公开(公告)号：US20090004078A1

公开(公告)日：2009-01-01

申请号：US11664467

申请日：2005-10-13

Applicant: Fhue Mao ,  Cheng G. Li ,  Robin Ziebarth

Inventor： Fhue Mao ,  Cheng G. Li ,  Robin Ziebarth

IPC: B01D53/94 ,  B01J23/10

CPC classification number: B01D53/944 ,  B01J23/10 ,  B01J23/63 ,  B01J37/024

Abstract: A catalyzed Diesel soot filter and process. The Diesel soot filter incorporates a porous filter element coated with a catalytic agent so that Diesel soot from Diesel exhaust gas is deposited into contact with the catalytic agent when Diesel exhaust gas is passed through the porous filter element and so that the ignition temperature or oxidation temperature of the deposited Diesel soot is reduced. The catalytic agent is a mixture of alkali metal and cerium oxides. The mole ratio of alkali metal to cerium of the catalytic agent is in the range of from 0.5 to 5.

Abstract translation: 催化柴油烟尘过滤器和过程。 柴油烟灰过滤器包括涂覆有催化剂的多孔过滤元件，使得当柴油废气通过多孔过滤器元件时，来自柴油废气的柴油烟尘沉积成与催化剂接触，并且使得点火温度或氧化温度 的沉积柴油烟灰减少。 催化剂是碱金属和氧化铈的混合物。 催化剂的碱金属与铈的摩尔比在0.5〜5的范围内。

公开(公告)号：US08661794B2

公开(公告)日：2014-03-04

申请号：US10567006

申请日：2004-08-27

Applicant: Cheng G. Li ,  Robin Ziebarth ,  Martin C. Cornell ,  Steven B. Swatzmiller

Inventor： Cheng G. Li ,  Robin Ziebarth ,  Martin C. Cornell ,  Steven B. Swatzmiller

IPC: F01N3/00 ,  F01N3/10 ,  F01N3/02 ,  B01D24/00 ,  B01D39/06 ,  B01D39/20 ,  B01D39/14

CPC classification number: B01J23/42 ,  B01D53/9422 ,  B01D53/944 ,  B01D53/945 ,  B01D53/9468 ,  B01D2255/1021 ,  B01D2255/1023 ,  B01D2255/1025 ,  B01D2255/2042 ,  B01D2255/9155 ,  B01J21/04 ,  B01J23/464 ,  B01J35/04 ,  B01J37/0201 ,  B01J37/0215 ,  C04B41/009 ,  C04B41/5122 ,  C04B41/88 ,  C04B2111/00793 ,  F01N3/0222 ,  F01N3/0231 ,  F01N3/035 ,  F01N3/0814 ,  F01N3/0821 ,  F01N3/0842 ,  F01N3/2828 ,  F01N2330/06 ,  F01N2370/02 ,  F01N2510/06 ,  Y02A50/2341 ,  Y02T10/22 ,  C04B41/4535 ,  C04B41/455 ,  C04B35/185 ,  C04B38/00

Abstract: An improved Diesel exhaust filter element of the type having a rigid porous wall portion formed of an acicular ceramic (such as acicular mullite), the porous wall portion having a first side and a second side, the porous wall portion being coated with a precious metal catalyst and a Nox absorbent, such that when exhaust gas from a Diesel engine is flowed through the rigid porous wall from the first side to the second side, the exhaust gas containing excess oxygen, Nox and soot, the soot in the exhaust gas in trapped within the rigid porous wall and catalytically oxidized to carbon dioxide, the NO is catalytically oxidized to NO2, which NO2 is then absorbed by the Nox absorbent, and such that when the exhaust gas is caused to contain excess hydrocarbon and carbon monoxide, then the Nox absorbent is regenerated and the remaining hydrocarbon and carbon monoxide are catalytically converted to nitrogen and carbon dioxide. In addition, a process for depositing precipitated metal ions on the surfaces of such a rigid porous wall.

