公开(公告)号：US20140213432A1

公开(公告)日：2014-07-31

申请号：US14229878

申请日：2014-03-29

Applicant: Rive Technology, Inc.

Inventor： Javier Garcia Martinez ,  Lawrence B. Dight ,  Barry K. Speronello

IPC: B01J29/08

CPC classification number: B01J29/084 ,  B01J29/04 ,  B01J29/041 ,  B01J29/08 ,  B01J29/082 ,  B01J29/18 ,  B01J29/40 ,  B01J29/7015 ,  B01J35/10 ,  B01J35/1042 ,  B01J35/1057 ,  B01J35/1061 ,  B01J35/109 ,  B01J37/08 ,  B01J2229/22 ,  B01J2229/37

Abstract: Methods for enhancing the mesoporosity of a zeolite-containing material. Such methods may comprise contacting a composite shaped article containing at least one zeolite and at least one non-zeolitic material with at least one pH controlling agent and at least one surfactant. Such methods may be performed under conditions sufficient to increase the pore volume of at least one 10 angstrom subset of mesoporosity.

Abstract translation: 提高含沸石材料的介孔度的方法。 这样的方法可以包括使包含至少一种沸石和至少一种非沸石材料的复合成型制品与至少一种pH控制剂和至少一种表面活性剂接触。 这样的方法可以在足以增加至少一个10埃的中孔子集的孔体积的条件下进行。

公开(公告)号：US20140163275A1

公开(公告)日：2014-06-12

申请号：US14119571

申请日：2012-05-24

Applicant: Shinichiro Yanagawa ,  Yasuyuki Iwasa ,  Susumu Yasui ,  Yoshishige Sugi ,  Atsushi Fukui ,  Atsuro Nagumo

Inventor： Shinichiro Yanagawa ,  Yasuyuki Iwasa ,  Susumu Yasui ,  Yoshishige Sugi ,  Atsushi Fukui ,  Atsuro Nagumo

IPC: C07C4/06 ,  B01D3/00

CPC classification number: C07C4/06 ,  B01D3/009 ,  B01J29/047 ,  B01J29/048 ,  B01J29/08 ,  B01J29/18 ,  B01J29/185 ,  B01J29/40 ,  B01J29/70 ,  B01J29/7007 ,  B01J29/7057 ,  B01J29/82 ,  B01J29/86 ,  B01J29/87 ,  B01J2229/186 ,  C10G11/187 ,  C10G35/14 ,  C10G35/24 ,  C10G49/26 ,  C10G2300/301 ,  C10G2400/30

Abstract: A producing method of monocyclic aromatic hydrocarbons from the oil feedstock having a 10 volume % distillation temperature of more than or equal to 140° C. and a 90 volume % distillation temperature of less than or equal to 380° C. by bringing into contact with an aromatic production catalyst includes the steps of: introducing the oil feedstock into a cracking and reforming reaction apparatus housing the aromatic production catalyst; bringing the oil feedstock and the aromatic production catalyst into contact with each other at the inside of the cracking and reforming reaction apparatus; heating the oil feedstock in advance before introducing the oil feedstock into the cracking and reforming reaction apparatus and forming a two-phase gas-liquid stream; separating the two-phase gas-liquid stream into a gas fraction and a liquid fraction; and introducing the gas fraction and the liquid fraction at different positions of the cracking and reforming reaction apparatus.

Abstract translation: 来自油原料的单环芳烃的制备方法，其具有大于或等于140℃的10体积％蒸馏温度和小于或等于380℃的90体积％蒸馏温度，通过与 芳族生产催化剂包括以下步骤：将油原料引入到容纳芳族生产催化剂的裂化和重整反应装置中; 使油原料和芳香族生成催化剂在裂化和重整反应装置的内部彼此接触; 在将油原料引入裂解和重整反应装置中并形成两相气 - 液流之前，预先加热油原料; 将两相气 - 液流分离成气体馏分和液体馏分; 并在裂化和重整反应装置的不同位置引入气体馏分和液体馏分。

公开(公告)号：US08748500B2

公开(公告)日：2014-06-10

申请号：US13457202

申请日：2012-04-26

Applicant: Duane A. Goetsch ,  Kym B Arcuri ,  Steven J. Schmit ,  Jacqueline R Hitchingham ,  Lloyd R. White

Inventor： Duane A. Goetsch ,  Kym B Arcuri ,  Steven J. Schmit ,  Jacqueline R Hitchingham ,  Lloyd R. White

IPC: C07C27/00 ,  C10G9/36

CPC classification number: B01J23/002 ,  B01J29/18 ,  B01J29/40 ,  B01J29/65 ,  B01J2229/186 ,  B01J2523/00 ,  C10G2/32 ,  C10G45/58 ,  C10G2300/1014 ,  Y02P30/20 ,  Y02P30/44 ,  B01J2523/17 ,  B01J2523/27 ,  B01J2523/31 ,  B01J2523/67

Abstract: A process for producing transportation fuels, such as gasoline and diesel fuel, from syngas with a low H2/CO ratio. The syngas is first converted to dimethyl ether which is then converted to gasoline by way of a dimethyl ether to gasoline process and to diesel fuel by way of a Fischer-Tropsch process.

