公开(公告)号：US20160008756A1

公开(公告)日：2016-01-14

申请号：US14744334

申请日：2015-06-19

申请人： Edward W. Corcoran, JR. ,  Pavel Kortunov ,  Charanjit S. Paur ,  Peter I. Ravikovitch ,  Yu Wang ,  Avelino Corma Canos ,  Fernando Rey Garcia ,  Susana Valencia Valencia ,  Angel Cantín Sanz ,  Miguel Palomino Roca

发明人： Edward W. Corcoran, JR. ,  Pavel Kortunov ,  Charanjit S. Paur ,  Peter I. Ravikovitch ,  Yu Wang ,  Avelino Corma Canos ,  Fernando Rey Garcia ,  Susana Valencia Valencia ,  Angel Cantín Sanz ,  Miguel Palomino Roca

IPC分类号： B01D53/22 ,  B01J20/18 ,  B01D53/02 ,  C01B17/16 ,  C01C1/12 ,  C01B21/04 ,  C01B39/48 ,  C01B3/50

CPC分类号： C01B39/48 ,  B01D53/02 ,  B01D53/04 ,  B01D53/0407 ,  B01D53/0462 ,  B01D53/047 ,  B01D53/228 ,  B01D53/229 ,  B01D71/028 ,  B01D2253/108 ,  B01D2256/10 ,  B01D2256/12 ,  B01D2256/16 ,  B01D2256/18 ,  B01D2256/20 ,  B01D2256/22 ,  B01D2256/24 ,  B01D2256/245 ,  B01D2256/26 ,  B01D2257/302 ,  B01D2257/304 ,  B01D2257/40 ,  B01D2257/404 ,  B01D2257/406 ,  B01D2257/50 ,  B01D2257/504 ,  B01D2257/70 ,  B01D2257/702 ,  B01D2257/7022 ,  B01D2257/80 ,  B01J20/18 ,  B01J20/3078 ,  B01J29/70 ,  B01J29/86 ,  B01J29/89 ,  C01B3/508 ,  C01B17/167 ,  C01B21/0466 ,  C01B37/002 ,  C01B37/007 ,  C01B37/02 ,  C01B39/06 ,  C01B39/08 ,  C01B39/12 ,  C01B2203/0405 ,  C01B2210/0018 ,  C01C1/12 ,  C07C1/20 ,  C07C1/322 ,  C07C2/76 ,  C07C29/00 ,  C07C41/01 ,  C07C2529/70 ,  C07C2529/76 ,  C07C2529/78 ,  Y02C10/08

摘要： This invention refers to a microporous crystalline material of zeolitic nature that has, in its calcined state and in the absence of defects in its crystalline matrix manifested by the presence of silanols, the empirical formula x(M1/nXO2):yYO2:gGeO2:(1−g)SiO2 in which M is selected between H+, at least one inorganic cation of charge +n, and a mixture of both, X is at least one chemical element of oxidation state +3, Y is at least one chemical element with oxidation state +4 different from Si, x takes a value between 0 and 0.2, both included, y takes a value between 0 and 0.1, both included, g takes a value between 0 and 0.5, both included that has been denoted ITQ-55, as well as a method for its preparation. This invention also relates to uses of the crystalline material of zeolitic nature for adsorption of fluid components, membrane separation of fluid components, storage of fluid components, and catalysis of various conversion reactions.

公开(公告)号：US20160008754A1

公开(公告)日：2016-01-14

申请号：US14744248

申请日：2015-06-19

申请人： Edward W. Corcoran, JR. ,  Pavel Kortunov ,  Charanjit S. Paur ,  Peter I. Ravikovitch ,  Yu Wang ,  Avelino Corma Canos ,  Fernando Rey Garcia ,  Susana Valencia Valencia ,  Angel Cantín Sanz ,  Miguel Palomino Roca

发明人： Edward W. Corcoran, JR. ,  Pavel Kortunov ,  Charanjit S. Paur ,  Peter I. Ravikovitch ,  Yu Wang ,  Avelino Corma Canos ,  Fernando Rey Garcia ,  Susana Valencia Valencia ,  Angel Cantín Sanz ,  Miguel Palomino Roca

