公开(公告)号：US4678519A

公开(公告)日：1987-07-07

申请号：US793346

申请日：1985-10-31

申请人： Joseph Schapira ,  Victor Ken ,  Denis Thery ,  Stephane Jelodin

发明人： Joseph Schapira ,  Victor Ken ,  Denis Thery ,  Stephane Jelodin

IPC分类号： C23C22/78 ,  C23C22/80 ,  C23C22/82

CPC分类号： C23C22/80

摘要： Method of zinc phosphatization of substrates essentially based on iron, zinc or their alloys, comprising successively:(1) one or several alkaline degreasing steps,(2) one or several rinsing steps with running city water,(3) an activating and refining step,(4) the zinc phosphatization step proper,(5) one or several rinsing steps with water,(6) preferably, a passivating final rinsing step, particularly by means of salts of hexavalent chromium or mixtures of hexavalent chromium and trivalent chromiumcharacterized by the fact that, to carry out the activating and refining step, recourse is had to a bath comprising, besides the conventional constituents among which are particularly at least one Jernstedt salt in a proportion corresponding to about 1 to 100 ppm of titanium, a proportion of 10 to 700 ppm, preferably from 50 to 200 ppm, of at least one alkane-phosphonic acid of formula ##STR1## or at least one of the alkali or ammonium salts corresponding to the abovesaid alkane-phosphonic acids, the pH of the bath being from 7 to 9.5, preferably from 7.5 to 9.

摘要翻译： 基本上基于铁，锌或其合金的基底的锌磷化的方法，包括：（1）一个或几个碱性脱脂步骤，（2）一个或多个漂洗步骤，其中有一个或几个漂洗步骤，（3）活化和精炼步骤 ，（4）适当的锌磷化步骤，（5）用水进行一次或几次漂洗步骤，（6）优选钝化最终漂洗步骤，特别是通过六价铬的盐或六价铬和三价铬的混合物，其特征在于 为了进行活化和精炼步骤，除了其中特别是至少一种与约1至100ppm钛的比例相对应的杰恩斯特德盐的常规成分之外，还要进行洗涤，其比例为 10至700ppm，优选50至200ppm的至少一种式（I）的烷烃 - 膦酸或至少一种对应于上述烷烃磷的碱金属盐或铵盐 皂酸，浴的pH为7至9.5，优选7.5至9。

公开(公告)号：US4647315A

公开(公告)日：1987-03-03

申请号：US750573

申请日：1985-07-01

申请人： Arvind Parthasarathi ,  Ned W. Polan

发明人： Arvind Parthasarathi ,  Ned W. Polan

IPC分类号： C23C22/24 ,  C23C22/33 ,  C23C22/68 ,  C23C22/82 ,  C23C22/83 ,  C23F11/00 ,  H05K3/28

CPC分类号： C23C22/33 ,  C23C22/83 ,  H05K3/282 ,  H05K2203/0307 ,  H05K2203/0723

摘要： The present invention relates to a technique for improving the tarnish and oxidation resistance of copper and copper base alloy materials. The technique of the present invention involves immersing the copper or copper base alloy material in a dilute aqueous chromic acid-phosphoric acid solution. After emerging from the chromic acid-phosphoric acid solution, the copper or copper base alloy material is preferably rinsed with a dilute aqueous caustic solution and dried. Copper and copper base alloy materials treated in accordance with the present invention have particular utility in printed circuit applications.

摘要翻译： 本发明涉及一种提高铜和铜基合金材料的抗褪色和抗氧化性能的技术。 本发明的技术包括将铜或铜基合金材料浸入稀酸铬酸 - 磷酸水溶液中。 在从铬酸 - 磷酸溶液中出来之后，铜或铜基合金材料优选用稀的苛性碱水溶液冲洗并干燥。 根据本发明处理的铜和铜基合金材料在印刷电路应用中具有特殊的用途。

公开(公告)号：US4000012A

公开(公告)日：1976-12-28

申请号：US509875

申请日：1974-09-27

申请人： John Burrows ,  James Roger Hargreaves ,  Peter Miles

发明人： John Burrows ,  James Roger Hargreaves ,  Peter Miles

IPC分类号： C23C2/06 ,  C07F9/38 ,  C07F9/48 ,  C23C22/82 ,  C23C22/83 ,  C23F11/167 ,  C25D5/26 ,  C23F7/10

CPC分类号： C23F11/1676 ,  C07F9/3808 ,  C07F9/383 ,  C07F9/4816 ,  C23C22/83

摘要： The corrosion protecting action of iron phosphate or zinc phosphate coatings on mild steel is markedly raised by treating with solutions of .alpha.-aminophosphonic or -phosphonous acids or their water soluble salts. Compounds having more than one amino and more than one phosphonic or phosphonous acid groups are also suitable. Paint films on metal surfaces pretreated in this manner show a considerably better adhesion than on untreated surfaces.

