公开(公告)号：US20050215818A1

公开(公告)日：2005-09-29

申请号：US11078680

申请日：2005-03-11

Applicant: Hiromi Yunoki ,  Michio Tanimoto

Inventor： Hiromi Yunoki ,  Michio Tanimoto

IPC: B01J23/00 ,  B01J23/30 ,  B01J23/885 ,  B01J23/887 ,  B01J23/888 ,  B01J35/00 ,  B01J35/02 ,  B01J37/00 ,  B01J37/02 ,  C07C51/25 ,  C07C51/16 ,  C08F2/00

CPC classification number: B01J23/002 ,  B01J23/30 ,  B01J23/885 ,  B01J23/8877 ,  B01J23/8885 ,  B01J35/0006 ,  B01J35/002 ,  B01J35/0073 ,  B01J35/023 ,  B01J37/0018 ,  B01J37/0219 ,  B01J37/0223 ,  B01J37/0228 ,  B01J37/0236 ,  B01J37/0244 ,  B01J2523/00 ,  C07C51/252 ,  C07C57/04 ,  B01J2523/17 ,  B01J2523/55 ,  B01J2523/68 ,  B01J2523/69

Abstract: An object of the present invention is to provide: a catalyst for production of acrylic acid which catalyst is so high active as to give a still higher selectivity of acrylic acid (which is the objective product) or a long-catalytic-life-time catalyst for production of acrylic acid which catalyst is so high active as to be able to give a high acrylic acid yield while suppressing the temperature rise of the oxidation reaction to a low one; and processes for production of acrylic acid using these catalysts. As a means of achieving this object, a catalyst according to the present invention for production of acrylic acid comprises an oxide and/or a composite oxide as an essential catalytic component, wherein the oxide and/or the composite oxide has a metal element composition shown by general formula (1): MoaVbWcCudOx   (1) (wherein: when a=12, then 1≦b≦14, 0≦c≦12, 0≦d≦10, and 0

Abstract translation: 本发明的目的是提供：用于制备丙烯酸的催化剂，该催化剂具有如此高的活性，以产生更高的丙烯酸（目标产物）的选择性或长催化寿命催化剂 为了生产丙烯酸，该催化剂具有如此高的活性，能够在将氧化反应的温度上升抑制在低温的同时产生高的丙烯酸收率; 以及使用这些催化剂生产丙烯酸的方法。 作为实现该目的的手段，根据本发明的用于生产丙烯酸的催化剂包含氧化物和/或复合氧化物作为必需催化组分，其中氧化物和/或复合氧化物具有所示的金属元素组成 通过通式（1）：<？in-line-formula description =“In-line formula”end =“lead”？> Mo _{a （1）<？in-line-formula description =“In-line Formulas”end =“tail”？>（ 其中：当a = 12时，则1 <= b <= 14,0 <= c <= 12,0 <= d <= 10和0}

公开(公告)号：US20040023798A1

公开(公告)日：2004-02-05

申请号：US10398394

申请日：2003-04-07

Inventor： Gerd Kaibel ,  Thomas Domschke ,  Mathias Haake ,  Harald Keller ,  Ekkehard Schwab ,  Carsten Oost

IPC: B01J023/40

CPC classification number: B01J33/00 ,  B01J35/02 ,  B01J37/0217 ,  B01J37/0225 ,  B01J37/0228 ,  B01J37/0244 ,  C07C29/172 ,  C07C29/17 ,  C07C33/025 ,  C07C31/207

Abstract: The invention provides a microstructured, self-cleaning, catalytically active surface with elevations and depressions, comprising a catalytically active material in the depressions. The invention additionally provides a process for producing a microstructured, self-cleaning, catalytically active surface and a catalyst molding having such a surface in which a support surface is powder coated with particles having a size of from 0.05 to 200 nullm and is subsequently coated with a catalytically active material. In a preferred embodiment of the process, (a) if desired, a base layer of metal is applied to a support surface by layer deposition from solution, (b) on the support surface or, if appropriate, on the surface of the base layer, a first layer of metal containing embedded particles with a size of from 0.05 to 200 nullm is applied by layer deposition from a solution containing these particles in dispersed form, and (c) the first layer is coated with a catalytically active second layer.

