公开(公告)号：US11565229B2

公开(公告)日：2023-01-31

申请号：US16342262

申请日：2017-10-10

申请人： ETH Zurich

发明人： Aldo Steinfeld ,  Philipp Furler ,  Andreas Haselbacher ,  Lukas Geissbühler

IPC分类号： B01J8/00 ,  B01J8/02 ,  B01J8/06 ,  B01J19/00 ,  B01J19/24 ,  C01B3/06 ,  C01B3/34 ,  C07C1/02

摘要： Disclosed is a thermochemical reactor system and method for a temperature swing cyclic process with integrated heat recovery having at least two modules, wherein each module includes at least one chemical reaction zone and at least one thermal energy storage unit. The at least two modules are operationally connected for at least one heat transfer fluid for transporting heat between the two modules. Each chemical reaction zone includes at least one reacting material that undergoes in a reversible manner an endothermic reaction at temperature Tendo and an exothermic reaction at temperature Texo, wherein Tendo and Texo differ from each other. The at least one reacting material is provided in at least one encapsulation within each of the chemical reaction zones such that a contact of the reacting material and the at least one heat transfer fluid is avoided.

公开(公告)号：US11136243B1

公开(公告)日：2021-10-05

申请号：US17095613

申请日：2020-11-11

申请人： Nant Holdings IP, LLC ,  Calcean Minerals & Materials LLC

发明人： Patrick Soon-Shiong ,  Anthony Myers

IPC分类号： C01F11/06 ,  C04B2/04 ,  C01B32/50 ,  F24S20/30 ,  C07C29/159 ,  C07C1/02 ,  C01B32/186

摘要： Methods and systems for making calcium oxide (CaO), carbon dioxide (CO2) and/or calcium hydroxide (Ca(OH)2) from aragonite, for example, oolitic aragonite, are provided. The method can include applying solar energy, for example, by focusing one or more mirrors in one or more heliostats, to heat a reactant mixture in a vessel. The reactant mixture includes oolitic aragonite and can be heated to a temperature from 500° C. to 950° C. The system can include a vessel and a means for applying solar energy to heat a supply of oolitic aragonite disposed inside the vessel. Methods of converting the CO2 to ethanol, ethylene, graphene, and/or methane are also provided.

公开(公告)号：US10151481B2

公开(公告)日：2018-12-11

申请号：US13825211

申请日：2011-09-16

申请人： Günter Schmid

发明人： Günter Schmid

IPC分类号： F23J7/00 ,  B01D53/62 ,  C01B21/06 ,  C01C1/02 ,  C07C29/151 ,  F23B99/00 ,  F23G7/06 ,  F25J3/04 ,  C07C1/02 ,  F23J15/00 ,  F23L7/00 ,  B01D53/14

摘要： A material is utilized with an electropositive metal. This can be used as post-oxyfuel process for oxyfuel power stations. Here, an energy circuit is realized by the material utilization. An electropositive metal, in particular lithium, serves as energy store and as central reaction product for the conversion of nitrogen and carbon dioxide into ammonia and methanol. The power station thus operates without CO2 emissions.

公开(公告)号：US09758740B2

公开(公告)日：2017-09-12

申请号：US14920907

申请日：2015-10-23

申请人： Wuhan Kaidi Engineering Technology Research Institute Co., Ltd.

发明人： Yanfeng Zhang ,  Yilong Chen ,  Zhilong Wang ,  Zhangjian Fang ,  Xingcai Zheng

IPC分类号： B01J7/00 ,  C10L3/00 ,  C10L3/06 ,  C10L3/08 ,  C07C1/00 ,  C07C1/02 ,  C07C1/12

CPC分类号： C10L3/08 ,  B01J7/00 ,  C07C1/12 ,  C10L3/06 ,  C10L2290/06 ,  C10L2290/10 ,  C10L2290/38 ,  C10L2290/42 ,  C10L2290/54 ,  Y02E60/366 ,  Y02P20/133 ,  C07C9/04

摘要： A device for converting carbon dioxide in flue gas into natural gas using dump energy. The device includes a transformer and rectifier device, an electrolytic cell, a turbine, a carbon dioxide heater, a primary fixed bed reactor, a secondary fixed bed reactor, a natural gas condenser, and a process water line. An outlet of the transformer and rectifier device is connected to a power interface of the electrolytic cell, a gas-liquid outlet of a cathode of the electrolytic cell is connected to a gas-liquid inlet of a hydrogen separator, and a liquid outlet of the hydrogen separator is connected to a liquid reflux port of the cathode of the electrolytic cell.

