摘要:
The material for proppant and method for producing the same relate to the chemistry of high-molecular weight compounds, and more particularly, to polymer materials with high requirements for physical and mechanical properties, for instance, for the production of proppants, i.e., propping granules, used in the oil and gas production by a method of hydraulic fracturing of formation. The technical result achieved by implementation of the present invention is an increase in thermal strength of the proppant material providing for a compressive strength of at least 150 MPa at a temperature of not less than 100° C. The method consists in the following. A mixture of oligocyclopentadienes is obtained by heating dicyclopentadiene (DCPD) to a temperature of 150-220° C. and holding at this temperature for 15-360 minutes. The oligomerization of dicyclopentadiene occurs. The mixture of oligomers is cooled down to 20-50° C., and polymer stabilizers, radical initiators, methacrylates and a catalyst are sequentially added thereto. The resultant polymer matrix is heated up to a temperature of 50-340° C. and is held at this temperature for 1-360 minutes, and thereafter is cooled down to room temperature. A metathesis polymerization (MP) and radical polymerization (RP) cross-linkage of the mixture of oligocyclopentadienes with methacrylic esters occurs.
摘要:
The present invention relates to a method for preparing a super absorbent polymer. The method for preparing a super absorbent polymer according to the present invention can provide a super absorbent resin exhibiting fast absorption rate and high saline flow conductivity while having excellent absorption properties such as a centrifuge retention capacity and an absorbency under pressure, by using the polycarboxylic acid-based copolymer under pulverization of the hydrous gel phase polymer.
摘要:
Disclosed herein are particulate core-shell materials, comprising a core comprising a polyurethane; and a shell comprising a polyacrylate, wherein the shell coats the core. Also disclosed are methods of making particulate core-shell materials, and aqueous dispersions and inkjet ink compositions comprising the same.
摘要:
A water-based ink for ink-jet recording includes: a self-dispersible pigment having an anionic group; water; a water-soluble resin; and an anionic surfactant, wherein the water-soluble resin is an ABA-type triblock copolymer which has a polymer block A composed only of methyl methacrylate and methacrylic acid and a polymer block B composed only of benzyl methacrylate and methacrylic acid; which has a weight average molecular weight of 3,000 to 30,000; which has an acid value of 90 mgKOH/g to 200 mgKOH/g; and which is partially or completely neutralized.
摘要:
Polymeric compositions are provided that include a 1,2,5-pentanetriol trialkylester plasticizer. The plasticizer has low odor, has good compatibility with a variety of polymers such as hydrophilic polymeric materials, and can be formed from renewable resources. Further, the plasticizer can be used at temperatures often encountered during hot melt processing of polymeric compositions.
摘要:
A method for the reversible crosslinking of, for example, adhesives or coating materials, and a composition stable on storage at room temperature for implementing the crosslinking reaction. The reversible crosslinking method allows very rapid crosslinking even at a low first temperature, and undoing of the crosslinks at higher temperatures, thereby recovering thermoplastic processability and, for example, allowing the originally bonded substrates to be parted from one another again easily. A particular aspect is that a plurality of cycles of crosslinking and undoing of the crosslinks are possible with the present system. A feature of the system used for the reversible crosslinking is that it contains two components, A and B, where component A is a compound having at least two protected dithioester functionalities, preferably cyanodithioester functionalities, and component B is a compound having at least two diene functionalities.
摘要:
The embodiments of the invention provide a polymerizable oligomer and a photoresist composition including the polymerizable oligomer, wherein the polymerizable oligomer contains a polymerizable double bond and a hydrophilic group.
摘要:
A copolymer includes the structure unit represented by the following Chemical formula 1 and the structure unit represented by the following Chemical formula 2, where R1 and R2 each, independently represent hydrogen atoms or methyl groups, and n represents a value in the range of from 1 to 90, where R3 represents a hydrogen atom or a methyl group and L represents an alkylene group having 2 to 18 carbon atoms.
摘要:
Pressure-sensitive adhesives that have good performance characteristics under typical use conditions and that later can be degraded and/or removed readily under basic conditions are provided. More specifically, the pressure-sensitive adhesives contain a copolymeric (meth)acrylic-based elastomeric material prepared from a polymerizable material that contains a (meth)acrylate monomer having both a (meth)acryloyl group plus an ester linkage that is not part of a (meth)acryloyl group.
摘要:
[Object] Materials may be used as adhesives and the like which may be cured with active energy rays, and cured products may be easily removed and separated from substrates by a method such as a hygrothermal degradation method as required such as when the products are to be disposed of.[Solution] A (meth)acrylic block copolymer includes a methacrylic polymer block (A) having at least one or more active energy ray curable groups represented by General Formula (1) below, and a (meth)acrylic polymer block (B) having no active energy ray curable groups, (wherein R1 is a methyl group, R2 and R3 are each independently a hydrocarbon group having 1 to 6 carbon atoms, and n is an integer of 1 to 5).