公开(公告)号：US10584288B2

公开(公告)日：2020-03-10

申请号：US14379137

申请日：2013-02-14

申请人： Advanced Refining Technologies LLC

发明人： Viorel D. Duma ,  Matthew P. Woods

IPC分类号： C01G45/10 ,  C10G45/10 ,  B01J37/03 ,  B01J21/06 ,  B01J35/10 ,  C10G45/08 ,  B01J27/19 ,  B01J37/02 ,  B01J37/00 ,  B01J23/24 ,  B01J23/40 ,  B01J23/652 ,  B01J23/74 ,  B01J23/85 ,  B01J27/185 ,  B01J27/188 ,  B01J37/08 ,  C10G45/06

摘要： Catalyst supports, supported catalysts, and a method of preparing and using the catalysts for the demetallation of metal-containing heavy oil feedstocks are disclosed. The catalyst supports comprise alumina and 5 wt % or less titania. Catalyst prepared from the supports have at least 30 to 80 volume percent of its pore volume in pores having a diameter of between 200 and 500 angstroms. Catalysts in accordance with the invention exhibit improved catalytic activity and stability to remove metals from heavy feedstocks during a hydroconversion process. The catalysts also exhibit increased sulfur and MCR conversion.

公开(公告)号：US10533141B2

公开(公告)日：2020-01-14

申请号：US16103897

申请日：2018-08-14

申请人： Mag{tilde over (e)}mã Technology, LLC

发明人： Michael Joseph Moore ,  Bertrand Ray Klussmann ,  Carter James White

IPC分类号： C10G45/04 ,  C10G67/06 ,  C10G45/22 ,  C10G45/08 ,  C10G25/02 ,  C10G25/00 ,  B01D53/14 ,  C10G7/00 ,  C10G45/06 ,  C10L1/04 ,  C10G45/02 ,  C10G67/02 ,  B01J8/00 ,  B01J8/04 ,  B01J21/04 ,  B01J23/24 ,  B01J23/40 ,  B01J23/74 ,  C10G65/16 ,  B01J8/02 ,  C10G47/02 ,  C10G69/02

摘要： A multi-stage process for transforming a high sulfur ISO 8217 compliant Feedstock Heavy Marine Fuel Oil involving a core desulfurizing process that produces a Product Heavy Marine Fuel Oil that can be used as a feedstock for subsequent refinery process such as anode grade coking, needle coking and fluid catalytic cracking. The Product Heavy Marine Fuel Oil exhibits multiple properties desirable as a feedstock for those processes including a sulfur level has a maximum sulfur content (ISO 14596 or ISO 8754) between the range of 0.05 mass % to 1.0 mass. A process plant for conducting the process is also disclosed.

公开(公告)号：US10449519B2

公开(公告)日：2019-10-22

申请号：US15553773

申请日：2016-02-23

申请人： LG Hausys, Ltd.

发明人： Joo-Hwan Seo ,  Dong-Il Lee ,  Seong-Moon Jung ,  Ha-Na Kim ,  Hye-Youn Jang

IPC分类号： B01J23/06 ,  B01J23/20 ,  B01J23/24 ,  B01J23/34 ,  B01J23/38 ,  B01J23/72 ,  B01J23/745 ,  B01J23/75 ,  B01J23/755 ,  B01J23/652 ,  B01D39/00 ,  B01J21/06 ,  B01J21/18 ,  B01D53/88 ,  B01J35/00 ,  B01J35/06 ,  C09D7/40 ,  B01D46/00 ,  B01D53/02 ,  B01D53/86 ,  B01J35/02 ,  B01J35/10 ,  B01J37/34

摘要： Disclosed is a visible light-activated photocatalytic coating composition comprising a visible light active photocatalytic material and an aqueous solvent.

公开(公告)号：US10329219B2

公开(公告)日：2019-06-25

申请号：US14782457

申请日：2014-03-28

申请人： SCG CHEMICALS COMPANY LIMITED

发明人： Kongkiat Suriye ,  Wuttithep Jareewatchara ,  Pruphanya Lekngam ,  Anuwat Nonkhamwong ,  Kesada Sutthiumporn

IPC分类号： C07C5/333 ,  B01J23/24 ,  B01J21/10 ,  B01J23/30 ,  C07C6/04 ,  B01J38/02 ,  B01J38/12 ,  B01J35/00 ,  B01J21/08 ,  B01J23/92 ,  B01J29/08 ,  B01J29/90 ,  B01J37/08 ,  B01J37/18

摘要： The invention relates to a process for converting paraffin to olefin comprising the following steps: (a) providing a hydrocarbon feedstock containing at least one paraffin having 1 to 12 carbon atoms and at least one olefin having 2 to 12 carbon atoms; (b) providing a catalyst containing at least one Group VIA and/or Group VIIA transition metal on a solid support; (c) pretreating the catalyst by contacting the catalyst with at least one reducing gas and at least one oxidizing gas; and (d) contacting the by hydrocarbon feedstock and the pretreated catalyst at a temperature in the range of 200° C. to 600° C., preferably 320° C. to 450° C. and to a catalyst for use therein.