Abstract translation: 从H2 / CO比低的合成气生产运输燃料如汽油和柴油的方法。 合成气首先转化为二甲醚，然后通过二甲醚将其转化为汽油，经过费 - 托法转化成柴油。

公开(公告)号：US08697930B2

公开(公告)日：2014-04-15

申请号：US13639940

申请日：2011-05-31

Applicant: Robert G. Bowman ,  Eric E. Stangland ,  Rainer Bruening ,  Angelika Heilmann ,  Roland Wagner ,  Jason Lee Bronkema

Inventor： Robert G. Bowman ,  Eric E. Stangland ,  Rainer Bruening ,  Angelika Heilmann ,  Roland Wagner ,  Jason Lee Bronkema

IPC: C07C211/03

CPC classification number: C07C1/323 ,  B01J29/08 ,  B01J29/18 ,  B01J29/40 ,  B01J29/50 ,  B01J29/65 ,  B01J29/85 ,  C07C2529/08 ,  C07C2529/18 ,  C07C2529/40 ,  C07C2529/50 ,  C07C2529/66 ,  C07C2529/85 ,  Y02P20/52 ,  C07C11/02 ,  C07C11/06 ,  C07C11/04

Abstract: Convert a methylamine (e.g. monomethylamine, dimethylamine and trimethylamine) to a mixture of olefins (e.g. ethylene, propylene and butylene) by placing the methylamine, optionally in a mixture with at least one of ammonia and an inert diluent, in contact with a microporous acidic silicoaluminophosphate catalyst or a microporous aluminosilicate catalyst.

Abstract translation: 将甲胺（例如一甲胺，二甲胺和三甲胺）转化为烯烃（如乙烯，丙烯和丁烯）的混合物，将甲胺，任选地与氨和惰性稀释剂中的至少一种的混合物与微孔酸 硅铝磷酸盐催化剂或微孔硅铝酸盐催化剂。

公开(公告)号：US08623777B2

公开(公告)日：2014-01-07

申请号：US12738061

申请日：2008-10-07

Applicant: Terry Eugene Helton ,  Vijay Nanda ,  Wei-Ping Tai ,  Teresa Ann Jurgens-Kowal ,  Kathleen Marie Keville

Inventor： Terry Eugene Helton ,  Vijay Nanda ,  Wei-Ping Tai ,  Teresa Ann Jurgens-Kowal ,  Kathleen Marie Keville

IPC: B01J38/04 ,  B01J38/10 ,  B01J38/06 ,  B01J38/02

CPC classification number: B01J38/02 ,  B01J29/041 ,  B01J29/08 ,  B01J29/18 ,  B01J29/7007 ,  B01J29/90 ,  B01J38/04

Abstract: This disclosure relates to a method for rejuvenating a catalyst, comprising contacting the catalyst with a gaseous feedstock at rejuvenation conditions for at least one hour to form a rejuvenated catalyst and a gaseous product, wherein the catalyst comprises at least 10 wt. % of a molecular sieve, wherein the catalyst prior to the contacting step comprises from 0.001 wt. % to 45 wt. % of hydrocarbons and 0.001 to 10 wt. % nitrogen containing components based on the total weight of the catalyst prior to the contacting step, wherein the molecular sieve comprises at least one of a MCM-22 family molecular sieve, a molecular sieve having a framework type of *BEA, a molecular sieve having a framework type of FAU, and a molecular sieve having a framework type of MOR, wherein the gaseous feedstock comprises at least one of N2, H2, alkane, He, Ar, CO, and CO2, wherein the gaseous product has at least a portion of the gaseous feedstock and at least a portion of the hydrocarbons of the catalyst and at least a portion of the nitrogen containing components of the catalyst, wherein the rejuvenation conditions comprise a temperature in the range from about 400 to 600° C., a pressure in the range from about 101.3 kPa-a to 10130 kPa-a, a space hourly velocity in the range of from 0.05 to 10 hr−1.