Abstract translation: 一种改进的具有由针状陶瓷（例如针状莫来石）形成的刚性多孔壁部分的柴油机排气过滤器元件，多孔壁部分具有第一侧和第二侧，多孔壁部分涂覆有贵金属 催化剂和Nox吸收剂，使得当来自柴油发动机的排气从第一侧向第二侧流过刚性多孔壁时，含有过量氧气，NOx和烟灰的废气在被捕获的废气中的烟灰 在刚性多孔壁内并催化氧化成二氧化碳，NO被催化氧化成NO2，然后NO2被Nox吸收剂吸收，使得当废气含有过量的碳氢化合物和一氧化碳时，Nox 吸收剂被再生，剩余的烃和一氧化碳被催化转化成氮和二氧化碳。 此外，在这种刚性多孔壁的表面上沉积沉淀的金属离子的方法。

公开(公告)号：US07928032B2

公开(公告)日：2011-04-19

申请号：US12338232

申请日：2008-12-18

Applicant: Robin Ziebarth ,  Robert T. Nilsson ,  Steven J. Martin

Inventor： Robin Ziebarth ,  Robert T. Nilsson ,  Steven J. Martin

IPC: B01J27/224 ,  B01J8/02 ,  B01D39/00 ,  B01D50/00 ,  B01D59/50 ,  B01D39/06 ,  B01D39/20 ,  B01D46/00 ,  B01D53/56 ,  B01D53/94 ,  F01N3/00 ,  F01N3/10 ,  F01N3/02 ,  C01B21/00 ,  C01B23/00 ,  C01B25/00 ,  C01B31/00 ,  C01B33/00 ,  C01B35/00 ,  C01G28/00 ,  C01G30/00

CPC classification number: B01J23/04 ,  B01D53/944 ,  B01D2255/20707 ,  B01D2255/20715 ,  B01D2255/20723 ,  B01D2255/2073 ,  B01D2255/20753 ,  B01D2255/20769 ,  B01D2255/20776 ,  B01D2258/012 ,  B01J27/22 ,  B01J27/224 ,  B01J37/084 ,  Y10S55/05 ,  Y10S55/10 ,  Y10S55/30

Abstract: An improved soot catalyst is comprised of an alkali compound at least partially coated by a ceramic coating comprised of C bonded to a metal, semimetallic element or combination thereof. The improved soot catalyst may be employed in catalyzed Diesel particulate filters. In one method to make a catalyzed Diesel particulate filter, the improved filter is made by contacting a porous ceramic body having an alkali catalyst thereon, coating the alkali catalyst with an organic ceramic precursor, heating the ceramic body to a temperature in an atmosphere sufficient to decompose the organic ceramic precursor to form the soot catalyst on the porous ceramic body without volatilizing substantial amount of the alkali catalyst away.

Abstract translation: 改进的烟灰催化剂由至少部分地被陶瓷涂层涂覆的碱性化合物组成，所述陶瓷涂层包含C键合到金属，半金属元素或其组合。 改进的烟灰催化剂可用于催化柴油微粒过滤器。 在制备催化柴油颗粒过滤器的一种方法中，改进的过滤器通过使其上具有碱性催化剂的多孔陶瓷体与其上涂覆碱催化剂与有机陶瓷前体进行接触来制备，将陶瓷体加热到足够大的温度 分解有机陶瓷前体以在多孔陶瓷体上形成烟灰催化剂，而不会使相当大量的碱催化剂挥发掉。

公开(公告)号：US20070021291A1

公开(公告)日：2007-01-25

申请号：US11526483

申请日：2006-09-25

Applicant: Robert Nilsson ,  Robin Ziebarth

Inventor： Robert Nilsson ,  Robin Ziebarth

IPC: C04B35/00 ,  B01J21/02

CPC classification number: C04B41/009 ,  B01D39/2093 ,  C04B35/185 ,  C04B35/195 ,  C04B35/565 ,  C04B41/5006 ,  C04B41/52 ,  C04B41/87 ,  C04B41/89 ,  C04B2111/00793 ,  C04B2235/3224 ,  C04B2235/3229 ,  C04B2235/3409 ,  C04B2235/36 ,  C04B2235/3826 ,  C04B2235/483 ,  C04B2235/77 ,  C04B2235/80 ,  C04B2235/96 ,  C04B2235/9607 ,  F01N3/0222 ,  F01N3/2828 ,  F01N2330/06 ,  Y02T10/20 ,  C04B41/0072 ,  C04B41/457 ,  C04B41/5045 ,  C04B41/4554 ,  C04B41/5059 ,  C04B35/00 ,  C04B38/0006

Abstract: A porous ceramic body having increased strength is formed by exposing a porous ceramic body to a source of boron and heating the porous body to a sufficient temperature in an oxygen containing atmosphere to form the porous ceramic body. The porous ceramic body has a boron containing oxide glassy phase on at least a portion of the ceramic grains of the porous ceramic body.