IPC分类号： B01D53/04 ,  C01B3/50 ,  B01D53/047 ,  C01B39/48

CPC分类号： C01B39/48 ,  B01D53/02 ,  B01D53/04 ,  B01D53/0407 ,  B01D53/0462 ,  B01D53/047 ,  B01D53/228 ,  B01D53/229 ,  B01D71/028 ,  B01D2253/108 ,  B01D2256/10 ,  B01D2256/12 ,  B01D2256/16 ,  B01D2256/18 ,  B01D2256/20 ,  B01D2256/22 ,  B01D2256/24 ,  B01D2256/245 ,  B01D2256/26 ,  B01D2257/302 ,  B01D2257/304 ,  B01D2257/40 ,  B01D2257/404 ,  B01D2257/406 ,  B01D2257/50 ,  B01D2257/504 ,  B01D2257/70 ,  B01D2257/702 ,  B01D2257/7022 ,  B01D2257/80 ,  B01J20/18 ,  B01J20/3078 ,  B01J29/70 ,  B01J29/86 ,  B01J29/89 ,  C01B3/508 ,  C01B17/167 ,  C01B21/0466 ,  C01B37/002 ,  C01B37/007 ,  C01B37/02 ,  C01B39/06 ,  C01B39/08 ,  C01B39/12 ,  C01B2203/0405 ,  C01B2210/0018 ,  C01C1/12 ,  C07C1/20 ,  C07C1/322 ,  C07C2/76 ,  C07C29/00 ,  C07C41/01 ,  C07C2529/70 ,  C07C2529/76 ,  C07C2529/78 ,  Y02C10/08

摘要： This invention refers to a microporous crystalline material of zeolitic nature that has, in its calcined state and in the absence of defects in its crystalline matrix manifested by the presence of silanols, the empirical formula x(M1/nXO2):yYO2:gGeO2:(1−g)SiO2 in which M is selected between H+, at least one inorganic cation of charge +n, and a mixture of both, X is at least one chemical element of oxidation state +3, Y is at least one chemical element with oxidation state +4 different from Si, x takes a value between 0 and 0.2, both included, y takes a value between 0 and 0.1, both included, g takes a value between 0 and 0.5, both included that has been denoted ITQ-55, as well as a method for its preparation. This invention also relates to uses of the crystalline material of zeolitic nature for adsorption of fluid components, membrane separation of fluid components, storage of fluid components, and catalysis of various conversion reactions.

公开(公告)号：US08702974B2

公开(公告)日：2014-04-22

申请号：US13395834

申请日：2010-09-02

申请人： Gordon Edward Wilson ,  Norman Macleod ,  Elaine Margaret Vass ,  Antonio Chica Lara ,  Avelino Corma Canos ,  Yonhy Saavedra Lopez

发明人： Gordon Edward Wilson ,  Norman Macleod ,  Elaine Margaret Vass ,  Antonio Chica Lara ,  Avelino Corma Canos ,  Yonhy Saavedra Lopez

IPC分类号： C10G45/06 ,  C10G45/04

CPC分类号： B01D53/52 ,  B01D53/75 ,  B01D53/8603 ,  B01D2253/112 ,  B01D2255/20 ,  B01D2255/20753 ,  B01D2257/304 ,  B01D2257/306 ,  B01D2257/308 ,  B01D2258/06 ,  B01D2259/40 ,  B01J20/06 ,  B01J20/28004 ,  B01J20/28019 ,  B01J20/2803 ,  B01J20/3007 ,  B01J20/3028 ,  B01J20/3042 ,  B01J20/3078 ,  B01J20/3204 ,  B01J20/3236 ,  C01B3/38 ,  C01B3/382 ,  C01B2203/0233 ,  C01B2203/0244 ,  C01B2203/0811 ,  C01B2203/0827 ,  C01B2203/1058 ,  C01B2203/1235 ,  C01B2203/1241 ,  C01B2203/1247 ,  C01B2203/127 ,  C01B2203/148 ,  C10G45/08 ,  C10G2300/1025 ,  C10G2300/1044 ,  C10G2300/1051 ,  C10G2300/1059 ,  C10G2300/1081 ,  C10G2300/202 ,  C10G2300/207 ,  C10G2300/705 ,  C10L3/10 ,  C10L3/102

摘要： A process for desulphurizing hydrocarbons includes passing a mixture of hydrocarbon and hydrogen over a hydrodesulphurization catalyst to convert organosulphur compounds present in the hydrocarbon to hydrogen sulphide, passing the resulting mixture over a hydrogen sulphide sorbent including zinc oxide to reduce the hydrogen sulphide content of the mixture, and passing the hydrogen sulphide-depleted mixture over a further desulphurization material. The further desulphurization material includes one or more nickel compounds, a zinc oxide support material, and optionally one or more promoter metal compounds of iron, cobalt, copper and precious metals. The desulphurization material has a nickel content in the range 0.3 to 20% by weight and a promoter metal compound content in the range 0 to 10% by weight.

