摘要:
The invention relates to a catalytically active composition for the selective methanation of carbon monoxide which comprises at least one element selected from the group consisting of ruthenium, rhodium, nickel and cobalt as active component and a support material based on carbon.The invention further provides for the use of this catalytically active composition for the selective methanation of carbon monoxide and in the production of hydrogen for fuel cell applications.
摘要:
A robust, high-temperature catalyst comprising a catalytic component supported on a porous ceramic carrier is provided for propellant decomposition. The catalyst comprises a porous, high-surface-area ceramic carrier material and up to 40% of metal and/or metal oxide, based upon the total weight of the catalyst. The supported species include metals and/or oxides of transition and lanthanide metals that possess high activity for the decomposition of liquid propellants. The carrier can be produced via a wet chemical process and then impregnated with salt solutions containing desired active-phase precursors. The catalyst can cause a liquid propellant to react upon contact with the catalyst and to produce hot gases that can be used to provide thrust, drive turbines, inflate devices, etc.
摘要:
A device for additive-free, catalytically induced oxidation of solid carbon particles and decomposition of chemical compounds, comprising a converter chamber with compartments, in which porous structure catalyst carrier matrix profiles are mounted, so that a space between the internal diameter of catalyst profiles is connected to an inlet connection of the converter chamber, and a space around the external diameter of the catalyst profiles is connected to an outlet connection into the catalyst chamber. The profiles are mounted so that gas particles reach outlets only by passing through porous profiles. Advantageously, a third opening through which liquid, gaseous media, e.g., NO2, O3 or H2O or auxiliary means maybe in front of the porous structures. The porous structures are made of catalytically active material with catalytic action at temperatures below 400° C., preferably below 350° C. and especially below 300° C. The low-temperature below 250° C. by H2O is preferred.
摘要:
In one embodiment, a method of treating a gas stream comprises: controlling an amount of the NH3 entering a catalytic unit and converting NO2 and the NH3 to N2 in the catalytic unit, wherein greater than or equal to about 60 wt % of NOx initially in the gas stream is converted to N2. In one embodiment, a gas treatment system comprises: a plasma reactor disposed downstream of an engine; a cracking catalyst disposed downstream of the engine; and a catalytic unit capable of converting NO and HC to NH3, and capable of converting NH3 and NO2 to N2.
摘要:
The invention pertains to a layered ammonia oxidation catalyst. The layered catalyst causes ammonia to be selectively oxidized in the presence of an oxidant such as air, while minimizing the formation of nitrogen oxides (NOx). The layered catalyst comprises a refractory oxide support such as gamma alumina upon which a platinum component is deposited and a vanadia component is deposited on the platinum. The catalyst is preferably disposed on a substrate such as a metal foil whose surface contains a “herringbone” pattern.
摘要:
In one embodiment, a method of treating a gas stream comprises: controlling an amount of the NH3 entering a catalytic unit and converting NO2 and the NH3 to N2 in the catalytic unit, wherein greater than or equal to about 60 wt % of NOx initially in the gas stream is converted to N2. In one embodiment, a gas treatment system comprises: a plasma reactor disposed downstream of an engine; a cracking catalyst disposed downstream of the engine; and a catalytic unit capable of converting NO and HC to NH3, and capable of converting NH3 and NO2 to N2.
摘要:
A gas treatment device, comprises a substrate disposed within a shell. The substrate comprises a catalyst composition comprising a support, a catalyst, and a sufficient amount of SMSI material such that, upon exposure to a gas stream (at a gas treatment device operating temperature), less than or equal to about 35 wt % of hydrocarbons in the gas stream are burned. A method for forming a gas treatment device, comprises applying a slurry to a substrate, wherein the slurry comprises a support and a sufficient amount of SMSI material such that, upon exposure to a gas stream at a gas treatment device operating temperature, greater than or equal to about 50 wt % of hydrocarbons in the gas stream are cracked to a light fraction; applying a catalyst to the substrate; calcining the catalyst; and disposing the calcined substrate into a shell, with a retention material disposed between the shell and the calcined substrate.
摘要:
A gas treatment device, comprises a substrate disposed within a shell. The substrate comprises a catalyst composition comprising a support, a catalyst, and a sufficient amount of SMSI material such that, upon exposure to a gas stream (at a gas treatment device operating temperature), less than or equal to about 35 wt % of hydrocarbons in the gas stream are burned. A method for forming a gas treatment device, comprises applying a slurry to a substrate, wherein the slurry comprises a support and a sufficient amount of SMSI material such that, upon exposure to a gas stream at a gas treatment device operating temperature, greater than or equal to about 50 wt % of hydrocarbons in the gas stream are cracked to a light fraction; applying a catalyst to the substrate; calcining the catalyst; and disposing the calcined substrate into a shell, with a retention material disposed between the shell and the calcined substrate.
摘要:
The invention concerns a catalyst for hydrorefining and hydroconverting hydrocarbon feeds, comprising a mixed sulphide comprising at least two elements selected from elements with an atomic number selected from the group formed by the following numbers: 3, 11, 12, 19 to 33, 37, to 51, 55 to 83, 87 to 103, characterized in that the mixed sulphide results from a combination of at least one element the sulphide of which has a bond energy between the metal and sulphur of less than 50.+-.3 kcal/mol (209.+-.12 kJ/mol) and at least one element the sulphide of which has a bond energy between the metal and sulphur of more than 50.+-.3 kcal/mol (209.+-.12 kJ/mol), the mixed sulphide thus having a mean bond energy between the metal and sulphur which is in the range 30 to 70 kcal/mol (125 to 293 kJ/mol).
摘要:
A catalyst of the present invention is adapted for purifying fumigation exhaust gases, and comprises, as a catalyst component A, a metal oxide containing at least one, or a composite oxide containing two or more metals selected from the group consisting of Ti, Si and Zr; and, as a catalyst component B, an oxide containing at least one selected from the group consisting of V, Cu, W and Cr; and has an average micropore diameter in the range of 0.010 to 0.070 .mu.m, a total micropore volume in the range of 0.30 to 0.60 ml/g, and a specific surface area in the range of 50 to 200 m.sup.2 /g. The use of this catalyst makes it possible to economically and efficiently purify fumigation exhaust gas.