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公开(公告)号：US09669390B2
公开(公告)日：2017-06-06
申请号：US14767240
申请日：2014-02-11
Applicant: RES USA, LLC
Inventor： Dawid J. Duvenhage , Christine Schmidt , Mark Still , Khalid Azzam , Karl C. Kharas , Sara Hunegnaw , Olga Ionkina , Ray J. Huang , Harold A. Wright
IPC: B01J23/78 , B01J37/03 , B01J23/889 , B01J21/06 , B01J21/08 , B01J21/10 , B01J23/745 , B01J35/00 , B01J35/10 , C10G2/00 , B01J23/86 , B01J35/02 , B01J37/02 , B01J37/04 , B01J37/06 , B01J37/08
CPC classification number: B01J23/78 , B01J21/066 , B01J21/08 , B01J21/10 , B01J23/745 , B01J23/862 , B01J23/8892 , B01J35/0026 , B01J35/0046 , B01J35/006 , B01J35/023 , B01J35/1014 , B01J35/1019 , B01J35/1038 , B01J35/1042 , B01J35/1061 , B01J35/1066 , B01J37/0236 , B01J37/03 , B01J37/031 , B01J37/04 , B01J37/06 , B01J37/08 , C10G2/332
Abstract: A method for controllably producing a hematite-containing Fischer-Tropsch catalyst by combining an iron nitrate solution with a precipitating agent solution at a precipitating temperature and over a precipitation time to form a precipitate comprising iron phases; holding the precipitate from at a hold temperature for a hold time to provide a hematite containing precipitate; and washing the hematite containing precipitate via contact with a wash solution and filtering, to provide a washed hematite containing catalyst. The method may further comprise promoting the washed hematite containing catalyst with a chemical promoter; spray drying the promoted hematite containing catalyst; and calcining the spray dried hematite containing catalyst to provide a calcined hematite-containing Fischer-Tropsch catalyst.
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公开(公告)号：US20170066652A1
公开(公告)日：2017-03-09
申请号：US15355485
申请日：2016-11-18
Applicant: RES USA, LLC
Inventor： George Apanel , Harold A. Wright
IPC: C01B3/44 , C10K3/02 , C10K1/00 , B01J7/00 , B01J38/32 , B01J8/18 , B01J23/755 , B01J21/04 , B01J23/94 , C10J3/56 , B01J8/26
CPC classification number: C01B3/44 , B01J7/00 , B01J8/0055 , B01J8/006 , B01J8/1836 , B01J8/26 , B01J21/04 , B01J23/755 , B01J23/94 , B01J38/30 , B01J38/32 , B01J2208/00274 , B01J2208/00292 , B01J2219/00006 , C01B2203/0233 , C01B2203/0238 , C01B2203/0283 , C01B2203/061 , C01B2203/062 , C01B2203/0811 , C01B2203/0822 , C01B2203/0827 , C01B2203/1058 , C01B2203/1082 , C01B2203/1241 , C01B2203/1247 , C10G2/32 , C10G2300/1003 , C10G2300/1011 , C10G2300/1022 , C10G2300/202 , C10G2300/207 , C10J3/56 , C10J2300/092 , C10J2300/0976 , C10J2300/0986 , C10J2300/1637 , C10J2300/1659 , C10J2300/1807 , C10J2300/1853 , C10K1/002 , C10K1/004 , C10K1/34 , C10K3/003 , C10K3/023 , C10K3/04 , Y02E20/18 , Y02E50/32 , Y02P20/128 , Y02P20/52 , Y02P20/584 , Y02P30/20
Abstract: A system, for production of high-quality syngas, comprising a first dual fluidized bed loop having a fluid bed conditioner operable to produce high quality syngas comprising a first percentage of components other than CO and H2 from a gas feed, wherein the conditioner comprises an outlet for a first catalytic heat transfer stream comprising a catalytic heat transfer material and having a first temperature, and an inlet for a second catalytic heat transfer stream comprising catalytic heat transfer material and having a second temperature greater than the first temperature; a fluid bed combustor operable to combust fuel and oxidant, wherein the fluid bed combustor comprises an inlet connected with the outlet for a first catalytic heat transfer stream of the conditioner, and an outlet connected with the inlet for a second catalytic heat transfer stream of the conditioner; and a catalytic heat transfer material.