摘要翻译： 一种用于脱硫烃的方法包括使烃和氢气的混合物通过加氢脱硫催化剂以将存在于烃中的有机硫化合物转化为硫化氢，将所得混合物通过包含氧化锌的硫化氢吸附剂，以降低混合物中的硫化氢含量 ，并将硫化氢贫乏的混合物通过另外的脱硫材料。 进一步的脱硫材料包括一种或多种镍化合物，氧化锌载体材料和任选的一种或多种铁，钴，铜和贵金属的助催化剂金属化合物。 脱硫材料的镍含量为0.3〜20重量％，助催化剂金属化合物的含量为0〜10重量％。

公开(公告)号：US20120232322A1

公开(公告)日：2012-09-13

申请号：US13395834

申请日：2010-09-02

申请人： Gordon Edward Wilson ,  Norman Macleod ,  Elaine Margaret Vass ,  Antonio Chica Lara ,  Avelino Corma Canos ,  Yonhy Saavedra Lopez

发明人： Gordon Edward Wilson ,  Norman Macleod ,  Elaine Margaret Vass ,  Antonio Chica Lara ,  Avelino Corma Canos ,  Yonhy Saavedra Lopez

IPC分类号： C07C7/148 ,  C10J3/82 ,  C10G29/04

CPC分类号： B01D53/52 ,  B01D53/75 ,  B01D53/8603 ,  B01D2253/112 ,  B01D2255/20 ,  B01D2255/20753 ,  B01D2257/304 ,  B01D2257/306 ,  B01D2257/308 ,  B01D2258/06 ,  B01D2259/40 ,  B01J20/06 ,  B01J20/28004 ,  B01J20/28019 ,  B01J20/2803 ,  B01J20/3007 ,  B01J20/3028 ,  B01J20/3042 ,  B01J20/3078 ,  B01J20/3204 ,  B01J20/3236 ,  C01B3/38 ,  C01B3/382 ,  C01B2203/0233 ,  C01B2203/0244 ,  C01B2203/0811 ,  C01B2203/0827 ,  C01B2203/1058 ,  C01B2203/1235 ,  C01B2203/1241 ,  C01B2203/1247 ,  C01B2203/127 ,  C01B2203/148 ,  C10G45/08 ,  C10G2300/1025 ,  C10G2300/1044 ,  C10G2300/1051 ,  C10G2300/1059 ,  C10G2300/1081 ,  C10G2300/202 ,  C10G2300/207 ,  C10G2300/705 ,  C10L3/10 ,  C10L3/102

摘要： A process for desulphurising hydrocarbons includes the steps of (i) passing a mixture of hydrocarbon and hydrogen over a hydrodesulphurisation catalyst to convert organosulphur compounds present in the hydrocarbon to hydrogen sulphide, (ii) passing the resulting mixture over a hydrogen sulphide sorbent including zinc oxide to reduce the hydrogen sulphide content of the mixture and (iii) passing the hydrogen sulphide-depleted mixture over a further desulphurisation material, where the further desulphurisation material includes one or more nickel compounds, a zinc oxide support material, and optionally one or more promoter metal compounds selected from one or more compounds of iron, cobalt, copper and precious metals, the desulphurisation material having a nickel content in the range 0.3 to 20% by weight and a promoter metal content in the range 0 to 10% by weight.

摘要翻译： 一种用于脱硫烃的方法包括以下步骤：（i）将烃和氢气的混合物通过加氢脱硫催化剂以将存在于烃中的有机硫化合物转化成硫化氢，（ii）将所得混合物通过包含氧化锌的硫化氢吸附剂 以减少混合物中的硫化氢含量，和（iii）将贫硫化氢混合物通过另一脱硫材料，其中进一步的脱硫材料包括一种或多种镍化合物，氧化锌载体材料和任选的一种或多种助催化剂 选自一种或多种铁，钴，铜和贵金属化合物的金属化合物，所述脱硫材料的镍含量在0.3至20重量％的范围内，助催化剂金属含量在0至10重量％的范围内。

