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公开(公告)号:US11225535B2
公开(公告)日:2022-01-18
申请号:US17042243
申请日:2019-05-21
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Thomas P. Klun , Zeba Parkar , John M. Riedesel , Richard J. Pokorny , Chad M. Amb , Benjamin R. Coonce , Robert S. Clough , Tianyu Wu , Saswata Chakraborty , Yongshang Lu , Benjamin C. MacMurray , Ian Dailey , David B. Olson
IPC: C08F2/46 , C08F2/50 , C08G61/04 , C08F220/18 , C08F2/44 , C08F290/06 , C08G18/44 , B33Y70/00 , C08K5/00 , C08K5/3437 , B29C64/129 , B33Y10/00 , B33Y30/00 , C08G18/67
Abstract: The present disclosure provides a photopolymerizable composition. The photopolymerizable composition includes a) 40-60 parts by weight of a monofunctional (meth)acrylate monomer, per 100 parts of the total photopolymerizable composition; b) a photoinitiator; and c) a polymerization reaction product of components. A cured homopolymer of the monofunctional (meth)acrylate monomer has a glass transition temperature of 125 degrees Celsius or greater. The polymerization reaction product of components includes i) a diisocyanate; ii) a hydroxy functional methacrylate; iii) a polycarbonate diol; and iv) a catalyst. The polymerization reaction product includes a polyurethane methacrylate polymer. Often, the polycarbonate diol has a number average molecular weight of greater than 1,000 grams per mole (g/mol) or a weighted average of all polycarbonate diols present in the components has a Mn of greater than 1,000 g/mol; alternatively, the polyurethane methacrylate polymer has a weight average molecular weight of 8,000 g/mol or greater. An article is also provided including the photopolymerizable composition reaction product. Further, the present disclosure provides articles and methods of making articles. Methods are additionally provided, including receiving, by a manufacturing device having one or more processors, a digital object comprising data specifying an article; and generating, with the manufacturing device by an additive manufacturing process, the article based on the digital object. A system is also provided, including a display that displays a 3D model of an article; and one or more processors that, in response to the 3D model selected by a user, cause a 3D printer to create a physical object of an article.
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公开(公告)号:US20210364682A1
公开(公告)日:2021-11-25
申请号:US17044685
申请日:2019-06-07
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Gregg A. Ambur , Benjamin G. Sonnek , Jo A. Etter , Timothy L. Wong , Thomas P. Klun , Richard J. Pokorny , Benjamin R. Coonce , Douglas S. Dunn , Henry A. Kostalik, IV , Christopher S. DeGraw , John R. Jacobson , Chunjie Zhang , Jung-Sheng Wu
Abstract: An optical assembly including an optical element insert molded directly onto an optical stack is provided. The optical stack includes an optical film and may include a liner with the optical film being disposed between the optical element and the liner. The liner, if included, is removable from the optical film without substantial damage to the optical film. An outermost layer of the optical film may be diffusion bonded to a major surface of the optical element. The optical film includes a protective coating having an average thickness of no more than 30 micrometers. The protective coating includes an at least partially cured composition. The composition includes 70 to 96 weight percent of urethane (meth)acrylate compound having an average (meth)acrylate functionality of 2 to 9.5, and 2 to 20 weight percent of (meth)acrylate monomer having a (meth)acrylate functionality of 1 to 2.
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公开(公告)号:US11054558B2
公开(公告)日:2021-07-06
申请号:US16342239
申请日:2017-11-28
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Adam D. Miller , Donovan G. Weiblen, III , William Blake Kolb , Thomas P. Klun , Richard J. Pokorny
Abstract: A photochromic article is provided, containing a structural component, a fluid in contact with the structural component, and a photochromic organic dye in contact with the fluid; and a barrier layer disposed on the structural component to provide a barrier for the fluid and photochromic organic dye. The structural component includes a polymeric material that is porous, includes a plurality of cavities, or a combination thereof. A method of changing a light transmission of a photochromic article is provided. A method of forming a photochromic article is also provided.