公开(公告)号：US10308884B2

公开(公告)日：2019-06-04

申请号：US16048914

申请日：2018-07-30

申请人： Magema Technology, LLC

发明人： Bertrand R. Klussman ,  Michael J. Moore

IPC分类号： C10L1/04 ,  C10G45/02 ,  C10G67/06 ,  B01D53/14 ,  C10G7/00 ,  C10G45/06 ,  C10G67/02 ,  B01J8/00 ,  B01J8/04 ,  B01J21/04 ,  B01J23/24 ,  B01J23/40 ,  B01J23/74 ,  C10G65/16 ,  B01J8/02 ,  C10G45/04 ,  C10G47/02 ,  C10G69/02

摘要： A process for reducing the environmental contaminants in a ISO8217 compliant Feedstock Heavy Marine Fuel Oil, the process involving: mixing a quantity of the Feedstock Heavy Marine Fuel Oil with a quantity of Activating Gas mixture to give a feedstock mixture; contacting the feedstock mixture with one or more catalysts to form a Process Mixture from the feedstock mixture; separating the Product Heavy Marine Fuel Oil liquid components of the Process Mixture from the gaseous components and by-product hydrocarbon components of the Process Mixture and, discharging the Product Heavy Marine Fuel Oil. The Product Heavy Marine Fuel Oil is compliant with ISO 8217A for residual marine fuel oils and has a sulfur level has a maximum sulfur content (ISO 14596 or ISO 8754) between the range of 0.05% wt. to 0.50% wt. The Product Heavy Marine Fuel Oil can be used as or as a blending stock for an ISO 8217 compliant, IMO MARPOL Annex VI (revised) compliant low sulfur or ultralow sulfur heavy marine fuel oil. A device for conducting the process is also disclosed.

公开(公告)号：US10105683B2

公开(公告)日：2018-10-23

申请号：US14767077

申请日：2014-02-20

申请人： SUMITOMO ELECTRIC INDUSTRIES, LTD.

发明人： Soichiro Okubo ,  Takeshi Hikata ,  Risa Utsunomiya ,  Teruaki Matsuba ,  Hitoshi Matsumoto ,  Yugo Higashi

IPC分类号： B01J21/18 ,  B01J23/38 ,  B01J23/76 ,  B01J23/755 ,  B01J37/02 ,  B01J23/20 ,  B01J23/34 ,  C01B32/05 ,  C01B32/15 ,  B01J35/00 ,  B01J37/34 ,  B01J23/24 ,  B01J23/48 ,  B01J23/56 ,  B01J23/74

摘要： A porous member includes a base member and carbon nanostructures. The base member includes a porous body having a porosity of more than or equal to 80%. The carbon nanostructures are formed on a surface of the base member, and have a width of less than or equal to 100 nm. A catalyst member includes a catalyst arranged on surfaces of the carbon nano structures.

公开(公告)号：US20170291862A1

公开(公告)日：2017-10-12

申请号：US15633336

申请日：2017-06-26

申请人： ASAHI GLASS COMPANY,LIMITED

发明人： Yusuke TAKAHIRA

IPC分类号： C07C6/04 ,  B01J23/24 ,  C07C21/18

CPC分类号： C07C6/04 ,  B01J23/24 ,  C07B61/00 ,  C07C17/00 ,  C07C21/18 ,  C07C41/18 ,  C07C41/22 ,  C07C43/17 ,  C07C67/28 ,  C07C69/007 ,  C07D207/18

摘要： A method for producing at least one olefin compound selected from the group consisting of a compound of formula (51), a compound of formula (52), a compound of formula (53), and a compound of formula (54), the method including reacting an olefin compound of formula (21) with a olefin compound of formula (31) in the presence of at least one metal catalyst selected from the group consisting of a compound of formula (11), a compound of formula (12), a compound of formula (13), a compound of formula (14), and a compound of formula (15).

公开(公告)号：US09579632B2

公开(公告)日：2017-02-28

申请号：US13990440

申请日：2011-12-02

申请人： Jihad M. Dakka ,  Lorenzo C. DeCaul ,  Terry E. Helton ,  Keith H. Kuechler ,  Jenna L. Wallace

发明人： Jihad M. Dakka ,  Lorenzo C. DeCaul ,  Terry E. Helton ,  Keith H. Kuechler ,  Jenna L. Wallace

IPC分类号： B01J23/62 ,  B01J35/00 ,  B01J37/02 ,  C07C37/06 ,  C07C37/07 ,  B01J21/08 ,  B01J23/24 ,  B01J23/32

CPC分类号： B01J23/626 ,  B01J21/08 ,  B01J23/24 ,  B01J23/32 ,  B01J35/0066 ,  B01J37/0207 ,  C07C37/06 ,  C07C37/07 ,  Y02P20/52 ,  C07C39/04

摘要： A catalyst composition comprises (i) a support; (ii) a dehydrogenation component comprising at least one metal or compound thereof selected from Groups 6 to 10 of the Periodic Table of Elements; and (iii) tin or a tin compound, wherein the tin is present in an amount of 0.01 wt % to about 0.25 wt %, the wt % based upon the total weight of the catalyst composition.