摘要翻译： 通过用α-氨基膦酸或亚磷酸或其水溶性盐的溶液处理，磷酸铁或磷酸锌涂层对软钢的腐蚀保护作用显着提高。 具有多于一个氨基和多于一个膦酸或膦酸基团的化合物也是合适的。 以这种方式预处理的金属表面上的涂膜比未处理的表面显示出相当好的粘合力。

公开(公告)号：US3996074A

公开(公告)日：1976-12-07

申请号：US608428

申请日：1975-08-28

申请人： Lawrence F. Rakestraw ,  Richard W. Bullard ,  John E. Niesse ,  Malcolm F. Bender

发明人： Lawrence F. Rakestraw ,  Richard W. Bullard ,  John E. Niesse ,  Malcolm F. Bender

IPC分类号： B29C70/00 ,  B29C55/00 ,  B29C65/70 ,  B29C65/78 ,  C08J5/12 ,  C09J5/02 ,  C23C22/08 ,  C23C22/82 ,  C23F7/10

CPC分类号： C09J5/02 ,  C23C22/08 ,  C09J2205/306 ,  Y10T428/2942 ,  Y10T428/2945 ,  Y10T428/2947

摘要： A method is disclosed for improving the hydrolytic stability of the adhesive bond between an RFL type organic adhesive and the steel reinforcing element in steel-rubber composite articles. This is accomplished by a pre-treatment of the steel surface before it is coated with the organic adhesive. The pre-treatment is conducted in a continuous operation which includes the sequential steps of: (1) cleaning the metal surface by a vapor degreasing method or by immersion in a detergent containing aqueous bath followed by a hot water rinse; (2) coating the surface with a crystalline or microcrystalline zinc phosphate; (3) rinsing the phosphated steel surface with water; (4) subjecting the phosphated surface to a chromate or chromic acid rinse; (5) rinsing again with deionized water; and finally (6) drying the steel reinforcing element.

摘要翻译： 公开了一种提高钢 - 橡胶复合制品中的RFL型有机粘合剂和钢增强元件之间的粘结剂的水解稳定性的方法。 这是通过在钢表面涂覆有机粘合剂之前进行预处理来实现的。 预处理在连续操作中进行，其包括以下顺序步骤：（1）通过蒸汽脱脂方法或浸入含有水浴的洗涤剂中，随后进行热水冲洗来清洗金属表面; （2）用晶体或微晶磷酸锌涂覆表面; （3）用水冲洗磷化钢表面; （4）使磷酸盐化处理的表面经铬酸盐或铬酸冲洗; （5）用去离子水再次冲洗; 最后（6）干燥钢筋。

公开(公告)号：US1873363A

公开(公告)日：1932-08-23

申请号：US35734329

申请日：1929-04-22

申请人： PARKER RUST PROOF CO

发明人： TANNER ROBERT R

IPC分类号： C23C22/82

CPC分类号： C23C22/82

公开(公告)号：US12080801B2

公开(公告)日：2024-09-03

申请号：US17571858

申请日：2022-01-10

申请人： The Board of Trustees of the University of Illinois

发明人： Edmund G. Seebauer

IPC分类号： H01L29/78 ,  C23C22/82 ,  C23C22/83 ,  C23F1/30 ,  H01L21/3213 ,  H01L21/67 ,  H01L27/12 ,  H01L29/786

CPC分类号： H01L29/7869 ,  C23C22/82 ,  C23C22/83 ,  C23F1/30 ,  H01L21/32134 ,  H01L21/67075 ,  H01L27/1225

摘要： A method of controlling oxygen vacancy concentration in a semiconducting metal oxide includes exposing a treated surface of a crystalline metal oxide to water at a temperature and pressure sufficient to maintain the water in a liquid phase. During the exposure, a portion of the water is adsorbed onto the treated surface and dissociates into atomic oxygen and hydrogen. The atomic oxygen is injected into and diffuses through the crystalline metal oxide, forming isolated oxygen interstitials and oxygen defect complexes. The isolated oxygen interstitials replace oxygen vacancies in the crystalline metal oxide.