公开(公告)号：US08236262B2

公开(公告)日：2012-08-07

申请号：US12921936

申请日：2009-02-25

申请人： Gavin Potter ,  Gordon Edward Wilson ,  Norman Macleod ,  Antonio Chica Lara ,  Avelino Corma Canos ,  Yonhy Saavedra Lopez

发明人： Gavin Potter ,  Gordon Edward Wilson ,  Norman Macleod ,  Antonio Chica Lara ,  Avelino Corma Canos ,  Yonhy Saavedra Lopez

IPC分类号： B01D53/00 ,  B01J8/00 ,  B01J23/00 ,  B01J21/00 ,  B01J20/00 ,  B01J29/00 ,  B01J37/00 ,  C01B7/00 ,  C01G45/00 ,  C01G25/00

CPC分类号： B01J23/80 ,  B01J20/02 ,  B01J20/0225 ,  B01J20/0237 ,  B01J20/0244 ,  B01J20/0277 ,  B01J20/0296 ,  B01J20/041 ,  B01J20/043 ,  B01J20/06 ,  B01J20/08 ,  B01J20/223 ,  B01J20/2803 ,  B01J20/3204 ,  B01J20/3234 ,  B01J20/3236 ,  B01J37/0063 ,  C10G25/003 ,  C10G45/06 ,  C10G2300/202 ,  C10L3/10 ,  C10L3/102

摘要： A particulate desulfurization material includes one or more nickel compounds, a zinc oxide support material, and one or more alkali metal compounds wherein the nickel content of the material is in the range 0.3 to 10% by weight and the alkali metal content of the material is in the range 0.2 to 10% by weight. A method of making the desulfurization material includes the steps: (i) contacting a nickel compound with a particulate zinc support material and an alkali metal compound to form an alkali-doped composition, (ii) shaping the alkali-doped composition, and (iii) drying, calcining, and optionally reducing the resulting material. The desulfurization material may be used to desulfurize hydrocarbon gas streams with reduced levels of hydrocarbon hydrogenolysis.

摘要翻译： 颗粒状脱硫材料包括一种或多种镍化合物，氧化锌载体材料和一种或多种碱金属化合物，其中所述材料的镍含量在0.3至10重量％的范围内，并且所述材料的碱金属含量为 在0.2至10重量％的范围内。 制备脱硫材料的方法包括以下步骤：（i）使镍化合物与颗粒状锌载体材料和碱金属化合物接触以形成碱掺杂组合物，（ii）使碱掺杂组合物成形，和（iii ）干燥，煅烧和任选地还原所得材料。 脱硫材料可用于以低氢化烃氢解水解硫化烃气流。

公开(公告)号：US20100193399A1

公开(公告)日：2010-08-05

申请号：US12158982

申请日：2006-12-22

申请人： Paul O'connor ,  King Yen Yung ,  Avelino Corma Canos ,  Elbert Arjan De Graaf ,  Erja Päivi Helena Rautiainen

发明人： Paul O'connor ,  King Yen Yung ,  Avelino Corma Canos ,  Elbert Arjan De Graaf ,  Erja Päivi Helena Rautiainen

IPC分类号： C10G11/04 ,  B01J21/06 ,  C10G51/00 ,  C10L1/04

CPC分类号： C10G11/04 ,  B01J21/16 ,  B01J23/007 ,  B01J27/16 ,  B01J27/1804 ,  B01J27/1808 ,  B01J27/236 ,  C10G2300/1033 ,  C10G2300/107 ,  C10G2300/1074 ,  C10G2300/1077 ,  C10G2300/4093 ,  C10G2400/02

摘要： Novel catalytic compositions for cracking of crude oil fractions are disclosed. The catalytic compositions comprise a basic material. When used in a cracking process, preferably a FCC process, the resulting LCO and HCO fractions have desirably low aromatics levels. Further disclosed is a one-stage FCC process using the catalytic composition of the invention. Also disclosed is a two-stage FCC process for maximizing the LCO yield.

