公开(公告)号：US20050154160A1

公开(公告)日：2005-07-14

申请号：US11003959

申请日：2004-12-03

Applicant: Brendan Kneafsey ,  Gerry Coughlan

Inventor： Brendan Kneafsey ,  Gerry Coughlan

IPC: C08F4/52 ,  C08F220/18 ,  C09J4/00 ,  C09J4/02 ,  B32B27/00

CPC classification number: C08F4/52 ,  C09J4/00 ,  Y10T428/31504 ,  Y10T428/31855 ,  Y10T428/31928 ,  Y10T428/31935 ,  C08F220/18

Abstract: Quaternary boron salts are used as initiators of polymerisation in adhesive compositions for bonding low surface energy substrates such as polyolefins. The quaternary boron salts are of the formula I wherein R1 is C1-C10 alkyl, R2, R3 and R4, which may be the same or different, are, C1-C10 alkyl or C3-C10 cycloalkyl, phenyl, or phenyl-substituted C1-C10 alkyl or C3-C10 cycloalkyl, provided that any two of R1-R4 may optionally be part of a carbocyclic ring, and M+ is a metal ion or a quaternary ammonium ion. Particular examples of initiator compounds include sodium tetraethyl borate and lithium tetraethyl borate, lithium phenyl triethyl borate and tetraethylammonium phenyl triethyl borate.

Abstract translation: 在粘合剂组合物中用作键合低表面能基底如聚烯烃的季铵硼盐作为聚合引发剂。 季硼盐具有式I的化合物，其中R 1是C 1 -C 10烷基，R 2， R 3和R 4可以相同或不同，是C 1 -C 10烷基， 烷基或C 3 -C 10环烷基，苯基或苯基取代的C 1 -C 10烷基或 C 3 -C 10环烷基，条件是R 1〜R 4中的任意两个可以任选地为 碳环，M + +是金属离子或季铵离子。 引发剂化合物的具体实例包括硼酸四乙酯和硼酸四乙酯锂，苯基硼酸三乙酯和硼酸四乙基铵苯酯。

公开(公告)号：US06908957B2

公开(公告)日：2005-06-21

申请号：US09922187

申请日：2001-08-03

Applicant: Osama M. Musa ,  Donald E. Herr ,  Nikola A. Nikolic

Inventor： Osama M. Musa ,  Donald E. Herr ,  Nikola A. Nikolic

IPC: C07C43/166 ,  C07C45/00 ,  C07C49/217 ,  C07C69/34 ,  C07C69/347 ,  C07C211/27 ,  C07C211/28 ,  C07C233/05 ,  C07C233/36 ,  C07C271/12 ,  C07C271/16 ,  C07C271/44 ,  C07C271/52 ,  C07C275/14 ,  C07C275/24 ,  C07C309/30 ,  C07C309/73 ,  C07C321/20 ,  C07C333/04 ,  C07D251/34 ,  C07F7/08 ,  C07F7/10 ,  C08F290/06 ,  C09J4/00 ,  C09J4/02 ,  C09J9/02 ,  C09J11/04 ,  C09J109/00 ,  C09J143/04 ,  C09J167/06 ,  C09J171/00 ,  C09J175/14 ,  C09J183/04 ,  H01L21/52 ,  C08K5/20

CPC classification number: C09J4/00 ,  C07C43/166 ,  C07C45/004 ,  C07C49/217 ,  C07C69/34 ,  C07C211/27 ,  C07C211/28 ,  C07C233/36 ,  C07C271/12 ,  C07C271/16 ,  C07C271/52 ,  C07C275/24 ,  C07C309/30 ,  C07D251/34 ,  C07F7/0838 ,  C08K3/08

Abstract: Electron donor compounds, suitable for use as adhesives or as components in adhesives, contain a carbon to carbon double bond attached to an aromatic ring and conjugated with the unsaturation in the aromatic ring.

