公开(公告)号：US20130131402A1

公开(公告)日：2013-05-23

申请号：US13704001

申请日：2011-06-22

Applicant: Stefano Millefanti ,  Vito Tortelli ,  Giuseppe Marchionni

Inventor： Stefano Millefanti ,  Vito Tortelli ,  Giuseppe Marchionni

IPC: C07C17/23

CPC classification number: B01J23/44 ,  B01J21/18 ,  B01J23/42 ,  B01J35/023 ,  B01J35/1023 ,  B01J35/1028 ,  B01J37/0009 ,  B01J37/18 ,  C07C17/23 ,  C07C21/18

Abstract: A catalytic process for the synthesis of trifluoroethylene from chlorotrifluoroethylene which comprises contacting chlorotrifluoroethylene with hydrogen in the presence of a catalyst consisting of palladium or platinum supported on extruded activated carbon.

Abstract translation: 用于从三氟氯乙烯合成三氟乙烯的催化方法，其包括在负载在挤出的活性炭上的由钯或铂组成的催化剂存在下使氯三氟乙烯与氢接触。

公开(公告)号：US08372779B2

公开(公告)日：2013-02-12

申请号：US12597616

申请日：2008-04-23

Applicant: Markus Schubert ,  Ulrich Mueller ,  Stefan Marx

Inventor： Markus Schubert ,  Ulrich Mueller ,  Stefan Marx

IPC: B01J23/00

CPC classification number: B01D53/02 ,  B01D2253/204 ,  B01J20/226 ,  B01J20/28014 ,  B01J20/28042 ,  B01J20/28054 ,  B01J31/1691 ,  B01J31/2239 ,  B01J35/1028 ,  B01J2531/31 ,  B01J2531/62 ,  B01J2531/842 ,  C07C51/418 ,  C07C63/28 ,  C07C63/38

Abstract: The present invention relates to a porous metal organic framework comprising a bidentate organic compound coordinated to a metal ion selected from the group of metals consisting of Al, Fe and Cr, with the bidentate organic compound being derived from a dicarboxylic acid, wherein the framework has a structure whose projection along [001] has a pattern in which each side of a hexagon is bounded by a triangle. The present invention further relates to shaped bodies and a process for preparing the porous metal organic framework and its use.

Abstract translation: 本发明涉及多孔金属有机骨架，其包含与选自Al，Fe和Cr的金属组合的金属离子配位的二齿有机化合物，二齿有机化合物衍生自二羧酸，其中骨架具有 沿[001]的投影具有六边形的每一边由三角形界定的图案的结构。 本发明还涉及成型体及其制备多孔金属有机骨架及其用途的方法。

公开(公告)号：US20120258855A1

公开(公告)日：2012-10-11

申请号：US13333357

申请日：2011-12-21

Applicant: Desmond Marinus Cornelis DEKKER ,  Gerardus Petrus Lambertus NIESEN ,  Daan VLAAR

Inventor： Desmond Marinus Cornelis DEKKER ,  Gerardus Petrus Lambertus NIESEN ,  Daan VLAAR

IPC: B01J37/04 ,  B01J21/06 ,  B01J23/08 ,  B01J23/10 ,  B01J23/46 ,  B01J21/04 ,  B01J29/00 ,  B01J23/75 ,  B01J23/745 ,  B01J23/755 ,  B01J32/00 ,  B01J21/08

CPC classification number: B01J37/0225 ,  B01J23/85 ,  B01J35/023 ,  B01J35/026 ,  B01J35/04 ,  B01J35/06 ,  B01J35/1023 ,  B01J35/1028 ,  B01J37/0207 ,  B25J11/00

Abstract: The invention relates to a process for manufacturing a catalyst support, in which one or more fibres are fed into a mould, said fibre having a diameter in the range of 5-300 microns, and a length over diameter ratio greater than 500. The body in the mould is compressed and then contacted with a mixture comprising a liquid and a carrier material. The liquid is removed from the wetted body to provide a catalyst support comprising an entangled fibre and carrier material. A catalyst can be made using the same process and additionally adding a catalytically active metal with the mixture comprising a liquid and a carrier material. Alternatively a catalyst can be made using the process for manufacturing a catalyst support followed by impregnation with a catalytically active metal.

