公开(公告)号：US20050132959A1

公开(公告)日：2005-06-23

申请号：US11014488

申请日：2004-12-16

申请人： Hartmut Bauch ,  Lars Bewig ,  Lutz Klippe ,  Thomas Kupper

发明人： Hartmut Bauch ,  Lars Bewig ,  Lutz Klippe ,  Thomas Kupper

IPC分类号： C23C16/448 ,  B01D3/42 ,  B05C11/00 ,  C23C16/00 ,  F25J3/00

CPC分类号： C23C16/448

摘要： A gas supply device for delivering precursors with a low vapor pressure to CVD coating systems. The gas supply device has a supply container for the precursor which is at a first temperature T1, an intermediate storage device for intermediately storing the vaporous precursor at a second temperature T2 and at a constant pressure p2, a first gas line between the supply container and the intermediate storage device and a second gas line for removing gas from the intermediate storage device. The gas supply device is developed in such a way that the first temperature T1 is higher than the second temperature T2. The lower temperature T2 of the intermediate storage device facilitates maintenance work on the same, while the precursor evaporates at a greater rate at the higher temperature T1 in the supply container. A first precursor vapor may be mixed with a gas and/or a second precursor vapor in the intermediate storage device. The partial pressure of the first precursor vapor is lower than that of the undiluted first precursor vapor at a constant overall pressure in the intermediate storage device, so that the temperature T2 of the intermediate storage device and the successive lines can be reduced.

摘要翻译： 一种气体供应装置，用于将CVD蒸气压低的前体输送到CVD涂层系统。 气体供给装置具有用于前体的供给容器，该供应容器处于第一温度T 1，中间储存装置用于在第二温度T 2和恒定压力p 2下将气态前体中间储存在第一温度T 1之间的第一气体管线 供给容器和中间储存装置以及用于从中间储存装置除去气体的第二气体管线。 气体供给装置以第一温度T 1高于第二温度T 2的方式展开。 中间储存装置的较低温度T 2有助于维护工作，而前体在供应容器中的较高温度T 1下以更大的速率蒸发。 第一前体蒸气可以与中间存储装置中的气体和/或第二前体蒸气混合。 在中间储存装置中，在恒定的总体压力下，第一前体蒸气的分压低于未稀释的第一前体蒸汽的分压，从而可以减少中间储存装置的温度T 2和连续的管线。

公开(公告)号：US07413767B2

公开(公告)日：2008-08-19

申请号：US11014488

申请日：2004-12-16

申请人： Hartmut Bauch ,  Lars Bewig ,  Lutz Klippe ,  Thomas Küpper

发明人： Hartmut Bauch ,  Lars Bewig ,  Lutz Klippe ,  Thomas Küpper

IPC分类号： C23C16/00

CPC分类号： C23C16/448

摘要： A method for producing optical functional coatings comprising niobium, tantalum, titanium or aluminum by supplying a precursor gas of low vapor pressure in a CVD coating system. A precursor selected from the group consisting of Nb, Ta, Ti, and Al compounds having a vapor pressure is maintained within a first supply container at a first temperature T1 and a first pressure p1. Precursor vapor of the precursor is supplied from the first supply container to an intermediate storage device through a first gas line which fluidly communicates the first supply container and the intermediate storage device. A carrier gas or reaction gas is supplied to the first gas line such that a mixture of the precursor with the carrier gas or the reaction gas is provided. The mixture is maintained in the intermediate storage device at a constant second pressure p2 lower than the first pressure p1 and at a second temperature T2 lower than the first temperature T1, and the mixture is supplied from the intermediate storage device through a second gas line.

