.30:1, and the atomic ratio of phosphorus to Group VI metal is at least about 0.33:1. Optionally, the primary solution is heated at a temperature above about 40° C. to form a heated solution. The heated solution is optionally cooled to form a cooled solution. Also provided are compositions formed by such processes, processes for forming catalyst compositions from these compositions, and catalyst compositions formed by these processes.

Abstract translation: 本发明提供一种形成溶液组合物的方法，该方法包括通过在水性介质中混合形成初级溶液，i）至少一种磷化合物，ii）至少一种VI族金属化合物，iii）至少一种 VIII族金属化合物，和iv）a）四乙二醇，b）平均分子量在约200至约400范围内的聚乙二醇的添加剂，c）四甘醇和聚乙二醇的混合物，其平均分子量 重量在约200至约400的范围内，或d）平均分子量在约200至约400范围内的（1）四甘醇和/或聚乙二醇的混合物，和（2）一种或多种单乙烯 乙二醇，二甘醇和三甘醇。 VI族金属和VIII族金属的添加剂与总摩尔数的摩尔比大于0.30:1，磷与Ⅵ族金属的原子比为至少约0.33:1。 任选地，将主溶液在高于约40℃的温度下加热以形成加热溶液。 加热的溶液任选地冷却以形成冷却的溶液。 还提供了通过这些方法形成的组合物，由这些组合物形成催化剂组合物的方法，以及由这些方法形成的催化剂组合物。

公开(公告)号：US09211536B2

公开(公告)日：2015-12-15

申请号：US13208148

申请日：2011-08-11

Applicant: Alexei Grigorievich Gabrielov ,  Ed Ganja ,  Salvatore Philip Torrisi

Inventor： Alexei Grigorievich Gabrielov ,  Ed Ganja ,  Salvatore Philip Torrisi

IPC: B01J21/08 ,  B01J23/00 ,  B01J23/28 ,  B01J23/30 ,  C10G45/04 ,  B01J35/00 ,  B01J23/85 ,  B01J23/882 ,  B01J23/883 ,  B01J23/888 ,  B01J27/19 ,  B01J35/10 ,  B01J37/02 ,  B01J37/18 ,  B01J37/20 ,  C10G49/04 ,  B01J35/02 ,  B01J37/04

CPC classification number: B01J27/19 ,  B01J23/85 ,  B01J23/882 ,  B01J23/883 ,  B01J23/888 ,  B01J23/8885 ,  B01J35/002 ,  B01J35/026 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1061 ,  B01J37/0201 ,  B01J37/0203 ,  B01J37/0236 ,  B01J37/04 ,  B01J37/18 ,  B01J37/20 ,  C10G45/08 ,  C10G49/04

Abstract: A hydroprocessing catalyst composition that comprises a shaped support that is formed from a mixture of inorganic oxide powder and catalyst fines and wherein the shaped support has incorporated therein at least one metal component, a chelating agent and a polar additive. The hydroprocessing catalyst composition is prepared by incorporating into the shaped support a metal component, a chelating agent and a polar additive. The hydroprocessing catalyst composition has particular application in the catalytic hydroprocessing of petroleum derived feedstocks.

Abstract translation: 一种加氢处理催化剂组合物，其包含由无机氧化物粉末和催化剂细粉的混合物形成的成形载体，并且其中所述成形载体中并入至少一种金属组分，螯合剂和极性添加剂。 加氢处理催化剂组合物通过将金属组分，螯合剂和极性添加剂并入成形载体来制备。 加氢处理催化剂组合物特别适用于石油衍生原料的催化加氢处理。

公开(公告)号：US20150306579A1

公开(公告)日：2015-10-29

申请号：US14441806

申请日：2013-10-31

Applicant: CHINA PETROLEUM & CHEMICAL CORPORATION ,  FUSHUN RESEARCH INSTITUTE OF PETROLEUM AND PETROCHEMICALS, SINOPEC

Inventor： Zhanlin Yang ,  Hong Jiang ,  Zhaoji Tang ,  Jifeng Wang ,  Derong Wen ,  Dengling Wei

IPC: B01J27/19 ,  C10G45/08 ,  B01J35/10

CPC classification number: B01J27/19 ,  B01J23/881 ,  B01J23/882 ,  B01J23/883 ,  B01J31/04 ,  B01J35/1019 ,  C10G45/02 ,  C10G45/04 ,  C10G45/08 ,  C10G2300/107 ,  C10G2300/1074 ,  C10G2300/1077

Abstract: This invention relates to a hydrotreating catalyst suitable for heavy distillate oil hydrodesulfurization, production and use thereof. The present hydrotreating catalyst exhibits significantly improved heavy distillate oil (deep) hydrodesulfurization activity.