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公开(公告)号:US20210171701A1
公开(公告)日:2021-06-10
申请号:US17052221
申请日:2019-06-27
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Thomas P. Klun , Zeba Parkar , John M. Riedesel , Richard J. Pokorny , Chad M. Amb , Benjamin R. Coonce , Robert S. Clough , Tianyu Wu , Saswata Chakraborty , Yongshang Lu , Benjamin C. Mac Murray , Ahmed S. Abuelyaman , Karl J.L. Geisler , Jodi L. Connell , Ta-Hua Yu
IPC: C08G18/44 , B33Y10/00 , B33Y40/20 , B33Y70/00 , B33Y80/00 , A61C7/08 , A61C13/00 , A61C7/00 , C08G18/22 , C08G18/24 , C08K5/3437 , C08K5/00 , C08G18/32 , C08G64/30 , B29C71/00 , B29C71/02 , B29C71/04
Abstract: The present disclosure provides an orthodontic article including the reaction product of the polymerizable composition. Further, the present disclosure provides polymerizable compositions and methods of making an orthodontic article. The method includes obtaining a polymerizable composition and selectively curing the polymerizable composition to form an orthodontic article. Further, methods are provided, including receiving, by a manufacturing device having one or more processors, a digital object comprising data specifying an orthodontic article; and generating, with the manufacturing device by an additive manufacturing process, the orthodontic article based on the digital object. A system is also provided, including a display that displays a 3D model of an orthodontic article; and one or more processors that, in response to the 3D model selected by a user, cause a 3D printer to create a physical object of an orthodontic article.
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公开(公告)号:US10738224B2
公开(公告)日:2020-08-11
申请号:US15753222
申请日:2016-08-15
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Jacob P. Johnson , Fred B. McCormick , Adam J. Meuler , Richard J. Pokorny , Daniel J. Schmidt
IPC: B32B27/36 , B32B7/12 , B32B27/34 , B32B27/28 , B32B27/20 , B32B27/08 , B32B27/32 , C09J123/22 , C09J7/38 , C09J7/22 , C09J11/04 , C08K5/19 , C08K9/06 , C08K9/04 , C08L23/22 , C08K3/34 , H01L51/52
Abstract: A barrier adhesive composition comprising a resin system and organically modified nanoclay. The resin system comprises (a) a first polyisobutylene resin having a viscosity average molecular weight of about 300,000 to about 500,000 g/mol, (b) a second polyisobutylene resin having a viscosity average molecular of about 700,000 to about 900,000 g/mol and (c) tackifier.
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公开(公告)号:US20190310404A1
公开(公告)日:2019-10-10
申请号:US16468808
申请日:2017-12-13
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Thomas P. Klun , Richard J. Pokorny , Benjamin R. Coonce , Douglas S. Dunn , Gregg A. Ambur , Henry A. Kostalik, IV , John R. Jacobson , Christopher S. DeGraw , Chunjie Zhang
IPC: G02B5/28 , B32B27/08 , B32B27/36 , B32B7/12 , B32B37/02 , C08G77/442 , C09J183/10 , C08J5/12
Abstract: A method of making an infrared-reflecting optically transparent assembly comprises: coating a curable composition onto a major surface of an optically transparent thermoplastic polymer film; at least partially curing the curable composition, which may be optionally at least partially dried, to provide a thermoformable composite film; and laminating the thermoformable composite film to an infrared-reflecting multilayer optical film to provide the infrared-reflecting optically transparent assembly. The curable composition comprises urethane (meth)acrylate compound, (meth)acrylate monomer, and silicone (meth)acrylate. The infrared-reflecting optically transparent assembly and methods of including it in an infrared-reflecting lens assembly are also disclosed.
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公开(公告)号:US20180362553A1
公开(公告)日:2018-12-20
申请号:US16114401
申请日:2018-08-28
Applicant: 3M Innovative Properties Company
Inventor: Thomas P. Klun , Mark A. Roehrig , Joseph C. Spagnola , Alan K. Nachtigal , Charles J. Hoy , Richard J. Pokorny , William J. Hunt , Jason T. Petrin , Paul B. Armstrong , Suresh S. Iyer
IPC: C07F7/18
CPC classification number: C07F7/1804 , C08F222/22 , C08K3/36 , C08K5/3435 , C08K9/06 , C09C3/12 , C09D7/62
Abstract: Compounds having hindered amine and oxyalkyl amine light stabilizers can mitigate the adverse effects of actinic radiation, such as visible and ultraviolet light, in particular on substrates such as glass or ceramic substrates. Polymers derived from such compounds. Nanoparticles, substrates, such as glass or ceramic substrates, or both nanoparticles and substrates, having such compounds affixed thereto. Articles containing at least one of such polymers, nanoparticles, substrates, or compounds.