摘要翻译： 一种通过在CVD涂覆系统中提供低蒸气压的前体气体来制造包括铌，钽，钛或铝的光学功能涂层的方法。 选自具有蒸气压的Nb，Ta，Ti和Al化合物的前体的前体在第一温度T 1和第一压力p 1下保持在第一供应容器内。 前体的前体蒸气通过与第一供给容器和中间储存装置流体连通的第一气体管线从第一供给容器供给到中间储存装置。 向第一气体管线供给载气或反应气体，使得前体与载体气体或反应气体的混合物被提供。 将混合物以比第一压力p 1低的恒定的第二压力p 2和低于第一温度T 1的第二温度T 2保持在中间储存装置中，并且将混合物从中间储存装置通过 第二条天然气线。

公开(公告)号：US20060127699A1

公开(公告)日：2006-06-15

申请号：US10527520

申请日：2003-09-13

申请人： Christoph Moelle ,  Lars Bewig ,  Frank Koppe ,  Thomas Kupper ,  Stefan Geisler ,  Stefan Bauer ,  Juergen Dzick ,  Lutz Klippe ,  Christian Henn

发明人： Christoph Moelle ,  Lars Bewig ,  Frank Koppe ,  Thomas Kupper ,  Stefan Geisler ,  Stefan Bauer ,  Juergen Dzick ,  Lutz Klippe ,  Christian Henn

IPC分类号： B32B17/06 ,  B32B9/00 ,  B32B19/00 ,  F24B1/182

CPC分类号： G02B5/285 ,  C03C17/3417 ,  C03C2217/734 ,  C03C2218/156 ,  C03C2218/322 ,  C23C14/0078 ,  C23C14/022 ,  C23C14/34 ,  C23C14/56 ,  C23C28/042 ,  C23C28/42 ,  G02B1/105 ,  G02B1/14 ,  Y10T428/12576 ,  Y10T428/12611

摘要： A scratchproof, temperature-stable protective layer, in particular a scratch-resistant protective layer for cooking hobs is provided. In addition, processes and an apparatus for producing these protective layers are provided. The protective layer includes at least one hard-material layer having a functional layer interrupted by very thin interlayers so that the functional layer has a morphologically dense columnar structure that grows substantially perpendicular to the body surface. The production of layers of this type is achieved by a magnetron sputtering process and a corresponding arrangement, with the tendency of the columnar structures to widen out being reduced by targeted interruption of the growth of the functional layers.

摘要翻译： 提供了耐刮擦，温度稳定的保护层，特别是用于烹饪炉盘的耐刮擦保护层。 此外，提供了用于制造这些保护层的工艺和设备。 保护层包括至少一个具有由非常薄的夹层中断的功能层的硬质材料层，使得功能层具有生长基本垂直于体表的形态致密的柱状结构。 这种类型的层的生产通过磁控溅射工艺和相应的布置实现，其中柱状结构扩大的趋势通过功能层的生长的目标中断而减少。

公开(公告)号：US07931955B2

公开(公告)日：2011-04-26

申请号：US10486056

申请日：2002-08-07

申请人： Stephan Behle ,  Lutz Klippe ,  Matthias Bicker ,  Marten Walther

发明人： Stephan Behle ,  Lutz Klippe ,  Matthias Bicker ,  Marten Walther

IPC分类号： B32B7/02

CPC分类号： C23C16/401 ,  C23C16/045 ,  C23C16/30 ,  C23C16/405 ,  C23C16/515 ,  Y10T428/24967 ,  Y10T428/24975 ,  Y10T428/265 ,  Y10T428/31507 ,  Y10T428/31565 ,  Y10T428/31587 ,  Y10T428/31667

摘要： A composite material having a substrate material and at least one barrier coating on one side of the substrate material. The barrier coating is plasma impulse chemical vapor deposited (PICVD) to the substrate material. The barrier coating includes at least one of material selected from the group consisting of SiOx, TiOx, SnOx, Si3Ny, Nb2Oy, and Al2Oy.