Abstract translation: 通过将多孔陶瓷体暴露于硼源并在含氧气氛中将多孔体加热到足够的温度以形成多孔陶瓷体，形成具有增强强度的多孔陶瓷体。 多孔陶瓷体在多孔陶瓷体的陶瓷颗粒的至少一部分上具有含硼氧化物玻璃相。

公开(公告)号：US08092579B2

公开(公告)日：2012-01-10

申请号：US12248107

申请日：2008-10-09

Applicant: Robin Ziebarth ,  Robert T. Nilsson

Inventor： Robin Ziebarth ,  Robert T. Nilsson

IPC: B01D46/00

CPC classification number: B01D46/0063 ,  B01D46/2418 ,  B01D2279/30 ,  F01N2260/10 ,  F01N2330/06 ,  Y10S55/10 ,  Y10S55/30

Abstract: A ceramic honeycomb filter having improved thermal shock resistance is comprised of a ceramic honeycomb filter that has a heat absorbing material that undergoes a reversible phase change that absorbs at least in part the heat energy, for example, arising from the combustion of Diesel soot entrapped in the filter.

Abstract translation: 具有改善的耐热冲击性的陶瓷蜂窝过滤器由陶瓷蜂窝过滤器组成，该陶瓷蜂窝过滤器具有经历可逆相变的吸热材料，所述吸热材料至少部分吸收热能，例如由于柴油烟炱的燃烧引起的热能 过滤器。

公开(公告)号：US07485594B2

公开(公告)日：2009-02-03

申请号：US11799413

申请日：2007-05-01

Applicant: Chandan Saha ,  Sharon Allen ,  Chan Han ,  Robert T. Nilsson ,  Arthur R. Prunier, Jr. ,  Aleksander J. Pyzik ,  Sten A. Wallin ,  Robin Ziebarth ,  Timothy J. Gallagher

Inventor： Chandan Saha ,  Sharon Allen ,  Chan Han ,  Robert T. Nilsson ,  Arthur R. Prunier, Jr. ,  Aleksander J. Pyzik ,  Sten A. Wallin ,  Robin Ziebarth ,  Timothy J. Gallagher

IPC: C04B35/00

CPC classification number: B01J23/10 ,  B01D39/2093 ,  B01J23/63 ,  B01J35/04 ,  B01J37/0215 ,  C04B35/185 ,  C04B35/6365 ,  C04B2235/3206 ,  C04B2235/3208 ,  C04B2235/322 ,  C04B2235/3224 ,  C04B2235/3225 ,  C04B2235/3229 ,  C04B2235/3409 ,  C04B2235/349 ,  C04B2235/449 ,  C04B2235/604 ,  C04B2235/658 ,  C04B2235/661 ,  C04B2235/72 ,  C04B2235/77 ,  C04B2235/96 ,  C04B2235/9607 ,  F01N2330/06 ,  F01N2510/06 ,  F01N2510/0682

Abstract: A porous mullite composition is made by forming a mixture of one or more precursor compounds having the elements present in mullite (e.g., clay, alumina, silica) and a property enhancing compound. The property enhancing compound is a compound having an element selected from the group consisting of Mg, Ca, Fe, Na, K, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, B, Y, Sc, La and combination thereof. The mixture is shaped and to form a porous green shape which is heated under an atmosphere having a fluorine containing gas to a temperature sufficient to form a mullite composition comprised substantially of acicular mullite grains that are essentially chemically bound.

Abstract translation: 通过形成具有莫来石（例如粘土，氧化铝，二氧化硅）和性能增强化合物中存在的元素的一种或多种前体化合物的混合物来制备多孔莫来石组合物。 性质增强化合物是具有选自Mg，Ca，Fe，Na，K，Ce，Pr，Nd，Sm，Eu，Gd，Tb，Dy，Ho，Er，Tm，Yb， Lu，B，Y，Sc，La及其组合。 混合物成型并形成多孔绿色形状，其在具有含氟气体的气氛下加热到足以形成基本上化学结合的基本上由针状莫来石颗粒组成的莫来石组合物的温度。

公开(公告)号：US20060197265A1

公开(公告)日：2006-09-07

申请号：US10551728

申请日：2004-04-23

Applicant: Chandan Saha ,  Sharon Allen ,  Chan Han ,  Robert Nilsson ,  Arthur Prunier ,  Aleksander Pyzik ,  Sten Wallin ,  Robin Ziebarth ,  Timothy Gallagher

Inventor： Chandan Saha ,  Sharon Allen ,  Chan Han ,  Robert Nilsson ,  Arthur Prunier ,  Aleksander Pyzik ,  Sten Wallin ,  Robin Ziebarth ,  Timothy Gallagher