摘要翻译： 公开了用于裂解原油馏分的新型催化组合物。 催化组合物包含基本材料。 当用于裂化过程，优选FCC方法时，所得到的LCO和HCO馏分具有期望的低芳烃含量。 进一步公开了使用本发明的催化剂组合物的一级FCC方法。 还公开了用于最大化LCO产率的两阶段FCC方法。

公开(公告)号：US20080103040A1

公开(公告)日：2008-05-01

申请号：US11660995

申请日：2005-08-24

申请人： Mercedes Alvaro Rodriguez ,  Esther Carbonell Llopis ,  Avelino Corma Canos ,  Hermenegildo Garcia Gomez

发明人： Mercedes Alvaro Rodriguez ,  Esther Carbonell Llopis ,  Avelino Corma Canos ,  Hermenegildo Garcia Gomez

IPC分类号： B01J31/12 ,  C07C68/04

CPC分类号： B01J31/0292 ,  B01J31/0284 ,  B01J31/1608 ,  B01J31/1616 ,  B01J31/1633 ,  B01J31/1658 ,  B01J31/1805 ,  B01J31/181 ,  B01J31/2243 ,  B01J2531/0252 ,  B01J2531/31 ,  B01J2531/56 ,  B01J2531/62 ,  B01J2531/842 ,  B01J2531/845 ,  C07B41/00 ,  C07B41/06 ,  C07C68/04 ,  C07D317/38 ,  Y02P20/142 ,  C07C69/96

摘要： The invention relates to a catalytic composition comprising: a first component which is at least a component with one or more metals from groups 3A, 4A, 5A, 6A, 7A, 8, 1B, 2B, 3B, 4B; and a second component selected from (1) at least one ionic liquid which consists of a compound formed by cations and anions and which is a liquid at ambient temperature, (ii) a matrix to which the first component is bound or on which it is supported, and (iii) a combination of the two. The invention relates to the use of said catalytic composition in a method for the insertion of carbon dioxide into an organic compound and, preferably, a compound selected from epoxides, acetals and orthoesters. The invention also relates to catalytic compositions comprising said metallic compounds.

摘要翻译： 本发明涉及一种催化组合物，其包括：第一组分，其至少是具有来自3A，4A，5A，6A，7A，8，1B，2B，3B，4B族的一种或多种金属的组分; 和选自（1）至少一种离子液体的第二组分，所述离子液体由阳离子和阴离子形成的化合物组成，并且在环境温度下为液体，（ii）第一组分与其结合的基质， 支持，和（iii）两者的组合。 本发明涉及所述催化组合物在将二氧化碳插入有机化合物，优选选自环氧化物，缩醛和原酸酯的化合物的方法中的用途。 本发明还涉及包含所述金属化合物的催化组合物。

公开(公告)号：US20070261995A1

公开(公告)日：2007-11-15

申请号：US11662762

申请日：2005-09-15

申请人： Avelino Corma Canos ,  Fernando Rey Garcia ,  Susana Valencia Valencia

发明人： Avelino Corma Canos ,  Fernando Rey Garcia ,  Susana Valencia Valencia

IPC分类号： B01D53/04 ,  B01J29/035 ,  B01J29/70 ,  C01B37/02 ,  C01B39/04 ,  C07C7/12

CPC分类号： C07C7/12 ,  B01D53/02 ,  B01D2253/108 ,  B01D2257/702 ,  B01D2257/80 ,  C01B39/145

摘要： The invention relates to a method of separating the components of a mixture. The inventive method is characterised in that it comprises the following steps: (a) the bringing into contact of the components of a mixture selected from (i) at least two hydrocarbons, (ii) a mixture containing at least nitrogen and oxygen, and (iii) at least one hydrocarbon and water, with an ITQ-29 zeolite material having a T(IV)/T(III) ratio of greater than 7, whereby T(IV) denotes one or more tetravalent elements and T(III) denotes one or more trivalent elements; (b) preferential adsorption of one or more of the components by the ITQ-29 zeolite material and (c) recovery of one or more of the components, preferably for the separation of hydrocarbon mixtures, such as linear or branched olefins from paraffins.

摘要翻译： 本发明涉及一种分离混合物组分的方法。 本发明的方法的特征在于其包括以下步骤：（a）使选自（i）至少两种烃的混合物的组分与（ii）至少含有氮和氧的混合物和（ iii）至少一种烃和水，其具有T（IV）/ T（III）比大于7的ITQ-29沸石材料，由此T（IV）表示一种或多种四价元素，并且T（III）表示 一种或多种三价元素; （b）通过ITQ-29沸石材料优先吸附一种或多种组分，和（c）回收一种或多种组分，优选用于从石蜡中分离烃混合物，例如直链或支链烯烃。