公开(公告)号：US09757714B2

公开(公告)日：2017-09-12

申请号：US14763914

申请日：2014-02-24

申请人： Haldor Topsøe A/S

发明人： Herman Teunissen ,  Thoa Thi Minh Nguyen ,  Jens Sehested

IPC分类号： C07C1/02 ,  C07C1/04 ,  C07C1/10 ,  C07C1/12 ,  B01J23/83 ,  B01J37/03 ,  B01J21/04 ,  B01J23/755 ,  B01J35/00 ,  B01J35/10 ,  B01J37/00 ,  C01B3/40 ,  C10G2/00 ,  B01J23/10 ,  C10L3/08 ,  B01J37/08 ,  B01J37/10 ,  B01J37/18

CPC分类号： B01J23/83 ,  B01J21/04 ,  B01J23/10 ,  B01J23/755 ,  B01J35/002 ,  B01J35/006 ,  B01J35/1004 ,  B01J37/0009 ,  B01J37/031 ,  B01J37/08 ,  B01J37/10 ,  B01J37/18 ,  B01J2523/00 ,  C01B3/40 ,  C01B2203/0233 ,  C01B2203/0261 ,  C01B2203/1058 ,  C01B2203/1082 ,  C07C1/0435 ,  C10G2/33 ,  C10L3/08 ,  C10L2290/42 ,  Y02P20/52 ,  B01J2523/31 ,  B01J2523/3706 ,  B01J2523/48 ,  B01J2523/847 ,  B01J2523/3718

摘要： In a broad form the present disclosure relates to a stabilized catalyst support comprising in oxide form; aluminum, zirconium, and one or more lanthanoid elements taken from the lanthanoid group of the periodic system characterized in that at least a part of the aluminum is present as transition alumina such as χ, κ, γ, δ, η, ρ and θ-alumina, characterized in the concentration of zirconium being at least 1.5 wt %, 5 wt % or 10 wt %, the concentration of lanthanoid being at least 0.5 wt %, 1.0 wt %, 2 wt % or 4 wt % and the combined concentration of zirconium and lanthanoid being at least 4 wt %, 7 wt % or 10 wt %, with the associated benefit of a support comprising transition alumina being a high surface area due to the small crystallites typical for transition alumina, and the benefit of the combined presence of oxides of zirconium and lanthanoid in the stated amounts being that at these levels these oxides stabilize the structure of the transition alumina.

公开(公告)号：US09662639B2

公开(公告)日：2017-05-30

申请号：US15152245

申请日：2016-05-11

申请人： University of Wyoming

发明人： Maohong Fan ,  Mingchen Tang

IPC分类号： C01B3/38 ,  C07C1/02 ,  B01J23/10 ,  B01J23/70 ,  B01J23/74 ,  B01J23/83 ,  C01B3/40

CPC分类号： B01J23/83 ,  B01J23/002 ,  B01J35/1014 ,  B01J37/0036 ,  B01J37/035 ,  B01J37/32 ,  B01J2523/00 ,  C01B3/40 ,  C01B2203/0238 ,  C01B2203/1047 ,  C01B2203/1088 ,  C01B2203/1241 ,  Y02P20/52 ,  B01J2523/31 ,  B01J2523/3706 ,  B01J2523/3712 ,  B01J2523/842

摘要： The invention relates to CeO2 and La2O3 for catalyzing Fe2O3—Al2O3 based chemical-looping reforming of CH4 with CO2 (CL-DRM). The reaction performance of all the composite oxygen carriers was evaluated in a fixed-bed reactor at atmospheric pressure condition. The influencing factors, including temperature and time-on-stream (TOS) were investigated. The characteristics of the oxygen carriers were checked with Brunauer-Emmett-Teller (BET) analysis and X-ray diffraction (XRD). The reducibility of the composite materials was elucidated with temperature-programmed reduction by CH4 (CH4-TPR). Preliminary experimental observations suggest that the simultaneous presence of CeO2 and La2O3 can not only enhance the reactivity of Fe2O3—Al2O3 toward CH4 oxidation and its oxygen releasing rate for fast reaction kinetics, but also improve the reactivity of its reduced form toward CO2 splitting.