IPC: C04B35/18 ,  C04B35/64 ,  C01B33/26 ,  B01J21/12 ,  C01B15/12

CPC classification number: B01D53/885 ,  B01D53/944 ,  B01D71/02 ,  B01J21/12 ,  B01J21/16 ,  B01J23/002 ,  B01J23/02 ,  B01J23/10 ,  B01J23/63 ,  B01J23/78 ,  B01J35/002 ,  B01J35/1033 ,  B01J37/0018 ,  B01J37/0027 ,  B01J37/08 ,  B01J37/26 ,  B01J2523/00 ,  C04B35/185 ,  C04B35/64 ,  C04B38/00 ,  C04B2111/00793 ,  C04B2111/0081 ,  C04B2235/3201 ,  C04B2235/3206 ,  C04B2235/3208 ,  C04B2235/3217 ,  C04B2235/3224 ,  C04B2235/3225 ,  C04B2235/3229 ,  C04B2235/3272 ,  C04B2235/3409 ,  C04B2235/3418 ,  C04B2235/3445 ,  C04B2235/349 ,  C04B2235/449 ,  C04B2235/658 ,  C04B2235/661 ,  C04B2235/72 ,  C04B2235/77 ,  C04B2235/78 ,  C04B2235/85 ,  C04B2235/96 ,  C04B2235/9607 ,  F01N3/022 ,  F01N3/0222 ,  F01N3/035 ,  F01N2330/06 ,  F01N2370/02 ,  C04B38/0022 ,  C04B38/0074 ,  C04B38/0645 ,  B01J2523/22 ,  B01J2523/31 ,  B01J2523/41 ,  B01J2523/842 ,  B01J2523/3725

Abstract: A porous mullite composition is made by Forming a mixture of one or more precursor compounds having the elements present in mullite (e.g., clay, alumina, silica) and a property enhancing compound. The property enhancing compound is a compound having an element selected from the group consisting of Mg, Ca, Fe, Na, K, Ce, Pr, Nd, Sm, Eu, Gd, Th, Dy, Ho, Er, Tm, Yb, Lu, B, Y, Sc, La and combination thereof. The mixture is shaped and to form a porous green shape which is heated under an atmosphere having a fluorine containing gas to a temperature sufficient to form a mullite composition comprised substantially of acicular mullite grains that are essentially chemically bound.

公开(公告)号：US20060193757A1

公开(公告)日：2006-08-31

申请号：US10567006

申请日：2004-08-27

Applicant: Cheng Li ,  Robin Ziebarth ,  Martin Cornell ,  Steven Swartzmiller

Inventor： Cheng Li ,  Robin Ziebarth ,  Martin Cornell ,  Steven Swartzmiller

IPC: B01D50/00

CPC classification number: B01J23/42 ,  B01D53/9422 ,  B01D53/944 ,  B01D53/945 ,  B01D53/9468 ,  B01D2255/1021 ,  B01D2255/1023 ,  B01D2255/1025 ,  B01D2255/2042 ,  B01D2255/9155 ,  B01J21/04 ,  B01J23/464 ,  B01J35/04 ,  B01J37/0201 ,  B01J37/0215 ,  C04B41/009 ,  C04B41/5122 ,  C04B41/88 ,  C04B2111/00793 ,  F01N3/0222 ,  F01N3/0231 ,  F01N3/035 ,  F01N3/0814 ,  F01N3/0821 ,  F01N3/0842 ,  F01N3/2828 ,  F01N2330/06 ,  F01N2370/02 ,  F01N2510/06 ,  Y02A50/2341 ,  Y02T10/22 ,  C04B41/4535 ,  C04B41/455 ,  C04B35/185 ,  C04B38/00

Abstract: An improved Diesel exhaust filter element of the type having a rigid porous wall portion formed of an acicular ceramic (such as acicular mullite), the porous wall portion having a first side and a second side, the porous wall portion being coated with a precious metal catalyst and a Nox absorbent, such that when exhaust gas from a Diesel engine is flowed through the rigid porous wall from the first side to the second side, the exhaust gas containing excess oxygen, Nox and soot, the soot in the exhaust gas in trapped within the rigid porous wall and catalytically oxidized to carbon dioxide, the NO is catalytically oxidized to NO2, which NO2 is then absorbed by the Nox absorbent, and such that when the exhaust gas is caused to contain excess hydrocarbon and carbon monoxide, then the Nox absorbent is regenerated and the remaining hydrocarbon and carbon monoxide are catalytically converted to nitrogen and carbon dioxide. In addition, a process for depositing precipitated metal ions on the surfaces of such a rigid porous wall.