摘要翻译： 一种复合材料，其具有衬底材料和在衬底材料的一侧上的至少一个阻挡涂层。 阻挡涂层是等离子体脉冲化学气相沉积（PICVD）到基底材料。 阻挡涂层包括选自SiO x，TiO x，SnO x，Si 3 N y，Nb 2 O y和Al 2 O y的材料中的至少一种。

公开(公告)号：US20080199622A1

公开(公告)日：2008-08-21

申请号：US12026262

申请日：2008-02-05

申请人： Gabriele Roemer-Scheuermann ,  Andrea Anton ,  Harald Striegler ,  Thomas Kraus ,  Gerhard Weber ,  Lutz Klippe ,  Veit Luther ,  Petra Grewer

发明人： Gabriele Roemer-Scheuermann ,  Andrea Anton ,  Harald Striegler ,  Thomas Kraus ,  Gerhard Weber ,  Lutz Klippe ,  Veit Luther ,  Petra Grewer

IPC分类号： B05D3/02

CPC分类号： C03C17/009 ,  C03C17/007 ,  C03C2217/475 ,  C03C2217/485 ,  C03C2218/113 ,  C03C2218/32 ,  F24C15/10

摘要： A transparent, colorless glass or glass-ceramic panel has a visually dense, high-temperature-stable coating having an organic/inorganic network structure containing filling material particles and a color-imparting pigment. The mechanically stable, visually dense coating has no melt-reaction zone at the surface of the panel, which is coated with the coating, so that it does not impair the panel strength. The inorganic network structure can be made from a SiO2-based sol. The coating is made by introducing the color-imparting pigment and the filling material particles into a reactive organic/inorganic network structure; applying the resulting organic/inorganic network structure containing the pigment and the filling material particles to the panel to coat the panel and then burning-in the organic/inorganic network structure with the pigment and the filling material particles under thermal conditions to form the coating with no melt-reaction zone.

摘要翻译： 透明无色的玻璃或玻璃陶瓷面板具有视觉密实的高温稳定涂层，其具有含有填充材料颗粒和赋颜色颜料的有机/无机网状结构。 机械稳定的，目视密实的涂层在面板的表面没有熔融反应区，涂覆有涂层，从而不会损害面板强度。 无机网状结构可以由SiO 2基的溶胶制成。 通过将着色颜料和填充材料颗粒引入反应性有机/无机网络结构中来制备涂层; 将所得的含有颜料和填充材料颗粒的有机/无机网络结构施加到面板上以涂覆面板，然后在有机/无机网状结构中用颜料和填充材料颗粒在热条件下燃烧以形成具有 无熔融反应区。

公开(公告)号：US07399500B2

公开(公告)日：2008-07-15

申请号：US10637779

申请日：2003-08-07

申请人： Matthias Bicker ,  Stephan Behle ,  Lutz Klippe ,  Andreas Lüttringhaus-Henkel ,  Gregor Arnold

发明人： Matthias Bicker ,  Stephan Behle ,  Lutz Klippe ,  Andreas Lüttringhaus-Henkel ,  Gregor Arnold

IPC分类号： C23C16/511 ,  H05H1/24

CPC分类号： B05D7/50 ,  B05D1/60 ,  B05D1/62 ,  B05D7/02 ,  C23C16/0272 ,  C23C16/045 ,  C23C16/30 ,  C23C16/401 ,  C23C16/515 ,  Y10T428/31504 ,  Y10T428/31681

摘要： A process for applying alternating layers by chemical vapor deposition comprises the process steps of depositing an adhesion-promoter layer on a substrate and applying a barrier layer. Alternating layers comprising organic and inorganic materials are deposited alternately, and in this process the coating time for application of the adhesion-promoter layer is between 0.05 s and 4.0 s and the coating time for application of the inorganic barrier layer is between 0.1 s and 6.0 s. A composite material is also produced using the process.

摘要翻译： 通过化学气相沉积施加交替层的方法包括在衬底上沉积粘合促进剂层并施加阻挡层的工艺步骤。 包含有机和无机材料的交替层交替沉积，并且在该过程中，涂覆粘合促进剂层的涂布时间为0.05s至4.0s，并且施加无机阻挡层的涂布时间为0.1s至6.0 s。 还使用该方法生产复合材料。