Abstract translation: 本发明涉及一种用于制造催化剂载体的方法，其中将一种或多种纤维进料到模具中，所述纤维的直径在5-300微米的范围内，并且长度超过直径比大于500.本体 在模具中被压缩，然后与包含液体和载体材料的混合物接触。 将液体从润湿体移除以提供包含缠结纤维和载体材料的催化剂载体。 可以使用相同的方法制备催化剂，并且另外加入含有液体和载体材料的混合物的催化活性金属。 或者，可以使用制备催化剂载体的方法制备催化剂，然后用催化活性金属浸渍。

公开(公告)号：US20110301381A1

公开(公告)日：2011-12-08

申请号：US13049496

申请日：2011-03-16

Applicant: James P. Coleman ,  Martin P. McGrath ,  Fuchen Liu ,  Juan Arhancet

Inventor： James P. Coleman ,  Martin P. McGrath ,  Fuchen Liu ,  Juan Arhancet

IPC: C07F9/28 ,  B82Y30/00

CPC classification number: B01J27/24 ,  B01J21/18 ,  B01J23/40 ,  B01J23/72 ,  B01J27/22 ,  B01J35/023 ,  B01J35/1023 ,  B01J35/1028 ,  B01J37/084 ,  B82Y30/00 ,  C07C209/68 ,  C07C249/02 ,  C07F9/3813 ,  Y02P20/582 ,  C07C251/06

Abstract: This invention relates to the field of heterogeneous catalysis, and more particularly to catalysts including carbon supports having formed thereon compositions which comprise a transition metal in combination with nitrogen and/or carbon. The invention further relates to the fields of catalytic oxidation and dehydrogenation reactions, including the preparation of secondary amines by the catalytic oxidation of tertiary amines and the preparation of carboxylic acids by the catalytic dehydrogenation of alcohols.

Abstract translation: 本发明涉及非均相催化领域，更具体地说涉及包括其上形成的碳载体的催化剂，其包含与氮和/或碳组合的过渡金属。 本发明还涉及催化氧化和脱氢反应的领域，包括通过叔胺的催化氧化制备仲胺和通过醇的催化脱氢制备羧酸。

公开(公告)号：US08043991B2

公开(公告)日：2011-10-25

申请号：US12639729

申请日：2009-12-16

Applicant: Ta Yen Ching ,  Jeffery Gee ,  Ruthann M. Hickox

Inventor： Ta Yen Ching ,  Jeffery Gee ,  Ruthann M. Hickox

IPC: B01J31/02

CPC classification number: B01J21/08 ,  B01J29/0308 ,  B01J29/041 ,  B01J31/0209 ,  B01J31/0225 ,  B01J31/0231 ,  B01J31/0232 ,  B01J31/0274 ,  B01J31/0275 ,  B01J31/1633 ,  B01J35/1023 ,  B01J35/1028 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1061 ,  B01J2229/32 ,  C07C5/2562 ,  C07C2531/025 ,  C07C2531/04 ,  C07C11/02

Abstract: A process for selectively making 2-alkenes from a NAO using a mesoporous catalyst that has been surface modified with a Brönsted acid compound. The Brönsted acid compound has a reactive silane connector, an organic linking group, and a Brönsted acid group. The mesoporous catalyst has an average pore diameter in a range of about 12 to about 100 Angstroms and a surface area of between about 400 to about 1400 m2/gram.