Abstract translation: 本发明涉及一种适用于重馏分油加氢脱硫的加氢处理催化剂，其生产和使用。 本发明加氢处理催化剂显着提高重馏油（深）加氢脱硫活性。

公开(公告)号：US09162954B2

公开(公告)日：2015-10-20

申请号：US14491433

申请日：2014-09-19

Applicant: ARKEMA FRANCE

Inventor： Yasuhiro Magatani ,  Kimito Okumura ,  Jean-Luc Dubois ,  Jean-Francois Devaux

IPC: C07C45/00 ,  C07C51/00 ,  C07C253/00 ,  B01J27/182 ,  B01J27/186 ,  B01J27/19 ,  B01J27/198 ,  B01J27/199 ,  B01J23/00 ,  B01J23/30 ,  B01J27/188 ,  B01J37/02 ,  C07C45/52 ,  C07C51/25 ,  C07K14/78 ,  G01N33/68 ,  B01J21/06 ,  B01J21/12 ,  C07C51/235 ,  C07C253/26

CPC classification number: C07C45/002 ,  B01J21/063 ,  B01J21/12 ,  B01J23/002 ,  B01J23/30 ,  B01J27/188 ,  B01J37/0205 ,  B01J2523/00 ,  C07C45/52 ,  C07C51/235 ,  C07C51/252 ,  C07C253/26 ,  C07K14/78 ,  G01N33/6887 ,  G01N33/6893 ,  G01N2333/705 ,  C07C47/22 ,  C07C57/04 ,  B01J2523/15 ,  B01J2523/51 ,  B01J2523/69 ,  B01J2523/41

Abstract: A catalyst composition comprising at least an heteropolyacid deposited on a porous titania carrier.A catalyst composition comprising at least an heteropolyacid in which protons in the heteropolyacid may be partially exchanged by at least one cation selected from elements belonging to Group 1 to Group 16 of the Periodic Table of Elements that have been deposited on a porous titania carrier.A method for preparing the catalyst composition, comprising impregnating a titania carrier with a solution of at least one metal selected from elements belonging to the Group 1 to Group 16 of the Periodic Table of Elements or onium, drying and firing the resulting solid mixture, secondly impregnating the resulting solid mixture with a solution of heteropolyacid, drying, and firing the resulting solid mixture.A process for preparing acrolein and acrylic acid by dehydration of glycerin, carried out in the presence of the catalyst.

Abstract translation: 一种催化剂组合物，其至少包含沉积在多孔二氧化钛载体上的杂多酸。 至少包含杂多酸的催化剂组合物，其中杂多酸中的质子可以通过选自元素周期表第1族至第16族的元素的至少一种阳离子部分交换，所述元素已经沉积在多孔二氧化钛载体上。 一种制备催化剂组合物的方法，包括用选自元素周期表第1族至第16族的元素或鎓的至少一种金属的溶液浸渍二氧化钛载体，干燥并焙烧得到的固体混合物 用杂多酸溶液浸渍所得固体混合物，干燥并焙烧所得固体混合物。 在催化剂存在下进行甘油脱水制备丙烯醛和丙烯酸的方法。

公开(公告)号：US20150209766A1

公开(公告)日：2015-07-30

申请号：US14417290

申请日：2013-08-29

Applicant: INDIAN OIL CORPORATION LTD.

Inventor： Kochappilly Ouseph Xavier ,  Alex Cheru Pulikottil ,  Mohan Prabhu Kuvettu ,  Brijesh Kumar ,  Santanam Rajagopal ,  Ravinder Kumar Malhotra

IPC: B01J27/19 ,  B01J21/12 ,  B01J37/00 ,  B01J27/051 ,  B01J37/04 ,  B01J37/08 ,  B01J37/02 ,  B01J35/00 ,  B01J21/06 ,  B01J37/06

CPC classification number: B01J27/19 ,  B01J21/04 ,  B01J21/06 ,  B01J21/063 ,  B01J21/12 ,  B01J23/882 ,  B01J27/051 ,  B01J35/0013 ,  B01J37/0009 ,  B01J37/009 ,  B01J37/0203 ,  B01J37/0207 ,  B01J37/04 ,  B01J37/06 ,  B01J37/08

Abstract: The current invention provides a hydrotreating catalyst comprising of metals of at least one each from Group VIB, preferably molybdenum and Group VIII, preferably nickel, of the periodic table supported on alumina modified with small amounts of modifying elements well dispersed on the surface so as to retain the physico-chemical characteristics of the support and result in high performance for hydrodesulphurization catalyst, and a commercially viable process for producing such a catalyst. The present invention also discloses a commercially viable method for modifying alumina in the powder form without affecting the porous structure of the support obtained.

Abstract translation: 本发明提供了一种加氢处理催化剂，其由至少一种金属组成，其中VIB族优选为钼和VIII族，优选为镍，优选为含有少量改性元素的氧化铝负载在氧化铝上的元素周期表，优选为镍， 保留载体的物理化学特性并导致加氢脱硫催化剂的高性能，以及用于生产这种催化剂的商业上可行的方法。 本发明还公开了一种商业上可行的粉末形式的氧化铝改性方法，而不影响所获得的载体的多孔结构。