公开(公告)号：US09464010B2

公开(公告)日：2016-10-11

申请号：US14442007

申请日：2013-11-12

申请人： UNIVERSITY OF ONTARIO INSTITUTE OF TECHNOLOGY

发明人： Greg Naterer ,  Zhaolin (Forest) Wang

IPC分类号： B01J8/00 ,  B01J8/18 ,  B01J8/24 ,  B01J8/34 ,  C25B1/00 ,  C25B1/14 ,  C25B1/16 ,  C25B1/24 ,  C25B1/26 ,  B01D53/14 ,  C07C1/12 ,  C07C29/151 ,  C07C43/02 ,  C01C1/04 ,  C10G2/00 ,  C25B1/04 ,  B01D53/00 ,  B01D53/02 ,  B01D53/04 ,  C07C1/00 ,  C07C1/02 ,  C07C29/15 ,  C07C43/00 ,  C01C1/00 ,  C01C1/02

CPC分类号： C07C1/12 ,  B01D53/04 ,  B01D53/1425 ,  B01D53/1475 ,  B01D2257/504 ,  B01J8/002 ,  B01J8/003 ,  B01J8/0035 ,  B01J8/1827 ,  B01J8/28 ,  B01J8/34 ,  B01J2208/00752 ,  B01J2208/00761 ,  B01J2208/00796 ,  C01B3/063 ,  C01B2203/061 ,  C01B2203/068 ,  C01C1/0488 ,  C07C29/1518 ,  C07C43/02 ,  C10G2/50 ,  C10G2300/4043 ,  C25B1/04 ,  C25B1/16 ,  C25B1/26 ,  Y02C10/06 ,  Y02C10/08 ,  Y02E60/366 ,  Y02P20/129 ,  Y02P20/152 ,  Y02P20/52 ,  Y02P30/446 ,  C07C31/04 ,  C07C9/04

摘要： Systems, methods, and devices for producing hydrogen and capturing CO2 from emissions combine both H2 production and CO2 capture processes in forms of thermochemical cycles to produce useful products from captured CO2. The thermochemical cycles are copper-chlorine (Cu—Cl) and magnesium-chlorine-sodium/potassium cycles (Mg—Cl—Na/K—CO2). One system comprises a Cu—Cl cycle, a CO2 capture loop, and a hydrogenation cycle. Another system comprises an Mg—Cl—Na/K—CO2 cycle and a hydrogenation cycle. Devices for hydrogen production, CO2 capture, hydrogenation, and process and equipment integration include a two-stage fluidized/packed bed, hybrid two-stage spray-fluidized/packed bed reactor, a two-stage wet-mode absorber, a hybrid two-stage absorber, and a catalyst packed/fluidized bed reactor.

摘要翻译： 用于生产氢气和从排放物捕获二氧化碳的系统，方法和装置结合H2生产和CO2捕获过程，以热化学循环的形式，从捕获的二氧化碳产生有用的产物。 热化学循环是铜 - 氯（Cu-Cl）和镁 - 氯 - 钠/钾循环（Mg-Cl-Na / K-CO2）。 一个系统包括Cu-Cl循环，CO 2捕获循环和氢化循环。 另一种体系包括Mg-Cl-Na / K-CO2循环和氢化循环。 用于氢气生产，二氧化碳捕获，氢化和过程和设备集成的装置包括两级流化/填充床，混合两级喷雾流化/填充床反应器，两级湿式吸收器， 阶段吸收器和催化剂填充/流化床反应器。

公开(公告)号：US09434613B2

公开(公告)日：2016-09-06

申请号：US14410045

申请日：2013-06-12

申请人： Haldor Topsøe A/S

发明人： Lari Bjerg Knudsen ,  Martin Frahm Jensen

IPC分类号： C07C27/00 ,  C07C1/02 ,  C01B3/38 ,  B01J19/24 ,  C01C1/04 ,  C10G2/00 ,  C07C29/151 ,  C07C41/01

CPC分类号： B01J7/00 ,  B01J19/0046 ,  B01J19/2445 ,  B01J19/245 ,  B01J2219/00087 ,  B01J2219/00103 ,  B01J2219/00495 ,  B01J2219/00585 ,  B01J2219/0059 ,  B01J2219/00594 ,  B01J2219/00756 ,  B01J2219/24 ,  C01B3/382 ,  C01B3/386 ,  C01B3/388 ,  C01B2203/0205 ,  C01B2203/0227 ,  C01B2203/0233 ,  C01B2203/0244 ,  C01B2203/0255 ,  C01B2203/0261 ,  C01B2203/06 ,  C01B2203/061 ,  C01B2203/062 ,  C01B2203/068 ,  C01B2203/0833 ,  C01B2203/0844 ,  C01B2203/0883 ,  C01B2203/0894 ,  C01B2203/1235 ,  C01B2203/1258 ,  C01B2203/141 ,  C01B2203/142 ,  C01B2203/143 ,  C01B2203/1604 ,  C01C1/04 ,  C07C29/1518 ,  C07C41/01 ,  C10G2/30 ,  Y02P20/129

摘要： The invention relates to the production of synthesis gas by means of particularly a series arrangement of heat exchange reforming and autothermal reforming stages, in which the heat required for the reforming reactions in the heat exchange reforming stage, is provided by hot effluent synthesis gas from the autothermal reforming stage. More particularly, the invention relates to optimisation of the operation and control of an arrangement of heat exchange reforming and autothermal reforming stages and introduction of an additional waste heat boiler.