Abstract translation: 一种用于生产高质量合成气的系统，包括具有流化床调节器的第一双流化床回路，该流化床调节器可操作以产生高质量合成气，所述合成气包括来自气体进料的除了CO和H 2之外的第一百分比的组分，其中所述调节剂包括 包括催化传热材料并具有第一温度的第一催化传热流的出口和用于第二催化传热流的入口，其包含催化传热材料并具有大于第一温度的第二温度; 可操作以燃烧燃料和氧化剂的流化床燃烧器，其中所述流化床燃烧器包括与所述出口连接的用于所述调节器的第一催化传热流的入口，以及与所述入口连接的用于第二催化传热流的出口 护发素 和催化传热材料。
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公开(公告)号：US20150291897A1
公开(公告)日：2015-10-15
申请号：US14748964
申请日：2015-06-24
Applicant: RES USA LLC.
Inventor： Randy BLEVINS , Joshua B. Pearson , Harold A. Wright
CPC classification number: C10J3/466 , B01J8/067 , B01J19/2415 , B01J19/242 , B01J19/2425 , B01J19/243 , B01J2208/00309 , B01J2208/00504 , B01J2219/00006 , B01J2219/00157 , B01J2219/00159 , B01J2219/24 , C01B3/02 , C01B3/346 , C01B2203/0216 , C01B2203/0811 , C01B2203/1241 , C10G2/30 , C10G2/34 , C10J3/30 , C10J3/485 , C10J3/80 , C10J2200/09 , C10J2300/0906 , C10J2300/0909 , C10J2300/0916 , C10J2300/0976 , C10J2300/1223 , C10J2300/1246 , C10J2300/1659 , C10J2300/1687 , C10J2300/1853 , F23G5/033 , F23G5/04 , F23G5/444 , Y02E50/32 , Y02P20/145 , Y02P30/30
Abstract: A system for the production of synthesis gas, the system including a mixing apparatus configured for combining steam with at least one carbonaceous material to produce a reformer feedstock; and a reformer comprising a cylindrical vessel containing a plurality of coiled tubes, each of the plurality of coiled tubes having a vertical height in the range of from about 40 feet 12.2 m) to about 100 feet (30.5 m) and a coil length that is at least four times the vertical height; at least one burner configured to combust a fuel and provide heat to maintain the reformer at a reformer temperature; at least one outlet for reformer product comprising synthesis gas; and at least one outlet for flue gas produced via combustion of fuel in the burners. A suitable mixing apparatus is also provided.
Abstract translation: 一种用于生产合成气的系统，该系统包括配置用于将蒸汽与至少一种碳质材料组合以产生重整器原料的混合装置; 以及重整器，其包括容纳多个螺旋管的圆柱形容器，所述多个盘管中的每一个具有在约40英尺12.2m至约100英尺（30.5m）的范围内的垂直高度，以及线圈长度 至少是垂直高度的四倍; 至少一个燃烧器，其构造成燃烧燃料并提供热量以将所述重整器维持在重整器温度; 至少一个包含合成气的重整产物出口; 以及至少一个通过燃烧器中的燃料燃烧产生的用于烟道气的出口。 还提供了合适的混合装置。
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4.发明申请INTEGRATION OF SYNGAS GENERATION TECHNOLOGY WITH FISCHER-TROPSCH PRODUCTION VIA CATALYTIC GAS CONVERSION 审中-公开通过催化气体转换将基因产生技术与FISCHER-TROPSCH生产整合公开(公告)号：US20150126627A1
公开(公告)日：2015-05-07
申请号：US14414535
申请日：2013-07-15
Applicant: RES USA, LLC
Inventor： George Apanel , Weibin Jiang , Sergio Mohedas , Harold A. Wright
CPC classification number: C07C1/049 , C01B3/02 , C01B3/44 , C01B2203/0227 , C01B2203/0238 , C01B2203/062 , C01B2203/0805 , C01B2203/1058 , C01B2203/1235 , C07C1/0485 , C10B49/22 , C10G2/32 , C10J3/46 , C10J3/48 , C10J2200/06 , C10J2300/0976 , C10J2300/0993 , C10J2300/0996 , C10J2300/1659 , C10J2300/1807 , C10J2300/1853 , C10K1/003 , C10K1/004 , C10K1/046 , C10K1/34 , C10K3/02 , C10K3/023 , Y02E50/32 , Y02P20/582
Abstract: A system for the production of synthetic fuel, the system including a catalytic dual fluidized bed (DFB) configured to produce, from a DFB feedgas, a DFB product containing synthesis gas; and a Fischer-Tropsch (FT) synthesis apparatus fluidly connected with the catalytic DFB, wherein the FT synthesis apparatus includes an FT synthesis reactor configured to produce, from an FT feedgas, an FT overhead and a liquid FT product containing FT wax, wherein the FT feedgas contains at least a portion of the DFB product; and a product separator downstream of and fluidly connected with the FT synthesis reactor, wherein the product separator is configured to separate, from the FT overhead, an FT tailgas and an LFTL product containing LFTL. A method of producing synthetic fuel is also provided.