公开(公告)号：US07108802B2

公开(公告)日：2006-09-19

申请号：US11026328

申请日：2004-12-30

申请人： Avelino Corma Canos ,  Maria Sales Galletero Pedroche ,  Mercedes Alvaro Rodríguez ,  Hermenegildo García Gómez

发明人： Avelino Corma Canos ,  Maria Sales Galletero Pedroche ,  Mercedes Alvaro Rodríguez ,  Hermenegildo García Gómez

IPC分类号： C01B39/00 ,  C01B37/00 ,  C08G61/00 ,  C09K11/06 ,  H01L51/54

CPC分类号： C08G61/02 ,  C08G61/10 ,  C09B57/10 ,  C09K11/02 ,  C09K11/06 ,  C09K11/08 ,  C09K2211/1029 ,  C09K2211/1425 ,  C09K2211/187 ,  C09K2211/188 ,  H01L51/0038 ,  H01L51/0079 ,  H01L51/5012 ,  H01L51/5237 ,  H01L51/56 ,  Y10S428/917 ,  Y10T428/249953 ,  Y10T428/249967

摘要： An electroluminescent material comprising at least one electroluminescent compound supported in a matrix, wherein the matrix is selected from among microporous and mesoporous materials, selected from among zeolites, porous oxides, molecular sieves, silicoaluminophosphates and aluminosilicates, the electroluminescent compound is selected from among polymers derived from polyphenylenevinylene, complexes of IIIA group metal ions with 8-hydroxyquinoline and combinations thereof, and where the electroluminescent compound is housed in interior spaces of the matrix. These electroluminescent materials possess excellent properties in terms of chemical stability towards the environment (oxygen, humidity, CO2, etc.), durability (number of electroluminescent cycles under aerobic conditions), control of the state of aggregation (isolated or being associated in pairs or more) of aromatics.

摘要翻译： 一种电致发光材料，其包含负载在基质中的至少一种电致发光化合物，其中所述基质选自选自沸石，多孔氧化物，分子筛，硅铝磷酸盐和铝硅酸盐的微孔和介孔材料，所述电致发光化合物选自衍生 来自聚亚苯基亚乙烯基，IIIA族金属离子与8-羟基喹啉的络合物及其组合，并且其中电致发光化合物容纳在基质的内部空间中。 这些电致发光材料在对环境（氧气，湿度，CO 2等）的化学稳定性方面具有优异的性能，耐久性（有氧条件下的电致发光循环次数），聚集状态的控制 （孤立或相关联或成对）芳烃。

公开(公告)号：US20060036120A1

公开(公告)日：2006-02-16

申请号：US11200534

申请日：2005-08-09

申请人： Avelino Corma Canos ,  Rafael Castaneda Sanchez ,  Vicente Fornes Segui ,  Fernando Rey Garcia

发明人： Avelino Corma Canos ,  Rafael Castaneda Sanchez ,  Vicente Fornes Segui ,  Fernando Rey Garcia

IPC分类号： C07C2/68

CPC分类号： C01B39/085 ,  C01B39/06 ,  C01B39/12 ,  C10G11/05 ,  C10G2300/1088 ,  C10G2300/1096 ,  C10G2400/30

摘要： The invention relates to a porous crystalline material (ITQ-24), the preparation method thereof and the use of same in the catalytic conversion of organic compounds. More specifically, the invention relates to a synthetic porous crystalline material which is characterised in that it is formed by tetrahedrally coordinated atoms which are interconnected by means of oxygens. Said material, which comprises a unit cell containing 56 tetrahedrally coordinated atoms, is known as ITQ-24. Moreover, in the calcined anhydrous state, the material has chemical formula nM1/pXO2: YO2, wherein: X is at least one trivalent element, Y is at least one tetravalent element, n is between 0 and 0.2 and M is at least one charge compensation cation in oxidation state p.

摘要翻译： 本发明涉及多孔结晶材料（ITQ-24），其制备方法及其在有机化合物的催化转化中的用途。 更具体地说，本发明涉及一种合成多孔结晶材料，其特征在于它由四面体配位的原子形成，这些原子通过氧相互连接。 所述材料包括含有56个四面体配位原子的晶胞，称为ITQ-24。 此外，在煅烧无水状态下，该材料具有化学式nM 1 / p XO 2：YO 2 N，其中：X至少为 一个三价元素，Y是至少一种四价元素，n在0和0.2之间，M是氧化态p中的至少一种电荷补偿阳离子。