摘要翻译： 本发明涉及通过特别是热交换重整和自热重整阶段的串联布置来生产合成气，其中热交换重整阶段中的重整反应所需的热量由来自 自热重整阶段。 更具体地，本发明涉及优化热交换重整和自热重整阶段的布置的操作和控制以及引入另外的废热锅炉。

公开(公告)号：US09421509B2

公开(公告)日：2016-08-23

申请号：US14004954

申请日：2012-03-13

申请人： Shinya Arai

发明人： Shinya Arai

IPC分类号： B01J8/00 ,  B01J8/08 ,  B01J19/00 ,  B01J19/24 ,  C10G2/00 ,  C07C1/00 ,  C07C1/02

CPC分类号： B01J8/08 ,  B01J2208/00796 ,  C07C1/02 ,  C10G2/00 ,  C10G2300/1022 ,  C10G2300/304 ,  C10G2300/4031

摘要： The hydrocarbon production apparatus is provided with a gas-liquid separator for cooling gaseous state hydrocarbons drawn out from a gas phase portion of a reactor for the Fischer-Tropsch synthesis reaction and liquefying a portion of the hydrocarbons. A light liquid hydrocarbon supply line for supplying light hydrocarbons is disposed between a downstream side line which is downstream from the last stage of a gas-liquid separating unit of the gas-liquid separator, and an upstream side line which is upstream from the last stage of the gas-liquid separating unit of the gas-liquid separator, wherein the downstream side line is a liquid hydrocarbon line on the downstream side through which the light hydrocarbons having cloud points lower than the temperature at an outlet of a cooler in the last stage of the gas-liquid separating unit are flowed.

摘要翻译： 烃制造装置设置有用于冷却从费 - 托合成反应的反应器的气相部分抽出的气态烃并液化一部分烃的气液分离器。 用于供给轻质烃的轻液态碳氢化合物供给管路配置在气液分离器的气液分离装置的最后级的下游侧的下游侧管线和最后级的上游侧的上游侧管线 气液分离器的气液分离单元，其中下游侧线是下游侧的液体碳氢化合物管线，其中浊点低于最后阶段的冷却器出口处的温度 的气液分离装置。

公开(公告)号：US09327970B2

公开(公告)日：2016-05-03

申请号：US14004321

申请日：2012-03-09

申请人： Satoru Nakamura ,  Akio Tada

发明人： Satoru Nakamura ,  Akio Tada

IPC分类号： C07C1/02 ,  C07C27/00 ,  C01B3/26 ,  C10K3/02 ,  C10K3/06 ,  C01B31/02 ,  C01B31/18 ,  B01J7/00 ,  C07C29/151 ,  B01J38/04 ,  B01J23/94 ,  B01J23/745 ,  B01J23/755 ,  B01J23/78 ,  B82Y30/00 ,  B82Y40/00 ,  B01J23/80

CPC分类号： B01J19/2445 ,  B01J7/00 ,  B01J23/745 ,  B01J23/755 ,  B01J23/78 ,  B01J23/80 ,  B01J23/94 ,  B01J38/04 ,  B01J2219/00103 ,  B01J2219/24 ,  B82Y30/00 ,  B82Y40/00 ,  C01B3/26 ,  C01B32/15 ,  C01B32/40 ,  C01B2203/0277 ,  C01B2203/043 ,  C01B2203/048 ,  C01B2203/0827 ,  C01B2203/1235 ,  C07C29/1516 ,  C10K3/026 ,  C10K3/06 ,  Y02P20/129 ,  Y02P20/584

摘要： A synthesis gas and nanocarbon production method has a lower hydrocarbon decomposition step for decomposing lower hydrocarbon to produce hydrogen and nanocarbon, a carbon dioxide reduction step for reacting a part of the nanocarbon produced with carbon dioxide to produce carbon monoxide, and a mixing step for mixing the hydrogen and carbon monoxide produced in a predetermined ratio, thereby nanocarbon and a synthesis gas having a desired gas ratio can be simultaneously produced easily.

摘要翻译： 合成气和纳米碳生产方法具有较低的烃分解步骤，用于分解低级碳氢化合物以产生氢气和纳米碳;二氧化碳还原步骤，用于使产生的二氧化碳的一部分纳米碳与一氧化碳反应，以及混合步骤 可以容易地同时制造以规定比例生成的氢和一氧化碳，从而可以容易地同时制造纳米碳和具有所需气体比的合成气。