Abstract translation: 使用已经用布朗斯台德酸化合物表面改性的介孔催化剂从NAO选择性制备2-烯烃的方法。 布朗斯台德酸化合物具有反应性硅烷连接剂，有机连接基团和布朗斯台德酸基团。 介孔催化剂的平均孔径在约12至约100埃的范围内，表面积为约400至约1400m 2 / g。

公开(公告)号：US20110152069A1

公开(公告)日：2011-06-23

申请号：US13038100

申请日：2011-03-01

Applicant: José de Jesús DÍAZ VELÁSQUEZ ,  Yazmin Yaneth AGAMEZ ,  Luis Ignacio RODRÍGUEZ ,  Orlando HERNÁNDEZ ,  Oscar Andres VILLALBA VARÓN ,  José Alexander JIMENEZ SÁNCHEZ

Inventor： José de Jesús DÍAZ VELÁSQUEZ ,  Yazmin Yaneth AGAMEZ ,  Luis Ignacio RODRÍGUEZ ,  Orlando HERNÁNDEZ ,  Oscar Andres VILLALBA VARÓN ,  José Alexander JIMENEZ SÁNCHEZ

IPC: B01J27/04 ,  B01J37/02 ,  B01J37/08

CPC classification number: B01J21/18 ,  B01J27/043 ,  B01J35/1028 ,  B01J37/0201 ,  B01J37/0203 ,  B01J37/0207 ,  C10G1/08 ,  C10G1/086

Abstract: A method to obtain a catalyst of transition metals supported on a carbonaceous material, via impregnation, with a solution of metal-thiourea complex, obtained from precursor salts. The formation of the sulfur on the surface of the support occurs through the thermal decomposition of the complex. The obtained catalysts are applicable toward the direct liquefaction of coal.

Abstract translation: 通过浸渍得到载体在碳质材料上的过渡金属催化剂与由前体盐获得的金属 - 硫脲络合物溶液的方法。 通过复合物的热分解，发生在载体表面上的硫的形成。 得到的催化剂适用于煤的直接液化。

公开(公告)号：US07923583B2

公开(公告)日：2011-04-12

申请号：US12392122

申请日：2009-02-25

Applicant: Masahiro Hoshino ,  Nobufumi Watanabe ,  Keisuke Sugita

Inventor： Masahiro Hoshino ,  Nobufumi Watanabe ,  Keisuke Sugita

IPC: C07C45/33 ,  C07C35/08

CPC classification number: B01J35/1061 ,  B01J23/38 ,  B01J23/70 ,  B01J23/75 ,  B01J29/0308 ,  B01J35/1023 ,  B01J35/1028 ,  B01J37/0018 ,  B01J37/033 ,  B01J37/10 ,  B01J2229/32 ,  C07C29/50 ,  C07C45/33 ,  C07C2601/14 ,  C07C35/08 ,  C07C49/403

Abstract: An object of the present invention is to provide a method capable of producing a cycloalkanol and/or a cycloalkanone with a favorable selectivity coefficient by oxidizing a cycloalkane with a favorable conversion ratio.Disclosed is a method for producing a cycloalkanol and/or a cycloalkanone, which comprises oxidizing a cycloalkane with oxygen in the presence of a mesoporous silica which contains at least one transition metal and has been also subjected to contact treatment with an amine and/or ammonia. Preferably, a crystal obtained by mixing a compound containing the metal, a silicon compound, a structure-directing agent and water is subjected to contact treatment with an amine and/or ammonia and then fired to obtain a mesoporous silica, and a cycloalkane is oxidized with oxygen in the presence of the mesoporous silica.