公开(公告)号：US20240209513A1

公开(公告)日：2024-06-27

申请号：US18602585

申请日：2024-03-12

申请人： Chemetall GmbH

发明人： Norbert MAURUS ,  Thomas WENDEL ,  Nawel Souad KHELFALLAH

IPC分类号： C23C22/44 ,  C23C22/73 ,  C23C22/76 ,  C23C22/78 ,  C23C22/80 ,  C23C22/82 ,  C23G1/12

CPC分类号： C23C22/44 ,  C23C22/73 ,  C23C22/76 ,  C23C22/78 ,  C23C22/80 ,  C23C22/82 ,  C23G1/125

摘要： Provided herein is a process for the pretreatment of workpieces having a surface of aluminum or aluminum alloys for noncutting forming and/or joining by welding or adhesive bonding to similarly pretreated, precoated workpieces, or to optionally precoated parts. The parts are composed of steel, galvanized steel, and/or alloy-galvanized steel. Further provided herein is a subsequent permanent corrosion-protecting treatment by phosphating, by means of a chromium-free conversion treatment, by application of primer, or by surface coating, where the workpieces are a) pickled by means of an aqueous, acidic solution comprising mineral acid by dipping or spraying, b) rinsed with water, and c) brought into contact with an aqueous, acidic, chromium-free solution including Zr as complex fluoride and Mo as molybdate by application by dipping or spraying. After subsequent drying, a layer weight from 2 to 15 mg/m2 of Zr and Mo is formed.

公开(公告)号：US11948710B2

公开(公告)日：2024-04-02

申请号：US18271622

申请日：2022-03-30

申请人： NIPPON STEEL CORPORATION

发明人： Hiroyasu Fujii ,  Jun Maki ,  Kazutoshi Takeda ,  Akira Akagi ,  Yuya Fujii

IPC分类号： H01F1/147 ,  B32B15/04 ,  B32B15/18 ,  C23C22/03 ,  C23C22/82

CPC分类号： H01F1/147 ,  B32B15/043 ,  B32B15/18 ,  C23C22/03 ,  C23C22/82 ,  B32B2255/06 ,  B32B2255/26 ,  B32B2307/206 ,  B32B2307/704 ,  B32B2307/714 ,  B32B2307/748

摘要： A non-oriented electrical steel sheet according to an embodiment of the present invention is a non-oriented electrical steel sheet including a base metal steel sheet and a composite coating film that is formed on surfaces of the base metal steel sheet and includes Zn-containing phosphate and an organic resin, wherein the non-oriented electrical steel sheet contains crystalline aluminum phosphate showing diffraction lines belonging to ICDD No. 01-074-3256 when the composite coating film is measured by a wide-angle X-ray diffraction method.

公开(公告)号：US11898240B2

公开(公告)日：2024-02-13

申请号：US17216466

申请日：2021-03-29

申请人： ASM IP Holding B.V.

发明人： Andrea Illiberi ,  Giuseppe Alessio Verni ,  Shaoren Deng ,  Daniele Chiappe ,  Eva Tois ,  Marko Tuominen ,  Michael Givens

IPC分类号： C23C16/04 ,  B01J21/02 ,  C23C22/82 ,  C23C22/77 ,  C23C16/40

CPC分类号： C23C16/04 ,  B01J21/02 ,  C23C16/402 ,  C23C22/77 ,  C23C22/82

摘要： Methods for selective deposition of silicon oxide films on dielectric surfaces relative to metal surfaces are provided. A metal surface of a substrate may be selectively passivated relative to the dielectric surface, such as with a polyimide layer or thiol SAM. Silicon oxide is selectively deposited on the dielectric surface relative to the passivated metal surface by contacting the dielectric surface with a metal catalyst and a silicon precursor comprising a silanol.

公开(公告)号：US20220372626A1

公开(公告)日：2022-11-24

申请号：US17763072

申请日：2020-09-23

申请人： NOF METAL COATINGS ASIA PACIFIC CO., LTD.

发明人： Takumi KOMATSUZAKI ,  Satoru TAMAKI

IPC分类号： C23C22/48 ,  C23C22/07 ,  C23C22/82

摘要： The present invention relates to: a rust-proofing treatment method comprising the step of treating an object that comprises a metal or an alloy and is heated to a temperature higher than 180° C. or an object that has, formed on the surface thereof, a film or layer comprising a metal or an alloy and is heated to a temperature higher than 180° C. with an aqueous solution containing an inorganic acid or an inorganic salt, or comprising the step of treating an object comprising a metal or an alloy or an object having, formed on the surface thereof, a film or layer comprising a metal or an alloy with an aqueous solution containing at least one component selected from silicic acid, a silicic acid salt, phosphoric acid, a phosphoric acid salt, a monohydrogen phosphate salt, a dihydrogen phosphate salt and a zirconium salt; and an article characterized by being rust-proofing-treated by the rust-proofing treatment method.