Abstract translation: 本发明提供具有升高和凹陷的微结构化，自清洁，催化活性的表面，其在凹陷中包含催化活性材料。 本发明另外提供了一种用于生产微结构化，自清洁，催化活性表面的方法和具有这样一种表面的催化剂模制物，其中支撑表面被粉末涂覆有尺寸为0.05至200μm的颗粒并随后涂覆有 催化活性材料。 在该方法的一个优选实施方案中，（a）如果需要，通过从溶液中沉积层，（b）在支撑表面上，或者如果合适的话，在基底层的表面上将基底金属层施加到支撑体表面 通过从包含这些分散形式的这些颗粒的溶液通过层沉积施加含有尺寸为0.05至200μm的嵌入颗粒的第一金属层，和（c）第一层涂覆有催化活性的第二层。

公开(公告)号：US06613225B1

公开(公告)日：2003-09-02

申请号：US09719135

申请日：2001-01-26

Applicant: Atsushi Toyoda ,  Tatsuo Kanki

Inventor： Atsushi Toyoda ,  Tatsuo Kanki

IPC: C02F130

CPC classification number: C02F1/32 ,  B01J21/063 ,  B01J35/002 ,  B01J35/004 ,  B01J37/0228 ,  C02F1/725 ,  C02F2101/16 ,  C02F2101/30 ,  C02F2305/10 ,  C03C17/007 ,  C03C17/256 ,  C03C2217/42 ,  C03C2217/71 ,  Y02W10/37

Abstract: A first object is to provide an apparatus for photocatalytic reaction with high treating efficiency and treatment ability that is not degraded with an elapse of operating time and a second object is to provide a method for simply and efficiently immobilizing a photocatalyst on a support. The first invention is to immobilize (coat) a photocatalyst on a surface of a support, continuously supply solution to be treated in atmosphere in thin film shape on the surface of the immobilized photocatalyst, and irradiate the photocatalyst surface with light for causing photocatalytic reaction to occur. A second invention is a method for immobilizing a photocatalyst on a support by using alkali metal silicate as a binding agent, comprising: a first step for coating and immobilizing an aqueous solution of the alkali metal silicate on the support; a second step for coating and immobilizing a powdered photocatalyst on the alkali metal silicate after the first step; and a third step for curing the coated and immobilized photocatalyst after the second step.

Abstract translation: 第一个目的是提供一种具有高处理效率和处理能力的光催化反应装置，其在经过时间后不会降解，第二个目的是提供简单有效地将光催化剂固定在载体上的方法。 第一发明是在载体表面上固定（涂布）光催化剂，在固定的光催化剂的表面上连续供给薄膜状的待处理溶液，并将光催化剂表面用光引发光催化反应 发生。 第二发明是通过使用碱金属硅酸盐作为粘合剂将光催化剂固定在载体上的方法，包括：将碱金属硅酸盐的水溶液涂布并固定在载体上的第一步骤; 在第一步骤之后将粉状光催化剂涂覆并固定在碱金属硅酸盐上的第二步骤; 以及在第二步骤之后固化涂覆和固定的光催化剂的第三步骤。

公开(公告)号：US06497851B1

公开(公告)日：2002-12-24

申请号：US08576198

申请日：1995-12-21

Applicant: Zhicheng Hu ,  Ronald M. Heck ,  Rudolf M. Smaling ,  Alan R. Amundsen

Inventor： Zhicheng Hu ,  Ronald M. Heck ,  Rudolf M. Smaling ,  Alan R. Amundsen

IPC: F01N310

CPC classification number: B01D53/945 ,  B01D53/944 ,  B01D53/9477 ,  B01D2255/102 ,  B01D2255/1023 ,  B01D2255/1025 ,  B01D2255/204 ,  B01D2255/2042 ,  B01D2255/20715 ,  B01D2255/908 ,  B01J23/44 ,  B01J23/58 ,  B01J23/63 ,  B01J35/0006 ,  B01J35/04 ,  B01J37/0228 ,  F01N3/0864 ,  F01N3/103 ,  F01N3/2006 ,  F01N3/2828 ,  F01N13/009 ,  F01N13/0097 ,  F01N2370/00 ,  F02B1/04 ,  Y02T10/22 ,  Y02T10/26

Abstract: An exhaust gas treatment apparatus and method for its use includes an upstream catalyst and a downstream catalyst. The upstream catalyst contains a catalytic metal effective at least for the oxidation of hydrocarbons in the exhaust gas stream, and preferably contains a palladium catalytic component and contains substantially no oxygen storage components, i.e., oxides of cerium, cobalt, iron, magnesium, molybdenum, nickel, praseodymium, tungsten and vanadium, but the downstream catalyst includes an oxygen storage component. Preferably, the upstream catalyst is a close-coupled catalyst. The downstream catalyst may be an underfloor catalyst or a close-coupled catalyst, in which case there is, preferably, an additional, underfloor catalyst.