公开(公告)号：US07541102B2

公开(公告)日：2009-06-02

申请号：US10936368

申请日：2004-09-08

申请人： Lutz Klippe ,  Cora Krause ,  Jürgen Dzick

发明人： Lutz Klippe ,  Cora Krause ,  Jürgen Dzick

IPC分类号： B32B9/00

CPC分类号： C23C14/568 ,  C03C17/002 ,  C03C17/22 ,  C03C17/225 ,  C03C17/245 ,  C03C2217/22 ,  C03C2217/23 ,  C03C2217/77 ,  C03C2218/155 ,  C03C2218/156 ,  C03C2218/322 ,  C23C14/3442 ,  C23C16/405 ,  C23C16/56 ,  C23C30/00 ,  Y10T428/12576 ,  Y10T428/1259 ,  Y10T428/12618 ,  Y10T428/12771

摘要： A protective layer having at least one hard-material layer is provided. The hard-material layer is formed from one or more of the following materials metal oxide, metal nitride, metal carbide, metal oxynitride, metal carbonitride, and metal oxycarbonitride. The hard-material layer has laterally closely cohesive, crystalline columns which grow perpendicular to the surface of the body. In some embodiments, the crystalline columns have a lateral dimension which is on average less than 1 μm, preferably less than 200 nm, and which predominantly has crystal orientations which, in the case of columnar growth, have little tendency to widen out, the surface roughness of the hard-material layer having an Ra value of less than 50 nm, preferably less than 20 nm.

摘要翻译： 提供具有至少一个硬质材料层的保护层。 硬质材料层由以下金属氧化物，金属氮化物，金属碳化物，金属氮氧化物，金属碳氮化物和金属碳氮氧化物中的一种或多种形成。 硬质材料层具有垂直于身体表面生长的侧向紧密粘合的结晶柱。 在一些实施方案中，晶体柱具有平均小于1um，优选小于200nm的横向尺寸，并且其主要具有晶体取向，其在柱状生长的情况下几乎没有变宽的倾向，表面 Ra值小于50nm，优选小于20nm的硬质材料层的粗糙度。

公开(公告)号：US20050084705A1

公开(公告)日：2005-04-21

申请号：US10936368

申请日：2004-09-08

申请人： Lutz Klippe ,  Cora Krause ,  Jurgen Dzick

发明人： Lutz Klippe ,  Cora Krause ,  Jurgen Dzick

IPC分类号： F24C15/10 ,  B32B9/00 ,  C03C17/00 ,  C03C17/22 ,  C03C17/245 ,  C03C17/34 ,  C04B41/87 ,  C23C14/02 ,  C23C14/08 ,  C23C14/34 ,  C23C14/46 ,  C23C14/56 ,  C23C16/40 ,  C23C16/56 ,  C23C30/00 ,  B32B15/00

CPC分类号： C23C14/568 ,  C03C17/002 ,  C03C17/22 ,  C03C17/225 ,  C03C17/245 ,  C03C2217/22 ,  C03C2217/23 ,  C03C2217/77 ,  C03C2218/155 ,  C03C2218/156 ,  C03C2218/322 ,  C23C14/3442 ,  C23C16/405 ,  C23C16/56 ,  C23C30/00 ,  Y10T428/12576 ,  Y10T428/1259 ,  Y10T428/12618 ,  Y10T428/12771

摘要： Many applications, in particular in the domestic sector, require bodies which have a protective layer with a high scratch resistance and thermal stability. One typical example is glass-ceramic cooking surfaces of modern cooking hobs. The invention provides a corresponding protective layer which comprises at least one hard-material layer formed from a metal oxide and/or metal nitride and/or metal carbide and/or metal oxynitride and/or metal carbonitride and/or metal oxycarbonitride which has laterally closely cohesive, crystalline columns which grow perpendicular to the surface of the body and the lateral dimension of which is on average less than 1 μm, preferably less than 200 nm, and which predominantly has crystal orientations which, in the case of columnar growth, have little tendency to widen out, the surface roughness of the hard-material layer having an Ra value of less than 50 nm, preferably less than 20 nm.