Abstract translation: 本发明的目的是提供一种通过以良好的转化率氧化环烷烃，能够制备具有良好选择性系数的环烷醇和/或环烷酮的方法。 公开了一种制备环烷醇和/或环烷酮的方法，其包括在含有至少一种过渡金属的介孔二氧化硅的存在下用氧氧化环烷烃，并且还已经用胺和/或氨进行接触处理 。 优选将通过混合含有金属，硅化合物，结构导向剂和水的化合物得到的晶体与胺和/或氨进行接触处理，然后烧制以获得介孔二氧化硅，并且环烷烃被氧化 在介孔二氧化硅存在下用氧气。

公开(公告)号：US07875742B2

公开(公告)日：2011-01-25

申请号：US12712793

申请日：2010-02-25

Applicant: Stuart Leon Soled ,  Andrzej Malek ,  James Clarke Vartuli ,  Jennifer Schaefer Feeley ,  Sabato Miseo ,  Shifang Luo ,  Richard Henry Schlosberg ,  Joseph Ernest Baumgartner ,  Christine E. Kliewer ,  Steven T. Ragomo

Inventor： Stuart Leon Soled ,  Andrzej Malek ,  James Clarke Vartuli ,  Jennifer Schaefer Feeley ,  Sabato Miseo ,  Shifang Luo ,  Richard Henry Schlosberg ,  Joseph Ernest Baumgartner ,  Christine E. Kliewer ,  Steven T. Ragomo

IPC: C07C69/74

CPC classification number: C08F8/04 ,  B01J23/462 ,  B01J23/75 ,  B01J35/0053 ,  B01J35/0066 ,  B01J35/1023 ,  B01J35/1028 ,  B01J35/1061 ,  B01J37/0203 ,  B01J37/08 ,  B01J37/082 ,  C07C29/19 ,  C07C67/303 ,  C07C69/75

Abstract: The present invention is directed to a process for hydrogenating one or more organic compounds especially unsaturated organic compounds by bringing the compound into contact with a hydrogen-containing gas in the presence of a catalyst, which comprises one or more catalytically active metals applied to a porous catalyst support. The one or more catalytically active metals having been derived via a decomposed organic complex of the metal on the support, in particular amine complexes of the metal. The decomposed complex may be treated with hydrogen to activate the catalyst before use as a hydrogenation catalyst.

Abstract translation: 本发明涉及一种通过在催化剂存在下使化合物与含氢气体接触来氢化一种或多种有机化合物，特别是不饱和有机化合物的方法，所述催化剂包含一种或多种催化活性金属施加到多孔 催化剂载体。 一种或多种催化活性金属已经通过载体上的金属的分解的有机络合物，特别是金属的胺络合物衍生。 分解的络合物可以用氢处理以在使用前活化催化剂作为氢化催化剂。

公开(公告)号：US20110003074A1

公开(公告)日：2011-01-06

申请号：US12919745

申请日：2009-02-26

Applicant: Ralf Böhling ,  Jörg Pastre ,  Katrin Freitag

Inventor： Ralf Böhling ,  Jörg Pastre ,  Katrin Freitag

IPC: B05D5/00

CPC classification number: B01J20/20 ,  B01J21/18 ,  B01J23/745 ,  B01J35/1028 ,  B01J37/0238 ,  B09C1/002 ,  C01B32/354 ,  C01P2006/12 ,  C02F1/283 ,  C02F1/288 ,  C02F1/705 ,  C02F2103/06 ,  C23C14/22 ,  C23C14/228

Abstract: A process for the preparation of a metal-doped support material. The metal-doped support material comprises at least one metal in elemental form on at least one support material which is based on carbon by gas-phase deposition of at least one compound comprising the at least one metal in the oxidation state 0 in combination with carbon monoxide on the at least one support material and thermal decomposition of the at least one compound comprising the at least one metal in the oxidation state 0 in order to obtain the at least one metal in elemental form. During and after the deposition and the decomposition, the support material is not brought into contact with reducing compounds during the preparation.

