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    CATALYST PREPARED BY IMPREGNATION OF AN AQUEOUS SOLUTION CONTAINING OXY(HYDROXIDE) PARTICLES OF A CATION IN INTERACTION WITH A MOLECULAR SPECIES OF A GROUP VIII METAL
    4.
    发明申请
    CATALYST PREPARED BY IMPREGNATION OF AN AQUEOUS SOLUTION CONTAINING OXY(HYDROXIDE) PARTICLES OF A CATION IN INTERACTION WITH A MOLECULAR SPECIES OF A GROUP VIII METAL 审中-公开
    包含含有氧化物（羟基）的颗粒的水溶液与通过VIII族金属的分子物质相互作用的水溶液制备的催化剂

    公开(公告)号：US20080154074A1

    公开(公告)日：2008-06-26

    申请号：US11953272

    申请日：2007-12-10

    申请人： Cecile Thomazeau ,  Denis Uzio ,  Catherine Verdon ,  Lars Fischer

    发明人： Cecile Thomazeau ,  Denis Uzio ,  Catherine Verdon ,  Lars Fischer

    IPC分类号： C07C5/03 ,  B01J37/00 ,  B01J23/00

    CPC分类号： B01J23/58 ,  B01J21/04 ,  B01J23/54 ,  B01J23/63 ,  B01J23/76 ,  B01J35/0013 ,  B01J35/008 ,  B01J37/0211 ,  B01J37/0213 ,  C07C5/3337 ,  C07C2523/58 ,  C07C2523/63 ,  C10G45/40 ,  C07C11/08

    摘要： The invention concerns a process for preparing a catalyst precursor comprising the following steps: 1)a) preparing a colloidal solution A with a defined pH containing oxy(hydroxide) particles of a cation Mz+ selected from the group constituted by cations from columns IIA, IIIA, IIIB, IVB and IVA of the periodic table; or 1)b) using a commercial aqueous colloidal solution (solution A) with a defined pH containing oxy(hydroxide) particles of a cation Mz+ selected from the group constituted by cations from columns IIA, IIIA, IIIB, IVB and IVA of the periodic table; 2) adding in an aqueous solution B containing a precursor salt of a group VIII metal with a concentration of 0.001 to 1 mole/litre, the precursor salt of the metal being soluble under the pH conditions used in step 1. The invention also concerns the catalyst obtained from a catalyst precursor and its application in selective hydrogenation.

    摘要翻译： 本发明涉及一种制备催化剂前体的方法，其包括以下步骤：1）a）制备胶体溶液A，其中所述胶体溶液A具有含有选自以下基团的阳离子M z（z）的氧（氢氧化物）颗粒的定义的pH 由周期表的列IIA，IIIA，IIIB，IVB和IVA的阳离子构成; 或1）b）使用具有规定的pH的市售含水胶体溶液（溶液A），其含有选自由IIA，IIIA，IIIA，IIIA族中的阳离子构成的组的阳离子M z z + 周期表IIIB，IVB和IVA; 2）在含有浓度为0.001〜1摩尔/升的Ⅷ族金属的前体盐的水溶液B中加入，该金属的前体盐在步骤1中使用的pH条件下是可溶的。本发明还涉及 由催化剂前体获得的催化剂及其在选择性氢化中的应用。

    Fischer-Tropsch synthesis process in the presence of a catalyst the metallic particles of which have a controlled size
    5.
    发明授权
    Fischer-Tropsch synthesis process in the presence of a catalyst the metallic particles of which have a controlled size 有权
    在其催化剂存在下的费 - 托合成方法，其金属颗粒具有受控的尺寸

    公开(公告)号：US06214890B1

    公开(公告)日：2001-04-10

    申请号：US09373229

    申请日：1999-08-12

    申请人： Magalie Roy ,  Blaise Didillon ,  Denis Uzio ,  Catherine Verdon

    发明人： Magalie Roy ,  Blaise Didillon ,  Denis Uzio ,  Catherine Verdon

    IPC分类号： C07C2700

    CPC分类号： B01J37/0211 ,  B01J23/75 ,  B01J35/0013 ,  B01J35/023 ,  C07C1/0425 ,  C07C1/0445 ,  C07C2523/75

    摘要： The invention relates to a synthesis process for hydrocarbons using a mixture containing carbon monoxide and hydrogen, called Fischer-Tropsch synthesis in the presence of a catalyst comprising a support, at least one group VIII metal said process being characterized in that at least 80% of the group VIII metallic particles of the catalyst have a size comprised between D−(D.0.2) and D+(D.0.2), where D represents the average size of the metallic particles. The process can be used in a fixed-bed reactor of the catalyst or in a reactor operating in liquid phase of the catalyst.

    摘要翻译： 本发明涉及使用含有一氧化碳和氢气的混合物的烃的合成方法，在催化剂存在下，称为费 - 托合成，所述催化剂包含载体，至少一种第Ⅷ族金属，所述方法的特征在于至少80％ 催化剂的第VIII族金属颗粒的尺寸为D（D.0.2）和D +（D.0.2）之间，其中D表示金属颗粒的平均尺寸。 该方法可用于催化剂的固定床反应器或在催化剂的液相中操作的反应器中。

    Process for recovering hydrogen in a gaseous hydrocarbon effluent by chemical reaction
    9.
    发明授权
    Process for recovering hydrogen in a gaseous hydrocarbon effluent by chemical reaction 有权
    通过化学反应回收气态烃流出物中的氢气的方法

    公开(公告)号：US07081558B2

    公开(公告)日：2006-07-25

    申请号：US10680417

    申请日：2003-10-08

    申请人： Thierry Gauthier ,  Jean-Francois Joly ,  Denis Uzio ,  Germain Martino

    发明人： Thierry Gauthier ,  Jean-Francois Joly ,  Denis Uzio ,  Germain Martino

    IPC分类号： C07C7/157 ,  C07C7/163

    CPC分类号： C01B3/38 ,  C01B3/52 ,  C01B3/58 ,  C01B2203/0415 ,  C01B2203/0435 ,  C01B2203/048 ,  C01B2203/0485 ,  C01B2203/0495 ,  C01B2203/147 ,  C10G45/00 ,  C10G69/08

    摘要： Process for recovery of hydrogen in an effluent that is rich in hydrocarbons and that also contains hydrogen and a light olefin fraction, whereby said process comprises: a stage a) in which said effluent is brought into contact with at least one reagent that can react with said olefins to form with them a complex or a molecule; a stage c) in which the effluent that is obtained from stage a) is brought into contact with a composition that comprises at least one unsaturated compound in the presence of a suitable catalyst under hydrogenation conditions of at least a portion of said unsaturated compound by at least a portion of the hydrogen that is present in said effluent; a stage d) in which a reaction for dehydrogenation of hydrocarbons that are present in the effluent that is obtained from stage c) is carried out.

    摘要翻译： 在富含烃并且还含有氢和轻质烯烃馏分的流出物中回收氢气的方法，其中所述方法包括：a）使所述流出物与至少一种可与 所述烯烃与它们形成复合物或分子; 阶段c），其中从阶段a）获得的流出物与包含至少一种不饱和化合物的组合物在合适的催化剂存在下在至少部分所述不饱和化合物的氢化条件下与在 所述流出物中存在的至少一部分氢; 阶段d），其中进行从阶段c）获得的流出物中存在的烃的脱氢反应。