摘要翻译： 催化剂组合物包含（i）载体; （ii）包含选自元素周期表第6至10族的至少一种金属或其化合物的脱氢组分; 和（iii）锡或锡化合物，其中锡的存在量为0.01重量％至约0.25重量％，基于催化剂组合物的总重量的wt％。

公开(公告)号：US09126194B2

公开(公告)日：2015-09-08

申请号：US13408226

申请日：2012-02-29

申请人： Heiko Weiner ,  Zhenhua Zhou ,  Radmila Jevtic ,  Victor J. Johnston

发明人： Heiko Weiner ,  Zhenhua Zhou ,  Radmila Jevtic ,  Victor J. Johnston

IPC分类号： C07C29/149 ,  B01J37/02 ,  B01J21/08 ,  B01J23/06 ,  B01J23/10 ,  B01J23/14 ,  B01J23/24 ,  B01J23/38 ,  B01J23/42 ,  B01J23/52 ,  B01J23/62 ,  B01J23/70

CPC分类号： B01J37/0217 ,  B01J21/08 ,  B01J23/06 ,  B01J23/10 ,  B01J23/14 ,  B01J23/24 ,  B01J23/38 ,  B01J23/42 ,  B01J23/52 ,  B01J23/626 ,  B01J23/70 ,  B01J37/0207 ,  B01J37/0242 ,  B01J37/0244 ,  C07C29/149 ,  C07C31/08

摘要： The present invention relates to a catalyst composition having a support that contains tin. The catalyst is used for converting acetic acid to ethanol. The catalyst may also comprise one or more active metals and a support modifier.

摘要翻译： 本发明涉及具有含锡的载体的催化剂组合物。 催化剂用于将乙酸转化为乙醇。 催化剂还可以包含一种或多种活性金属和载体改性剂。

公开(公告)号：US09067191B2

公开(公告)日：2015-06-30

申请号：US13498165

申请日：2010-09-14

申请人： Hiroyuki Seki ,  Yoshiaki Fukui ,  Masanori Yoshida ,  Shogo Tagawa ,  Tomoyasu Kagawa

发明人： Hiroyuki Seki ,  Yoshiaki Fukui ,  Masanori Yoshida ,  Shogo Tagawa ,  Tomoyasu Kagawa

IPC分类号： B01J21/06 ,  B01J21/12 ,  C10G45/06 ,  C10G45/08 ,  B01J21/08 ,  B01J23/24 ,  B01J23/74 ,  B01J23/85 ,  B01J23/882 ,  B01J23/883 ,  B01J35/00 ,  B01J35/10 ,  C10G45/04 ,  B01J37/28

CPC分类号： B01J21/063 ,  B01J21/08 ,  B01J21/12 ,  B01J23/24 ,  B01J23/74 ,  B01J23/85 ,  B01J23/882 ,  B01J23/883 ,  B01J35/002 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1061 ,  B01J35/108 ,  B01J37/28 ,  C10G45/04 ,  C10G45/06 ,  C10G45/08 ,  C10G2300/1059 ,  C10G2300/1074 ,  C10G2300/202 ,  C10G2300/301 ,  C10G2300/4018 ,  C10G2300/70

摘要： The present invention provides a hydrodesulfurization catalyst that exhibits a high desulfurization activity when used in hydrotreatment of hydrocarbon oil, in particular straight-run gas oil. The catalyst includes at least one type of metal component selected from Groups VIA and VIII in the periodic table, supported on a silica-titania-alumina support where the total of the diffraction peak area indicating the crystal structure of anatase titania (101) planes and the diffraction peak area indicating the crystal structure of rutile titania (110) planes is ¼ or less of the diffraction peak area indicating the aluminum crystal structure ascribed to γ-alumina (400) planes, as measured by X-ray diffraction analysis. The catalyst has (a) a specific surface area (SA) of 150 m2/g or greater, (b) a total pore volume (PVo) of 0.30 ml/g or greater, (c) an average pore diameter (PD) of 6 to 15 nm (60 to 150 Å), and (d) the ratio of the pore volume (PVp) of pores having diameters within ±30 percent of the average pore diameter (PD) being 70 percent or greater of the total pore volume (PVo).

摘要翻译： 本发明提供一种加氢脱硫催化剂，其在用于烃油，特别是直馏瓦斯油的加氢处理中表现出高的脱硫活性。 催化剂包括至少一种选自元素周期表中的VIA和VIII族的金属组分，负载在二氧化硅 - 二氧化钛 - 氧化铝载体上，其中表示锐钛型二氧化钛（101）晶面的晶体结构的衍射峰面积的总和和 表示金红石型二氧化钛（110）面的晶体结构的衍射峰面积，通过X射线衍射分析测定，表示归因于γ-氧化铝（400）面的铝结晶结构的衍射峰面积的1/4以下。 催化剂的（a）比表面积（SA）为150m 2 / g以上，（b）总孔体积（PVo）为0.30ml / g以上，（c）平均孔径（PD）为 6〜15nm（60〜150），（d）直径在平均孔径（PD）±30％以内的孔的孔体积（PVp）的比例为总孔体积的70％以上 （PVo）。