Abstract translation: 一种用于生产合成燃料的系统，所述系统包括催化双流化床（DFB），其被配置为从DFB原料气生产含有合成气的DFB产物; 和与所述催化剂DFB流体连接的费 - 托（FT）合成装置，其中所述FT合成装置包括FT合成反应器，所述FT合成反应器被配置为从FT原料气制备含有FT蜡的FT塔顶馏出物和液体FT产物，其中 FT原料气含有至少一部分DFB产品; 和与FT合成反应器流体连接的产物分离器，其中产物分离器构造成与FT塔顶馏分分离出含有LFTL的FT尾气和LFTL产物。 还提供了一种生产合成燃料的方法。
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公开(公告)号：US10035963B2
公开(公告)日：2018-07-31
申请号：US15398394
申请日：2017-01-04
Applicant: RES USA, LLC
Inventor： Randy Blevins , Joshua B. Pearson , Harold A. Wright
CPC classification number: C10J3/466 , B01J8/067 , B01J19/2415 , B01J19/242 , B01J19/2425 , B01J19/243 , B01J2208/00309 , B01J2208/00504 , B01J2219/00006 , B01J2219/00157 , B01J2219/00159 , B01J2219/24 , C01B3/02 , C01B3/346 , C01B2203/0216 , C01B2203/0811 , C01B2203/1241 , C10G2/30 , C10G2/34 , C10J3/30 , C10J3/485 , C10J3/80 , C10J2200/09 , C10J2300/0906 , C10J2300/0909 , C10J2300/0916 , C10J2300/0976 , C10J2300/1223 , C10J2300/1246 , C10J2300/1659 , C10J2300/1687 , C10J2300/1853 , F23G5/033 , F23G5/04 , F23G5/444 , Y02E50/32 , Y02P20/145 , Y02P30/30
Abstract: A mixing apparatus for producing a feedstock for a reformer, the mixing apparatus including at least one mixing vessel comprising a cylindrical vessel with a conical bottom; a steam inlet configured for introducing steam into the conical bottom; a carbonaceous material inlet configured for introducing a carbonaceous feed into the cylindrical vessel; and an outlet for a reformer feedstock comprising at least 0.3 pounds of steam per pound of carbonaceous material, with the at least one mixing vessel configured for operation at a pressure of greater than about 10 psig.
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Patent Agency Ranking
公开(公告)号：US20180002265A1
公开(公告)日：2018-01-04
申请号：US15612312
申请日：2017-06-02
Applicant: RES USA, LLC
Inventor： Harold A. Wright , Mark K. Robertson , Weibin Jiang
CPC classification number: C07C41/09 , C01B3/38 , C01B3/44 , C01B3/505 , C01B2203/0238 , C01B2203/0405 , C01B2203/041 , C01B2203/06 , C01B2203/1058 , C01B2203/1241 , C01B2203/148 , C07C41/01 , C07C41/34 , C07C43/043
Abstract: Herein disclosed is a method of producing dimethyl ether (DME) comprising introducing one or more feed streams comprising methane and carbon dioxide into a reformer to generate synthesis gas; and converting synthesis gas to DME in one step. In some cases, the reformer comprises a Ni catalyst. In some cases, the reformer is a pressurized fluidized bed dry reforming reactor. In some cases, the reformer comprises a hydrogen membrane. The hydrogen membrane removes hydrogen contained in the synthesis gas and shifts reforming reactions toward completion.