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公开(公告)号:US20180362279A1
公开(公告)日:2018-12-20
申请号:US16072684
申请日:2017-01-20
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Yuko Yoshida , Yorinobu Takamatsu , Daniel J. Theis , Richard J. Pokorny , Christine M. Andres
IPC: B65H18/28 , C09D11/101 , C09J133/08 , B32B7/14 , B32B7/06
Abstract: Web-wound rolls with a web edge treatment by printable adhesive compositions and processes to make the same are provided. The web-wound rolls include a substrate web having at least two web edges. One or more quantities of adhesive are disposed and subsequent curing adjacent to one or both of the web edges. The substrate web is wound upon itself in multiple revolutions about a central core, and each revolution is held substantially separate from the next by the adhesive.
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公开(公告)号:US20170307786A1
公开(公告)日:2017-10-26
申请号:US15528796
申请日:2015-12-01
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Naota Sugiyama , Chikara Abe , Richard J. Pokorny , Kristy A. Gillette
CPC classification number: G02B1/14 , C08K3/22 , C08K3/36 , C08K9/04 , C08K2201/003 , C08K2201/011 , C09D4/00 , C09D7/62 , C09D7/67 , G02B5/30 , G02B5/3041 , G02B5/3066 , G02F1/133536
Abstract: Article comprising a reflective polarizer having a first major surface, and an exposed hardcoat on the first major surface, the hardcoat comprising binder, wherein the hardcoat has a thickness less than 500 nanometers and has a scratch rating of not greater than 1 as determined by the Linear Abrasion Test in the Examples. Articles described herein are useful, for example, for applications benefiting from reflective polarizers having brightness enhancement properties (e.g., use with liquid crystal display (LCD) devices).
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公开(公告)号:US20170051164A1
公开(公告)日:2017-02-23
申请号:US15308408
申请日:2015-04-27
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Raghunath Padiyath , Naota Sugiyama , Richard J. Pokorny , Ta-Hua Yu , Gregory F. King , Stephen P. Maki , Robert R. Owings
IPC: C09D7/12 , C09D133/08 , C03C17/32 , C03C17/00 , C03C17/25 , C03C17/30 , C09D175/04 , C09D175/16
CPC classification number: C09D175/04 , C03C17/009 , C03C17/25 , C03C17/30 , C03C17/322 , C03C17/326 , C03C2217/29 , C03C2217/445 , C03C2217/478 , C03C2217/78 , C03C2218/114 , C03C2218/32 , C08K3/36 , C08K9/04 , C08K2003/2231 , C08K2003/2296 , C08K2201/005 , C09D5/00 , C09D7/67 , C09D133/08 , C09D175/16
Abstract: Article comprising a substrate having a first major surface, wherein the major surface has an emissivity not greater than 0.2 and an exposed hardcoat on the first major surface, the hardcoat comprising binder, wherein the hardcoat has a thickness less than 200 nanometers and has a scratch rating of not greater than 1 as determined by the Linear Abrasion Test in the Examples. Articles described herein are useful, for example, for sun control window films having insulative properties. Such films are applied on the interior or exterior surfaces of automotive windows or building fenestrations
Abstract translation: 该制品包括具有第一主表面的基底,其中主表面具有不大于0.2的发射率和在第一主表面上的暴露的硬涂层,所述硬涂层包含粘合剂,其中所述硬涂层具有小于200纳米的厚度并且具有刮痕 通过实施例中的线性磨损试验确定的不大于1的等级。 本文所述的物品例如对于具有绝缘性能的太阳控制窗膜是有用的。 这种膜被应用在汽车窗户的内部或外部表面或建筑开窗上
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