Abstract translation: 废气处理装置及其使用方法包括上游催化剂和下游催化剂​​。 上游催化剂含有至少有效地用于废气流中的烃的氧化的催化金属，并且优选含有钯催化组分，并且基本上不含有储氧组分，即铈，钴，铁，镁，钼， 镍，镨，钨和钒，但是下游催化剂​​包括储氧组分。 优选地，上游催化剂是紧密耦合的催化剂。 下游催化剂​​可以是地板下催化剂或紧密耦合的催化剂，在这种情况下，优选地有另外的地板下催化剂。

公开(公告)号：US20020002112A1

公开(公告)日：2002-01-03

申请号：US09886836

申请日：2001-06-21

Inventor： Keiichi Muramatsu

IPC: B01J023/00

CPC classification number: B01J37/0244 ,  B01J21/063 ,  B01J35/0013 ,  B01J35/002 ,  B01J35/004 ,  B01J37/0228 ,  B01J37/0232

Abstract: This invention relates to a photocatalyst and a manufacturing method therefore, in which the adhesion to a support is increased and a baking step is simplified. The photocatalyst comprises the support and a metallic oxide layer provided on the support by applying and baking a colloidal solution including at least a metallic oxide precursor on the support, wherein the metallic oxide layer includes a high density metallic oxide layer of a less porous structure and a low density metallic oxide layer of a more porous structure.

Abstract translation: 本发明涉及一种光催化剂及其制造方法，其中对载体的粘附性增加并且烘烤步骤简化。 所述光催化剂包括载体和金属氧化物层，所述金属氧化物层通过在载体上施加和烘烤至少包含金属氧化物前体的胶体溶液而形成，其中所述金属氧化物层包括具有较小孔结构的高密度金属氧化物层， 更多孔结构的低密度金属氧化物层。

公开(公告)号：US20240278213A1

公开(公告)日：2024-08-22

申请号：US18693297

申请日：2022-07-29

Applicant: DR. JOHANNES HEIDENHAIN GmbH

Inventor： Peter SPECKBACHER ,  Wolfgang SEDLMEIER ,  Martina DOWY ,  Réka CSIKI ,  Bernhard WUNDERLICH

IPC: B01J21/06 ,  B01J23/26 ,  B01J35/30 ,  B01J35/39 ,  B01J35/40 ,  B01J37/02 ,  B01J37/34 ,  C03C17/36 ,  C23C14/00 ,  C23C14/08

CPC classification number: B01J21/063 ,  B01J23/26 ,  B01J35/39 ,  B01J35/393 ,  B01J35/40 ,  B01J37/0228 ,  B01J37/0244 ,  B01J37/347 ,  C03C17/3605 ,  C03C17/3649 ,  C23C14/0057 ,  C23C14/083 ,  C03C2218/155

Abstract: A photocatalytic layer arrangement includes a carrier substrate on which a chromium layer with a defined nitrogen content is deposited. A titanium oxide layer having the formula TiOx (x=2-4) is grown on the chromium layer, and the anatase phase of the titanium oxide layer with respect to the rutile phase of the titanium oxide layer has a percentage in the range of 30%-90%.

公开(公告)号：US20240149257A1

公开(公告)日：2024-05-09

申请号：US18549506

申请日：2022-03-22

Applicant: UMICORE AG & CO. KG

Inventor： Meike Antonia GOTTHARDT ,  Jan SCHOENHABER ,  Naina DEIBEL ,  Gabriela KUCEROVA

IPC: B01J35/00 ,  B01D53/94 ,  B01J23/00 ,  B01J23/63 ,  B01J35/56 ,  B01J37/02 ,  B01J37/08 ,  F01N3/022 ,  F01N3/20 ,  F01N3/28

CPC classification number: B01J35/19 ,  B01D53/9454 ,  B01J23/002 ,  B01J23/63 ,  B01J35/56 ,  B01J37/0228 ,  B01J37/088 ,  F01N3/0222 ,  F01N3/2066 ,  F01N3/2803 ,  B01D2255/1023 ,  B01D2255/1025 ,  B01D2255/2061 ,  B01D2255/2063 ,  B01D2255/2066 ,  B01D2255/407 ,  B01D2255/9037 ,  B01D2255/908 ,  B01D2255/9155 ,  B01D2258/014 ,  B01J2523/36 ,  B01J2523/3706 ,  B01J2523/3712 ,  B01J2523/3718 ,  B01J2523/48 ,  F01N2510/063 ,  F01N2510/0682

Abstract: The present invention is directed to a wall-flow filter which is used in particular in exhaust gas systems of vehicles driven by gasoline engines. The filter has three-way activity and filters fine particles, which result from the combustion of gasoline, from the exhaust gas stream. The invention also relates to a method for producing a corresponding filter and to the preferred use thereof.