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公开(公告)号：US20180002264A1
公开(公告)日：2018-01-04
申请号：US15657849
申请日：2017-07-24
Applicant: RES USA, LLC
Inventor： Harold A. Wright , Mark K. Robertson , Weibin Jiang
CPC classification number: C07C41/01 , B01J8/0055 , B01J8/009 , B01J8/067 , B01J8/1827 , B01J8/1854 , B01J8/1872 , B01J8/26 , B01J21/04 , B01J23/755 , B01J23/94 , B01J38/02 , B01J2208/0038 , B01J2208/00504 , B01J2208/00991 , B01J2219/00006 , C01B3/44 , C01B3/505 , C01B2203/0238 , C01B2203/041 , C01B2203/06 , C01B2203/1058 , C01B2203/1082 , C01B2203/1241 , Y02P20/584 , C07C43/043
Abstract: Herein disclosed is a dry reforming reactor comprising a gas inlet near the bottom of the reactor; a gas outlet near the top of the reactor; a fluidized bed comprising a catalyst; and one or more hydrogen membranes comprising palladium (Pd). In some cases, the one or more hydrogen membranes comprises Pd alloy membranes, or Pd supported on ceramics or metals. In some cases, the one or more hydrogen membranes are placed vertically in the reactor as hydrogen membrane tubes hanging from the top of the reactor. In some cases, the hydrogen membranes are configured to selectively collect hydrogen from the tubes via one or more internal manifolds and sent to an external hydrogen collection system.
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公开(公告)号：US20160002547A1
公开(公告)日：2016-01-07
申请号：US14851633
申请日：2015-09-11
Applicant: RES USA, LLC
Inventor： Weibin Jiang , Bruce E. McComish , Bryan C. Borum , Benjamin H. Carryer , Mark K. Robertson , Eric R. Elrod , Sim Weeks , Harold A. Wright
CPC classification number: C10J3/721 , B01J8/18 , C01B2203/0244 , C01B2203/025 , C01B2203/0283 , C01B2203/0405 , C01B2203/0415 , C01B2203/043 , C01B2203/0475 , C01B2203/048 , C01B2203/0485 , C01B2203/062 , C01B2203/0877 , C01B2203/146 , C10G2/00 , C10G2/30 , C10G2/34 , C10G49/007 , C10J3/48 , C10J3/482 , C10J3/485 , C10J3/50 , C10J2200/09 , C10J2300/0909 , C10J2300/0916 , C10J2300/093 , C10J2300/0943 , C10J2300/0969 , C10J2300/0976 , C10J2300/0993 , C10J2300/1606 , C10J2300/1643 , C10J2300/1659 , C10J2300/1671 , C10J2300/1807 , C10J2300/1815 , C10J2300/1823 , C10K1/005 , C10K1/22 , C10K1/32 , C10K3/00 , C10K3/04
Abstract: A system for the production of synthesis gas, including a gasification apparatus configured to convert at least a portion of a gasifier feed material introduced thereto into a gasification product gas comprising synthesis gas having a molar ratio of hydrogen to carbon monoxide; at least one additional apparatus selected from the group consisting of feed preparation apparatus located upstream of the gasification apparatus, synthesis gas conditioning apparatus, and synthesis gas utilization apparatus; and at least one line fluidly connecting the at least one additional apparatus or an outlet of the gasification apparatus with the at least one vessel of the gasification apparatus, whereby a gas from the at least one additional apparatus or exiting the gasification apparatus may provide at least one non-steam component of a fluidization gas. A method of utilizing the system is also provided.