Abstract translation: 本公开涉及一种用于使催化剂再生的方法，包括在再生条件下将催化剂与气态原料接触至少1小时，以形成复原的催化剂和气态产物，其中催化剂包含至少10wt。 ％的分子筛，其中在接触步骤之前的催化剂包含0.001重量％ ％至45重量％ ％的烃和0.001至10wt。 ％的含氮组分基于在接触步骤之前的催化剂的总重量，其中分子筛包括MCM-22族分子筛，具有骨架类型为* BEA的分子筛中的至少一种，分子筛具有 骨架类型的FAU和具有骨架类型MOR的分子筛，其中气态原料包括N 2，H 2，烷烃，He，Ar，CO和CO 2中的至少一种，其中气态产物具有至少一部分 的气态原料和催化剂的烃的至少一部分和催化剂的至少一部分含氮组分，其中再生条件包括约400-600℃的温度，压力 在约101.3kPa-a至10130kPa-a的范围内，空间时速在0.05至10小时-1的范围内。

公开(公告)号：US20130292300A1

公开(公告)日：2013-11-07

申请号：US13937721

申请日：2013-07-09

Applicant: Massachusetts Institute of Technology

Inventor： Jackie Y. Ying ,  Javier Garcia-Martinez

IPC: C10G47/20 ,  B01J29/16

CPC classification number: C10G47/20 ,  B01J20/18 ,  B01J20/186 ,  B01J20/28007 ,  B01J20/2803 ,  B01J20/28057 ,  B01J20/28071 ,  B01J20/28073 ,  B01J20/28083 ,  B01J29/005 ,  B01J29/0308 ,  B01J29/041 ,  B01J29/084 ,  B01J29/106 ,  B01J29/166 ,  B01J29/18 ,  B01J29/40 ,  B01J29/80 ,  B01J2229/42 ,  B01J2229/62 ,  B82Y30/00 ,  C01B39/02 ,  C01B39/023 ,  C01B39/026 ,  C01B39/04 ,  C10G1/086 ,  C10G11/02 ,  C10G11/05 ,  C10G11/18 ,  C10G45/04 ,  C10G47/02 ,  C10G47/16 ,  C10G47/18 ,  C10G2300/1033 ,  C10G2300/1074 ,  C10G2300/1096 ,  C10G2400/02 ,  C10G2400/20

Abstract: Hydrocracking processes and catalyst composition for use therein are provided. The catalyst compositions described herein include a mesoporous support material and at least one catalytic metal supported thereon. The mesoporous support material may comprise a single-phase crystalline mesostructured zeolite. Additionally, the mesoporous structure may exhibit long range crystallinity and include a plurality of mesopores defined within of the volume of the crystalline mesostructure. Suitable feedstocks for the hydrocracking processes according to embodiments of the present invention crude oil, a gas oil fraction, vacuum gas oil, and combinations thereof.

Abstract translation: 提供加氢裂化方法和用于其中的催化剂组合物。 本文所述的催化剂组合物包括介孔载体材料和至少一种在其上负载的催化金属。 介孔载体材料可以包含单相结晶介孔结构的沸石。 此外，介孔结构可以表现出长程结晶度，并且包括在结晶介孔结构的体积内限定的多个介孔。 用于根据本发明实施方案的加氢裂化方法的合适的原料油，粗柴油馏分，减压瓦斯油及其组合。

公开(公告)号：US08569556B2

公开(公告)日：2013-10-29

申请号：US13779172

申请日：2013-02-27

Applicant: UOP LLC

Inventor： Mark G. Riley ,  Deng-Yang Jan ,  Stephen W. Sohn

IPC: C07C2/66

CPC classification number: C07C2/66 ,  B01J29/085 ,  B01J29/088 ,  B01J29/18 ,  B01J29/50 ,  B01J29/60 ,  B01J29/70 ,  B01J29/7007 ,  B01J29/7034 ,  B01J29/7038 ,  B01J29/80 ,  B01J37/0009 ,  B01J2229/42 ,  C07C2529/08 ,  C07C2529/18 ,  C07C2529/70 ,  C07C2529/80 ,  C07C15/107

Abstract: A method for controlling 2-isomer content in linear alkylbenzene obtained by alkylating benzene with olefins and catalyst used in the method.

公开(公告)号：US20130167430A1

公开(公告)日：2013-07-04

申请号：US13729227

申请日：2012-12-28

Applicant: SHELL OIL COMPANY

Inventor： John William HARRIS ,  Ye-Mon CHEN

IPC: C10L1/18 ,  B01F5/00

CPC classification number: C10L1/1802 ,  B01F5/00 ,  B01J8/24 ,  B01J29/082 ,  B01J29/084 ,  B01J29/088 ,  B01J29/18 ,  B01J29/40 ,  B01J29/50 ,  B01J29/60 ,  B01J29/70 ,  B01J29/7034 ,  B01J29/7042 ,  B01J29/7046 ,  B01J29/80 ,  B01J29/90 ,  B01J2208/00902 ,  B01J2219/00024 ,  C10G1/08 ,  C10G3/57 ,  C10G2300/1011 ,  C10G2300/4056 ,  Y02P30/20 ,  Y10T29/49718 ,  Y10T137/87652

Abstract: A process for converting a solid biomass material comprising (a) mixing the solid biomass material with a fluid to form a fluidized biomass stream; and (b) propagating the fluidized biomass stream into the riser reactor via one or more delivery aperture(s); wherein the solid biomass material has a particle size distribution with a mean particle size diameter, and wherein the delivery aperture has a diameter equal to or more than three times the mean particle size diameter of the particle size distribution of the solid biomass material.