公开(公告)号：US11969720B1

公开(公告)日：2024-04-30

申请号：US18110525

申请日：2023-02-16

Applicant: King Faisal University

Inventor： Mohamed Shaker Sayed Adam ,  Amel Musa Taha ,  Mohamed M. Makhlouf

IPC: B01J21/06 ,  B01J23/06 ,  B01J31/22 ,  B01J31/38 ,  B01J35/00 ,  B01J37/02 ,  B01J37/03 ,  B01J37/04 ,  B01J37/34 ,  C07C45/29 ,  C07C51/295

CPC classification number: B01J31/2217 ,  B01J21/063 ,  B01J23/06 ,  B01J31/38 ,  B01J35/0013 ,  B01J37/0221 ,  B01J37/0228 ,  B01J37/0244 ,  B01J37/035 ,  B01J37/04 ,  B01J37/343 ,  C07C45/29 ,  C07C51/295 ,  B01J2231/40 ,  B01J2231/763 ,  B01J2531/004 ,  B01J2531/16

Abstract: A method of forming TiO2—ZnO nanoparticles coated by a copper (II) complex includes forming a mononuclear copper complex by treating a ligand with Cu2+ ions; and immobilizing the mononuclear copper complex on TiO2—ZnO nanoparticles to obtain the TiO2—ZnO nanoparticle coated by the copper (II) complex. The TiO2—ZnO nanoparticles coated by a copper (II) complex thus produced have improved catalytic effectiveness and increased efficiency by reducing catalytic reaction time and temperature, particularly in methods of catalyzing oxidation of an alcohol or of catalyzing decarboxylative bromination of an acid.

公开(公告)号：US11969712B2

公开(公告)日：2024-04-30

申请号：US17979571

申请日：2022-11-02

Applicant: TOYOTA JIDOSHA KABUSHIKI KAISHA

Inventor： Naoki Kumatani ,  Akira Morikawa ,  Masaoki Iwasaki ,  Miho Hatanaka ,  Taizo Yoshinaga ,  Masahide Miura ,  Takahiro Hayashi

IPC: B01J21/04 ,  B01D53/94 ,  B01J21/06 ,  B01J23/10 ,  B01J23/44 ,  B01J23/63 ,  B01J35/00 ,  B01J35/23 ,  B01J35/30 ,  B01J37/02

CPC classification number: B01J23/63 ,  B01D53/94 ,  B01J23/10 ,  B01J35/23 ,  B01J35/394 ,  B01J37/0221 ,  B01J37/0228 ,  B01J37/0244 ,  B01D2255/1023 ,  B01D2255/2065 ,  B01D2255/908

Abstract: A catalyst for purification of exhaust gas in which Pd-based nanoparticles and ceria nanoparticles are supported on a composite metal oxide support containing alumina, ceria, and zirconia, wherein a molar ratio (Ce/Pd) of Ce and Pd supported on the support is 1 to 8, a proximity α between Pd and Ce is 0.15 to 0.50, wherein the proximity α is determined, based on Pd and Ce distribution maps in an element mapping image of energy dispersive X-ray analysis, by the following formula (1):








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a Pd dispersity after a heat-resistance test at 1050° C. for 25 hours is 0.8% or more.

公开(公告)号：US11964264B1

公开(公告)日：2024-04-23

申请号：US18218365

申请日：2023-07-05

Applicant: King Faisal University

Inventor： Mohamed Shaker Sayed Adam ,  Amel Musa Taha ,  Mohamed M. Makhlouf

IPC: B01J21/06 ,  B01J23/06 ,  B01J31/22 ,  B01J31/38 ,  B01J35/00 ,  B01J37/02 ,  B01J37/03 ,  B01J37/04 ,  B01J37/34 ,  C07C45/29 ,  C07C51/295

CPC classification number: B01J31/2217 ,  B01J21/063 ,  B01J23/06 ,  B01J31/38 ,  B01J35/0013 ,  B01J37/0221 ,  B01J37/0228 ,  B01J37/0244 ,  B01J37/035 ,  B01J37/04 ,  B01J37/343 ,  C07C45/29 ,  C07C51/295 ,  B01J2231/40 ,  B01J2231/763 ,  B01J2531/004 ,  B01J2531/16

Abstract: A method of forming TiO2—ZnO nanoparticles coated by a copper (II) complex includes forming a mononuclear copper complex by treating a ligand with Cu2+ ions; and immobilizing the mononuclear copper complex on TiO2—ZnO nanoparticles to obtain the TiO2—ZnO nanoparticle coated by the copper (II) complex. The TiO2—ZnO nanoparticles coated by a copper (II) complex thus produced have improved catalytic effectiveness and increased efficiency by reducing catalytic reaction time and temperature, particularly in methods of catalyzing oxidation of an alcohol or of catalyzing decarboxylative bromination of an acid.