Abstract translation: 适用于粘合剂或作为粘合剂组分的电子给体化合物含有连接到芳族环上并与芳族环中的不饱和键结合的碳 - 碳双键。

公开(公告)号：US20050031860A1

公开(公告)日：2005-02-10

申请号：US10902931

申请日：2004-08-02

Applicant: Katsuhiro Okada ,  Yasuyuki Sasaki ,  Seishi Suzuki ,  Masayoshi Kuniya

Inventor： Katsuhiro Okada ,  Yasuyuki Sasaki ,  Seishi Suzuki ,  Masayoshi Kuniya

IPC: A61F13/02 ,  C09J4/02 ,  C09J7/02 ,  B32B7/12

CPC classification number: C09J7/29 ,  Y10T428/2848 ,  Y10T428/2891

Abstract: To provide a pressure-sensitive adhesive sheet that is free of swelling or deformation of a substrate due to migration of a liquid component from the pressure-sensitive adhesive layer and has acceptable processability, the pressure-sensitive adhesive sheet includes a carrier film; an elastomer film provided on one surface of the carrier film; and a pressure-sensitive adhesive layer provided on the elastomer film, in which the pressure-sensitive adhesive layer includes a composition that contains an acrylic polymer as a main component and a compatible component being compatible with the acrylic polymer and liquid or paste-like at room temperature, and in which the carrier film has a heat shrinkage of 3.0% or more and 4.5% or less in the longitudinal direction and 1.2% or more and 4.2% or less in the transverse direction.

Abstract translation: 为了提供由于液体成分从压敏粘合剂层的迁移而不会引起基体膨胀或变形的压敏粘合片，并且具有可接受的加工性，所以压敏粘合片包括载体膜; 设置在载体膜的一个表面上的弹性体膜; 以及设置在弹性体膜上的压敏粘合剂层，其中压敏粘合剂层包括含有丙烯酸类聚合物作为主要成分的组合物和与丙烯酸类聚合物相容的相容成分和液体或糊状物 室温，其中载体膜的纵向热收缩率为3.0％以上且4.5％以下，横向为1.2％以上且4.2％以下。

公开(公告)号：US06844080B2

公开(公告)日：2005-01-18

申请号：US10399229

申请日：2001-10-23

Applicant: Brendan J. Kneafsey ,  Gerry Coughlan

Inventor： Brendan J. Kneafsey ,  Gerry Coughlan

IPC: C08F4/52 ,  C08F220/18 ,  C09J4/00 ,  C09J4/02 ,  B32B27/30

CPC classification number: C08F4/52 ,  C09J4/00 ,  Y10T428/31504 ,  Y10T428/31855 ,  Y10T428/31928 ,  Y10T428/31935 ,  C08F220/18

Abstract: Metal alkyl borohydrides are used as initiators of polymerisation, particularly in adhesive compositions for bonding a wide range of substrates including low surface energy substrates such as polyolefins. As described, the metal alkyl borohydrides are of the formula I or II. wherein R1 is C1-C10 alkyl, R2 and R3, which may be the same or different, are H, D, C1-C10 alkyl or C3-C10 cycloalkyl, phenyl, or phenyl-substituted C1-C10 alkyl or C3-C10 cycloalkyl, provided that any two of R1-R3 may optionally be part of a carbocyclic ring, and M+ is a metal ion. In particular, alkali metal trialkyl borohydrides are used, the alkali metal salt being selected from: Lithium triethylborohydride, Sodium triethylborohydride, Potassium triethylborohydride, Lithium tri-sec-butylborohydride, Sodium tri-sec-butylborohydride, Potassium tri-sec-butylborohydride, and Lithium triethylborodeuteride. Other exemplified compounds which are less effective on low surface energy substrates include Lithium 9-borabicyclo [3.3.1]-nonane (9BBN) hydride, Lithium thexylborohydride, Lithium trisiamylborohydride and Potassium trisiamylborohydride.

Abstract translation: 金属烷基硼氢化物用作聚合引发剂，特别是用于粘合包括低表面能底物如聚烯烃在内的各种基材的粘合剂组合物。 如上所述，金属烷基硼氢化物具有式I或II。其中R 1为C 1 -C 10烷基，R 2和R 3可以相同或不同，为H，D，C1- C10烷基或C3-C10环烷基，苯基或苯基取代的C1-C10烷基或C3-C10环烷基，条件是R 1 -R 3中的任意两个可任选地是碳环的一部分，并且M + 特别是使用碱金属三烷基硼氢化物，碱金属盐选自：三乙基硼氢化锂，三乙基硼氢化钠，三乙基硼氢化钾，三仲丁基硼氢化锂，三仲丁基硼氢化钠，三 - 仲丁基硼氢化钠和三乙基硼化钕。 在低表面能底物上效力较低的其它示例性化合物包括9-硼双环[3.3.1] - 壬烷（9BBN）氢化锂，三异丁基硼氢化锂，三氨基硼氢化锂和三丁基硼氢化钾。