Abstract translation: 一种用于生产合成气的系统，包括气化装置，其被配置为将引入到其中的气化器进料的至少一部分转化成包含氢与一氧化碳摩尔比的合成气的气化产物气体; 至少一种选自由气化装置上游的进料制备装置，合成气调节装置和合成气利用装置组成的组的附加装置; 以及将所述气化装置的所述至少一个附加装置或出口与所述气化装置的所述至少一个容器流体连接的至少一个管线，由此来自所述至少一个附加装置或离开所述气化装置的气体可以至少提供 流化气体的一种非蒸汽组分。 还提供了利用该系统的方法。
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公开(公告)号：US20160002541A1
公开(公告)日：2016-01-07
申请号：US14852248
申请日：2015-09-11
Applicant: RES USA, LLC
Inventor： Mark Ibsen , Sergio Mohedas , Frank Hogsett , Mark Bohn , Harold A. Wright
CPC classification number: B03C1/02 , B01J8/005 , B01J8/007 , B01J8/22 , B01J8/228 , B01J35/0033 , B03C1/288 , B03C1/30 , B03C2201/18 , C10G2/33 , C10G2/332 , C10G2/342 , C10G45/00 , C10G45/58 , C10G47/00
Abstract: A method for converting synthesis gas into liquid hydrocarbons by introducing a synthesis gas feed into a Fischer-Tropsch system that includes a catalytic reactor fluidly connected with at least two slurry loops, the reactor comprising at least as many reactor product outlets and slurry return inlets as slurry loops; each slurry loop comprising a separation system comprising at least one separator, an inlet of each separator fluidly connected to a reactor product outlet via a slurry offtake, and an outlet of each separator fluidly connected to a slurry return inlet via a slurry return; separating concentrated catalyst slurry from the reaction product via the slurry loops; removing liquid hydrocarbon product from each separator; and returning concentrated catalyst slurry to the catalytic reactor via the slurry returns and slurry return inlets. A system for converting synthesis gas into liquid hydrocarbons via the method is also disclosed.
Abstract translation: 通过将合成气进料引入费 - 托系统中来将合成气转化成液体烃的方法，所述费 - 托系统包括与至少两个浆液回路流体连接的催化反应器，所述反应器至少包含反应器产物出口和浆料返回入口 浆液回路; 每个浆料回路包括分离系统，该分离系统包括至少一个分离器，每个分离器的入口经由浆料出口流体连接到反应器产物出口，以及每个分离器的出口通过浆料回流器流体连接到浆料返回入口; 通过浆料循环从反应产物中分离浓缩的催化剂浆料; 从每个分离器去除液体烃产物; 并通过浆料返回和浆料返回入口将浓缩的催化剂浆料返回到催化反应器。 还公开了一种通过该方法将合成气转化为液态烃的系统。
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公开(公告)号：US20160001267A1
公开(公告)日：2016-01-07
申请号：US14767240
申请日：2014-02-11
Applicant: RES USA, LLC
Inventor： Dawid J. Duvenhage , Christine Schmidt , Mark Still , Khalid Azzam , Karl C. Kharas , Sara Hunegnaw , Olga Ionkina , Ray J. Huang , Harold A. Wright
IPC: B01J23/78 , B01J23/86 , B01J35/02 , B01J35/10 , B01J37/02 , B01J37/03 , B01J37/04 , B01J37/06 , B01J37/08 , B01J23/745 , C10G2/00
CPC classification number: B01J23/78 , B01J21/066 , B01J21/08 , B01J21/10 , B01J23/745 , B01J23/862 , B01J23/8892 , B01J35/0026 , B01J35/0046 , B01J35/006 , B01J35/023 , B01J35/1014 , B01J35/1019 , B01J35/1038 , B01J35/1042 , B01J35/1061 , B01J35/1066 , B01J37/0236 , B01J37/03 , B01J37/031 , B01J37/04 , B01J37/06 , B01J37/08 , C10G2/332
Abstract: A method for controllably producing a hematite-containing Fischer-Tropsch catalyst by combining an iron nitrate solution with a precipitating agent solution at a precipitating temperature and over a precipitation time to form a precipitate comprising iron phases; holding the precipitate from at a hold temperature for a hold time to provide a hematite containing precipitate; and washing the hematite containing precipitate via contact with a wash solution and filtering, to provide a washed hematite containing catalyst. The method may further comprise promoting the washed hematite containing catalyst with a chemical promoter; spray drying the promoted hematite containing catalyst; and calcining the spray dried hematite containing catalyst to provide a calcined hematite-containing Fischer-Tropsch catalyst.
Abstract translation: 一种通过在沉淀温度和沉淀时间结合硝酸铁溶液与沉淀剂溶液以形成包含铁相的沉淀物来可控地生产含赤铁矿的费 - 托催化剂的方法; 在保持温度下保持沉淀物保持时间以提供含有沉淀物的赤铁矿; 并通过与洗涤溶液接触来洗涤含有赤铁矿的沉淀物并过滤，以提供洗涤的含赤铁矿的催化剂。 该方法还可以包括用化学促进剂促进含洗涤的含赤铁矿催化剂; 喷雾干燥促进含赤铁矿的催化剂; 并煅烧含有干燥的含赤铁矿的催化剂以提供含煅烧赤铁矿的费 - 托催化剂。
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