Abstract translation: 一种用于转化固体生物质材料的方法，包括（a）将固体生物质材料与流体混合以形成流化的生物质流; 和（b）通过一个或多个输送孔将流化的生物物流传播到提升管反应器中; 其中所述固体生物质材料具有平均粒度直径的粒度分布，并且其中所述输送孔的直径等于或大于所述固体生物质材料的粒度分布的平均粒度直径的三倍。

公开(公告)号：US08450521B2

公开(公告)日：2013-05-28

申请号：US12998684

申请日：2009-10-08

Applicant: Evert Jan Ditzel ,  David John Law ,  John Glenn Sunley

Inventor： Evert Jan Ditzel ,  David John Law ,  John Glenn Sunley

IPC: C07C51/23 ,  C07C67/37

CPC classification number: C07C67/37 ,  B01J29/18 ,  B01J35/023 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1061 ,  B01J35/109 ,  B01J37/0009 ,  B01J37/08 ,  B01J2229/42 ,  C07C51/12 ,  C07C53/08 ,  C07C69/14

Abstract: Process for preparing methyl acetate and/or acetic acid by contacting a carbonylatable reactant selected from dimethyl ether and methanol with carbon monoxide in the presence of a catalyst. The catalyst is a H-mordenite bound with a mesoporous binder selected from silicas, aluminas, silica-aluminas, magnesium silicates and magnesium aluminum silicates.

Abstract translation: 在催化剂存在下使选自二甲醚和甲醇的羰基化反应物与一氧化碳接触来制备乙酸甲酯和/或乙酸的方法。 催化剂是与选自二氧化硅，氧化铝，二氧化硅 - 氧化铝，硅酸镁和硅酸镁铝的介孔粘合剂结合的H-丝光沸石。

公开(公告)号：US20130090507A1

公开(公告)日：2013-04-11

申请号：US13687982

申请日：2012-11-28

Applicant: King Fahd University Of Petrolum and Minerals

Inventor： MOHAMMAD A. ASHRAF ALI

IPC: C07C2/66

CPC classification number: C07C2/66 ,  B01J29/005 ,  B01J29/061 ,  B01J29/064 ,  B01J29/076 ,  B01J29/18 ,  B01J29/26 ,  B01J29/40 ,  B01J29/48 ,  B01J29/80 ,  B01J29/85 ,  B01J37/0009 ,  B01J2229/20 ,  B01J2229/42 ,  C07C6/123 ,  C07C2521/04 ,  C07C2523/28 ,  C07C2529/18 ,  C07C2529/40 ,  C07C2529/80 ,  Y02P20/52 ,  C07C15/08

Abstract: The multiple zeolite catalyst is a catalytic composition used to convert alkylaromatic hydrocarbons to BTX, particularly to commercially valuable xylenes. The catalyst is formed by mixing at least two zeolites selected from mordenite, beta zeolite, ZSM-5, ZSM-11, ZSM-12, ZSM-22, ZSM-23, MFI topology zeolite, NES topology zeolite, EU-1, MAPO-36, SAPO-5, SAPO-11, SAPO-34, and SAPO-41, and adding at least one metal component selected from Group VI of the Periodic Table of the Elements. The two zeolites have different physical and chemical characteristics, such as pore size and acidity. An exemplary catalyst includes mordenite, ZSM-5, and 3 wt % molybdenum. The multiple zeolite catalyst may further be used to convert toluene to mixed xylene isomers, particularly with a ZSM-5:mordenite ratio of 2:1 by weight.

Abstract translation: 多重沸石催化剂是用于将烷基芳族烃转化为BTX，特别是商业上有价值的二甲苯的催化组合物。 催化剂是通过混合至少两种选自丝光沸石，β沸石，ZSM-5，ZSM-11，ZSM-12，ZSM-22，ZSM-23，MFI拓扑沸石，NES拓扑沸石，EU-1，MAPO -36，SAPO-5，SAPO-11，SAPO-34和SAPO-41，并加入至少一种选自元素周期表第Ⅵ族的金属组分。 两种沸石具有不同的物理和化学特性，如孔径和酸度。 示例性催化剂包括丝光沸石，ZSM-5和3重量％的钼。 多沸石催化剂还可用于将甲苯转化为混合二甲苯异构体，特别是ZSM-5：丝光沸石比例为2:1重量比。