Abstract translation: 一种制备掺杂金属的载体材料的方法。 金属掺杂的载体材料在至少一种载体材料上包含至少一种元素形式的金属，所述至少一种载体材料基于碳，通过气相沉积至少一种包含至少一种处于氧化态的金属0的化合物与碳的组合 至少一种载体材料上的一氧化物和包含至少一种处于氧化态0的金属的至少一种化合物的热分解，以获得至少一种元素形式的金属。 在沉积和分解期间和之后，在制备过程中，载体材料不与还原化合物接触。

公开(公告)号：US20100247407A1

公开(公告)日：2010-09-30

申请号：US12446201

申请日：2007-10-19

Applicant: Olivier Larcher ,  Emmanuel Rohart ,  Stephan Verdier ,  Heather Bradshaw ,  Clive Butler ,  Deborah Harris ,  Mairead Feeley ,  Guillaume Criniere

Inventor： Olivier Larcher ,  Emmanuel Rohart ,  Stephan Verdier ,  Heather Bradshaw ,  Clive Butler ,  Deborah Harris ,  Mairead Feeley ,  Guillaume Criniere

IPC: B01D53/94 ,  B01J21/08

CPC classification number: B01D53/944 ,  B01D53/9418 ,  B01D53/945 ,  B01D2251/2062 ,  B01D2251/2067 ,  B01D2255/1021 ,  B01D2255/2061 ,  B01D2255/2063 ,  B01D2255/2065 ,  B01D2255/20707 ,  B01D2255/20715 ,  B01D2255/2073 ,  B01D2255/20738 ,  B01D2255/20769 ,  B01D2255/20776 ,  B01D2255/20792 ,  B01D2255/2092 ,  B01D2255/2094 ,  B01D2255/30 ,  B01D2257/404 ,  B01D2258/012 ,  B01D2259/4566 ,  B01J21/063 ,  B01J21/066 ,  B01J21/08 ,  B01J21/12 ,  B01J23/002 ,  B01J23/06 ,  B01J23/10 ,  B01J23/14 ,  B01J23/28 ,  B01J23/30 ,  B01J23/34 ,  B01J23/60 ,  B01J23/626 ,  B01J23/63 ,  B01J23/652 ,  B01J23/6562 ,  B01J23/745 ,  B01J23/888 ,  B01J23/894 ,  B01J23/8993 ,  B01J35/002 ,  B01J35/10 ,  B01J35/1023 ,  B01J35/1028 ,  B01J37/0248 ,  B01J37/03 ,  B01J2523/00 ,  C01B13/363 ,  C01G39/006 ,  C01G41/006 ,  C01G45/006 ,  C01G49/009 ,  C01P2006/12 ,  C01P2006/13 ,  Y02T10/22 ,  Y02T10/24 ,  B01J2523/31 ,  B01J2523/41 ,  B01J2523/48 ,  B01J2523/36 ,  B01J2523/69 ,  B01J2523/72 ,  B01J2523/842 ,  B01J2523/47 ,  B01J2523/3712 ,  B01J2523/27 ,  B01J2523/43

Abstract: Compositions useful for treating the exhaust gases of diesel engines contain zirconium oxide, silicon oxide and at least one oxide of at least one element M selected from among titanium, aluminum, tungsten, molybdenum, cerium, iron, tin, zinc, and manganese, in the following mass proportions of these different elements: silicon oxide: 5%-30%; M-element oxide: 1%-20%; the balance being zirconium oxide; such compositions also have an acidity, as measured by the methylbutynol test, of at least 90% and are prepared by placing a zirconium compound, a silicon compound, at least one M-element compound and a basic compound in a liquid medium, thereby generating a precipitate, maturing the precipitate in a liquid medium and separating and calcining the precipitate.

Abstract translation: 用于处理柴油发动机废气的组合物含有氧化锆，氧化硅和选自钛，铝，钨，钼，铈，铁，锡，锌和锰中的至少一种元素M的至少一种氧化物， 这些不同元素的以下质量比例：氧化硅：5％-30％; M元素氧化物：1％-20％; 余量为氧化锆; 这种组合物还具有至少90％的通过甲基丁炔测试测得的酸度，并且通过在液体介质中放置锆化合物，硅化合物，至少一种M元素化合物和碱性化合物来制备，由此产生 沉淀物，使沉淀物在液体介质中成熟并分离和煅烧沉淀物。