Abstract translation: 一种改进的具有由针状陶瓷（例如针状莫来石）形成的刚性多孔壁部分的柴油机排气过滤器元件，多孔壁部分具有第一侧和第二侧，多孔壁部分涂覆有贵金属 催化剂和无吸收剂，使得当来自柴油发动机的废气从第一侧流到第二侧时，含有过量氧气，NOx和烟尘的废气， 废气中的烟灰被捕获在刚性多孔壁内并催化氧化成二氧化碳，NO被催化氧化成NO 2，然后NO 2被< 并且使得当使废气含有过量的碳氢化合物和一氧化碳时，则再次使用NO x吸收剂，并且剩余的烃和一氧化碳 催化转化成氮和二氧化碳。 此外，在这种刚性多孔壁的表面上沉积沉淀的金属离子的方法。

公开(公告)号：US07947102B2

公开(公告)日：2011-05-24

申请号：US11954283

申请日：2007-12-12

Applicant: Robin Ziebarth

Inventor： Robin Ziebarth

IPC: B01D39/14 ,  B01D50/00 ,  B01D39/00 ,  B01D39/06

CPC classification number: B01D46/2429 ,  B01D46/2455 ,  B01D46/2466 ,  B01D46/2474 ,  B01D2046/2481 ,  B01D2046/2488 ,  B01D2046/2492 ,  B01D2046/2496 ,  B01D2275/30 ,  B01J35/04 ,  C04B35/185 ,  C04B38/0009 ,  C04B2111/0081 ,  C04B2235/3213 ,  C04B2235/322 ,  C04B2235/3229 ,  C04B2235/349 ,  C04B2235/445 ,  C04B2235/78 ,  F01N3/0222 ,  F01N2330/06 ,  C04B38/0074

Abstract: An improved ceramic honeycomb filter has at least one porous partition wall defining a channel that is (1) microstructurally different along the length of the channel, (2) microstructurally different than at least a portion of a partition wall defining another channel or (3) combination thereof. The improved filter may be used for filtering Diesel exhaust and may have reduced back pressure and equivalent soot capture efficiency compared to a filter without having said microstructural differences.

Abstract translation: 改进的陶瓷蜂窝过滤器具有限定通道的至少一个多孔分隔壁，其通道沿着通道的长度显微结构不同;（2）与限定另一通道的分隔壁的至少一部分微结构不同;（3） 的组合。 改进的过滤器可用于过滤柴油机排气，并且与过滤器相比可以具有降低的背压和等效的烟灰捕获效率，而不具有所述微结构差异。

公开(公告)号：US20090163356A1

公开(公告)日：2009-06-25

申请号：US12338232

申请日：2008-12-18

Applicant: Robert T. Nilsson ,  Robin Ziebarth ,  Steven J. Martin

Inventor： Robert T. Nilsson ,  Robin Ziebarth ,  Steven J. Martin

IPC: B01J27/224

CPC classification number: B01J23/04 ,  B01D53/944 ,  B01D2255/20707 ,  B01D2255/20715 ,  B01D2255/20723 ,  B01D2255/2073 ,  B01D2255/20753 ,  B01D2255/20769 ,  B01D2255/20776 ,  B01D2258/012 ,  B01J27/22 ,  B01J27/224 ,  B01J37/084 ,  Y10S55/05 ,  Y10S55/10 ,  Y10S55/30

Abstract: An improved soot catalyst is comprised of an alkali compound at least partially coated by a ceramic coating comprised of C bonded to a metal, semimetallic element or combination thereof. The improved soot catalyst may be employed in catalyzed Diesel particulate filters. In one method to make a catalyzed Diesel particulate filter, the improved filter is made by contacting a porous ceramic body having an alkali catalyst thereon, coating the alkali catalyst with an organic ceramic precursor, heating the ceramic body to a temperature in an atmosphere sufficient to decompose the organic ceramic precursor to form the soot catalyst on the porous ceramic body without volatilizing substantial amount of the alkali catalyst away.

Abstract translation: 改进的烟灰催化剂由至少部分地被陶瓷涂层涂覆的碱性化合物组成，所述陶瓷涂层包含C键合到金属，半金属元素或其组合。 改进的烟灰催化剂可用于催化柴油微粒过滤器。 在制备催化柴油颗粒过滤器的一种方法中，改进的过滤器通过使其上具有碱性催化剂的多孔陶瓷体与其上涂覆碱催化剂与有机陶瓷前体进行接触来制备，将陶瓷体加热到足够大的温度 分解有机陶瓷前体以在多孔陶瓷体上形成烟灰催化剂，而不会使相当大量的碱催化剂挥发掉。