公开(公告)号：US5164444C2

公开(公告)日：2001-10-16

申请号：US56714190

申请日：1990-08-14

Applicant: AVERY DENNISON CORP

Inventor： BERNARD MARGARET M

IPC: C08F2/00 ,  C08F220/18 ,  C09J4/02 ,  C09J133/08 ,  C08F20/64 ,  C08F22/14 ,  C08F220/10

CPC classification number: C08F220/18 ,  C09J133/08 ,  C09J2201/606 ,  Y10S526/931

公开(公告)号：US6096842A

公开(公告)日：2000-08-01

申请号：US875394

申请日：1997-07-24

Applicant: Carsten Friese ,  Frank Bergmann

Inventor： Carsten Friese ,  Frank Bergmann

IPC: C09J4/00 ,  C09J4/02 ,  C09J4/06

CPC classification number: C09J4/00 ,  C09J4/06

Abstract: Aerobically hardening adhesives based on polymers of acrylates or methacrylates having a relatively high boiling point such as polyurethane (meth)acrylates are described, wherein the adhesives contain at least one initiator capable of forming free radicals, at least one accelerator, and at least one siccative. Such adhesives are largely odorless and harden completely such that the adhesive surface at the boundary with air is not tacky.

Abstract translation: PCT No.PCT / EP96 / 00199 Sec。 371日期1997年7月24日 102（e）1997年7月24日PCT PCT 1996年1月18日PCT公布。 公开号WO96 / 23036 日本1996年8月1日描述了基于具有较高沸点的丙烯酸酯或甲基丙烯酸酯如聚氨酯（甲基）丙烯酸酯的聚合物的自动硬化粘合剂，其中粘合剂含有至少一种能形成自由基的引发剂，至少一种促进剂， 和至少一个siccative。 这种粘合剂大部分无臭并且完全硬化，使得与空气边界处的粘合剂表面不发粘。

公开(公告)号：US6069214A

公开(公告)日：2000-05-30

申请号：US66966

申请日：1998-04-27

Applicant: Fred B. McCormick ,  David J. Drath ,  Ilya Gorodisher ,  Michael A. Kropp ,  Michael C. Palazzotto ,  Melville R. V. Sahyun

Inventor： Fred B. McCormick ,  David J. Drath ,  Ilya Gorodisher ,  Michael A. Kropp ,  Michael C. Palazzotto ,  Melville R. V. Sahyun

IPC: F16F15/02 ,  B32B27/00 ,  B32B27/06 ,  C08F4/42 ,  C08G73/00 ,  C08G73/06 ,  C08J5/00 ,  C08L79/04 ,  C09J4/02 ,  G03F7/027 ,  G03F7/029 ,  C08L67/07

CPC classification number: G03F7/027 ,  B32B27/06 ,  C08G73/065 ,  C08G73/0655 ,  C08G73/0661 ,  G03F7/029 ,  Y10T428/31855

Abstract: A composition of matter includes a polymerizable mixture comprising 1 to 99 weight percent of a first monomer and an initiator therefor, the first monomer being one of 1) at least one free-radically polymerizable monomer or 2) at least one cyanate ester monomer, and 99 to 1 weight percent of a second monomer and an initiator therefor, the second monomer being the member of 1) or 2) that is not selected as the first monomer, wherein the curative for the cyanate ester is a transition metal-containing organometallic compound curing agent and the curative for the free-radically polymerizable monomer is a free-radical generating curing agent or a transition metal-containing organometallic compound. The polymeric mixtures are useful, for example, in applications requiring high performance, such as high temperature performance; in composites, particularly structural composites; structural adhesives; vibration damping materials; electronic applications such as printed wiring boards, semiconductor encapsulants and electronic adhesives; photoresists; injection molding and prepregs; protective coatings; tough self-supporting films; and high performance binders. In addition, a curable composition including (1) an ethylenically unsaturated monomer or (2) an ethylenically unsaturated monomer and a cyanate ester monomer, and certain organometallic neutral compounds is useful in the graphic arts.