摘要翻译： 许多应用，特别是在国内的应用，需要具有高耐擦伤性和热稳定性的保护层的主体。 一个典型的例子是现代炉灶的玻璃陶瓷烹饪表面。 本发明提供了一种相应的保护层，其包括由金属氧化物和/或金属碳化物和/或金属碳氮化物和/或金属碳氮化物和/或金属碳氮氧化物形成的至少一个硬质材料层，金属氧化物和/ 粘结的结晶柱，其垂直于身体的表面生长，其横向尺寸平均小于1μm，优选小于200nm，并且主要具有晶体取向，在柱状生长的情况下，晶体取向具有少量 倾向于扩大，R a值小于50nm，优选小于20nm的硬质材料层的表面粗糙度。

公开(公告)号：US10028580B2

公开(公告)日：2018-07-24

申请号：US13489992

申请日：2012-06-06

申请人： Birgit Doerk ,  Evelin Weiss ,  Thomas Zenker ,  Ulf Hoffmann ,  Silke Knoche ,  Martin Taplan ,  Friedrich Siebers ,  Thomas Kraus ,  Lutz Klippe ,  Wolfgang Schmidbauer

发明人： Birgit Doerk ,  Evelin Weiss ,  Thomas Zenker ,  Ulf Hoffmann ,  Silke Knoche ,  Martin Taplan ,  Friedrich Siebers ,  Thomas Kraus ,  Lutz Klippe ,  Wolfgang Schmidbauer

IPC分类号： H05B3/68 ,  A47B77/08 ,  C03C10/00 ,  C03C17/00 ,  F24C15/10

摘要： A glass-ceramic cooktop is provided that is made of glass-ceramic material with a flat upper side and an underside. The glass-ceramic material has transmittance values of greater than 0.1% in the visible light range in the total wavelength region greater than 420 nm, a light transmittance in the visible range of 0.8-2.5%, and a transmittance of 0-85% in the infrared at 1600 nm, and wherein the glass-ceramic material has high quartz mixed crystals as the prevalent crystal phase. The underside is flat, unstructured, and coplanar with the upper side.

公开(公告)号：US07361405B2

公开(公告)日：2008-04-22

申请号：US10993741

申请日：2004-11-19

申请人： Gabriele Roemer-Scheuermann ,  Andrea Anton ,  Harald Striegler ,  Thomas Kraus ,  Gerhard Weber ,  Lutz Klippe ,  Veit Luther ,  Petra Grewer

发明人： Gabriele Roemer-Scheuermann ,  Andrea Anton ,  Harald Striegler ,  Thomas Kraus ,  Gerhard Weber ,  Lutz Klippe ,  Veit Luther ,  Petra Grewer

IPC分类号： B32B17/06

CPC分类号： C03C17/009 ,  C03C17/007 ,  C03C2217/475 ,  C03C2217/485 ,  C03C2218/113 ,  C03C2218/32

摘要： A transparent, colorless glass or glass-ceramic panel has a visually dense, high-temperature-stable coating having an organic/inorganic network structure containing filling material particles and a color-imparting pigment. The mechanically stable, visually dense coating has no melt-reaction zone at the surface of the panel, which is coated with the coating, so that it does not impair the panel strength. The inorganic network structure can be made from a SiO2-based sol. The coating is made by introducing the color-imparting pigment and the filling material particles into a reactive organic/inorganic network structure; applying the resulting organic/inorganic network structure containing the pigment and the filling material particles to the panel to coat the panel and then burning-in the organic/inorganic network structure with the pigment and the filling material particles under thermal conditions to form the coating with no melt-reaction zone.

摘要翻译： 透明无色的玻璃或玻璃陶瓷面板具有视觉密实的高温稳定涂层，其具有含有填充材料颗粒和赋颜色颜料的有机/无机网状结构。 机械稳定的，目视密实的涂层在面板的表面没有熔融反应区，涂覆有涂层，从而不会损害面板强度。 无机网状结构可以由SiO 2基的溶胶制成。 通过将着色颜料和填充材料颗粒引入反应性有机/无机网络结构中来制备涂层; 将所得的含有颜料和填充材料颗粒的有机/无机网络结构施加到面板上以涂覆面板，然后在有机/无机网络结构中用颜料和填充材料颗粒在热条件下燃烧以形成涂层 无熔融反应区。