Abstract translation: 物质组合物包括可聚合的混合物，其包含1至99重量％的第一单体和其引发剂，第一单体是1）至少一种可自由基聚合的单体之一或2）至少一种氰酸酯单体之一，以及 99至1重量％的第二单体及其引发剂，第二单体为1）或2）未被选择为第一单体的成分，其中氰酸酯的固化剂为含过渡金属的有机金属化合物 固化剂和可自由基聚合单体的固化剂是自由基产生固化剂或含过渡金属的有机金属化合物。 聚合物混合物可用于例如需要高性能的应用，例如高温性能; 在复合材料中，特别是结构复合材料; 结构胶; 振动阻尼材料; 电子应用如印刷线路板，半导体密封剂和电子粘合剂; 光致抗蚀剂 注塑和预浸料; 保护涂层; 强硬的自我支持的电影; 和高性能粘合剂。 此外，包含（1）烯键式不饱和单体或（2）烯键式不饱和单体和氰酸酯单体以及某些有机金属中性化合物的可固化组合物在图形领域中是有用的。

公开(公告)号：US06037408A

公开(公告)日：2000-03-14

申请号：US119205

申请日：1993-09-22

Applicant: Christian Weber ,  Jurgen Grun ,  Elke Wasmer

Inventor： Christian Weber ,  Jurgen Grun ,  Elke Wasmer

IPC: C08F299/02 ,  C08F283/01 ,  C08F290/00 ,  C08F290/06 ,  C08F299/04 ,  C08L67/06 ,  C09J4/00 ,  C09J4/02 ,  C09J4/06 ,  F16B13/14 ,  C09J133/14 ,  C09J163/10 ,  C09J167/06

CPC classification number: F16B13/142 ,  C09J4/00

Abstract: The invention concerns a reagent kit designed to produce elements of synthetic resin for anchoring fixation elements in place by bonding them in multi-cavity plugs. The reagent kit comprises (a) a reagent mixture containing 2,2-bis-[4-(methacryloxyethoxy)phenyl]propane and an optionally unsaturated polyester resin, vinyl resin or acrylic resin or a mixture of these, (b) an accelerator component comprises an organic peroxide and (c) a filler component, the accelerator component (b) being kept separate from the reagent mixture (a) before use.

Abstract translation: 本发明涉及一种设计用于生产合成树脂元件的试剂盒，用于通过将固定元件粘合在多腔塞中将固定元件固定在适当位置。 试剂盒包含（a）含有2,2-双 - [4-（甲基丙烯酰氧基乙氧基）苯基]丙烷和任选不饱和聚酯树脂，乙烯基树脂或丙烯酸树脂或它们的混合物的试剂混合物，（b）促进剂组分 包括有机过氧化物和（c）填充剂组分，促进剂组分（b）在使用前与试剂混合物（a）分离。

公开(公告)号：US6017634A

公开(公告)日：2000-01-25

申请号：US012382

申请日：1998-01-23

Applicant: M. Albert Capote ,  Liqui Zhou ,  Xioqui Zhu

Inventor： M. Albert Capote ,  Liqui Zhou ,  Xioqui Zhu

IPC: B23K35/34 ,  B23K35/02 ,  B23K35/36 ,  B32B7/12 ,  C08G59/40 ,  C09D11/10 ,  C09J4/00 ,  C09J4/02 ,  H01B1/02 ,  H01B1/06 ,  H01L21/60 ,  H01L23/29 ,  H01L23/31 ,  H01L23/498 ,  H05K1/09 ,  H05K3/32 ,  B32B27/04 ,  B32B27/38 ,  C08L63/10

CPC classification number: C09J4/00 ,  B23K35/025 ,  B23K35/3613 ,  B23K35/3618 ,  B32B7/12 ,  H01L23/49883 ,  H01L24/29 ,  H01L24/32 ,  H01L24/83 ,  H01L2224/16225 ,  H01L2224/29111 ,  H01L2224/2919 ,  H01L2224/32225 ,  H01L2224/48227 ,  H01L2224/73104 ,  H01L2224/73204 ,  H01L2224/81191 ,  H01L2224/83191 ,  H01L2224/83192 ,  H01L2224/838 ,  H01L2924/01004 ,  H01L2924/01005 ,  H01L2924/01006 ,  H01L2924/01009 ,  H01L2924/01013 ,  H01L2924/01015 ,  H01L2924/01018 ,  H01L2924/0102 ,  H01L2924/01023 ,  H01L2924/01024 ,  H01L2924/01025 ,  H01L2924/01027 ,  H01L2924/01029 ,  H01L2924/0103 ,  H01L2924/01033 ,  H01L2924/01039 ,  H01L2924/01042 ,  H01L2924/01045 ,  H01L2924/01046 ,  H01L2924/01047 ,  H01L2924/0105 ,  H01L2924/01051 ,  H01L2924/01058 ,  H01L2924/01074 ,  H01L2924/01077 ,  H01L2924/01078 ,  H01L2924/01079 ,  H01L2924/01082 ,  H01L2924/0132 ,  H01L2924/0133 ,  H01L2924/014 ,  H01L2924/0665 ,  H01L2924/0781 ,  H01L2924/10253 ,  H01L2924/14 ,  H01L2924/1579 ,  H01L2924/351 ,  H05K1/095 ,  H05K3/321 ,  Y10S428/901 ,  Y10T428/31515 ,  Y10T428/31522

Abstract: A thermally curable adhesive composition that includes a fluxing agent that also acts as an adhesive is provided. The composition includes: (a) a fluxing agent represented by the formula RCOOH, wherein R comprises a moiety having two or more carbon-carbon double bonds wherein in one embodiment, at least one is within an acrylate or methacrylate group, and which may further contain at least one aromatic moiety; (b) a carboxylic acid neutralizing agent; (c) optionally, a crosslinkable diluent; (d) optionally, a source of free radical initiators; and (e) optionally, a resin. The composition can be applied directly onto the surface(s) of devices that are to be joined electrically and mechanically. These devices include, printed circuit substrates, connectors, components, cables, and other electrical devices having metallization patterns to be soldered together by means of a solder-bumped pattern on one or both surfaces. Alternatively, a solder paste, comprising solder powder mixed with the fluxing agent of the present invention can be used. During the reflow step, the fluxing agent promotes wetting of the solder to the metallization patterns and, simultaneously, the fluxing agent itself crosslinks to mechanically bond and encapsulate the surfaces and their metallizations. The compositions can also be used to formulate sinterable conductive ink.

Abstract translation: 本发明提供一种包含还可作为粘合剂使用的助熔剂的热固性粘合剂组合物。 组合物包括：（a）由式RCOOH表示的助熔剂，其中R包含具有两个或更多个碳 - 碳双键的部分，其中在一个实施方案中，至少一个在丙烯酸酯或甲基丙烯酸酯基团内，并且其还可以进一步 含有至少一个芳族部分; （b）羧酸中和剂; （c）任选地，可交联的稀释剂; （d）任选的自由基引发剂源; 和（e）任选的树脂。 组合物可以直接施加到要电连接和机械连接的装置的表面上。 这些装置包括印刷电路基板，连接器，部件，电缆以及具有通过在一个或两个表面上通过焊料凸起图案焊接在一起的金属化图案的其它电气装置。 或者，可以使用包含与本发明的助熔剂混合的焊料粉末的焊膏。 在回流步骤期间，助熔剂促进焊料对金属化图案的润湿，同时，助熔剂本身交联以机械地结合并包封表面及其金属化。 组合物也可用于配制可烧结导电油墨。

公开(公告)号：US6013722A

公开(公告)日：2000-01-11

申请号：US13741

申请日：1998-01-27

Applicant: Jie Yang ,  Ying-Yuh Lu ,  James E. Kropp

Inventor： Jie Yang ,  Ying-Yuh Lu ,  James E. Kropp

IPC: C08F265/06 ,  C08F220/18 ,  C08F220/28 ,  C09J4/00 ,  C09J4/02 ,  C09J4/06 ,  C09J133/00 ,  C09J133/14 ,  C08L31/02 ,  C08F220/26

CPC classification number: C09J4/00 ,  C09J4/06 ,  Y10S526/931

Abstract: Water resistant, low haze acrylic emulsion pressure sensitive adhesive compositions for use in decorative, light management or optical articles are disclosed. These emulsion pressure sensitive adhesives comprise (a) 50-90% by weight n-butyl acrylate, and (b) 10-50% by weight 2-hydroxy ethyl acrylate, or 2-hydroxy ethyl methacrylate, hydroxy propyl acrylate monomer, or mixtures thereof. These emulsion pressure sensitive adhesives can be used in wet lamination processes, and exhibit less than 2% increase in haze, less than 2% increase in opacity and greater than 95% transmittance after the wet lamination process.

Abstract translation: 公开了用于装饰，光管理或光学制品的防水低雾丙烯酸乳液压敏粘合剂组合物。 这些乳液压敏粘合剂包含（a）50-90重量％的丙烯酸正丁酯，和（b）10-50重量％的丙烯酸2-羟基乙酯或甲基丙烯酸2-羟基乙酯，丙烯酸羟丙酯单体或混合物 其中。 这些乳液压敏粘合剂可用于湿层压工艺，并且在湿层压工艺之后，雾度增加小于2％，不透明度增加小于2％，透光率大于95％。